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Coherent control of fragmentation of methyl iodide by shaped femtosecond pulse train

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Chinese Physics B 2019年第9期28卷 157-163页

作者： Qiu-Nan Tong De-Hou Fei Zhen-Zhong Lian Hong-Xia Qi Sheng-Peng Zhou si-zuo luo Zhou Chen Zhan Hu Institute of Atomic and Molecular Physics Jilin UniversityChangchun 130012China Advanced Light Field and Modern Medical Treatment Science and Technology Innovation Center of Jilin Province Jilin UniversityChangchun 130012China

Coherent control of fragmentation of CH_3I using shaped femtosecond pulse train is *** dissociation processes can be modulated by changing the separation of the shaped pulse train, and the yield of I^+under the irradiation of the optimal pulse is significantly increased compared with that using the transform-limited *** discuss the control mechanism of dissociation processes with coherent interference in time domain.A three-pulse control model is proposed to explain the counterintuitive experimental results.

关键词： coherent control fragmentation shaped pulse

Increasing operational stability of journal bearing in hydraulic suspension micro-pump by herringbone grooved structure

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Science China(Technological Sciences) 2024年第3期67卷 853-862页

作者： HONG Tao XING GuanYing zuo HuaiYu XUE Song luo XiaoBing State Key Laboratory of Coal Combustion School of Energy and Power EngineeringHuazhong University of Science and TechnologyWuhan 430074China

The operational stability of radial journal bearings is the bottleneck that limits the reliability of hydraulic suspension micropump. Due to self-excited vibrations, the whirl amplitude of the plain journal bearing(PJB) is large at high rotational speeds,which will accelerate wear failure. It has been proven that employing herringbone grooved journal bearing(HGJB) is an effective method to reduce the whirl amplitude and improve operational stability. However, enhancing the stability of journal bearings in micro-pumps by herringbone grooved structures has rarely been studied, and its effect needs to be verified. We validated the mechanism of the stability improvement with the CFD method and compared the dynamic characteristics of HGJB and PJB by rotor dynamics evaluation and experiment. The experimental results show that under the same conditions the whirl amplitude of the HGJB decreases by 29.61% in the x direction and by 24.09% in the y direction compared with that of the PJB. This study reveals the effect of the herringbone grooved structure on the operational stability of bearings and may provide guidance for the reliability improvement of hydraulic suspension micro-pump.

关键词： journal bearing herringbone groove hydrodynamic effect micro-pump

Hydrophobic tag tethering degrader as a promising paradigm of protein degradation:Past,present and future perspectives

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Chinese Chemical Letters 2024年第8期35卷 187-200页

作者： si Ha Jiacheng Zhu Hua Xiang Guoshun luo State Key Laboratory of Natural Medicines and Department of Medicinal Chemistry China Pharmaceutical UniversityNanjing 211198China

Small molecule inhibitors have dominated the pharmaceutical landscape for a long time as the primary therapeutic paradigm targeting pathogenic ***,their efficacy heavily relies on the amino acid composition and spatial constitution of proteins,rendering them susceptible to drug resistance and failing to target undruggable *** recent years,the advent of targeted protein degradation(TPD)technology has captured substantial attention from both industry and *** an event-driven mode,TPD offers a novel approach to eliminate pathogenic proteins by promoting their degrada-tion,thus circumventing the limitations associated with traditional small molecule ***-bic tag tethering degrader(HyTTD)technology represents one such TPD approach that is currently in the burgeoning *** employ endogenous protein degradation systems to induce the degrada-tion of target proteins through the proteasome pathway,which displays significant potential for medical *** this review,we provide a comprehensive overview of the development history and the reported mechanism of action of ***,we delve into the physiological roles,structure-activity re-lationships,and medical implications of HyTTDs targeting various disease-associated ***,we propose insights into the challenges that necessitate resolution for the successful development of HyTTDs,with the ultimate goal of initiating a new age of clinical treatment leveraging the immense po-tential of HyTTDs.

关键词： Targeted protein degradation(TPD) Hydrophobic tag Degrader Hydrophobic tag tethering degrader(HyTTD) Targeted therapy

Photoelectron imaging on vibrational excitation and Rydberg intermediate states in multi-photon ionization process of NH3 molecule

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Chinese Physics B 2020年第9期29卷 274-280页

作者： Ya-Nan Sun Yan-Hui Wang Le-Le Song Hai-Bin Du Xiao-Chun Wang Lan-Lai He si-zuo luo Qin Yang Jing Leng Fu-Chun Liu Institute of Atomic and Molecular Physics Jilin UniversityChangchun 130012China College of Electronic Science and Engineering State Key Laboratory on Integrated OptoelectronicsJilin UniversityChangchun 130012China Jilin Institute of Chemical Technology Jilin 132022China Jilin Provincial Key Laboratory of Applied Atomic and Molecular Spectroscopy Jilin UniversityChangchun 130012China Department of Comprehensive Harbin City Vocational CollegeHaerbin 150000China

