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Effect of permeability and its horizontal anisotropy on enhanced coalbed methane recovery with CO_(2) storage:quantitative evaluation based on staged CH_(4) output inhibition

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Frontiers of Earth Science 2023年第3期17卷 856-866页

作者： Ziliang WANG Shuxun SANG Xiaozhi ZHOU Xudong LIU shouren zhang Key Laboratory of Coalbed Methane Resources&Reservior Formation Process(Ministry of Education) China University of Mining and TechnologyXuzhou 221008China School of Resources and Geosciences China University of Mining and TechnologyXuzhou 221008China Carbon Neutrality Institute China University of Mining and TechnologyXuzhou 221008China Jiangsu Key Laboratory of Coal-Based Greenhouse Gas Control and Utilization Xuzhou 221008China China United Coalbed Methane Co.Ltd.(CUCBM) Beijing 100011China

The permeability and its horizontal anisotropy induce a critical influence on staged CH_(4) output inhibition process.However,a quantitative evaluation of this influence has been rarely reported in the literature.In this work,the impact of horizontal anisotropic permeability on CO_(2)-ECBM was numerically investigated.The variation in the staged CH_(4) output inhibition was analyzed.The ideal displacement profile of the CO_(2)-ECBM process was established for the first time.Moreover,the variation in CH_(4) output of different wellbores was discussed.The results showed that 1)low-permeable or weak-anisotropic reservoirs were not conducive to enhanced CH_(4) recovery owing to long inhibition time(>1091 days)and high inhibition level(>36.9%).As permeability and anisotropy increased,due to the accelerated seepage of free water,the hysteresis time and inhibition time could decrease to as short as 5 days and 87 days,respectively,and the inhibition level could weaken to as low as 5.00%.Additionally,the CH_(4) output and CO_(2) injection could increase significantly.2)Nevertheless,high permeability and strong anisotropy easily induced CO_(2) breakthrough,resulting in lower CH_(4) production,CO_(2) injection and CO_(2) storage than expected.While maintaining high efficiency of CO_(2) storage(>99%),upregulating CO_(2) breakthrough concentration from 10%to 20%might ease the unfavorable trend.3)Along the direction of fluid flow,the ideal displacement profile consisted of CO_(2) enriched bank,CO_(2) and CH_(4) mixed bank,CH_(4) enriched bank,and water enriched bank,whereas a remarkable gap in the displacement profiles of the dominant and non-dominant seepage directions was observed.4)The potential of CH_(4) output might vary greatly among different wellbores.The producers along the dominant seepage direction held more potential for CH_(4) recovery in the short-term,while those along the non-dominant seepage direction avoided becoming invalid only if a long-time injection measure was taken for the injectors.These findings pave

关键词： CO_(2)-ECBM permeability anisotropy the staged CH_(4)output inhibition displacement profile

Highly efficient electrocatalytic nitrogen fixation enabled by the bridging effect of Ru in plasmonic nanoparticles

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Nano Research 2023年第1期16卷 360-370页

作者： Hang Yin Jinwu Hu Caihong Fang Yuyang Wang Lixia Ma Nan zhang shouren zhang Ruibin Jiang Jianfang Wang Shaanxi Key Laboratory for Advanced Energy Devices Shaanxi Engineering Lab for Advanced Energy TechnologySchool of Materials Science and EngineeringShaanxi Normal UniversityXi’an 710119China College of Chemistry and Materials Science The Key Laboratory of Functional Molecular SolidsMinistry of EducationAnhui Laboratory of Molecular-Based MaterialsCenter for Nano Science and TechnologyKey Laboratory of Electrochemical Clean Energy of Anhui Higher Education InstitutesAnhui Normal UniversityWuhu 241000China Henan Provincial Key Laboratory of Nanocomposites and Applications Institute of Nanostructured Functional MaterialsHuanghe Science and Technology CollegeZhengzhou 450006China Department of Physics The Chinese University of Hong KongHong Kong 999077China

