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Synergistic effect of bonding heterogeneity and phonon localization in introducing excellent thermoelectric properties in layered heteroanionic NdZnSbO material

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Journal of Energy Chemistry 2025年第1期100卷 259-272页

作者： Da Wan Shuwei Tang shulin Bai Xiaodong Li Peng Ai Wanrong Guo Tuo Zheng College of Materials Science and Engineering Liaoning Technical UniversityFuxin 123000LiaoningChina Faculty of Chemistry Northeast Normal UniversityChangchun 130024JilinChina

Layered rare-earth metal oxides,harnessing the dual properties of oxides and two-dimensional layered materials,exhibit remarkable thermal stability and quantum confinement ***,this work adopts the first-principles calculation combined with the Boltzmann transport theory to predict the thermoelectric properties of NdZnSbO *** coexistence of weak interlayer van der Waals interactions,robust intralayer ionic bonding,and partial covalent bonding leads to remarkable bonding heterogeneity,which engenders pronounced phonon scattering and imposes constraints on thermal transport along the out-of-plane *** weakened chemical bonds induced by the antibonding states,together with the rattling-like behavior of the Zn atom,culminate in the profound anharmonicity in the layered NdZnSbO *** weakening bond and heavy element contribute to the softness of phonon modes,which significantly diminishes the phonon group *** redistribution-dominated four-phonon scattering process spans a large optical gap,which effectively reduces the lattice thermal *** NdZnSbO compound exhibits direct semiconductor characteristic with a bandgap of 0.73 e V by adopting the Heyd-Scuseria-Ernzerhof(HSE06)functional in combination with spin–orbit coupling(SOC)*** multi-valley feature of NdZnSbO compound augur favorably for band degeneracy,thus amplifying the power ***,an optimal figure-of-merit(ZT)of 3.40 at 900 K is achieved for the n-type NdZnSbO *** present study delves deeply insights into the origins for the low thermal conductivity of NdZnSbO compound and proposes an optimization scheme to enhance overall thermoelectric performance.

关键词： Heteroanionic materials Multi-valley characteristics Four-phonon scattering Bonding heterogeneity Rattling-like behavior

Recent advances in bio-integrated electrochemical sensors for neuroengineering

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FUNDAMENTAL RESEARCH 2025年第1期5卷 29-47页

作者： Chen, shulin Liu, Tzu-Li Jia, Yizhen Li, Jinghua Ohio State Univ Dept Mat Sci & Engn Columbus OH 43210 USA Ohio State Univ Chron Brain Injury Program Columbus OH 43210 USA

Detecting and diagnosing neurological diseases in modern healthcare presents substantial challenges that directly impact patient outcomes. The complex nature of these conditions demands precise and quantitative monitoring of disease-associated biomarkers in a continuous, real-time manner. Current chemical sensing strategies exhibit restricted clinical effectiveness due to labor-intensive laboratory analysis prerequisites, dependence on clinician expertise, and prolonged and recurrent interventions. Bio-integrated electronics for chemical sensing is an emerging, multidisciplinary field enabled by rapid advances in electrical engineering, biosensing, materials science, analytical chemistry, and biomedical engineering. This review presents an overview of recent progress in bio-integrated electrochemical sensors, with an emphasis on their relevance to neuroengineering and neuromodulation. It traverses vital neurological biomarkers and explores bio-recognition elements, sensing strategies, transducer designs, and wireless signal transmission methods. The integration of in vivo biochemical sensors is showcased through applications. The review concludes by outlining future trends and advancements in in vivo electrochemical sensing, and highlighting ongoing research and technological innovation, which aims to provide inspiring and practical instructions for future research.

关键词： Biochemical sensing Neuroengineering Bioimplants Analytical chemistry Bio-integrated electronics

Status and prospects for symmetric organic redox flow batteries

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Journal of Energy Chemistry 2025年第1期100卷 125-143页

作者： md Al Raihan C.Adam Dyker Department of Chemistry University of New BrunswickFrederictonNB E3B 5A3Canada

As environmental concerns from fossil fuel consumption intensify,large-scale energy storage becomes imperative for the integration of renewable sources like wind,hydro,and solar with the electrical *** flow batteries,particularly those employing organic molecules,are positioned as a key technology for this *** review explores the growing field of symmetric organic redox flow batteries(ORFBs)within this *** traditional asymmetric designs based on unique active materials for each electrode,symmetric ORFBs involve a single bipolar species for both *** review highlights the benefits of a symmetric design,and categorizes five distinct classes of organic bipolar molecules used in both aqueous and non-aqueous *** providing a comprehensive overview of their cell cycling and performance characteristics,the strengths and weaknesses of the diverse categories of bipolar molecules are highlighted for both solvent systems,as are opportunities for future *** should guide new research directions and advance the development of practical symmetric ORFBs.

