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Enhancing micro-scale SiOx anode durability:Electro-mechanical strengthening of binder networks via anchoring carbon nanotubes with carboxymethyl cellulose

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Journal of Energy Chemistry 2025年第2期101卷 23-33页

作者： Chaeyeon ha Jin Kyo Koo Jun Myoung Sheem Young-Jun Kim SKKU Advanced Institute of Nano Technology (SAINT) Sungkyunkwan University Department of Nano Science and Technology Sungkyunkwan University Advanced Center for Convergence Energy Storage System Sungkyunkwan University SKKU Institute of Energy Science and Technology (SIEST) Sungkyunkwan University

With the increasing prevalence of lithium-ion batteries（LIBs） applications,the demand for high-capacity next-generation materials has also *** currently considered a promising anode material due to its exceptionally high capacity for ***,the significant volumetric changes of SiOxduring cycling and its initial Coulombic efficiency（ICE） complicate its use,whether alone or in combination with graphite *** this study,a three-dimensional conductive binder network with high electronic conductivity and robust elasticity for graphite/SiOxblended anodes was proposed by chemically anchoring carbon nanotubes and carboxymethyl cellulose binders using tannic acid as a chemical *** addition,a dehydrogenation-based prelithiation strategy employing lithium hydride was utilized to enhance the ICE of *** combination of these two strategies increased the CE of SiOxfrom 74% to87% and effectively mitigated its volume expansion in the graphite/SiOxblended electrode,resulting in an efficient electron-conductive binder *** led to a remarkable capacity retention of 94% after30 cycles,even under challenging conditions,with a high capacity of 550 mA h g-1and a current density of 4 mA ***,to validate the feasibility of utilizing prelithiated SiOxanode materials and the conductive binder network in LIBs,a full cell incorporating these materials and a single-crystalline Ni-rich cathode was *** cell demonstrated a～27.3% increase in discharge capacity of the first cycle(～185.7 mA h g-1) and exhibited a cycling stability of 300 ***,this study reports a simple,feasible,and insightful method for designing high-performance LIB electrodes.

关键词： Lithium-ion batteries SiO x anode Blended anode Carbon nanotubes Carboxymethyl cellulose Conductive binder network

Effect of Parameter Variation in the BMJ Scheme on the Simulation of MJO Propagation and Structure

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Advances in Atmospheric Sciences 2025年第2期42卷 397-409页

作者： Xiaoyu ZHU Zhong ZHONG Yimin ZHU Yunying LI Yijia HU Yao ha College of Meteorology and Oceanography National University of Defense TechnologyChangsha 410073China Key Laboratory for Virtual Geographic Environment School of Geography ScienceNanjing Normal UniversityNanjing 210023China Jiangsu Collaborative Innovation Center for Climate Change School of Atmospheric SciencesNanjing UniversityNanjing 210023China

In this study,the Betts-Miller-Janjic(BMJ)convective adjustment scheme in the Weather Research and Forecasting(WRF)model version 4.0 was used to investigate the effect of itsα-parameter,which influences the first-guess potential temperature reference profile on the Madden-Julian oscillation(MJO)propagation and *** study diagnosed the MJO active phase composites of the MJO-filtered outgoing longwave radiation(OLR)during the December-to-February(DJF)period of 2006-2016 over the Indian Ocean(IO),Maritime Continent(MC),and western Pacific(WP).The results show that the MJO-filtered OLR intensity,propagation pattern,and MJO classification(standing,jumping,and propagating clusters)are sensitive to theα-value,but the phase speeds of propagating MJOs are ***,with an increasingα-value,the simulated MJO-filtered OLR intensity increases,and the simulated propagation pattern is *** also show that the intensity and propagation pattern of an eastward-propagating MJO are associated with MJO circulation structures and thermodynamic ***αincreases,the front Walker cell and the low-level easterly anomaly are enhanced,which premoistens the lower troposphere and triggers more active shallow and congestus *** enhanced shallow and congestus convection preconditions the lower to middle troposphere,accelerating the transition from congestus to deep convection,thereby facilitating eastward propagation of the ***,the simulated MJO tends to transfer from standing to eastward propagating asα*** summary,increasing theα-value is a possible way to improve the simulation of the structure and propagation of the MJO.

