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Redox Charge Transfer Kinetics and Reversibility of VO_(2) in Aqueous and Non-Aqueous Electrolytes of Na-Ion Storage

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Energy & Environmental Materials 2022年第4期5卷 1222-1228页

作者： Sul Ki park Kang Ho shin Puritut Nakhanivej Harpalsinh H.Rana Ho Seok park School of Chemical Engineering College of EngineeringSungkyunkwan University2066Seobu-roJangan-guSuwon-si Gyeonggi-do 440-746Republic of Korea Department of Engineering University of CambridgeCambridge CB30FSUK Department of Health Sciences and Technology Samsung Advanced Institute for Health Sciences and Technology(SAIHST)Sungkyunkwan University2066SeoburoJangan-guSuwon 440-746South Korea SKKU Advanced Institute of Nano Technology(SAINT) Sungkyunkwan University2066SeoburoJangan-guSuwon 440-746South Korea

The deep understanding about the electrochemical behavior of the nanostructured electrode in electrolytes provides crucial insights for the rational design of electrode for sodium(Na)-ion storage system(NIS).Here,we report redox charge transfer kinetics and reversibility of VO_(2)(B) nanorod electrodes in both aqueous and organic electrolytes for *** assynthesized VO_(2)(B) nanorods show the reversible redox reaction with the higher specific and rate capacitances at high current density in aqueous electrolytes than in organic ***-dependent impedance measurements demonstrate the more facile interfacial charge transfer of Na ions into VO_(2)(B) nanorods in aqueous *** reversible evolution in oxidation state and chemical composition of VO_(2)(B) nanorods is observed in aqueous electrolytes,as confirmed by ex situ XRD and ex situ X-ray photoelectron spectroscopy *** by the facile and reversible pseudocapacitive feature,the electrochemical performances of VO_(2)(B) nanorods are further improved by constructing the hierarchical structure of the reduced graphene oxide-VO_(2) composite for aqueous Na+ion storage.

关键词： aqueous electrolyte energy storage mechanism hierarchical structure nanorod sodium ion storage

Blockchain-Based Secure and Fair IoT Data Trading System with Bilateral Authorization

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Computers, Materials & Continua 2023年第8期76卷 1871-1890页

作者： Youngho park Mi Hyeon Jeon Sang Uk shin Electronics and Information Communications Research Center Pukyong National UniversityBusanKorea Department of Information Security Graduate SchoolPukyong National UniversityBusanKorea Division of Computer Engineering Pukyong National UniversityBusanKorea

These days,data is regarded as a valuable asset in the era of the data economy,which demands a trading platform for buying and selling ***,online data trading poses challenges in terms of security and fairness because the seller and the buyer may not fully trust each ***,in this paper,a blockchain-based secure and fair data trading system is proposed by taking advantage of the smart contract and matchmaking *** proposed system enables bilateral authorization,where data trading between a seller and a buyer is accomplished only if their policies,required by each other,are satisfied *** can be achieved by exploiting the security features of the matchmaking *** guarantee non-repudiation and fairness between trading parties,the proposed system leverages a smart contract to ensure that the parties honestly carry out the data trading ***,the smart contract in the proposed system does not include complex cryptographic operations for the efficiency of onchain ***,these operations are carried out by off-chain parties and their results are used as input for the on-chain *** system also uses an arbitration protocol to resolve disputes based on the trading proof recorded on the *** performance of the protocol is evaluated in terms of off-chain computation overhead and on-chain gas *** results of the experiments demonstrate that the proposed protocols can enable the implementation of a cost-effective data trading system.

