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Highly anti-corrosive NiFe LDHs–NiFe alloy hybrid enables long-term stable alkaline seawater electrolysis

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Rare Metals 2024年第9期43卷 4321-4332页

作者： Jia-Hong Li Hao Chen Si-Hang You Gan-Xin Yang Peng liu Meng-Qi Gao shu-guang Chen Fei-Fei Zhang School of Materials Science and Engineering Changsha University of Science and TechnologyHunan 410114China Department of Materials Science and Engineering Faculty of EngineeringNational University of SingaporeSingapore 117576Singapore School of Materials Science and Engineering Jilin UniversityJilin 130022China

Owing to the significant potential of alkalin seawater electrolysis for converting surplus power into eco friendly hydrogen fuel,we developed bifunctional elec trodes that integrate low-crystalline NiFe LDHs and amorphous NiFe alloy on a Ni foam(NF)substrate to enhance this *** by the battery-like charac teristics of NiFe LDHs,an anti-corrosive and active oute layer of NiFe^(vac)OOH continuously forms over time in th hybrid on the anode for the oxygen evolution reaction(OER),effectively mitigating powder shedding caused by corrosion induced by multiple anions in *** while,the strong bond between the hybrid and the NF substrate maintains intact hybrid coatings to ensure a rel atively high overall conductivity of the electrodes,signif icantly reducing the negative effects of structura degradation during the OER and hydrogen evolution reaction(HER),as well as the accumulation of contami nants on the electrode *** long-term tests,thes bifunctionalhybridelectrodesmaintained stable performance,even at a high current density o500 mA·cm^(-2).The cell voltage increased by only 88 m V over 1000 h to 1.970 V during saline electrolysis and by103 mV over 500 h to 2.062 V during seawater electroly ***,this study provides valuable insights into efficient and stable seawater electrolysis using NiFe LDHs–NiFe alloy hybrids.

关键词： NiFe LDHs Bifunctional Corrosion Stability Seawater electrolysis

Facile construction of Mxene-supported niobium hydride nanoparticles toward reversible hydrogen storage in magnesium borohydride

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Rare Metals 2024年第9期43卷 4387-4400页

作者： Ao Xia Jia-guang Zheng Qing-Bo Zhang Yu-Gang shu Cheng-Guo Yan liu-Ting Zhang Zhan-Liang Tao Li-Xin Chen School of Energy and Power Jiangsu University of Science and TechnologyZhenjiang 212003China Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education) Nankai UniversityTianjin 300071China State Key Laboratory of Silicon and Advanced Semiconductor Materials School of Materials Science and EngineeringZhejiang UniversityHangzhou 310027China

The facile construction of nanoscale NbH_(x)supported by Ti_(3)C_(2)(NbH_(x)@Ti_(3)C_(2))was achieved using facile ball milling strategy to improve the hydrogen desorption kinetics and reversibility of magnesium borohydride(Mg(BH_(4))_(2)).The doping of 30 wt%NbH_(x)@Ti_(3)C_(2)catalyst reduced the onset dehydrogenation temperature of Mg(BH_(4))_(2)to 71.2℃.Additionally,the Mg(BH_(4))_(2)+30NbH_(x)@Ti_(3)C_(2)composite achieved remarkable hydrogen release of over 9.2 wt%at a temperature as low as 230℃,indicating unexpected dehydrogenation ***,the reversibility of NbH_(x)@Ti_(3)C_(2)doped Mg(BH_(4))_(2)was retained to more than 4.2 wt%after four cycles,which was increased by 68%compared to that of undoped Mg(BH_(4))_(2).The strong catalysis of NbH_(x)@Ti_(3)C_(2)catalyst could be attributed to the synergistic effect of NbH_(x)and Ti_(3)C_(2)in hydrogen spillover and ***_(x)acted as a"hydrogen pump"for effective hydrogen spillover,while Ti_(3)C_(2)created numerous diffusion channels for hydrogen dissolution and provided the active catalytic site to facilitate the re/dehydrogenation of Mg(BH_(4))_(2).

关键词： Hydrogen storage Magnesium borohydride Catalysts Mxene

Narrative review of latest research progress about robotic percutaneous coronary intervention

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Journal of Geriatric Cardiology 2024年第8期21卷 816-825页

作者： Zhen-Yu liu guang-Yao ZHAI Department of Clinical Medicine Beijing Luhe HospitalCapital Medical UniversityBeijingChina Department of Cardiology Beijing Luhe HospitalCapital Medical UniversityBeijingChina

Robotic percutaneous coronary intervention(R-PCI)is a novel technology in which operators can manipulate guidewires and catheter devices in interventional *** approach provides great benefits to interventional cardiologists in terms of reducing both radiation exposure and orthopedic *** large,high-quality cohort studies have confirmed the short-term safety and high technical success rate of ***,randomized long-term data are still needed before adopting them as part of standard coronary ***,tele-stenting for complex coronary lesions has significant potential for *** need to overcome the present relevant challenges for its application such as inherent delays,bedside care for unstable patients from R-PCIs to manual PCIs(M-PCIs),incompatibility for a thrombus aspiration catheter and heavily calcified *** is a great future in laboratory workflow teams,3D-printed anatomical models and multiple joint collaborative control *** narrative review summarizes the latest developments in R-PCI,with a focus on developments in robotic technology,and discusses the current and future potential use of R-PCI in clinical practice globally.