Plasmon-generated hot electrons show great potential for driving chemical reactions.The utilization efficiency of hot electrons is highly dependent on the interaction of the electronic states at the interfaces between plasmonic nanoparticles and other materials/molecules.Strong interaction can produce new hybridized electron states,which permit direct hot-electron transfer,a more efficient transfer mechanism.However,Au usually has very weak interaction with most molecules because of its inertness,which makes direct hot-electron transfer impossible.Herein,the improvement of the hot-electron transfer efficiency from Au to N_(2)is demonstrated by introducing a Ru bridging layer.Both the N_(2)fixation rate and Faradic efficiency(FE)are enhanced by the excitation of plasmons.The enhancement of the N_(2)fixation rate is found to arise from plasmon-generated hot electrons.Theoretical calculations show that the strong interaction of the Ru electronic states with the N_(2)molecular orbitals produces new hybridized electronic states,and the Ru d electrons also strongly couple with the Au sp electrons.Such a bridging role of Ru makes direct hot-electron transfer from Au to N_(2)possible,improving the FE of nitrogen fixation.Our findings demonstrate a new approach to increasing the utilization efficiency of plasmonic hot electrons for chemical reactions and will be helpful to the design of plasmonic catalysts in the future.

关键词： electrocatalytic nitrogen fixation Au/Ru electrocatalysts localized surface plasmon resonance electronic state hybridization hot electron

Regulating electronic structure of two-dimensional porous Ni/Ni_(3)N nanosheets architecture by Co atomic incorporation boosts alkaline water splitting

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InfoMat 2022年第6期4卷 141-152页

作者： Kaixi Wang Yingying Guo Zhonghui Chen Donghai Wu shouren zhang Baocheng Yang Jianan zhang Henan Provincial Key Laboratory of Nanocomposites and Applications Institute of Nanostructured Functional MaterialsHuanghe Science and Technology CollegeZhengzhouChina Key Lab for Special Functional Materials of Ministry of Education National&Local Joint Engineering Research Center for High-efficiency Display and Lighting TechnologySchool of Materials Science and EngineeringHenan UniversityKaifengChina College of Materials Science and Engineering Zhengzhou UniversityZhengzhouChina

Interfacial engineering is a powerful method to improve the bifunctional electrocatalytic performance of pure phase catalysts.While it is expected to further optimize the electronic configuration of heterojunctions to boost the reaction kinetics in hydrogen/oxygen evolution reaction(HER/OER),but remains a challenge.Herein,a novel in situ hybrid heterojunction strategy is developed to construct 2D porous Co-doped Ni/Ni_(3)N heterostructure nanosheets(Co-Ni/Ni_(3)N)by pyrolysis of partially cobalt substituted nickel-zeolitic imidazolate framework(CoNi-ZIF)nanosheets under NH3 atmosphere.A combined experimental and theoretical studies manifest that the hybrid heterostructures can display regulative electronic states and downshift d-band center from the Fermi level,as well as optimize the adsorption energy of reaction intermediates,thus reducing the thermodynamic energy barriers and accelerating the catalytic kinetics.Consequently,benefitting from the optimized electronic configuration,hierarchical hollow nanosheets architecture,and abundant doped heterojunctions,the hybrid Co-Ni/Ni_(3)N heterostructure catalyst exhibits efficient catalytic activity for both HER(60 mV)and OER(322 mV)at 10 mA cm^(-2)in alkaline media,which is 105 and 47 mV lower than that of pure Ni_(3)N,respectively.The electrochemically active surface area of Co-Ni/Ni_(3)N is two times higher than that of Ni3N.Furthermore,the coupled practical water electrolyzer requires a low voltage of 1.575 V to reach 10 mA cm^(-2),and it can be driven by a 1.5 V battery.This work highlights the interface engineering guidance for the rational establishment of hybrid interfaces by electronic modulation of interfacial effect for alkaline water splitting.