关键词： Bilateral authorization blockchain data marketplace fair exchange policy matching secure data trading

Mechanical and electrical properties of In-Bi solder at Bi_(2212) superconductor interface with annealed Ag spray layers and Ag precoating layers

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中国有色金属学会会刊：英文版 2009年第4期19卷 961-964页

作者： Seung-Yong shin Ji-Hyun LEE Hai-Woong park Department of Materials Engineering Korea University of Technology and Education(KUT)

The electrical properties of solder contact layers between Cu-Ni shunt metal and tube type Bi2212 superconductor that is applied in superconducting fault current limiter were *** contact properties of the solders are improved not only by Ag precoating layers,but also by the pre-sprayed Ag layer and subsequent Ag precoating *** annealed Ag sprayed layers onto Bi2212 superconductor prior to Ag electroplating work as protecting layers for the superconductor from plating *** contact angle of the electroplated Ag layer is 42.91° and decreases to 15.25° and 5.88° with Ag sprayed layer and additional Ag electroplated *** Ag sprayed layer with suitable annealing prior to Ag electroplating improves contact strength of the Ag electroplated layer by about 12% due to denser microstructure of the Ag electroplated layers.

关键词：超导故障限流器 Bi2212 电镀银电气性能喷涂层预涂层退火焊料

M1-polarized macrophage-derived cellular nanovesicle-coated lipid nanoparticles for enhanced cancer treatment through hybridization of gene therapy and cancer immunotherapy

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Acta Pharmaceutica Sinica B 2024年第7期14卷 3169-3183页

作者： Ha Eun shin Jun-Hyeok Han Seungyong shin Ga-Hyun Bae Boram Son Tae-Hyung Kim Hee Ho park Chun Gwon park Wooram park Department of Integrative Biotechnology Sungkyunkwan University(SKKU)SuwonGyeonggi 16419Republic of Korea Deparment of Inteligent Precision Healthcare Convergence SKKUSuwonGyeonggi 16419Republic of Korea Department of MetaBioHealth SKKU Institute for ConvergenceSKKUSuwonGyeonggi 16419Republic of Korea Department of Bioengineering Hanyang UniversitySeoul 04763Republic of Korea Department of Integrative Engineering Chung-Ang UniversitySeoul 06974Republic of Korea Department of Biomedical Engineering SKKUSuwonGyeonggi 16419Republic of Korea Korea Institute of Science and Technology(KIST) Seoul 02792Republic of Korea

Optimum genetic delivery for modulating target genes to diseased tissue is a major obstacle for profitable gene *** nanoparticles(LNPs),considered a prospective vehicle for nucleic acid delivery,have demonstrated efficacy in human use during the COVID-19 *** study introduces a novel biomaterial-based platform,M1-polarized macrophage-derived cellular nanovesicle-coated LNPs(M1-C-LNPs),specifically engineered for a combined gene-immunotherapy approach against solid *** dual-function system of M1-C-LNPs encapsulates Bcl2-targeting siRNA within LNPs and immune-modulating cytokines within M1 macrophage-derived cellular nanovesicles(M1-NVs),effectively facilitating apoptosis in cancer cells without impacting T and NK cells,which activate the intratumoral immune response to promote granule-mediating killing for solid tumor *** retention within tumor was observed upon intratumoral administration of M1-C-LNPs,owing to the presence of adhesion molecules on M1-NVs,thereby contributing to superior tumor growth *** findings represent a promising strategy for the development of targeted and effective nanoparticle-based cancer genetic-immunotherapy,with significant implications for advancing biomaterial use in cancer therapeutics.

关键词： Genetic-immunotherapy M1 macrophage-derived cellular nanovesicles Lipid nanoparticles(LNPs) Gene therapy siRNA Cancer immunotherapy Solid tumor Tumor microenvironment(TME)

Clinical importance and surgical decision-making regarding proximal resection margin for gastric cancer

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World Journal of Gastrointestinal Oncology 2013年第1期5卷 4-11页

作者： Doosup shin Sung-Soo park Department of Surgery Korea University College of Medicine Division of Upper GI Surgery Department of SurgeryKorea University College of MedicineMIS and Robotic Surgery Center Korea University Medical Center Korea University Anam Hospital