关键词： Redox flow battery Symmetric battery Organic battery Aqueous electrolyte Non-aqueousel ectrolyte

Al-F co-doping towards enhanced electrolyte-electrodes interface properties for halide and sulfide solid electrolytes

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Chinese Chemical Letters 2025年第1期36卷 610-617页

作者： Han Yan Jingming Yao Zhangran Ye Qiaoquan Lin Ziqi Zhang shulin Li Dawei Song Zhenyu Wang Chuang Yu Long Zhang College of Physics and Energy Fujian Normal UniversityFuzhou 350117China Clean Nano Energy Center State Key Laboratory of Metastable Materials Science and TechnologyYanshan UniversityQinhuangdao 066004China Tianjin Key Laboratory for Photoelectric Materials and Devices School of Materials Science and EngineeringTianjin University of TechnologyTianjin 300384China Guilin Electrical Equipment Scientific Research Institute Co. Ltd.Guilin 541004China State Key Laboratory of Advanced Electromagnetic Engineering and Technology School of Electrical and Electronic EngineeringHuazhong University of Science and TechnologyWuhan 430000China

All-solid-state Li batteries(ASSLBs)using solid electrolytes(SEs)have gained significant attention in recent years considering the safety issue and their high energy *** these advantages,the commercialization of ASSLBs still faces challenges regarding the electrolyte/electrodes interfaces and growth of Li *** doping is an effective and direct method to enhance the performance of ***,we report an Al-F co-doping strategy to improve the overall properties including ion conductivity,high voltage stability,and cathode and anode ***,the Al-F co-doping enables the formation of a thin Li-Al alloy layer and fluoride interphases,thereby constructing a relatively stable interface and promoting uniform Li *** similar merits of Al-F co-doping are also revealed in the Li-argyrodite *** assembled with these optimized electrolytes gain good electrochemical performance,demonstrating the universality of Al-F co-doping towards advanced SEs.

关键词： Solid electrolytes Li halides Li_(2)ZrCl_(6) Li argyrodites Fluorine doping

Quantitative impacts of meteorology and emissions on the long-term trend of O3 in the Yangtze River Delta(YRD),China from 2015 to 2022

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Journal of Environmental Sciences 2025年第3期149卷 314-329页

作者： Lingxia wu Junlin An Key Laboratory for Aerosol-Cloud-Precipitation of China Meteorological Administration Nanjing University of Information Science and TechnologyNanjing 210044China

Extensive spatiotemporal analyses of long-trend surface ozone in the Yangtze River Delta(YRD)region and itsmeteorology-related and emission-related have not been systematically *** this study,by using 8-year-long(2015–2022)surface ozone observation data,we attempted to reveal the variation ofmultiple timescale components using the Kolmogorov–Zurbenko filter,and the effects of meteorology and emissions were quantitatively isolated using multiple linear regression with meteorological *** results showed that the short-term,seasonal,and long-term components accounted for daily maximum 8-hr average O_(3)(O_(3–8)hr)concentration,46.4%,45.9%,and 1.0%,*** meteorological impacts account for an average of 71.8%of O_(3–8)hr,and the YRD’s eastern and northern sections aremeteorology-sensitive *** on statistical analysis technology with empirical orthogonal function,the contribution of meteorology,local emission,and transport in the long-term component of O_(3–8)hr were 0.21%,0.12%,and 0.6%,*** spatiotemporal analysis indicated that a distinct decreasing spatial pattern could be observed from coastal cities towards the northwest,influenced by the monsoon and synoptic *** central urban agglomeration north and south of the YRD was particularly susceptible to local *** the cities studied,Shanghai,Anqing,and Xuancheng,located at similar latitudes,were significantly impacted by atmospheric transmission—the contribution of Shanghai,the maximum accounting for 3.6%.

关键词： O_(3)Yangtze River Delta(YRD)Kolmogorov-Zurbenko filter Empirical orthogonal function Long-term trend

Effect of chlorination and ultraviolet on the adsorption of pefloxacin on polystyrene and polyvinyl chloride

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Journal of Environmental Sciences 2025年第3期149卷 21-34页

作者： Yanan Li Yaning wu Kai Guo Weiqin wu Meijing Yao School of Environmental Science and Engineering Taiyuan University of TechnologyShanxi 030600China

During thewater treatment process,chlorination and ultraviolet(UV)sterilization can modify microplastics(MPs)and alter their physicochemical properties,causing various changes between MPs and other *** this study,the impact of chlorination and UV modification on the physicochemical properties of polystyrene(PS)and polyvinyl chloride(PVC)were investigated,and the adsorption behavior of pefloxacin(PEF)before and after modificationwas *** effect of pH,ionic strength,dissolved organicmatter,heavymetal ions and other water environmental conditions on adsorption behavior was *** results showed that PS had a higher adsorption capacity of PEF than PVC,and the modification increased the presence of O-containing functional groups in the MPs,thereby enhancing the adsorption capacity of both *** had a more significant impact on the physicochemical properties of MPs compared to UV irradiation within the same time period,leading to better adsorption performance of *** optimal pH for adsorption was found to be 6,and NaCl,sodium alginate and Cu2+would inhibit adsorption to varying degrees,among which the inhibition caused by pH was the *** and UV modification would weaken the inhibitory effect of environmental factors on the adsorption of PEF by *** main mechanisms of adsorption involved electrostatic interaction and hydrogen *** study clarified the effects of modification on the physicochemical properties of MPs,providing reference for subsequent biotoxicity analysis and environmental protection studies.

