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growth,optical dispersion and magnetic behavior of Dy^(3+) doped yttrium iron garnet crystals

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Journal of Rare Earths 2024年第6期42卷 1110-1117,I0004页

作者： Yating Fang Hui Shen Yudie ma Shijie Liao shuang Xia Tian Tian Ding Zhou Yunfeng ma Jiayue Xu Institute of Crystal growth School of Materials Science and EngineeringShanghai Institute of Technology National Engineering Center of Electromagnetic Radiation Control materials School of Electronic Science and EngineeringUniversity of Electronic Science and Technology of China

Y_(3)Fe_(5)O_(12)(YIg)crystals are highly desirable for the fabrication of mid-infrared isolators with the rapid growth of optical communications,although it is rather challenging to grow large size and high-quality single ***^(3+)doping is expected to improve the optical and magneto-optical prope ***,high quality Dy:YIg crystals and the adjustment of Dy^(3+)on the structure and optical behavior of YIg crystal remain unclear,impeding its practical ***,a series of Y_(3-x)Dy_(x)Fe_(5)O_(12)(x=0,0.5,1.0,1.5,3)solid solution crystals was grown by the flux-Bridgman method and single crystals up to 25 mm were *** the introduction of Dy^(3+),lattice parameters are gradually enlarged from 1.2379 nm(YIg)to 1.2420 nm(DyIg).Typical Dy^(3+)absorption peaks are observed around 1070,1265 and 1670 *** refractive index decreases from 2.37(500 nm)to 2.10(2500 nm)for YIg crystal,and it reduces from 2.47(500 nm)to 2.16(2500 nm)for DyIg *** optical bandgaps remain almost unchanged for Dy:YIg *** optical dispersion of the refractive indices was finely fitted by the Wemple and DiDomenico(WDD)and the Sellmeier models,*** the increase of Dy^(3+)content,the saturation magnetization(Ms)decreases significantly from 23.62 emu/g(YIg)to 5.33 emu/g(DyIg).Small coercive field is persisted for this system,endowing small external magnetic *** results provide valuable references for the manipulation of rare earths on the properties of magnetooptical crystals,which is beneficial to the design of high-performance garnet crystals for the application of optical switching and non-reciprocal related devices.

关键词： magneto-optical crystal Yttrium iron garnet Dy^(3+)doping Crystal growth Optical dispersion Rare earths

Band-like transport in solution-processed perylene diimide dianion films with high Hall mobility

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National Science Review 2024年第5期11卷 264-271页

作者： Yanhua Jia Qinglin Jiang Hanlin gan Bohan Wang Xiandong He Jiadong Zhou Zetong ma Jiang Zhang Yuguang ma Institute of Polymer Optoelectronic materials and Devices State Key Laboratory of Luminescent Materials and Devices South China University of Technology Department of Physics South China University of Technology

It is crucial to prepare high-mobility organic polycrystalline film through solution ***,the delocalized carrier transport of polycrystalline films in organic semiconductors has rarely been investigated through Hall-effect *** study presents a strategy for building strong intermolecular interactions to fabricate solution-crystallized p-type perylene diimide（PDI） dianion films with a closer intermolecular π-π stacking distance of 3.25 ?.The highly delocalized carriers enable a competitive Hall mobility of 3 cm2V-1s-1,comparable to that of the reported high-mobility organic single *** PDI dianion films exhibit a high electrical conductivity of 17 S cm-1and typical band-like transport,as evidenced by the negative temperature linear coefficient of mobility proportional to T-3/*** work demonstrates that,as the intermolecular π-π interactions become strong enough,they will display high mobility and conductivity,providing a new approach to developing high-mobility organic semiconductor materials.

