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Polymer engineering for electrodes of aqueous zinc ion batteries

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Journal of Energy Chemistry 2024年第4期91卷 345-369页

作者： Zhi peng Zemin Feng Xuelian Zhou siwen Li Xuejing Yin Zekun Zhang Ningning Zhao Zhangxing He Lei Dai Ling Wang Chao Lu School of Chemical Engineering North China University of Science and TechnologyTangshan 063210HebeiChina State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical TechnologyBeijing 100029China

With the increasing demand for scalable and cost-effective electrochemical energy storage,aqueous zinc ion batteries(AZIBs)have a broad application prospect as an inexpensive,efficient,and naturally secure energy storage ***,the limitations suffered by AZIBs,including volume expansion and active materials dissolution of the cathode,electrochemical corrosion,irreversible side reactions,zinc dendrites of the anode,have seriously decelerated the civilianization process of ***,polymers have tremendous superiority for application in AZIBs attributed to their exceptional chemical stability,tunable structure,high energy density and outstanding mechanical *** the expanding applications of AZIBs and the superiority of polymers,this comprehensive paper meticulously reviews the benefits of utilizing polymeric applied to cathodes and anodes,*** begin with,with adjustable structure as an entry point,the correlation between polymer structure and the function of energy storage as well as optimization is deeply investigated in respect to the ***,depending on the diversity of properties and structures,the development of polymers in AZIBs is summarized,including conductive polymers,redox polymers as well as carbon composite polymers for cathode and polyvinylidene fluoride-,carbonyl-,amino-,nitrile-based polymers for anode,and a comprehensive evaluation of the shortcomings of these strategies is ***,an outlook highlights some of the challenges posed by the application of polymers and offers insights into the potential future direction of polymers in *** is designed to provide a thorough reference for researchers and developers working on polymer for AZIBs.

关键词： Aqueous zinc ion batteries Polymer Multi-function Anode protection Energy storage

Quantitative Determination of Sphingolipids by HPLC-ESI/MSn

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Agricultural Biotechnology 2022年第5期11卷 134-135,139页

作者： Jin XIE Rong SONG Li ZHOU siwen peng Yanning HUANG Xiaoqi ZHU Institute of Agricultural and Biological Resources Utilization Hunan Academy of Agricultural SciencesChangsha 430100China

The most predominant sphingoilipids bases are phytosphingosine(phyto-sph) and phytosphingosine-1-phosphate(phyto-S1 P), followed by dihydrosphingosine(dh-sph) and dihydroshingosine-1-phosphate(dh-S1 P). In this study, a fast, sensitive and selective method for determining those four of sphingolipids by high performance liquid chromatography coupled to electrospray ionization ion trap mass spectrometry was introduced. Comparing two methods, method B’s recovery was better than method A. And the limit of detection(LOD) was between 0.003 to 0.013 μM for 20 μl injection.

关键词： Sphingoilipids Liquid chromatography Mass spectrometry

Time-Periodic Solutions to Quasilinear Hyperbolic Systems on General Networks

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Chinese Annals of Mathematics,Series B 2024年第1期45卷 41-72页

作者： peng QU School of Mathematical Sciences Fudan UniversityShanghai 200433China

For quasilinear hyperbolic systems on general networks with time-periodic boundary-interface conditions with a dissipative structure,the existence and stability of the time-periodic classical solutions are discussed.