关键词： Microplastics Chlorination Ultraviolet Pefloxacin Adsorption mechanism

Regeneration mechanisms and therapeutic strategies for neuromuscular junctions in aging and diseases

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Neural Regeneration Research 2025年第1期20卷 193-194页

作者： Masashi Fujitani Abu md Mamun Tarif Yoshinori Otani Department of Anatomy and Neuroscience Faculty of MedicineShimane UniversityShimaneJapan

The neuromuscular junction(NMJ)is an essential synaptic structure composed of motor neurons,skeletal muscles,and glial cells that orchestrate the critical process of muscle contraction(Li et al.,2018).The typical NMJ structure is classically described as having a“pretzel-like”shape in mice(Figure 1),whereas human NMJs have a smaller,fragmented structure throughout *** NMJs exhibit smaller or fragmented endplates,partial denervation,reduced numbers of synaptic vesicles,abnormal presynaptic mitochondria,and dysfunctional perisynaptic Schwann cells(Alhindi et al.,2022).

关键词： aging structure Figure

Parametric Analysis and Designing Maps for Powder Spreading in Metal Additive Manufacturing

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Computer Modeling in Engineering & Sciences 2025年第2期142卷 2067-2090页

作者： Yuxuan wu Sirish Namilae Department of Aerospace Engineering Embry-Riddle Aeronautical UniversityDaytona BeachFL 32114USA

Powder bed fusion(PBF)in metallic additive manufacturing offers the ability to produce intricate geometries,high-strength components,and reliable ***,powder processing before energy-based binding significantly impacts the final product’s *** maps guide efficient process design to minimize defects,but creating them through experimentation alone is challenging due to the wide range of parameters,necessitating a comprehensive computational parametric *** this study,we used the discrete element method to parametrically analyze the powder processing design space in PBF of stainless steel 316L *** lattice parameter sweeps are often used for parametric analysis,but are computationally *** find that non-uniform parameter sweep based on the low discrepancy sequence(LDS)algorithm is ten times more efficient at exploring the design space while accurately capturing the relationship between powder flow dynamics and bed packing *** introduce a multi-layer perceptron(MLP)model to interpolate parametric causalities within the LDS parameter *** over 99%accuracy,it effectively captures these causalities while requiring fewer ***,we generate processing design maps for machine setups and powder selections for efficient process *** find that recoating speed has the highest impact on powder processing quality,followed by recoating layer thickness,particle size,and inter-particle friction.

关键词： Powder bed fusion additive manufacturing discrete element method parameter sweep process design

The Impact of Different Effective Models for Star Formation on the Properties of Simulated Milky Way-sized Galaxies

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Research in Astronomy and Astrophysics 2025年第1期25卷 194-210页

作者： Yiheng wu Volker Springel Shanghai Astronomical Observatory Chinese Academy of Sciences University of Chinese Academy of Sciences Max-Planck-Institut für Astrophysik

Hydrodynamical cosmological simulations of galaxy formation such as Illustris TNG or Auriga have shown considerable success in approximately matching many galaxy properties,but their treatment of the star-forming interstellar medium (ISM) has relied on heuristic sub-grid ***,recent high-resolution simulations of the ISM that directly resolve the regulation of star formation suggest different mean relations for the dependences of pressure and star formation rate on the average gas *** this study,we adopt such a modern,physically grounded parameterization inspired by the TIGRESS small-scale *** dub this model TEQS and use it for a detailed comparative analysis of the formation and evolution of a Milky Way-sized galaxy when compared with the widely used TNG *** employing high-resolution simulations in tall box setups,we first investigate the structural differences expected for these two models when applied to different self-gravitating gas surface *** results indicate that TEQS produces considerably thinner gaseous layers and can be expected to form stellar distributions with smaller scale-height than TNG,especially at higher surface *** test whether this induces systematic structural differences in cosmological galaxy formation simulations,we carry out zoom-in simulations of 12 galaxies taken from the set of Milky Way-sized galaxies that have been studied in the Auriga *** results for these galaxies shows that disk galaxies formed with the TEQS model have on average very similar stellar mass but are more concentrated in their central regions and exhibit smaller stellar radii compared to those formed with the TNG *** differences in the scale-heights of the formed stellar disks are only marginal,however,suggesting that other factors for setting the thickness of the disk are more important than the applied ISM equation-of-state ***,the predicted galaxy structure is quite similar for TNG and

关键词： Galaxy: evolution Galaxy: formation methods: numerical