关键词： band-like transport dianion aggregates Hall mobility solution-processed perylene diimide

Directly predicting N_(2) electroreduction reaction free energy using interpretable machine learning with non-DFT calculated features

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Journal of Energy Chemistry 2024年第10期97卷 139-148,I0004页

作者： Yaqin Zhang Yuhang Wang Ninggui ma Jun Fan Department of materials Science and Engineering City University of Hong KongHong Kong 999077China Center for Advanced Nuclear Safety and Sustainable Development City University of Hong KongHong Kong 9077China Department of Mechanical Engineering City University of Hong KongHong Kong 999077China

Electrocatalytic nitrogen reduction to ammonia has garnered significant attention with the blooming of single-atom catalysts(SACs),showcasing their potential for sustainable and energy-efficient ammonia ***,cost-effectively designing and screening efficient electrocatalysts remains a *** this study,we have successfully established interpretable machine learning(ML)models to evaluate the catalytic activity of SACs by directly and accurately predicting reaction gibbs free *** models were trained using non-density functional theory(DFT)calculated features from a dataset comprising 90 graphene-supported *** results underscore the superior prediction accuracy of the gradient boosting regression(gBR)model for bothΔg(N_(2)→NNH)andΔg(NH_(2)→NH_(3)),boasting coefficient of determination(R^(2))score of 0.972 and 0.984,along with root mean square error(RMSE)of 0.051 and 0.085 eV,***,feature importance analysis elucidates that the high accuracy of gBR model stems from its adept capture of characteristics pertinent to the active center and coordination environment,unveilling the significance of elementary descriptors,with the colvalent radius playing a dominant ***,Shapley additive explanations(SHAP)analysis provides global and local interpretation of the working mechanism of the gBR *** analysis identifies that a pyrrole-type coordination(flag=0),d-orbitals with a moderate occupation(N_(d)=5),and a moderate difference in covalent radius(r_(TM-ave)near 140 pm)are conducive to achieving high ***,we extend the prediction of activity to more catalysts without additional DFT calculations,validating the reliability of our feature engineering,model training,and design *** findings not only highlight new opportunity for accelerating catalyst design using non-DFT calculated features,but also shed light on the working mechanism of"black box"ML ***,the model provides valuable g

关键词： Nitrogen reduction Single-atom catalyst Interpretable machine learning graphene Non-DFT features

Clathrate metal superhydrides under high-pressure conditions: enroute to room-temperature superconductivity

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National Science Review 2024年第7期11卷 33-46页

作者： Ying Sun Xin Zhong Hanyu Liu Yanming ma Key Laboratory of material Simulation Methods&Software of Ministry of Education College of Physics Jilin University State Key Laboratory of Superhard materials College of PhysicsJilin University International Center of Future Science Jilin University

Room-temperature superconductivity has been a long-held dream of mankind and a focus of considerable interest in the research field of superconductivity. Significant progress has recently been achieved in hydrogen-based superconductors found in superhydrides（hydrides with unexpectedly high hydrogen contents） that are stabilized under high-pressure conditions and are not capturable at ambient *** particular interest is the discovery of a class of best-ever-known superconductors in clathrate metal superhydrides that hold the record for high superconductivity(e.g. Tc= 250–260 K for LaH10) among known superconductors and have great promise to be those that realize the long-sought room-temperature superconductivity. In these peculiar clathrate superhydrides, hydrogen forms unusual ‘clathrate’ cages containing encaged metal atoms, of which such a kind was first reported in a calcium hexa-superhydride（CaH6） showing a measured high Tcof 215 K under a pressure of 170 gPa. In this review, we aim to offer an overview of the current status of research progress on the clathrate metal superhydride superconductors,discuss the superconducting mechanism and highlight the key features（e.g. structure motifs, bonding features, electronic structure, etc.） that govern the high-temperature superconductivity. Future research direction along this line to find room-temperature superconductors will be discussed.

关键词： clathrate superhydrides high-temperature superconductivity high-pressure conditions crystal structure prediction

A practical guide for fast implementation of SNARE-mediated liposome fusion

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Biophysics Reports 2024年第1期10卷 31-40页

作者： Shen Wang Cong ma Key Laboratory of Molecular Biophysics of the Ministry of Education College of Life Science and TechnologyHuazhong University of Science and Technology