关键词： MJO WRF model BMJ scheme low-level easterly anomaly

Cardiovascular involvement in multisystem inflammatory syndrome in children and midterm follow-up from a pediatric tertiary center in India

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World Journal of Clinical Pediatrics 2025年第1期14卷 127-138页

作者： Poovazhagi Varadarajan Ritchie Sharon solomon Seenivasan Subramani Ramesh Subramanian Gomathy Srividya Elilarasi Raghunathan Department of Pediatric Intensive Care Institute of Child Health and Hospital for ChildrenMadras Medical CollegeChennai 600003Tamil NāduIndia Department of Pediatric Cardiology Institute of Child Health and Hospital for ChildrenMadras Medical CollegeChennai 600003Tamil NāduIndia Department of Pediatrics Institute of Child Health and Hospital for ChildrenMadras Medical CollegeChennai 600003Tamil NāduIndia

BACKGROUND In multisystem inflammatory syndrome in children(MIS-C)with coronavirus disease 2019,there was paucity of data from low-income and middle-income countries on cardiovascular involvement and its longitudinal *** planned to estimate the pattern of cardiovascular involvement among children with MIS-C and its mid-term *** To determine association between cardiovascular abnormalities and clinical and laboratory *** study the time-line for resolution of various *** In this prospective study done in a tertiary care hospital,270 were recruited from June 2020 to January *** demographic data and clinical presentation were *** parameters and echocardiography were done at ***-up was done at 2 weeks,3 months,6 months and 1 year after *** statistics were used for parametric and non-parametric *** factors were identified by multivariate regression *** The 211(78.2%)had cardiac involvement and 102 needed intensive care unit(ICU)*** abnormalities observed were shock 123(45.6%),coronary dilatation 28(10.4%),coronary aneurysm 77(28.5%),left ventricular(LV)dysfunction 78(29.3%),mitral regurgitation(MR)77(28.5%)and pericardial effusion 98(36.3%).Coronary artery aneurysm/dilatation during follow-up at 2 weeks and 1 year were 25.7%and 0.9%*** regression analysis revealed breathlessness[odds ratio(OR)=3.91,95%CI:1.25-12.21,P=0.019]and hi-flow nasal cannula(HFNC)support(OR=8.5,95%CI:1.06-68.38,P=0.044)as predictors of cardiovascular *** mean age(OR=1.16,95%CI:1.02-1.32,P=0.026),breathlessness(OR=4.99,95%CI:2.05-12.20,P<0.001),gallop(OR=4.45,95%CI:0.41-2.52,P=0.016),MR(OR=3.61,95%CI:1.53-8.53,P=0.004)and invasive ventilation(OR=4.01,95%CI:1.28-12.58,P=0.017)were predictive of LV *** sensorium(OR=4.96,95%CI:2.23-11.02,P<0.001),headache(OR=6.61,95%CI:1.46-29.92,P=0.014),HFNC(OR=7.03,95%CI:2.0

关键词： Multisystem inflammatory syndrome in children Cardiovascular Midterm follow-up Coronary artery aneurysm Shock Left ventricular dysfunction

Issyk-Ata fault and its two strong Holocene paleoearthquakes records near densely populated Chui basin:focus on Dzhal area of Kyrgyz Range,Tien Shan

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Journal of Mountain Science 2025年第2期22卷 404-421页

作者： CHOLPONBEK Ormukov ha Sangmin SEONG Yeong Bae SULTAN Baikulov ERKIN Rakhmedinov MIRLAN Dyldaev SANZhaR Samibekov Department of Applied Geology American University of Central AsiaBishkek 720060Kyrgyz Republic Department of Geography Education Korea UniversitySeoul 02841Korea Republic Institute of Seismology National Academy of ScienceBishkek 720060Kyrgyz Republic Department of Geography Ecology and TourismKyrgyz National University named after Zhusup BalasagynBishkek 720033Kyrgyz Republic

