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A supramolecular self-assembly material based on cucurbituril and cationic TPE as ultra-sensitive probe of energetic pentazolate salts

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Defence Technology（防务技术） 2024年第5期35卷 69-76页

作者： Boan Tang Jingxiang Zhong Shutao Wang shiyu Zhou Yongxing Tang wei Huang School of Chemistry and Chemical Engineering Nanjing University of Science and TechnologyNanjing 210094China

The successful synthesis of the pentazolate anion(cyclo-N-5)has been a great breakthrough in the field of energetic materials.However,the detection methods for these energetic materials based on the pentazolate anion are quite rare.Herein,two fluorescent probes for cyclo-N-5anion were designed.Sensor 1(TPE2N)was synthesized with a tetraphenylethylene functionalized by two cationic groups which can generate strong electrostatic interactions with pentazolate anion and result in specific fluorescent changes.Sensor 2 was designed based on sensor 1 and supramolecular cucurbit[7]uril(CB[7]).The unique structural features of CB[7]provide sites for the interaction between the cations and N-5anion in its cavity,which would generate a platform for the detection and enhance the recognition performance.Isothermal titration calorimetry(ITC)experiment and fluorescence titration experiment indicate the binding molar ratio between sensor 1 with CB[7]is 1:2.Both sensors display typical aggregation-induced emission(AIE)features and good water-solubility.The sensors demonstrate excellent sensitivity to pentazole hydrazine salt with high enhancement constant(sensor 1:1.34×10^(6);sensor 2:3.78×10^(6))and low limit of detection(LOD:sensor 1=4.33μM;sensor 2=1.54μM).The formation of an AIE-based supramolecular sensor effectively improves the sensitivity to N-5anion.In addition,the probes also have good selectivity of N-5anion salts.The research would shed some light on the design of novel fluorescent sensors to detect pentazolate-based molecules and provides an example of supramolecular chemistry combined with fluorescent probes.

关键词： Pentazolate anion Explosives detection Aggregation-induced emission(AIE) Host-guest interaction

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Enhancing pain modulation: the efficacy of synchronous combination of virtual reality and transcutaneous electrical nerve stimulation

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General Psychiatry 2023年第6期36卷 501-511页

作者： Yanzhi Bi Xu Liu Xiangyue Zhao shiyu wei Jingwei Li Faguang Wang Wenbo Luo Li Hu CAS Key Laboratory of Mental Health Institute of PsychologyChinese Academy of SciencesBeijingChina Department of Psychology University of Chinese Academy of SciencesBeijingChina Research Center of Brain and Cognitive Neuroscience Liaoning Normal UniversityDalianLiaoningChina School of Inteligent Manufacturing Wenzhou PolytechnicWenzhouZhejangChina Key Laboratory of Brain and Cognitive Neuroscience DalianLiaoningChina

Introduction Virtual reality(VR)and transcutaneous electrical nerve stimulation(TENS)have emerged as effective interventions for pain reduction.However,their standalone applications often yield limited analgesic effects,particularly in certain painful conditions.Aims Our hypothesis was that the combination of VR with TENS in a synchronous manner could produce the best analgesic effect among the four experimental conditions.Methods To address this challenge,we proposed a novel pain modulation strategy that synchronously combines VR and TENS,aiming to capitalise on both techniques'complementary pain modulation mechanisms.Thirty-two healthy subjects participated in the study and underwent three types of interventions:VR alone,a combination of VR with conventional TENS,and a combination of VR with synchronous TENS.Additionally,a control condition with no intervention was included.Perceived pain intensity,pain unpleasantness,positive and negativeaffect scores,and electroencephalographic(EEG)data were collected before and after the interventions.To delve into the potential moderating role of pain intensity on the analgesic efficacy of VR combined with synchronous TENS,we incorporated two distinct levels of painful stimuli:one representing mild to moderate pain(ie,low pain)and the other representing moderate to severe pain(ie,high pain).Results Our findings revealed that both combination interventions exhibited superior analgesic effects compared with the VR-alone intervention when exposed to low and high pain stimuli.Notably,the combination of VR with synchronous TENS demonstrated greater analgesic efficacy than the combination of VR with conventional TENS.EEG data further supported these results,indicating that both combination interventions elicited a greater reduction in event-related potential magnitude compared with the VR-alone intervention during exposure to low and high pain stimuli.Moreover,the synchronous combination intervention induced a more significant reduction in N2 amplitude than the VR-alone intervent