Soluble N-ethylmaleimide-sensitive factor attachment protein receptor(SNAER) family proteins are the engines of most intra-cellular and exocytotic membrane fusion pathways(Jahn and Scheller 2006).Over the past two decades, in-vitro liposome fusion has been proven to be a powerful tool to reconstruct physiological SNARE-mediated membrane fusion processes(Liu et al. 2017). The reconstitution of the membrane fusion process not only provides direct evidence of the capability of the cognate SNARE complex in driving membrane fusion but also allows researchers to study the functional mechanisms of regulatory proteins in related pathways(Wickner and Rizo 2017). Heretofore, a variety of delicate methods for in-vitro SNARE-mediated liposome fusion have been established(Bao et al. 2018;Diao et al. 2012; Duzgunes 2003; gong et al. 2015; Heo et al. 2021; Kiessling et al. 2015; Kreye et al.2008; Kyoung et al. 2013; Liu et al. 2017; Scott et al. 2003). Although technological advances have made reconstitution more physiologically relevant, increasingly elaborate experimental procedures, instruments, and data processing algorithms nevertheless hinder the non-experts from setting up basic SNARE-mediated liposome fusion assays. Here, we describe a low-cost, timesaving, and easy-to-handle protocol to set up a foundational in-vitro SNARE-mediated liposome fusion assay based on our previous publications(Liu et al. 2023; Wang and ma 2022). The protocol can be readily adapted to assess various types of SNARE-mediated membrane fusion and the actions of fusion regulators by using appropriate alternative additives(e.g., proteins, macromolecules, chemicals, etc.). The total time required for one round of the assay is typically two days and could be extremely compressed into one day.

关键词： Liposome fusion SNARE In-vitro reconstitution Protocol

Flag Varieties of Type B/C and Twisted Yangian

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Algebra Colloquium 2024年第1期31卷 129-148页

作者： Zhijie Dong Haitao ma Institute for Advanced Study in mathematics of HIT Harbin Institute of Technology Harbin 150001China College of mathematical Science Harbin Engineering University Harbin 150001China

We study the convolution algebra H_(*)^(g×C^(*))(Z)of g×C^(*)-equivariant homology group on the Steinberg variety of type B/C and define an algebra Y that maps to H_(*)^(g×C^(*))(Z).We also study the g-equivariant ... 详细信息

关键词： Yangian fag variety convolution algebra

High Power Density EV Integrated Fast Battery Chargers Based on the general Torque Cancelation Law for Three-Phase Motors

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CSEE Journal of Power and Energy Systems 2024年第2期10卷 756-766页

作者： Yanxiong Lei guiping Du Tuhuan Li Wenjie ma Xueyi Wang School of Electric Power South China University of TechnologyGuangzhou 510641China

Integrated battery chargers are highly effective for saving costs and improving the power density of on-board chargers in electric vehicles (EVs), However, achieving torque elimination of the commonly used three-phase (3p) motors during the fast-charging process is challenging. In this paper, the general torque cancelation law applied in 3p permanent magnet synchronous motors (PMSMs) and induction motors (IMs) is derived to design high power density integrated fast battery chargers. Two novel integrated systems with fast-charging and vehicle-to-grid (V2g) capabilities are proposed based on this law. The main advantages of the proposed systems are: (1) Two filter inductors are constituted by the stator windings while charging, and only one external inductor and several contactors are supplemented to the motor-drive circuit. Therefore, the proposed integrated systems possess high power density;(2) The 3p open-winding (OW) motor is employed, with no need to modify the propulsion system or redesign the interior structure of the motor;(3) Employing an individual controller for each phase of the inner current loop control, the proposed systems realize unity power factors and low current harmonics in the fast-charging and V2g mode. Simulation and experimental results verify the feasibility of the proposed topologies and control strategies.

关键词： Electric vehicles(EVs) fast charging integrated battery charger 3p PMSM/IM torque cancelation

Lightweight Dual‑Functional Segregated Nanocomposite Foams for Integrated Infrared Stealth and Absorption‑Dominant Electromagnetic Interference Shielding

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Nano-Micro Letters 2024年第11期16卷 38-55页

作者： Zhonglei ma Ruochu Jiang Jiayao Jing Songlei Kang Li ma Kefan Zhang Junxian Li Yu Zhang Jianbin Qin Shuhuan Yun guangcheng Zhang MOE Key Laboratory of material Physics and Chemistry Under Extraordinary Conditions Shaanxi Key Laboratory of Macromolecular Science and TechnologySchool of Chemistry and Chemical EngineeringNorthwestern Polytechnical UniversityXi’an 710072People’s Republic of China College of Chemistry and Chemical Engineering Key Laboratory of Auxiliary Chemistry and Technology for Chemical IndustryMinistry of EducationShaanxi University of Science and TechnologyXi’an 710072People’s Republic of China Department of Mechanical and Industrial Engineering University of Toronto5 King’s College RoadTorontoON M5S 3G8Canada Chongqing Innovation Center Northwestern Polytechnical UniversityChongqing 401135People’s Republic of China

