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Lithium-Metal Free Sulfur Battery Based on Waste Biomass Anode and Nano-Sized Li_(2)S Cathode

Energy & Environmental Materials 2024年第2期7卷 39-47页

作者： Pejman Salimi Eleonora Venezia somayeh taghavi Sebastiano Tieuli Lorenzo Carbone Mirko Prato Michela Signoretto Jianfeng Qiu Remo Proietti Zaccaria Istituto Italiano di Tecnologia via Morego 30Genoa 16163Italy Department of Chemistry and Industrial Chemistry University of Genovavia Dodecaneso 311-16146Genoa Italy CATMAT Lab Department of Molecular Sciences and NanosystemsCa'Foscari University Venice and INSTM ConsortiumRU of VeniceVia Torino 15530172Venezia Mestre Italy Department of Physics Shaoxing UniversityShaoxing 312000China

The realization of a stable lithium-metal free(LiMF)sulfur battery based on amorphous carbon anode and lithium sulfide(Li_(2)S)cathode is here *** particular,a biomass waste originating full-cell combining a carbonized brewer's spent grain(CBSG)biochar anode with a Li_(2)S-graphene composite cathode(Li_(2)S70Gr30)is *** design is particularly attractive for applying a cost-effective,high performance,environment friendly,and safe anode material,as an alternative to standard graphite and metallic lithium in emerging battery *** anodic and cathodic materials are characterized in terms of structure,morphology and composition through X-ray diffraction,scanning and transmission electron microscopy,X-ray photoelectron and Raman ***,an electrochemical characterization comprising galvanostatic cycling,rate capability and cyclic voltammetry tests were carried out both in half-cell and full-cell *** systematic investigation reveals that unlike graphite,the biochar electrode displays good compatibility with the electrolyte typically employed in sulfur *** CBSG/Li_(2)S70Gr30 full-cell demonstrates an initial charge and discharge capacities of 726 and 537 mAh g^(-1),respectively,at 0.05C with a coulombic efficiency of 74%.Moreover,it discloses a reversible capacity of 330 mAh g^(-1)(0.1 C)after over 300 *** on these achievements,the CBSG/Li_(2)S70Gr30 battery system can be considered as a promising energy storage solution for electric vehicles(EVs),especially when taking into account its easy scalability to an industrial level.

关键词： biochars ether-based electrolytes lithium sulfide lithium-metal free batteries superior cycling stability

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Comparing the deactivation behaviour of Co/CNT and Co/γ-Al_2O_3 nano catalysts in Fischer-Tropsch synthesis

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Journal of Natural Gas Chemistry 2012年第5期21卷 605-613页

作者： Ahmad Tavasoli Saba Karimi somayeh taghavi Zahra Zolfaghari Hamideh Amirfirouzkouhi School of Chemistry College of ScienceUniversity of TehranTehranIran

An extensive study of Fischer-Tropsch （FT） synthesis on cobalt nano particles supported on γ-alumina and carbon nanotubes （CNTs） catalysts is reported.20 wt% of cobalt is loaded on the supports by impregnation *** deactivation of the two catalysts was studied at 220 C,2 MPa and 2.7 L/h feed flow rate using a fixed bed *** calcined fresh and used catalysts were characterized extensively and different sources of catalyst deactivation were *** of cobalt-support mixed oxides in the form of xCoO yAl2O3 and cobalt aluminates formation were the main sources of the Co/γ-Al2O3 catalyst *** sintering and cluster growth of cobalt nano particles are the main sources of the Co/CNTs catalyst *** the case of the Co/γ-Al2O3 catalyst,after 720 h on stream of continuous FT synthesis the average cobalt nano particles diameter increased from 15.9 to 18.4 nm,whereas,under the same reaction conditions the average cobalt nano particles diameter of the Co/CNTs increased from 11.2 to 17.8 ***,the initial FT activity of the Co/CNTs was 26% higher than that of the Co/γ-Al2O3,the FT activity over the Co/CNTs after 720 h on stream decreased by 49% and that over the Co/γ-Al2O3 by 32%.For the Co/γ-Al2O3 catalyst 6.7% of total activity loss and for the Co/CNTs catalyst 11.6% of total activity loss cannot be recovered after regeneration of the catalyst at the same conditions of the first regeneration *** is concluded that using CNTs as cobalt catalyst support is beneficial in carbon utilization as compared to γ-Al2O3 support,but the Co/CNTs catalyst is more susceptible for deactivation.

关键词： Fischer-Tropsch synthesis cobalt carbon nanotube γ-alumina deactivation

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Performance enhancement of bimetallic Co-Ru/CNTs nano catalysts using microemulsion technique

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Journal of Energy Chemistry 2013年第5期22卷 747-754页

作者： Ahmad Tavasoli somayeh taghavi School of Chemistry College of Science University of Tehran

Bimetallic cobalt-ruthenium nano catalysts supported on carbon nanotubes(CNTs)are prepared using microemultion technique with water-to-surfactant ratios of 0.5—*** nano catalysts were extensively characterized by different methods and their activity and selectivity in Fischer-Tropsch synthesis(FTS)have been assessed in a fixed-bed *** physicochemical properties and performance of the nanocatalysts were compared with the catalyst prepared by impregnation *** narrow particle size distribution has been produced by the microemulsion technique at relatively high loadings of active metals(15 wt%Co and 1 wt%Ru).According to TEM images,small Co particles(2—7 nm)were mostly confined inside the *** with the catalyst prepared by impregnation,the use of microemulsion technique with water to surfactant ratio of 0.5 decreased the average cobalt oxide particle size to 4.8 nm,the dispersion was almost doubled and the reduction increased by 28%.Activity and selectivity were found to be dependent on the catalyst preparation method and water-to-surfactant ratio(as well as cobalt particle sizes).CO conversion increased from 59.1%to 75.1%and the FTS rate increased from 0.291 to0.372 gHC/(gcath).C5+liquid hydrocarbons selectivity decreased from 92.4%to 87.6%.

关键词： Fischer-Tropsch synthesis cobalt ruthenium microemulsion particle size

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