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In-plane isotropic separator-induced highly efficient sodium plating for unlocking the fast-charging capability of anode-free sodium battery at practical conditions

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Journal of Materiomics 2024年第3期10卷 643-651页

作者： Haocheng Yuan Kaihua Wen shundong guan Ying Liang Yu-Hsien Wu Sijie Liu Dengfeng Yu Liangliang Li Ce-Wen Nan State Key Laboratory of New Ceramics and Fine Processing School of Materials Science and EngineeringTsinghua UniversityBeijing100084China

Ether-based electrolytes with excellent reductive stability are compatible with sodium(Na)metal an-odes,which enables stable cycling for Na metal batteries even in an anode-free ***,the practical applications of anode-free sodium batteries(AFSBs)with a high theoretical energy density are restricted by the low-rate capability and limited cycle *** we demonstrate that the mechanical properties of the separators,which have been overlooked in previous studies,can significantly affect the cycling stability of AFSBs due to the intrinsic softness of Na and the large volume variation of AFSBs during Na plating/*** using various separators including polypropylene(PP),polyethylene(PE),PP/PE/PP tri-layer,and aluminum oxide-coated separators,we find that the balanced elastic moduli of the separator along the machine direction and transverse direction are crucial for enabling highly effi-cient Na plating and unlocking the 4 C fast-charging capability of the AFSBs at practical conditions including a high cathode active mass loading(13.5 mg/cm^(2)),lean electrolyte addition(8.8 mL/cm^(2)),and no pre-sodiation *** study provides an important separator design principle for the develop-ment of high-rate and long-cycle-life AFSBs.

关键词： Sodium metal Elastic modulus Ether electrolyte Sodium battery Short circuit

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Modification of solid electrolyte interface layer between PVDF-based electrolyte and lithium anode

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Journal of Materiomics 2024年第4期10卷 880-888页

作者： Ying Liang Jie Zhang shundong guan Kaihua Wen Chuangjie Guo Yu-Hsien Wu Haocheng Yuan Sijie Liu Ying Qi Wenbin Mo Xue Zhang Ce-Wen Nan State Key Laboratory of New Ceramics and Fine Processing School of Materials Science and EngineeringTsinghua UniversityBeijing100084China Qingtao Institute of New Energy Materials Qingtao(Kunshan)Energy Development Co.LtdKunshanJiangsu215300China

Poly(vinylidene fluoride)(PVDF)-based polymer electrolytes(PEs)with good electrochemical performance and processability as well as low-cost advantage,have great potential applications in solid-state lithium(Li)metal batteries(SSLMBs).PVDF-based PEs are generally produced by employing a solution-casting approach with N,N-dimethylformamide(DMF)as the solvent,accompanied by the formation of[DMF-Li^(+)]complex,which facilitates the Li-ion ***,the residual DMF can react continuously with lithium(Li)metal,thereby deteriorating the interface layer in the middle of the PVDF-based PEs and Li ***,we introduce propylene carbonate(PC)into the PVDF-based PEs to regulate the solvation structure and stabilize the interface layer between the PEs and Li *** accelerates the dissociation of lithium oxalyldifluoroborate(LiODFB).Consequently,“lithium propylene dicarbonate(LPDC)‒B-O”oligomer forms as the interfacial layer with high tenacity,homogeneity,and densification,which improves the interfacial contact and suppresses the continuous reaction between the residual DMF and Li *** further demonstrate that the PVDF-based PE prepared with DMF-PC mix-solvents shows improved room-temperature ionic conductivity(1.18×10^(-3) S/cm),enhanced stability against electrodes,and superior cycling performance in LiCoO_(2)-based SSLMBs(maintaining 84% of the initial discharge capacity after 300 cycles).

关键词： Solid-state battery Lithium metal Poly(vinylidene fluoride)electrolyte Propylene carbonate SEI layer

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A molecular sieve-containing protective separator to suppress the shuttle effect of redox mediators in lithium-oxygen batteries

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Nano Research 2023年第7期16卷 9453-9460页

作者： Xinbin Wu Huiping Wu shundong guan Ying Liang Kaihua Wen Huanchun Wang Xuanjun Wang Ce-Wen Nan Liangliang Li State Key Laboratory of New Ceramics and Fine Processing School of Materials Science and EngineeringTsinghua UniversityBeijing 100084China High-Tech Institute of Xi’an Xi’an 710025China

Lithium-oxygen(Li-O_(2))batteries have a great potential in energy storage and conversion due to their ultra-high theoretical specific energy,but their applications are hindered by sluggish redox reaction kinetics in the charge/discharge *** mediators(RMs),as soluble catalysts,are widely used to facilitate the electrochemical processes in the Li-O_(2)batteries.A drawback of RMs is the shuttle effect due to their solubility and mobility,which leads to the corrosion of a Li metal anode and the degradation of the electrochemical performance of the ***,we synthesize a polymer-based composite protective separator containing molecular *** nanopores with a diameter of 4Åin the zeolite powder(4A zeolite)are able to physically block the migration of 2,2,6,6-tetramethylpiperidinyloxy(TEMPO)molecules with a larger size;therefore,the shuttle effect of TEMPO is *** the assistance of the zeolite molecular sieves,the cycle life of the Li-O_(2)batteries is significantly extended from~20 to 170 cycles at a current density of 250 mA·g^(-1)and a limited capacity of 500 mAh·g^(-1).Our work provides a highly effective approach to suppress the shuttle effects of RMs and boost the electrochemical performance of Li-O_(2)batteries.

关键词： lithium-oxygen batteries redox mediators shuttle effects protective separators zeolite molecular sieves

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一例白鲸应激反应综合症的病例报道

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野生动物 2007年第4期28卷 31-32页

作者：李宁杨耀辉乔木关明玉李勋生何顺东沈阳市动物园沈阳110015 沈阳市东陵区动物疫病预防控制中心沈阳110015 沈阳市东陵区动物防疫监督所沈阳110015 沈阳市东陵区东陵街道兽医站沈阳110161

本文就一例幼年雌性白鲸在运输后发生的应激反应综合症进行了诊断、治疗。临床表现为精神不振、拒食、体重下降、体色暗淡、巩膜及结膜充血、皮肤瘙痒;血液学检查表明轻度贫血和脱水、肌肉炎症及胃炎。后进行综合措施调整后,4d后恢复采... 详细信息

本文就一例幼年雌性白鲸在运输后发生的应激反应综合症进行了诊断、治疗。临床表现为精神不振、拒食、体重下降、体色暗淡、巩膜及结膜充血、皮肤瘙痒;血液学检查表明轻度贫血和脱水、肌肉炎症及胃炎。后进行综合措施调整后,4d后恢复采食,2周后康复。同类鲸的疾病研究国内文献未见报道。

关键词：白鲸应激反应病例血液学

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