Lightweight infrared stealth and absorption-dominant electromagnetic interference(EMI)shielding materials are highly desirable in areas of aerospace,weapons,military and wearable ***,lightweight and high-efficiency dual-functional segregated nanocomposite foams with microcellular structures are developed for integrated infrared stealth and absorption-dominant EMI shielding via the efficient and scalable supercritical CO_(2)(SC-CO_(2))foaming combined with hydrogen bonding assembly and compression molding *** obtained lightweight segregated nanocomposite foams exhibit superior infrared stealth performances benefitting from the synergistic effect of highly effective thermal insulation and low infrared emissivity,and outstanding absorption-dominant EMI shielding performances attributed to the synchronous construction of microcellular structures and segregated ***,the segregated nanocomposite foams present a large radiation temperature reduction of 70.2℃ at the object temperature of 100℃,and a significantly improved EM wave absorptivity/reflectivity(A/R)ratio of 2.15 at an ultralow Ti_(3)C_(2)T_(x) content of 1.7 vol%.Moreover,the segregated nanocomposite foams exhibit outstanding working reliability and stability upon dynamic compression *** results demonstrate that the lightweight and high-efficiency dual-functional segregated nanocomposite foams have excellent potentials for infrared stealth and absorption-dominant EMI shielding applications in aerospace,weapons,military and wearable electronics.

关键词： Segregated nanocomposite foams Microcellular structures Infrared stealth EMI shielding Low infrared emissivity

Kinetic-Thermodynamic Promotion Engineering toward High-Density Hierarchical and Zn-Doping Activity-Enhancing ZnNiO@CF for High-Capacity Desalination

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Nano-Micro Letters 2024年第8期16卷 35-50页

作者： Jie ma Siyang Xing Yabo Wang Jinhu Yang Fei Yu College of marine Ecology and Environment Shanghai Ocean University201306 ShanghaiPeople’s Republic of China School of Civil Engineering Kashi University844000 KashiPeople’s Republic of China Research Center for Environmental Functional materials College of Environmental Science and EngineeringTongji University1239 Siping Road200092 ShanghaiPeople’s Republic of China School of Chemical Science and Engineering Tongji University1239 Siping Road200092 ShanghaiPeople’s Republic of China Department of Energy Environmental&Chemical EngineeringWashington University in St.LouisSt.LouisMO 63130USA

Despite the promising potential of transition metal oxides(TMOs)as capacitive deionization(CDI)electrodes,the actual capacity of TMOs electrodes for sodium storage is significantly lower than the theoretical capacity,posing a major ***,we prepared the kinetically favorable Zn_(x)Ni_(1−x)O electrode in situ growth on carbon felt(Zn_(x)Ni_(1−x)O@CF)through constraining the rate of OH^(−)generation in the hydrothermal ***_(x)Ni_(1−x)O@CF exhibited a high-density hierarchical nanosheet structure with three-dimensional open pores,benefitting the ion transport/electron *** tuning the moderate amount of redox-inert Zn-doping can enhance surface electroactive sites,actual activity of redox-active Ni species,and lower adsorption energy,promoting the adsorption kinetic and thermodynamic of the Zn_(0.2)Ni_(0.8)O@*** from the kinetic-thermodynamic facilitation mechanism,Zn_(0.2)Ni_(0.8)O@CF achieved ultrahigh desalination capacity(128.9 mgNaCl g^(-1)),ultra-low energy consumption(0.164 kW h kgNaCl^(-1)),high salt removal rate(1.21 mgNaCl g^(-1) min^(-1)),and good *** thermodynamic facilitation and Na^(+)intercalation mechanism of Zn_(0.2)Ni_(0.8)O@CF are identified by the density functional theory calculations and electrochemical quartz crystal microbalance with dissipation monitoring,*** research provides new insights into controlling electrochemically favorable morphology and demonstrates that Zn-doping,which is redox-inert,is essential for enhancing the electrochemical performance of CDI electrodes.

关键词： Zinc-nickel metal oxide High-density hierarchical Capacitive deionization Zinc-doping