Because of the intramural spread of gastric cancer,a sufficient length of a resection margin has to be attained to ensure complete excision of the *** has been debate on an adequate length of proximal resection margin(PRM) and its related ***,the objective of this article is to review several studies on PRM and to summarize the current evidence on the *** there is some discrepancy in the recommended values for PRM between authors,a PRM of more than 2-3 cm for early gastric cancer and 5-6 cm for advanced gastric cancer is thought to be *** the margin is confirmed to be clear,however,the length of PRM measured in postoperative pathologic examination does not affect the patient's survival,even when it is shorter than the recommended ***,the recommendations for PRM length should be applied only to intraoperative decision-making to prevent positive margins on the final *** that a negative resection margin is the ultimate goal of determining an adequate PRM,development and improvement of reliable methods to confirm a negative resection margin intraoperatively would minimize the extent of surgery and offer a better quality of life to more *** the same context,special attention has to be paid to patients who have advanced stage or diffuse-type gastric cancer,because they are more likely to have a positive ***,a wider excision with intraoperative frozen section(IFS) examination of the resection margin is *** all the attempts to avoid positive margins,there is still a certain rate of positive-margin *** the negative impact of a positive margin on prognosis is mostly obvious in low N stage patients,aggressive further management,such as extensive re-operation,is required for these *** conclusion,every possible preoperative and intraoperative evaluation should be thoroughly carried out to identify in advance the patients with a high risk of having positive margins;the

关键词： Resection margin Proximal resection margin Negative resection margin Positive resection margin Gastrectomy Gastric cancer

Comprehensive analysis of two-dimensional charge transport mechanism in thin-film transistors based on random networks of single-wall carbon nanotubes using transient measurements

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Nano Research 2022年第2期15卷 1524-1531页

作者： Hyeonwoo shin Sang-Joon park Byeong-Cheol Kang Tae-Jun Ha Department of Electrical Engineering and Computer Science Inter-university Semiconductor Research CenterSeoul National UniversitySeoul 08826Korea Department of Electronic Materials Engineering Kwangwoon UniversitySeoul 01897Korea

Understanding charge transport mechanisms in thin-film transistors based on random networks of single-wall carbon nanotubes(SWCNT-TFTs)is essential for further advances to improve the potential for various nanoelectronic ***,a comprehensive investigation of the two-dimensional(2D)charge transport mechanism in SWCNT-TFTs is reported by analyzing the temperature-dependent electrical characteristics determined from the direct-current and non-quasi-static transient measurements at 80-300 *** elucidate the time-domain charge transport characteristics of the random networks in the SWCNTs,an empirical equation was derived from a theoretical trapping model,and a carrier velocity distribution was determined from the differentiation of the transient ***,charge trapping and de-trapping in shallow-and deep-traps in SWCNT-TFTs were analyzed by investigating charge transport based on their trapping/de-trapping *** comprehensive analysis of this study provides fundamental insights into the 2D charge transport mechanism in TFTs based on random networks of nanomaterial channels.

关键词： single-wall carbon nanotube random networks two-dimensional(2D)charge transport time-domain transient measurements charge trapping/de-trapping shallow-/deep-traps

Evaluating the environmental efficiency of the *** industry using a directional distance function DEA approach

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Journal of Management Analytics 2021年第1期8卷 1-18页

作者： Yuan Xu Yong shin park Ju Dong park Wonjoo Cho Department of Transportation Logisticsand FinanceCollege of BusinessNorth Dakota State UniversityFargoNDUSA Department of Marketing Operationsand AnalyticsBill Munday School of BusinessSt.Edward’s UniversityAustinTXUSA Department of Maritime Police and Production System Gyeongsang National UniversityTongyeong-siGyeongsangnam-doRepublic of Korea Department of Environment and Resource Research Korea Rural Economic InstituteNaju-siJeollanam-doRepublic of Korea

This study applies a directional distance function(DDF)data envelopment analysis(DEA)model to measure the environmental efficiency of 12 *** 2013–2016 by considering flight delay and greenhouse gas(GHG)emissions as joint undesirable ***,the environmental efficiency of airlines is compared using the CCR DEA(without flight delay)and DDF DEA(with flight delay).We find that several airlines experienced substantial changes in environmental efficiency scores when flight delay is ***,a tobit regression is used to explore whether the environmental factors of fleet age,ownership type,freight traffic,market share,and carrier type affect airlines’environmental *** results demonstrate that all of these factors significantly influence airline performance.