关键词： pain stimulation alone

基于相位调谐的旋转摆盘发动机驱动机构运动与受力分析

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机械工程学报 2024年第3期60卷 109-119页

作者：魏振航王世宇夏春花天津大学机械工程学院天津300350 天津大学机构理论与装备设计教育部重点实验室天津300350 天津市非线性动力学与控制重点实验室天津300350

旋转摆盘发动机具有结构紧凑和比功率大等优点,广泛应用于潜航器和鱼雷等军事装备中。利用坐标变换矩阵求得了摆盘轨迹、活塞位移和连杆摆角的解析表达式,揭示了斜轴夹角和摆盘半径等结构参数对摆盘运动和连杆摆角的影响规律。考虑活塞... 详细信息

旋转摆盘发动机具有结构紧凑和比功率大等优点,广泛应用于潜航器和鱼雷等军事装备中。利用坐标变换矩阵求得了摆盘轨迹、活塞位移和连杆摆角的解析表达式,揭示了斜轴夹角和摆盘半径等结构参数对摆盘运动和连杆摆角的影响规律。考虑活塞分布的空间对称性以及燃气压力变化的时间对称性,利用相位调谐原理分析了摆盘的受力特征,揭示了燃气压力谐波阶次和活塞个数对摆盘受力的影响规律。研究结果表明,摆盘边缘的运动轨迹呈球面“8”字形;由于连杆的空间摆动,活塞位移并非连杆大头位移沿活塞轴向的分量;通过调整活塞个数与燃气压力谐波阶次之间的组合关系,可平衡摆盘上的力或力矩。

关键词：摆盘发动机驱动机构运动规律受力分析相位调谐

Two-step continuous flow process of sodium tanshinone ⅡA sulfonate using a 3D circular cyclone-type microreactor

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Chinese Chemical Letters 2024年第1期35卷 290-294页

作者： Maolin Sun Chaoming Liang Liming Cao Yaguo Wang Jiasheng Yang shiyu Hou wei Yu Yueyue Ma Ruihua Cheng Jinxing Ye School of Biomedical and Pharmaceutical Sciences Guangdong University of TechnologyGuangzhou 510006China School of Pharmacy East China University of Science and TechnologyShanghai 200237China School of Chemical Engineering East China University of Science and TechnologyShanghai 200237China Shanghai No.1 Biochemical&Pharmaceutical Co. Ltd.Shanghai 200080China

A sustainable and practical process is presented for the direct synthesis of sodium tanshinone IIA sulfonate(STS).Our approach was inspired by the well-established and industrially applied batch synthetic route for STS production.We constructed a telescoped two-step continuous flow platform.This involved a continuous tanshinone IIA sulfonation and in-line salt formation.For the setup,we constructed a 3D circular cyclone-type microreactor using femtosecond laser micromachining.Compared to the 68%yield for 2 h in batch,the two-step continuous flow had an STS yield of 90%,achieved for a total residence time of<3.0 min under optimal conditions.The proposed continuous flow method vastly simplified the operation and improved procedural safety,while significantly reducing the required acid content and wastewater production.

关键词： Continuous flow Sodium tanshinone IIA sulfonate Cardiovascular Microreactor Green chemistry

变截面单元环状周期结构固有频率分裂规律研究

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机械工程学报 2024年第7期60卷 114-123页

作者：高楠王世宇夏春花魏振航天津大学机械工程学院天津300354 天津大学机构理论与装备设计教育部重点实验室天津300354 天津市非线性动力学与控制重点实验室天津300354

在实际工程应用中,环状周期结构往往存在变截面单元。针对因变截面单元周期特性而导致的固有频率分裂现象,基于力矩平衡关系,采用Hamilton原理建立一般性动力学模型。以贯穿孔为例,基于经典振动理论得到固有频率及其分裂规律。考虑分组... 详细信息

在实际工程应用中,环状周期结构往往存在变截面单元。针对因变截面单元周期特性而导致的固有频率分裂现象,基于力矩平衡关系,采用Hamilton原理建立一般性动力学模型。以贯穿孔为例,基于经典振动理论得到固有频率及其分裂规律。考虑分组模式拓扑构型,推导具体消除频率分裂的规则,深入分析贯穿孔的孔径、数量和位置等参数对频率及其分裂行为的影响。设计试件并搭建实验台验证理论模型的正确性和消除规则的有效性。研究结果表明:由于贯穿孔使局部质量和弯曲刚度同时减小,进而导致固有频率改变,增大孔径和数量使重频频率减小,使分裂频率的分裂程度增大;保持孔径的一致性和位置的对称性可有效消除分裂。该研究方法和结论可用于工程领域类似周期结构动力学问题的研究并指导结构的设计。