关键词： 2D porous nanosheet hybrid heterojunction interfacial engineering nickel nitride overall water splitting

AP2铝硅合金超疏水表面的制备和耐腐蚀性研究

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表面技术 2024年第8期53卷 191-201,219页

作者：焦一帆王守仁王高琦张明远济南大学机械工程学院济南250022

目的针对AP2铝硅合金中相组织结构种类较为丰富的特点,通过化学刻蚀的方法,构建出层次丰富、耐腐蚀性强的超疏水表面结构。方法由于在不同刻蚀溶液中,所构建出的表面润湿性存在较大差距。因此采用正交设计的方法设计试验,找到最适宜的... 详细信息

目的针对AP2铝硅合金中相组织结构种类较为丰富的特点,通过化学刻蚀的方法,构建出层次丰富、耐腐蚀性强的超疏水表面结构。方法由于在不同刻蚀溶液中,所构建出的表面润湿性存在较大差距。因此采用正交设计的方法设计试验,找到最适宜的刻蚀浓度和反应时间。由于AP2铝硅合金中含量最多的Al与Si元素之间的固溶度低,NaOH溶液可以对主体α-Al相进行刻蚀,HCl溶液可以腐蚀Al、Cu、Mg、Si等元素形成的金属间相(IMPs)和共晶硅相,采用先碱后酸的刻蚀方法相比使用单一的刻蚀溶液推测能形成更丰富的触突结构。结果在0.25 mol/L NaOH溶液和9 mol/L HCl溶液中分别刻蚀60 s,在2%(质量分数)十七氟癸基三甲氧基硅烷(FAS-17)溶液表面改性的条件下,成功构建出了表面接触角为157°,滚动角为5.64°的超疏水表面。表面腐蚀电位由抛光后的−1.282 V提高到了超疏水表面制备完成后的–1.228 V,腐蚀速率由抛光后的1.07×10^(–4)A/cm^(2)降低到7.44×10^(–5)A/cm^(2),耐腐蚀性显著提高。结论制备的超疏水表面的耐腐蚀性有显著提高,为亚共晶铝硅合金材料在超疏水方向的应用提供了一定的参考。

关键词：铝硅合金先碱后酸超疏水化学刻蚀耐腐蚀

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铜合金表面激光制备Ni60-WC-Cu涂层的显微组织与摩擦磨损性能

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中国有色金属学报 2024年第4期34卷 1252-1267页

作者：张振宇王守仁王高琦段旭楠赵鹏杨海宁济南大学机械工程学院济南250022

激光熔覆涂层是解决铜合金零件因摩擦磨损导致失效的一种方法,但铜合金由于其对激光能量的高反射性、高导热性,使得在铜合金表面进行激光制备涂层成为一个难题。本文在白铜基体表面制备了不同WC含量的Ni60-WC-Cu复合涂层,对涂层相结构... 详细信息

激光熔覆涂层是解决铜合金零件因摩擦磨损导致失效的一种方法,但铜合金由于其对激光能量的高反射性、高导热性,使得在铜合金表面进行激光制备涂层成为一个难题。本文在白铜基体表面制备了不同WC含量的Ni60-WC-Cu复合涂层,对涂层相结构、微观形貌和显微硬度进行分析,并通过摩擦磨损试验,研究了涂层的耐磨性及磨损机理。结果表明:涂层中的相主要为NiW,其峰值随着WC含量的增加而增大;WC含量在20%与25%时观察到熔覆区出现大量的胞晶、枝晶组织,涂层顶部出现团聚状硬质相;涂层硬度均高于基体,WC含量为25%涂层的平均硬度为908.4HV;涂层耐磨性优于铜合金基体,随着WC含量增加,涂层耐磨性逐渐提高并均优于基体,氧化磨损、疲劳磨损和磨粒磨损;WC含量为25%时,涂层表现出最好的耐腐蚀性能;WC含量为20%时,表现出良好的导电率。

关键词：激光熔覆铜合金复合涂层显微组织摩擦磨损

苜蓿皂苷提取物对断奶湖羊免疫、抗氧化能力和瘤胃微生物区系的影响

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中国畜牧兽医 2024年第7期51卷 2799-2809页