关键词： Time-periodic solution Quasilinear hyperbolic system General net-work Classical solution Asymptotic stability

Thermal and mechanical behavior of casting copper alloy wheel during wheel and belt continuous casting process

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China Foundry 2024年第1期21卷 82-90页

作者： Kun Gao Yan peng School of Mechanical Engineering Yanshan UniversityQinhuangdao 066004HebeiChina

To investigate the thermal and mechanical behavior of casting wheel,a two-dimensional thermoelastic-plastic finite element model was used to predict the temperature,stress and distortion distribution of the casting wheel during the wheel and belt continuous casting *** effects of grinding thickness and casting speed on the thermal and mechanical behaviors of the center of the hot face of the casting wheel were discussed in *** each rotation,the casting wheel passes through four different spray *** results show that the temperature distribution of the casting wheel in different spray zones is similar,the temperature of the hot face is the highest and the temperature reaches the peak in the spray zoneⅢ.The stress and distortion depend on the temperature distribution,and the maximum stress and distortion of the hot face are 358.2 MPa and 1.82 mm,*** temperature at the center of the hot face decreases with increasing grinding thickness and increases with increasing casting speed.

关键词： casting wheel finite element model grinding thickness casting speed hot face spray zones

Electronic origin of structural degradation in Li-rich transition metal oxides:The case of Li_(2)MnO_(3)and Li_(2)RuO_(3)

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Journal of Semiconductors 2024年第4期45卷 82-86页

作者： peng Zhang Key Laboratory of Optoelectronic Devices and Systems of Ministry of Education and Guangdong Province College of Physics andOp toelec-tronic EngineeringShenzhen UniversityShenzhen 518060China

Li_(2)MnO_(3)and Li_(2)RuO_(3)represent two prototype Li-rich transition metal(TM)oxides as high-capacity cathodes for Li-ion batteries,which have similar crystal structures but show quite different cycling ***,based on the first-princi-ples calculations,we systematically studied the electronic structures and defect properties of these two Li-rich cathodes,in order to get more understanding on the structural degradation mechanism in Li-rich TM *** calculations indicated that the structural and cycling stability of Li_(2)MnO_(3)and Li_(2)RuO_(3)depend closely on their electronic structures,especially the energy of their highest occupied electronic states(HOS),as it largely determines the defect properties of these *** Li_(2)MnO_(3)with low-energy HOS,we found that,due to the defect charge transfer mechanism,various defects can form spontaneously in its host structure as Li ions are extracted upon delithiation,which seriously deteriorates its structural and cycling *** for Li_(2)RuO_(3),on the other hand,we identified that the high-energy HOS prevents it from the defect formation upon delithi-ation and thus preserve its cycling *** studies thus illustrated an electronic origin of the structural degradation in Li-rich TM oxides and implied that it is possible to improve their cycling performances by carefully adjusting their TM compo-nents.

关键词： defects Li-ion batteries first-principles calculations

Fourth-order phase-field modeling for brittle fracture in piezoelectric materials

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Applied Mathematics and Mechanics(English Edition) 2024年第5期45卷 837-856页

作者： Yu TAN Fan peng Chang LIU Daiming peng Xiangyu LI State Key Laboratory of Geohazard Prevention and Geoenvironment Protection Chengdu University of TechnologyChengdu 610059China College of Science Chang'an UniversityXi'an 710064China Applied Mechanics and Structure Safety Key Laboratory of Sichuan Province School of Mechanics and Aerospace EngineeringSouthwest Jiaotong UniversityChengdu 610031China

Failure analyses of piezoelectric structures and devices are of engineering and scientific *** this paper,a fourth-order phase-field fracture model for piezoelectric solids is developed based on the Hamilton *** typical electric boundary conditions are involved in the present model to characterize the fracture behaviors in various physical situations.A staggered algorithm is used to simulate the crack *** polynomial splines over hierarchical T-meshes(PHT-splines)are adopted as the basis function,which owns the *** numerical simulations are performed to study the influence of the electric boundary conditions and the applied electric field on the fracture behaviors of piezoelectric *** electric boundary conditions may influence crack paths and fracture loads *** present research may be helpful for the reliability evaluation of the piezoelectric structure in the future applications.