Geodetic observations over the past several decades identify the Tien Shan as a prominent and active intracontinental mountain belt,characterized by a meridional shortening rate of up to 20 mm/*** region has experienced significant seismic events,particularly along its northern boundary,highlighting the recurrent seismic activity in the Kyrgyz *** Issyk-Ata fault,stretching 120 km from west to east in the northern Tien Shan,bounds from the north a young,growing anticline demarcating the foothills of the Kyrgyz Range and the Chui *** region is susceptible to strong earthquakes,posing a significant threat to the Chui region and Bishkek,the capital city with over a million *** youngest fault in the area is the Issyk-Ata fault,traversing the southern part of Bishkek,where modern construction has obscured its *** study integrates remote sensing,detailed fieldwork,and paleoseismological investigations to map and analyze surface ruptures,quantify vertical displacements,and assess seismic hazards along the Issyk-Ata *** optically stimulated luminescence and radiocarbon dating,we determined ages for documented paleoseismic events,placing two ancient earthquakes in the *** estimates suggest seismic events with magnitudes ranging from 6.6 to *** the Dzhal area,geological and geomorphological analysis yielded a longterm fault-slip rate of 1.15 mm/*** Issyk-Ata fault shows variable rupture behavior,with distinct segments demonstrating different seismic characteristics and histories of *** variability necessitates comprehensive seismic hazard modeling to better understand and mitigate potential risks in the region.

关键词： Issyk-Ata fault Tien Shan Kyrgyz Range Tectonic scarps Paleo earthquake

Unlocking Novel Functionality:Pseudocapacitive Sensing in MXene-Based Flexible Supercapacitors

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Nano-Micro Letters 2025年第4期17卷 212-229页

作者： Eunji Kim Seongbeen Kim Hyeong Min Jin Gyungtae Kim Hwi-Heon ha Yunhui Choi Kyoungha Min Su-Ho Cho Hee han Chi Won Ahn Jaewoo Roh Il-Kwon Oh Jinwoo Lee Yonghee Lee Department of Chemical and Biomolecular Engineering Korea Advanced Institute of Science and Technology(KAIST)291 Daehak-RoYuseong-GuDaejeon 34141Republic of Korea National Nano Fab Center(NNFC) 291 Daehak-RoYuseong-GuDaejeon 34141Republic of Korea Department of Organic Materials Engineering Chungnam National University99 Daehak-RoYuseong-GuDaejeon 34134Republic of Korea Department of Materials Science and Engineering Chungnam National University99 Daehak-RoYuseong-GuDaejeon 34134Republic of Korea Department of Nano&Advanced Materials Science and Engineering Kyungpook National University2559Gyeongsang-DaeroSangju-SiGyeongsangbuk-Do 37224Republic of Korea Department of Mechanical Engineering Korea Advanced Institute of Science and Technology(KAIST)291 Daehak-RoYuseong-GuDaejeon 34141Republic of Korea

Extensively explored for their distinctive pseudocapacitance characteristics,MXenes,a distinguished group of 2D materials,have led to remarkable achievements,particularly in the realm of energy storage *** work presents an innovative Pseudocapacitive *** key lies in switching the energy storage kinetics from pseudocapacitor to electrical double layer capacitor by employing the change of local pH(-log[H^(+)])in MXene-based flexible supercapacitors during *** sensing is observed in acidic electrolyte but absent in neutral *** shearing during bending causes liquid-crystalline MXene sheets to increase in their degree of anisotropic *** blocking of H+mobility due to the higher diffusion barrier,local pH *** electrochemical energy storage kinetics transits from Faradaic chemical protonation(intercalation)to non-Faradaic physical *** utilize the phenomenon of capacitance change due to shifting energy storage kinetics for strain sensing *** developed highly sensitive Pseudocapacitive Sensors feature a remarkable gauge factor(GF)of approximately 1200,far surpassing conventional strain sensors(GF:~1 for dielectric-cap sensor).The introduction of the Pseudocapacitive Sensor represents a paradigm shift,expanding the application of pseudocapacitance from being solely confined to energy devices to the realm of multifunctional *** technological leap enriches our understanding of the pseudocapacitance mechanism of MXenes,and will drive innovation in cutting-edge technology areas,including advanced robotics,implantable biomedical devices,and health monitoring systems.