The ionization processes of NH3 molecule are studied by photoelectron velocity map imaging technique in a linearly polarized 400-nm femtosecond laser field. The two-dimensional photoelectron images from ammonia molecules under different laser intensities are obtained. In the slow electron region, the values of kinetic energy of photoelectrons corresponding to peaks 1, 2, 3, and 4 are 0.27, 0.86, 1.16, and 1.6 eV, respectively. With both the kinetic energy and angular distribution of photoelectrons from NH3 molecules, we can confirm that the two-photon excited intermediate Rydberg state is A^1 A2" (v2'=3) state for photoelectron peaks 2, 3, 4, and the three peaks are marked as 1223 (2 + 2), 1123 (2 + 2), and 1023 (2 + 2) multi-photon processes, respectively. Then, peak 1 is found by adding a hexapole between the source chamber and the detection chamber to realize the rotational state selection and beam focusing. Peak 1 is labeled as the 1323 (3 + 1) multi-photon process through the intermediate Rydberg state E^1A1'. The phenomena of channel switching are found in the slow electron kinetic energy distributions. Our calculations and experimental results indicate that the stretching vibrational mode of ammonia molecules varies with channels, while the umbrella vibration does not. In addition, we consider and discuss the ac-Stark effect in a strong laser field. Peaks 5 and 6 are marked as (2 + 2 + 1) and (2 + 2 + 2) above threshold ionization processes in the fast electron region.

关键词： photoelectron velocity map imaging photelectron angular distributions Rydberg state hexapole

Facile synthesis of W-Mo bimetallic oxides with high adsorption properties from secondary resources

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Tungsten 2024年第4期6卷 806-820页

作者： Jia-Li Cheng Yang-si Liu Xiao-Li Xi zuo-Ren Nie Collaborative Innovation Center of Capital Resource-Recycling Material Technology College of Materials Science and Engineering Beijing University of Technology National Engineering Laboratory for Industrial Big-Data Application Technology Beijing University of Technology Key Laboratory of Advanced Functional Materials Ministry of Education Beijing University of Technology

A simple solvothermal method was used to obtain W-Mo bimetallic oxides from W-Mo alloy scrap,and pure metal powders were also used as the raw materials to simulate *** products had a sea urchin-like structure with abundant oxygen vacancies and the products prepared at low temperatures forms a sosoloid resembling orthorhombic *** WMo bimetallic oxide prepared at the reaction temperature of 120 ℃ exhibited excellent selective adsorption performance for methylene blue（MB）,which the adsorption rate of MB reached 99% in 12 min and the adsorption rate reached 90% after6 adsorption *** the W-Mo molar ratio is 1:3,the maximum adsorption capacity of sample for MB can reach1148 mg·*** adsorption process followed the Langmuir and pseudo-second-order models,which is surface-controlled monolayer *** experimental results show the feasibility of preparing W-Mo bimetal oxide products from pure materials and *** process is simple and effective,which offered a potential approach for secondary resource recycling and reusing.

关键词： Oxygen vacancy Selective adsorption Solvothermal W–Mo alloy scrap W–Mo bimetallic oxide

Channel-Resolved Ultrafast Dissociation Dynamics of NO2 Molecules Studied via Femtosecond Time-Resolved Ion Imaging

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Chinese Journal of Chemical Physics 2019年第3期32卷 292-298,I0001页

作者： Qin-xin Wang Dan-dan Shi Jun-feng Zhang Xue Wang Yu si Chun-bin Gao Jian Fang si-zuo luo College of Electrical Engineering Jilin Engineering Normal UniversityChangchun 130012China Institute of Atomic and Molecular Physics and Jilin Provincial Key Laboratory of Applied Atomic and Molecular Spectroscopy Jilin UniversityChangchun 130012China

The ultrafast dissociation dynamics of NO2 molecules was investigated by femtosecond laser pump-probe mass spectra and ion *** results show that the kinetic energy release of NO+ions has two components,0.05 eV and 0.25 eV,and the possible dissociation channels have been *** channel resolved transient measurement of NO^+provides a method to disentangle the contribution of ultrafast dissociation pathways,and the transient curves of NO^+ions at different kinetic energy release are fitted by a biexponential *** fast component with a decay time of 0.25 ps is generated from the evolution of Rydberg *** slow component is generated from two competitive channels,one of the channel is absorbing one 400nm photon to the excited state A^2B2,which has a decay time of 30.0ps,and the other slow channel is absorbing three 400nm photons to valence type Rydberg states which have a decay time less than *** channel and time resolved experiment present the potential of sorting out the complex ultrafast dissociation dynamics of molecules.