关键词： Airline environmental efficiency directional distance function DEA airline sustainability tobit regression

Nanograin network memory with reconfigurable percolation paths for synaptic interactions

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Light(Science & Applications) 2023年第6期12卷 1040-1050页

作者： hoo-Cheol Lee Jungkil Kim Ha-Reem Kim Kyoung-Ho Kim Kyung-Jun park Jae-Pil So Jung Min Lee Min-Soo Hwang Hong-Gyu park Department of Physics Korea UniversitySeoul 02841Republic of Korea Department of Physics Jeju National UniversityJeju 63243Republic of Korea Department of Physics Chungbuk National UniversityCheongju 28644Republic of Korea

The development of memory devices with functions that simultaneously process and store data is required for efficient *** achieve this,artificial synaptic devices have been proposed because they can construct hybrid networks with biological neurons and perform neuromorphic ***,irreversible aging of these electrical devices causes unavoidable performance *** several photonic approaches to controlling currents have been suggested,suppression of current levels and switching of analog conductance in a simple photonic manner remain ***,we demonstrated a nanograin network memory using reconfigurable percolation paths in a single Si nanowire with solid core/porous shell and pure solid core *** electrical and photonic control of current percolation paths enabled the analog and reversible adjustment of the persistent current level,exhibiting memory behavior and current suppression in this single nanowire *** addition,the synaptic behaviors of memory and erasure were demonstrated through potentiation and habituation *** habituation was achieved using laser illumination on the porous nanowire shell,with a linear decrease in the postsynaptic ***,synaptic elimination was emulated using two adjacent devices interconnected on a single ***,electrical and photonic reconfiguration of the conductive paths in Si nanograin networks will pave the way for next-generation nanodevice technologies.

关键词： electrical percolation network

Preparation of human decellularized peripheral nerve allograft using amphoteric detergent and nuclease

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Neural Regeneration Research 2021年第9期16卷 1890-1896页

作者： Joo-Yul Bae Suk Young park Young Ho shin shin Woo Choi Jae Kwang Kim Department of Orthopedic Surgery University of Ulsan College of MedicineGangneung Asan HospitalGangneung-siKorea Department of Orthopedic Surgery University of Ulsan College of MedicineAsan Medical CenterSeoulKorea

Animal studies have shown that amphoteric detergent and nuclease(DNase I and ribonuclease A) is the most reliable decellularization method of the peripheral nerve. However, the optimal combination of chemical reagents for decellularization of human nerve allograft needs further investigation. To find the optimal protocol to remove the immunogenic cellular components of the nerve tissue and preserve the basal lamina and extracellular matrix and whether the optimal protocol can be applied to larger-diameter human peripheral nerves, in this study, we decellularized the median and sural nerves from the cadavers with two different methods: nonionic and anionic detergents(Triton X-100 and sodium deoxycholate) and amphoteric detergent and nuclease(3-[(3-cholamidopropyl)dimethylammonio]-1-propanesulfonate(CHAPS), deoxyribonuclease I, and ribonuclease A). All cellular components were successfully removed from the median and sural nerves by amphoteric detergent and nuclease. Not all cellular components were removed from the median nerve by nonionic and anionic detergent. Both median and sural nerves treated with amphoteric detergent and nuclease maintained a completely intact extracellular matrix. Treatment with nonionic and anionic detergent decreased collagen content in both median and sural nerves, while the amphoteric detergent and nuclease treatment did not reduce collagen content. In addition, a contact cytotoxicity assay revealed that the nerves decellularized by amphoteric detergent and nuclease was biocompatible. Strength failure testing demonstrated that the biomechanical properties of nerves decellularized with amphoteric detergent and nuclease were comparable to those of fresh controls. Decellularization with amphoteric detergent and nuclease better remove cellular components and better preserve extracellular matrix than decellularization with nonionic and anionic detergents, even in large-diameter human peripheral nerves. In Korea, cadaveric studies are not yet l

关键词： median nerve sural nerve nuclease detergent human decellularized nerve graft