关键词： MXenes Supercapacitors Pseudocapacitive sensing Local pH Operando measurements

Therapeutic actions of terpenes in neurodegenerative disorders and their correlations with the regulation and remodeling of the extracellular matrix

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BIOCELL 2025年第1期49卷 109-125页

作者： RENATA DA SILVA CARNEIRO MATEUS HENRIQUE DE ALMEIDA DA COSTA JOSÉZILTON LIMA VERDE SANTOS VALDILÉia TEIXEIRA UCHÔA LUCiaNO DA SILVA LOPES ANDERSON NOGUEIRA MENDES Laboratory of Science in Innovation and Technology-LACITEC Department of Biophysics and PhysiologyFederal University of PiauíTeresina64049Brazil Laboratory of Natural Products and Bioprospecting Natural Sciences CenterState University of PiauíTeresina64018Brazil Laboratory of Experimental Neurochemistry Research-LAPNEX Department of Biophysics and PhysiologyFederal University of PiauíTeresina64049Brazil

Neurodegenerative diseases are a major public health challenge,mainly affecting the elderly population and compromising their cognitive,sensory,and motor ***,available therapies focus on alleviating symptoms and slowing the progression of these conditions,but they do not yet offer a definitive *** this scenario,terpenes emerge as promising natural alternatives due to their neuroprotective *** compounds can reduce the formation of protein aggregates,neutralize free radicals,and inhibit pro-inflammatory enzymes,which are crucial factors in the development of neurodegenerative *** addition,terpenes also play an important role in the regulation and remodeling of the extracellular matrix,a key target for improving neuronal *** such as linalool,pinene,and eugenol,among others,have potential therapeutic effects by modulating inflammatory and oxidative stress processes,the main factors that contribute to the progression of these *** suggest that these compounds act on signaling pathways that regulate the extracellular matrix,improving neuronal integrity and,consequently,cognitive and motor *** work aims to review the potential of terpenes in the treatment of neurodegenerative disorders,with emphasis on their ability to regulate oxidative stress and inflammation,as well as to remodel the extracellular *** interaction between these mechanisms points to the promising use of terpenes as an innovative and natural therapeutic approach to combat these diseases.

关键词： Terpenes Neurodegenerative Disorders Extracellular matrix

Occasional Tillage in a Field Established under Conservation Agriculture for Tomato Cropping

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Agricultural Sciences 2025年第1期16卷 31-47页

作者： Roberto Botelho Ferraz Branco Bruno Cesar Ananias Andréia Cristina Silva Hirata Humberto Sampaio de Araújo Jane Maria de Carvalho Silveira Agronomic Institute So Paulo Agency of Agribusiness Technology (IAC/APTA) Centre of Horticulture Ribeiro Preto Brazil Syngenta Crop Protection So Paulo Brazil So Paulo Agency of Agribusiness Technology (APTA) Presidente Prudente Brazil So Paulo Agency of Agribusiness Technology (APTA) Andradina Brazil Agronomic Institute So Paulo Agency of Agribusiness Technology (IAC/APTA) Centre of Agricultural Biosystems and Post Harvest Campinas Brazil