关键词： isogeometric analysis(IGA) brittle fracture fourth-order phase-field model piezoelectric solid

A Weighted Flow related to a Trudinger–Moser Functional on Closed Riemann Surface

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Acta Mathematica Sinica,English Series 2024年第9期40卷 2244-2262页

作者： peng Xiu YU School of Mathematics Renmin University of ChinaBeijing 100872P.R.China

In this paper,with(Σ,g)being a closed Riemann surface,we analyze the possible concentration behavior of a heat flow related to the Trudinger–Moser *** obtain a long time existence for the *** along some sequence of times t_(k)→+∞,we can deduce the convergence of the flow in H2(Σ).Furthermore,the limit function is a critical point of the Trudinger–Moser functional under certain constraint.

关键词： Trudinger-Moser inequality global convergence heat flow

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杜鹃兰人工种子技术研究

中国中药杂志 2009年第15期34卷 1894-1897页

作者：张明生彭斯文杨小蕊徐利贵州大学生命科学学院贵州贵阳550025 贵州大学生命科学实验教学中心贵州贵阳550025

目的:建立杜鹃兰人工种子制作方法。方法:以杜鹃兰为实验材料,通过液体悬浮培养建立原球茎悬浮系,并以原球茎为人工种子的繁殖体,研究了人工种皮基质、人工胚乳组分、贮藏条件、萌发基质等对人工种子萌发率和成苗率的影响。结果:以4%海... 详细信息

目的:建立杜鹃兰人工种子制作方法。方法:以杜鹃兰为实验材料,通过液体悬浮培养建立原球茎悬浮系,并以原球茎为人工种子的繁殖体,研究了人工种皮基质、人工胚乳组分、贮藏条件、萌发基质等对人工种子萌发率和成苗率的影响。结果:以4%海藻酸钠+2%CaCl2+2%壳聚糖为人工种皮基质,1/2MS液体培养基+0.2mg.L-1NAA+0.1mg.L-1GA3+0.5mg.L-1BA+0.4mg.L-1青霉素+10.0mg.L-1内生真菌提取物+0.3%多菌灵粉剂+0.2%苯甲酸钠+1.0%蔗糖作为人工胚乳成分制作的人工种子,其萌发率和成苗率最高。这样的人工种子在4℃条件下贮藏20d后的萌发率及成苗率分别为68%,65%左右,随着贮藏温度的升高和贮藏时间的延长,人工种子的萌发率和成苗率均大幅度下降。结论:通过研究确立了杜鹃兰人工种子制作基本技术。

关键词：杜鹃兰人工种子原球茎萌发率成苗率

CFD-DEM study on the synergistic effect of coke consumption and particle dynamics in the blast furnace raceway

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Particuology 2024年第6期89卷 270-278页

作者： peng Xu peng Han Zhijun He Xizhong An Kang Sun Lihua Gao Key Laboratory of Green Low-Carbon and Intelligent Metallurgy School of Materials and MetallurgyUniversity of Science and Technology LiaoningAnshan 114000China Key Laboratory for Ecological Metallurgy of Multimetallic Mineral of Ministry of Education School of MetallurgyNortheastern UniversityShenyang110819China

In this study,the gas-solid flow process in the blast furnace raceway is numerically simulated using coupled computational fluid dynamics and the discrete element method(CFD-DEM).The coke reaction kinetics data are imported into the DEM model to reproduce the consumption process of each coke *** effects of inlet gas velocity and angle on the morphology of the raceway,coke consumption rate,coke bed temperature,and particle size distribution in the blast process are systematically investigated and *** results show that the consumption of coke particles promotes the formation of raceways during the blast *** the same time,a coke mixture layer is produced at the edge of the *** higher the inlet gas velocity,the thicker the coke mixture layer in the middle and upper parts of the raceway region,and the larger the proportion of small particles in the coke mixture *** effect of the inlet gas angle on the raceway region is less than the inlet gas ***,with the increase in the inlet gas angle,the high-temperature region of the coke bed extends downward gradually,which is conducive to activating the hearth.

关键词： Blast furnace Raceway Multiphase flow CFD-DEM Modeling