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Optimized synthesis and photovoltaic performance of TiO_2 nanoparticles for dye-sensitized solar cell

Particuology 2013年第6期11卷 753-759页

作者： siti Nur Fadhilah Zainudin Masturah Markom Huda Abdullah Renata Adami siti masrinda tasirin Department of Chemical Engineering and Process Faculty of Engineering and Built EnvironmentUniversiti Kebangsaan Malaysia Department of Electrical Electronic and System EngineeringFaculty of Engineering and Built EnvironmentUniversiti Kebangsaan Malaysia Department of Chemical and Food Engineering University of Salerno

This paper presents response surface methodology （RSM） as an efficient approach for modeling and optimizing TiO2 nanoparticles preparation via co-precipitation for dye-sensitized solar cell （DSSC） perfor- mance. Titanium （IV） bis-（acetylacetonate） di-isopropoxide （DIPBAT）, isopropanol and water were used as precursor, solvent and co-solvent, respectively. Molar ratio of water, aging temperature and calcina- tion temperature as preparation factors with main and interaction effects on particle characteristics and performances were investigated, Particle characteristics in terms of primary and secondary sizes, crys- tal orientation and morphology were determined by X-ray diffractometry （XRD） and scanning electron microscopy （SEM）. Band gap energy and power conversion efficiency of DSSCs were used for perfor- mance studies. According to analysis of variance （ANOVA） in response surface methodology （RSM）, all three independent parameters were statistically significant and the final model was accurate. The model predicted maximum power conversion efficiency （0.14%） under the optimal condition of molar ratio of DIPBAT-to-isopropanol-to-water of 1 ： 10：500, aging temperature of 36 C and calcination temperature of 400 ℃. A second set of data was adopted to validate the model at optimal conditions and was found to be 0.14 ± 0.015%, which was very close to the predicted value. This study proves the reliability of the model in identi（ving the optimal condition for maximum performance.

关键词： Titanium dioxide Hydrolysis precipitation Dye-sensitized solar cell Optimization Response surface methodology

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Amorphous particle deposition and product quality under different conditions in a spray dryer

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Particuology 2008年第4期6卷 265-270页

作者： Meng Wai Woo Wan Ramli Wan Daud siti masrinda tasirin Meor Zainal Meor Talib Department of Chemical & Processing Engineering Universiti Kebangsaan Malaysia

Deposition of amorphous particles, as a prevalent problem particularly in the spray drying of fruit and vegetable juices, is due to low-molecular-weight sugars and is strongly dependent on the condition of the particles upon collision with the dryer wall. This paper investigates the condition of the amorphous particles impacting the wall at different drying conditions with the aim of elucidating the deposition mechanism and physical phenomena in the drying chamber. A model sucrose-maltodextrin solution was used to represent the low-molecular-weight sugar. Particle deposits were collected on sampling plates placed inside the dryer for analyses of moisture content, particle rigidity (using SEM) and size distribution. Moisture content was adopted as a general indicator of stickiness. Product particles collected at the bottom of the experimental dryer were found to have higher moisture than particle deposits on samplers inside the dryer. Moisture content profile in the dryer shows that apart from the atomizer region, where particles are relatively wet, particle deposits at other regions exhibit similar lower moisture content. At the highest temperature adopted in the experiments, particles became rubbery suggesting liquid-bridge formation as the dominant deposition mechanism. Further analysis on particles size distribution reveals a particle segregation mechanism whereby smaller particles follow preferentially to the central air stream while larger particles tend to re-circulate in the chamber, as predicted in past CFD simulation. The findings from this work will form the basis and provide validating data for further modeling of wall deposition of amorphous particles in spray drying using CFD.

关键词： Powder handling Amorphous particles Deposition Particle condition Spray drying

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