关键词： coronary injuries unstable

Numerical simulations for radon migration and exhalation behavior during measuring radon exhalation rate with closed-loop method

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Nuclear Science and Techniques 2024年第1期35卷 81-95页

作者： Ming Xia Yong-Jun Ye shu-Yuan liu School of Resources Environment and Safety Engineering University of South ChinaHengyang 421001China Key Discipline Laboratory for National Defense for Biotechnology in Uranium Mining and Hydrometallurgy University of South ChinaHengyang 421001China

Accurate measurements of the radon exhalation rate help identify and evaluate radon risk regions in the *** these measurement methods,the closed-loop method is frequently ***,traditional experiments are insufficient or cannot analyze the radon migration and exhalation patterns at the gas–solid interface in the accumulation *** CFD-based technique was applied to predict the radon concentration distribution in a limited space,allowing radon accumulation and exhalation inside the chamber intuitively and *** this study,three radon exhalation rates were defined,and two structural ventilation tubes were designed for the *** consistency of the simulated results with the variation in the radon exhalation rate in a previous experiment or analytical solution was *** effects of the vent tube structure and flow rate on the radon uniformity in the chamber;permeability,insertion depth,and flow rate on the radon exhalation rate and the effective diffusion coefficient on back-diffusion were *** on the results,increasing the inser-tion depth from 1 to 5 cm decreased the effective decay constant by 19.55%,whereas the curve-fitted radon exhalation rate decreased(lower than the initial value)as the deviation from the initial value increased by approximately 7%.Increasing the effective diffusion coefficient from 2.77×10^(-7) to 7.77×10^(-6) m^(2) s^(-1) made the deviation expand from 2.14 to 15.96%.The conclusion is that an increased insertion depth helps reduce leakage in the chamber,subject to notable back-diffusion,and that the closed-loop method is reasonably used for porous media with a low effective diffusion coefficient in view of the back-diffusion *** CFD-based simulation is expected to provide guidance for the optimization of the radon exhalation rate measurement method and,thus,the accurate measurement of the radon exhalation rate.

关键词： Radon exhalation Numerical simulation Accumulation chamber

Microbial Sulfate Reduction and Its Role in Carbon Sequestration in Marine Sediments

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Journal of Earth Science 2024年第4期35卷 1378-1381页

作者： Xiting liu Houjie Wang Jiarui liu guang-Chao Zhuang Key Laboratory of Submarine Geosciences and Prospecting Technology College of Marine GeosciencesOcean University of ChinaQingdao266100China Qingdao Marine Science and Technology Center Laboratory for Marine GeologyQingdao266237China Department of Earth Planetaryand Space SciencesUniversity of CaliforniaLos Angeles90095USA Frontiers Science Center for Deep Ocean Multispheres and Earth System(FDOMES)and Key Laboratory of Marine Chemistry Theory and Technology Ministry of EducationOcean University of ChinaQingdao266100China

0 INTRODUCTION The carbon buried in marine sediments in the form of organic carbon or carbonate minerals represents the largest pathway for carbon removal from Earth's surface environments(Sun and Turchyn,2014).Microbial sulfate reduction(MSR)is a fundamental biogeochemical process occurring in marine sediments,where sulfate-reducing bacteria(SRB)reduce sulfate(SO42-)to sulfide(S2-)using organic matter or methane as electron donors(Jorgensen,2021).

关键词： buried carbonate environments

Simultaneous reconstruction of postoperative defects of mandibular osteoradionecrosis with free fibular osteocutaneous flap

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中国口腔颌面外科杂志 2008年第B5期6卷 170-171页

作者： shu guang liu Wei Jan Ai Xiu Wen Luan Hui Xi Zhou shu guang Zeng Jun Fa Zheng Department of Oral and Maxillofacial Surgery guangdong Provincial Stomatological Hospital The Affiliated Stomatologicalhospital of Southern Medical University guangzhou 510280 China

Purpose: To assess the effectiveness of flee fibular osteocutaneous flap transfer for treating the osteoradionecrosis of mandible。Methods: From October 2005 to November 2007, eight patients suffering from mandibular osteoradionecrosis after radiotherapy of nasopharyngeal carcinoma underwent extensive resection of sequestrum and simultaneous microsurgical reconstruction with vascularized free fibular osteocutaneous flaps。Results: All the free osteocutaneous fibular flaps survived completely without partial or total necrosis。All patients had complete resolution of ORNJ symptoms。No evidence of ORNJ recurrence was observed in any patient。Conclusion: fibular osteocutaneous flap transfer in patient for treatin osteoradionecrosis of mandible reconstruction is safe reliable Free g the and reliable。