关键词： Ultrafast dynamics Strong field ionization Photodissociation dynamic Velocity map imaging

Photoelectron imaging of resonance-enhanced multiphoton ionization and above-threshold ionization of ammonia molecules in a strong 800-nm laser pulse

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Chinese Physics B 2019年第6期28卷 140-145页

作者： Le-Le Song Ya-Nan Sun Yan-Hui Wang Xiao-Chun Wang Lan-Hai He si-zuo luo Wen-Hui Hu Qiu-Nan Tong Da-Jun Ding Fu-Chun Liu Institute of Atomic and Molecular Physics Jilin UniversityChangchun 130012China Jilin Institute of Chemical Technology Changchun 132022China Jilin Provincial Key Laboratory of Applied Atomic and Molecular Spectroscopy Jilin UniversityChangchun 130012China College of Electronic Science and Engineering State Key Laboratory on Integrated OptoelectronicsJilin UniversityChangchun 130012China

In this work, we mainly investigate the NH3 molecular multiphoton ionization process by using the photoelectron velocity map imaging technique. Under the condition of femtosecond laser(wavelength at 800 nm), the photoelectron images are detected. The channel switching and above-threshold ionization(ATI) effect are also confirmed. The kinetic energy spectrum(KES) and the photoelectron angular distributions(PADs) are obtained through the anti-Abel transformation from the original images, and then three ionization channels are confirmed successfully according to the Freeman resonance effect in a relatively low laser intensity region. In the excitation process, the intermediate resonance Rydberg states are C^1 A 1(6 + 2 photons process), B^1 E(6 + 2 photons process) and C^1 A 1(7 + 2 photons process), respectively. At the same time, we also find that the photoelectron angular distributions are independent of laser intensity. In addition, the electrons produced by different processes interfere with each other and they can produce a spider-like structure. We also find ac-Stark movement according to the Stark-shift-induced resonance effect when the laser intensity is relatively high.

关键词： photoelectron imaging Rydberg state resonance-enhanced multiphoton ionization photoelectron angular distribution

Glucose-sensitive Membrane with PBA-based Contraction-type Linear Polymer as Chemical Valves Prepared by Surface Grafting

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Chinese Journal of Polymer Science 2024年第8期42卷 1067-1076页

作者： Chun-Peng Zhang si-Jia Gao Ying luo Lei Zou Yong-Jun Zhang State Key Laboratory of Separation Membranes and Membrane Processes School of Material Science and EngineeringTiangong UniversityTianjin 300387China State Key Laboratory of Separation Membranes and Membrane Processes School of Pharmaceutical SciencesTiangong UniversityTianjin 300387China Tianjin Key Laboratory of Extracorporeal Life Support for Critical Diseases Institute of Hepatobiliary DiseaseNankai University Affiliated Third Center HospitalTianjin 300170China Cangzhou Institute of Tiangong University Cangzhou 061000China

Glucose-sensitive membrane has potential application in self-regulating insulin *** acid(PBA)is a well-known glucose ***,most PBA-based glucose-sensitive materials are expansion-type,which are not suitable as chemical valves in membrane pores for self-regulating insulin *** to a new glucose-sensitive mechanism,we synthesized PBA-based contraction-type glucose-sensitive liner polymer and ***,a glucose-sensitive membrane was prepared by grafting PBA-based contraction-type glucose-sensitive linear polymer on the membrane *** adjusting the chain length and chain density,the glucose-sensitivity of the membrane was *** membrane can reversibly regulate insulin release at physiologically relevant glucose concentrations in simulates body fluids and fetal bovine *** membrane also has good stability,anti-fouling and biocom *** has potential application in selfregulating insulin release.

关键词： Phenylboronic acid Glucose-sensitive Membrane Surface grafting Insulin

Imaging alignment of rotational state-selected CH_3I molecule

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Chinese Physics B 2019年第2期28卷 167-172页

作者： Le-Le Song Yan-Hui Wang Xiao-Chun Wang Hong-Tao Sun Lan-Hai He si-zuo luo Wen-Hui Hu Dong-Xu Li Wen-Hui Zhu Ya-Nan Sun Da-Jun Ding Fu-Chun Liu Institute of Atomic and Molecular Physics Jilin University Jilin Institute of Chemical Technology Jilin Provincial Key Laboratory of Applied Atomic and Molecular Spectroscopy Jilin University College of Electronic Science and Engineering State Key Laboratory on Integrated OptoelectronicsJilin University General Hospital of FAW

We experimentally and numerically investigate CH_3I molecular alignment by using a femtosecond laser and a hexapole. The hexapole provides the single |111〉rotational state condition at 4.5-kV hexapole rod voltage. Based on this single rotational state, an enhanced alignment degree of 0.73 is achieved. Our experimental results are in agreement with the simulation results. We experimentally obtain the ion velocity map images and show the influence of the initial rotational-state population. With the I+ion images and angular distributions at different pump-probe delay time, the alignment and anti-alignment phenomena are further demonstrated. The molecules will be under field-free conditions when the laser effect disappears completely at the full revival time. Our work shows that the quantum control and spatial control on CH_3I molecules can be realized and molecular coordinate frame can be obtained for further molecular experiment.

关键词： hexapole state selection velocity map imaging alignment