关键词：环状周期结构变截面单元固有频率分裂分组模式消除规则

财政政策对城乡不平等的影响——基于涉农贷款增量奖励政策的视角

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产业经济研究 2024年第2期 130-142页

作者：唐乐强微孙世玉首都经济贸易大学劳动经济学院北京100070 科学技术部科技人才交流开发服务中心调研与宣传处北京100045

城乡不平等是我国实现共同富裕面临的主要挑战。2009年,财政部发布了《财政县域金融机构涉农贷款增量奖励资金管理暂行办法》(以下简称涉农贷款增量奖励政策),建立了以财政资金为杠杆的激励机制,引导和激励县域金融机构加大涉农信贷投入... 详细信息

城乡不平等是我国实现共同富裕面临的主要挑战。2009年,财政部发布了《财政县域金融机构涉农贷款增量奖励资金管理暂行办法》(以下简称涉农贷款增量奖励政策),建立了以财政资金为杠杆的激励机制,引导和激励县域金融机构加大涉农信贷投入,统筹城乡协调发展。利用2004—2018年的省级面板数据和国泰安数据,借助交错型双重差分法估算了涉农贷款增量奖励政策对我国城乡不平等的影响。研究结果表明:(1)涉农贷款增量奖励政策的实施使得城乡收入不平等程度显著下降(泰尔指数下降0.012~0.014,城乡收入比下降11.5%~14.1%),且该效应在欠发达地区更为显著。(2)考虑到政策的动态效应,涉农贷款增量奖励政策实施时间越长,收入差距的缩小幅度越大。(3)涉农贷款增量奖励政策通过提高金融服务可及性、农户固定资产投资水平以及农村劳动力非农就业水平进而缓解城乡收入不平等。(4)涉农贷款增量奖励政策能有效缓解城乡消费不平等。通过实证分析,证实了涉农贷款增量奖励政策有助于缓解城乡收入不平等以及消费不平等,具有一定的政策启示意义。

关键词：涉农贷款增量奖励政策城乡收入不平等城乡消费不平等交错型双重差分法共同富裕

Efficient simultaneous removal of diesel particulate matter and hydrocarbons from diesel exhaust gas at low temperatures over Cu–CeO_(2)/Al_(2)O_(3)coupling with dielectric barrier discharge plasma

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Plasma Science and Technology 2024年第5期26卷 100-109页

作者：任保勇方世玉张甜甜孙燕高尔豪李晶吴祖良朱佳丽王伟姚水良 School of Safety Science and Engineering Changzhou UniversityChangzhou 213164People’s Republic of China School of Environmental Science and Engineering Changzhou UniversityChangzhou 213164People’s Republic of China Key Laboratory of Advanced Plasma Catalysis Engineering for China Petrochemical Industry Changzhou 213164People’s Republic of China

Diesel particulate matter(DPM)and hydrocarbons(HCs)emitted from diesel engines have a negative affect on air quality and human health.Catalysts for oxidative removal of DPM and HCs are currently used universally but their low removal efficiency at low temperatures is a problem.In this study,Cu-doped CeO_(2)loaded on Al_(2)O_(3)coupled with plasma was used to enhance low-temperature oxidation of DPM and HCs.Removals of DPM and HCs at 200℃using the catalyst were as high as 90%with plasma but below 30%without plasma.Operando plasma diffuse reflectance infrared Fourier transform spectroscopy coupled with mass spectrometry was conducted to reveal the functional mechanism of the oxygen species in the DPM oxidation process.It was found that Cu-CeO_(2)can promote the formation of adsorbed oxygen(M^(+)-O_(2)^(-))and terminal oxygen(M=O),which can react with DPM to form carbonates that are easily converted to gaseous CO_(2).Our results provide a practical plasma catalysis technology to obtain simultaneous removals of DPM and HCs at low temperatures.M+O-2Diesel particulate matter(DPM)and hydrocarbons(HCs)emitted from diesel engines have a negative affect on air quality and human health.Catalysts for oxidative removal of DPM and HCs are currently used universally but their low removal efficiency at low temperatures is a problem.In this study,Cu-doped Ce O2 loaded on Al2O3 coupled with plasma was used to enhance low-temperature oxidation of DPM and HCs.Removals of DPM and HCs at 200°C using the catalyst were as high as 90%with plasma but below 30%without plasma.Operando plasma diffuse reflectance infrared Fourier transform spectroscopy coupled with mass spectrometry was conducted to reveal the functional mechanism of the oxygen species in the DPM oxidation process.It was found that Cu–Ce O2 can promote the formation of adsorbed oxygen(–)and terminal oxygen(M=O),which can react with DPM to form carbonates that are easily converted to gaseous CO2.Our results provide a practical plasma catalysis technology to obtain simultaneous