作者：张艳马森栗守仁皇甫卫康腊邵凯马季祥王志昌史莹华河南农业大学动物科技学院郑州450002 河南省草地资源创新与利用重点实验室郑州450002 河南省牧草工程技术研究中心郑州450002

【目的】苜蓿皂苷作为一类天然生物活性物质,具有提高畜禽机体免疫力、促生长及调节胃肠道功能等多方面效用。试验旨在探究苜蓿皂苷提取物对断奶湖羊生长性能、免疫功能、抗氧化能力和瘤胃微生物区系的影响。【方法】选取45日龄、体重相... 详细信息

【目的】苜蓿皂苷作为一类天然生物活性物质,具有提高畜禽机体免疫力、促生长及调节胃肠道功能等多方面效用。试验旨在探究苜蓿皂苷提取物对断奶湖羊生长性能、免疫功能、抗氧化能力和瘤胃微生物区系的影响。【方法】选取45日龄、体重相近(15.67 kg±1.18 kg)的断奶湖羊32只,随机分为2组,每组4个重复,每个重复4只羊。对照组(CON)湖羊饲喂基础饲粮,皂苷组(AS)湖羊在基础饲粮中添加2 g/kg(饲粮干物质基础)苜蓿皂苷提取物,预试期7 d,正试期60 d。试验结束后收集断奶湖羊瘤胃液测定微生物组成,采集颈静脉血用于测定血清免疫和抗氧化性能相关指标。【结果】(1)两组湖羊平均日增重(ADG)和料重比(F/G)均无显著差异(P>0.05)。(2)与对照组相比,皂苷组湖羊血清中免疫球蛋白(IgA、IgM)、抗炎因子白介素-10(IL-10)、CD4^(+)T细胞和CD4/CD8水平极显著或显著升高(P0.05)。(5)两组间湖羊Shannon指数、Simpson指数和主坐标分析(PCoA)均无明显差异;在属水平上,皂苷组湖羊瘤胃液中硫酸盐还原菌脱硫弧菌属(Desulfovibrio)和有益菌罗氏菌属(Roseburia)、凸腹真杆菌群(Eubacterium_ventriosum_group)等的相对丰度均显著高于对照组(P<0.05)。【结论】饲粮中添加苜蓿皂苷提取物可以影响断奶湖羊瘤胃微生物的组成,提高机体免疫和抗氧化能力,且一定程度上有利于机体健康。

关键词：断奶湖羊苜蓿皂苷提取物免疫功能抗氧化能力瘤胃微生物

基于分段压裂水平井的临兴区块煤层气开发数值模拟

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煤质技术 2024年第2期39卷 53-60页

作者：王小东张守仁吴见梁渝刘世奇皇凡生中联煤层气(山西)有限责任公司山西太原030000 中联煤层气有限责任公司北京100015 中国矿业大学江苏省煤基温室气体减排与资源化利用重点实验室江苏徐州221008 中国矿业大学碳中和研究院江苏徐州221008 中国矿业大学资源与地球科学学院江苏徐州221008

煤层气作为非常规天然气的重要组成部分,其高效开发技术已引起广泛关注,而水平井分段压裂技术是目前非常规天然气开发的关键技术之一,因而有必要对基于分段压裂水平井的区块煤层气开发进行数值模拟,以期提高煤层气的开发效果以及实现工... 详细信息

煤层气作为非常规天然气的重要组成部分,其高效开发技术已引起广泛关注,而水平井分段压裂技术是目前非常规天然气开发的关键技术之一,因而有必要对基于分段压裂水平井的区块煤层气开发进行数值模拟,以期提高煤层气的开发效果以及实现工艺优化。基于煤层气开发流固耦合数学模型,考虑煤储层中割理系统发育与分布,以临兴区块为研究对象,建立水平井分段压裂物理模型,开展煤层气储层压力与产能数值模拟,并对煤层压力变化以及产气效果影响因素进行分析。结果表明:水平井分段压裂开发煤层气在365 d左右可实现较远区域控制,且水平井井周压力较稳定。割理条数、裂缝参数的增加可提高煤层气的产气效果,但需考虑水平井分段压裂技术的开发成本以及井间干扰等因素的影响。基于分段压裂水平井的区块煤层气开发数值模拟模型可为实现煤层气高效开发的水平井分段压裂技术提供参考与指导。