关键词：颚放射性骨坏死治疗方法手术治疗

Two-component dimers of ultracold atoms with center-of-mass-momentum dependent interactions

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Communications in Theoretical Physics 2024年第4期76卷 153-157页

作者： Yaru liu shu Yang Peng Zhang Department of Physics Renmin University of ChinaBeijing 100872China Graduate School of China Academy of Engineering Physics Beijing 100193China Key Laboratory of Quantum State Construction and Manipulation(Ministry of Education) Renmin University of ChinaBeijing 100872China

In a previous paper[***.A95,060701(R)(2017)],we demonstrated that a new type of two-body interaction,which depends on the center of mass(CoM)momentum,can be realized for ultracold atoms via laser-modulated magnetic Feshbach resonance(MFR).Further studies(e.g.L He et al,***.120,045302(2018))show that various interesting phenomena,such as Fulde–Ferrell superfluids,can be induced by scattering between ultracold atoms with this *** this work we investigate the shallow bound states of two ultracold atoms with this type of *** show that when the magnetic field B is below the MFR point B0,two shallow bound states can appear in this ***,a'two-component dimer'or a dimer with pseudo-spin 1/2 can be formed by two ***,the dispersion curve of the dimer may have either single or double minimums in the CoM momentum *** latter case can be explained as a result from significant pseudo-spin-orbital coupling(SOC)*** results show that the ultracold gases with CoM momentum dependent interaction may be a candidate for quantum simulations with ultracold two-component molecules,especially the molecule gases with SOC.

关键词： center-of-mass-momentum dependent interaction Raman-laser modulated MFR two-component dimer

B cell development and antibody responses in human immune system mice:current status and future perspective

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Science China(Life Sciences) 2024年第4期67卷 645-652页

作者： Tao Zhang Wentao liu Yong-guang Yang Key Laboratory of Organ Regeneration&Transplantation of the Ministry of Education The First Hospital of Jilin UniversityChangchun 130061China National-Local Joint Engineering Laboratory of Animal Models for Human Diseases Jilin UniversityChangchun 130061China International Center of Future Science Jilin UniversityChangchun 130061China

Humanized immune system(HIS)mice have been developed and used as a small surrogate model to study human immune function under normal or disease *** variations are found between models,most HIS mice show robust human T cell ***,there has been unsuccessful in constructing HIS mice that produce high-affinity human antibodies,primarily due to defects in terminal B cell differentiation,antibody affinity maturation,and development of primary follicles and germinal *** this review,we elaborate on the current knowledge about and previous attempts to improve human B cell development in HIS mice,and propose a potential strategy for constructing HIS mice with improved humoral immunity by transplantation of human follicular dendritic cells(FDCs)to facilitate the development of secondary follicles.

关键词： humanized immune system mouse humoral immunity germinal center B cell follicular dendritic cell

An efficient stiffness analysis model based on shear deformation theory for flexible skin shear variable-sweep wing

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Chinese Journal of Aeronautics 2024年第10期37卷 445-458页

作者： Yue BAI guang YANG Hong XIAO Hongwei GUO Rongqiang liu Bei liu State Key Laboratory of Robotics and System Harbin Institute of TechnologyHarbin 150001China China Aerodynamics Research and Development Center Institute of High-Speed AerodynamicsMianyang 621000China

Fixed-wing aircraft cannot maintain optimal aerodynamic performance at different flight *** a type of morphing aircraft,the shear variable-sweep wing(SVSW)can dramatically improve its aerodynamic performance by altering its shape to adapt to various flight *** order to achieve smooth continuous shear deformation,SVSW’s skin adopts a flexible composite skin design instead of traditional aluminum alloy ***,this also brings about the non-linear difficulty in stiffness modeling and *** this research,a new SVSW design and efficient stiffness modeling method are *** on shear deformation theory,the flexible composite skin is equivalently modeled as diagonally arranged nonlinear springs,simulating the elastic force interaction between the skin and the *** shear loading tests of flexible composite skin,the accuracy of this flexible composite skin modeling method is *** SVSW stiffness model was established,and its accuracy was verified through static loading *** effects of root connection,sweep angles,and flexible composite skin on the SVSW stiffness are ***,considering three typical flight conditions of SVSW:low-speed flow(Ma=0.3,Re=5.8210^(6)),transonic flow(Ma=0.9,Re=3.4410^(6)),and supersonic flow(Ma=3,Re=7.5110^(6)),the stiffness characteristics of SVSW under flight conditions were *** calculated results guide the application of SVSW.

关键词： Shear variable-sweep wing(SVSW) Flexible composite skin Morphing mechanism Stiffness analysis Loading tests Structure