The Conservation Agriculture (CA) is a current concept drives to save natural resources for agricultural production based on the minimum soil disturbance or no-tillage, crop rotation and permanent maintenance of straw on soil surface. The increasing in soil density is a problem to achieve great copping yield under CA, so occasional one-time tillage is considered as an alternative to continuous no-tillage. In this way, this experiment was carried out to compare occasional tillage and no-tillage interacting with cover crops in a field established under conservation agriculture. Thus, the experimental treatments were set up by two tillage methods, conventional tillage and no-tillage and two cover crops, white lupin and millet setting in a randomized blocks with split plot design with four replications. The traits evaluated in the research were soil fertility, soil resistance to penetration, soil moisture and tomato agronomic performance. No-tillage was more efficient to preserve soil moisture;however soil fertility, soil resistance to penetration and tomato yield were favored by conventional tillage. Regarding to cover crops white lupin increased the soil K concentration and enhanced the tomato growth. Although occasional tillage had better performance to the soil fertility and tomato yield, we highlighted that CA is the better way to increase soil health and soil and water conservation along the time leading to so desired regenerative agriculture.

关键词： No Tillage Crop Rotation Cover Crops Solanum lycopersicum L.

Ghost species form an important component of the epiphytic lichens in temperate forests

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Forest Ecosystems 2025年第01期 20-28页

作者： Jan Vondrák Ji?í Ko?nar Stanislav Svoboda Zdeněk Palice Jaroslav ?oun Ji?í Kubásek Pavel Ríha Ji?í Malí?ek Jan Rydlo Jeňyk Hofmeister Institute of Botany of the Czech Academy of Sciences Department of Botany Faculty of ScienceUniversity of South Bohemia Museum of Dr.Bohuslav Horák in Rokycany Branch of Museum of West Bohemia Department of Experimental Plant Biology Faculty of ScienceUniversity of South Bohemia ReDpeupbalritcment of Forest Ecology Faculty of Forestry and Wood SciencesCzech University of Life Sciences in Prague Global Change Research Institute of the Czech Academy of Sciences

Sequencing of environmental samples has great potential for biodiversity research, but its application is limited by the lack of reliable DNA barcode databases for species identifications. Such a database has been created for epiphytic lichens of Europe, allowing us to compare the results of environmental sequencing with standard taxonomic surveys. The species undetected by taxonomic surveys(what we term the ghost component) amount to about half of the species actually present in hectare plots of Central European forests. Some of these, which currently occur only as diaspores or weakly developed thalli, are likely to be favoured in the course of global change. The ghost component usually represents a larger fraction in managed forests than in old-growth unmanaged forests. The total species composition of different plots is much more similar than suggested by taxonomic surveys alone. On a regional scale, this supports the well-known statement that“everything is everywhere,but, the environment selects”.

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市场型环境规制对碳排放强度的影响效应和机制研究——基于碳交易试点政策的经验证据

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生态经济 2025年第2期41卷 38-44页

作者：哈梅芳黄奕晗宁夏大学经济管理学院宁夏银川750021

作为市场型环境规制手段的碳排放权交易是助力实现“双碳”目标的重要政策。基于2009—2019年中国省级面板数据,运用双重差分法,探究碳交易试点政策的实施对碳强度的影响效应和影响机制。研究发现:碳交易试点政策有效降低了试点地区的... 详细信息

作为市场型环境规制手段的碳排放权交易是助力实现“双碳”目标的重要政策。基于2009—2019年中国省级面板数据,运用双重差分法,探究碳交易试点政策的实施对碳强度的影响效应和影响机制。研究发现:碳交易试点政策有效降低了试点地区的碳排放强度,发挥了市场型环境规制的积极作用,而且碳交易机制通过影响能源消费量这一渠道遏制了碳排放强度的增长。通过调节效应模型发现,地区产业结构负向调节碳交易试点政策的降碳效应,而政府规模则正向调节碳交易试点政策的降碳效应。以上结论为进一步推动全国性碳交易市场稳健发展、发挥市场型环境规制的积极作用以及推进“双碳”目标实现提供了重要的经验证据。

关键词：市场型环境规制碳交易试点政策碳排放强度双重差分法机制