关键词：煤层气水平井分段压裂数值模拟裂缝参数储层压力割理条数产气效果

TC4钛合金表面激光熔覆Ti-Al涂层研究

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山东科学 2024年第3期37卷 55-65页

作者：孙永烁温道胜钱春光张铭浩吕庆华张明远王守仁汪鑫伟济南大学机械工程学院山东济南250014 哈尔滨工业大学空间环境与物质科学研究院黑龙江哈尔滨150001

钛合金具有密度低、比强度高和耐腐蚀性强等优异性能,因而被广泛应用于航空航天中,钛合金使用占比成为衡量航空航天设备是否先进的标准之一。由于该合金硬度低、耐磨性差,因此微动磨损成为钛合金零件失效的重要原因之一。为了提高钛合... 详细信息

钛合金具有密度低、比强度高和耐腐蚀性强等优异性能,因而被广泛应用于航空航天中,钛合金使用占比成为衡量航空航天设备是否先进的标准之一。由于该合金硬度低、耐磨性差,因此微动磨损成为钛合金零件失效的重要原因之一。为了提高钛合金的抗微动磨损性能,采用激光熔覆技术在TC4钛合金表面制备涂层。实验结果表明,激光熔覆Ti-Al粉末能改善TC4钛合金硬度和耐磨性能。

关键词： TC4钛合金激光熔覆抗氧化耐磨涂层

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Coarse root spatial distribution determined using a ground-penetrating radar technique in a subtropical evergreen broad-leaved forest,China

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Science China(Life Sciences) 2013年第11期56卷 1038-1046页

作者： YAN Hui DONG XinLiang FENG Gang zhang shouren MUCCIARDI Anthony State Key Laboratory of Vegetation and Environmental Change Institute of Botany Chinese Academy of Sciences University of Chinese Academy of Sciences Inner Mongolia Forestry Monitoring and Planning Academy TreeRadar Inc. Silver Spring MD 20910 USA

Coarse roots play a critical role in forest ecosystems and both abiotic and biotic factors affect their spatial distribution.To some extent,coarse root density may reflect the quantity of root biomass and biotic competition in forests.However,using traditional methods(e.g.,excavation)to study coarse roots is challenging,because those methods are time-consuming and laborious.Furthermore,these destructive methods cannot be repeated in the same forests.Therefore,the discovery of non-destructive methods for root studies will be very significant.In this study,we used a ground-penetrating radar technique to detect the coarse root density of three habitats(ridge,slope and valley)and the dominant tree species(Castanopsis eyrei and Schima superba)in a subtropical forest.We found that(i)the mean of coarse root density for these three habitats was 88.04roots m–2,with roots being mainly distributed at depths of 0–40 cm.Coarse root densities were lower in deeper soils and in areas far from the trunk.(ii)Coarse root densities differed significantly among the three habitats studied here with slope habitat having the lowest coarse root density.Compared with S.superba,C.eyrei had more roots distributed in deeper soils.Furthermore,coarse roots with a diameter>3 cm occurred more frequently in the valleys,compared with root densities in ridge and slope habitats,and most coarse roots occurred at soil depths of 20–40 cm.(iii)The coarse root density correlated negatively with tree species richness at soil depths of 40–60 cm.The abundances of the dominant species,such as C.eyrei,Cyclobalanopsis glauca,Pinus massoniana,had significant impacts on coarse root density.(iv)The soil depth of 0–40 cm was the"basic distribution layer"for coarse roots since the majority of coarse roots were found in this soil layer with an average root density of 84.18 roots m–2,which had no significant linear relationships with topography,tree species richness,rarefied tree species richness and tree density.Significant relationships between coarse root density

关键词：探地雷达技术亚热带常绿阔叶林空间分布森林生态系统树种丰富度非生物因素中国根密度