关键词： diesel PM plasma catalysis Cu-CeO2/Al2O3 DRIFTS-MS synergy effect

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基于微更新理念的上海公共电话亭再设计

包装工程 2024年第4期45卷 317-325页

作者：丁伟陆诗雨章彰华东理工大学艺术设计与传媒学院上海200237

目的以上海新华街道为研究对象,对微更新理念下大型城市的社区公共设施进行设计重构,以期提升其利用率。方法利用Citespace对社区微更新的研究现状进行分析,以PSPL法为指导理论进行具体实践调研,发现现存痛点,通过问卷、访谈等方式搜... 详细信息

目的以上海新华街道为研究对象,对微更新理念下大型城市的社区公共设施进行设计重构,以期提升其利用率。方法利用Citespace对社区微更新的研究现状进行分析,以PSPL法为指导理论进行具体实践调研,发现现存痛点,通过问卷、访谈等方式搜集相关需求后,使用TOPSIS法将设计需求定量分析得出亟待解决的需求,为设计重构提供依据,以实现老旧公共设施再造、提高居民生活质量的目的。结果基于Citespace得出目前我国社区微更新领域的研究趋向于公共设施,而上海新华街道的公共设施以公共电话亭为代表,具有使用率低的痛点,通过TOPSIS分析得出居民对其改造的6点需求,从外观和功能上对公共电话亭进行再设计。结论结合社区微更新理念和居民的需求对新华街道老旧公共电话亭进行再设计,有助于保留街道特色、提高老旧公共设施的利用率,具有一定的价值,对公共设施设计重构和微更新理念的结合有借鉴意义。

关键词：微更新公共设施公共电话亭 Citespace PSPL TOPSIS

Real-time monitoring system for quality monitoring of jujube slice during drying process

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International Journal of Agricultural and Biological Engineering 2022年第3期15卷 234-241页

作者： Yuxue Cao Xuedong Yao Yongzhen Zang Yubao Niu Hongwei Xiao Huan Liu Rongguang Zhu Xia Zheng Qiang Wang Xiangnan Zhang shiyu wei College of Mechanical and Electrical Engineering Shihezi UniversityShihezi 832000XinjiangChina Key Laboratory of Northwest Agricultural Equipment Ministry of Agriculture and Rural AffairsShihezi 832000XinjiangChina Key Laboratory of Modern Agricultural Machinery Corps Shihezi 832000XinjiangChina College of Engineering China Agricultural UniversityBeijing 100083China College of Mechanical Engineering and Automation Northeastern UniversityShenyang 110819China

The real-time monitoring and prediction system for quality attributes of jujube slices during the drying process was designed to solve the problem of destructive and inconvenient of the traditional quality detection method and realize quality online monitoring.Firstly,machine vision and automatic weighing were employed to monitor the color and moisture content changes of jujube slices in real-time.Secondly,correlation models between color parameter(a^(*)value)and nutritional quality attributes(vitamin C,reducing sugar)were established to predict vitamin C and reducing sugar content of jujube slices during the drying process.Finally,the upper computer monitoring software was integrated and designed based on LABVIEW virtual instrument,and the real-time monitoring system was tested and validated.Results showed that:the changing trends of color(L^(*),a^(*),and b^(*)values)monitored by the system were basically the same as the results detected by color difference meter,and the average errors of L^(*),a^(*),and b^(*)values were 0.93,0.52,and 0.73,respectively.The average relative error of moisture content between the system monitoring and manual static detection was 0.18%.The average error of vitamin C and reducing sugar content between the system prediction and manual detection were 50 mg/100 g in dry basis and 0.71g/100 g in dry basis,respectively.The current work can provide a useful reference for real-time monitoring of quality attributes of fruits and vegetables during the drying process.

关键词： jujube slice quality attributes real-time monitoring system drying process