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Modification strategies for non-aqueous, highly proton-conductive benzimidazole-based high-temperature proton exchange membranes

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Chinese Chemical Letters 2024年第4期35卷 43-51页

作者： Yunfa Dong shijie zhong Yuhui He Zhezhi Liu Shengyu Zhou Qun Li Yashuai Pang Haodong Xie Yuanpeng Ji Yuanpeng Liu Jiecai Han Weidong He National Key Laboratory of Science and Technology on Advanced Composites in Special Environments and Center for Composite Materials and StructuresHarbin Institute of TechnologyHarbin 150080China School of Petroleum Engineering Chongqing University of Science and TechnologyChongqing 401331China School of Physics University of Electronic Science and Technology of ChinaChengdu 610054China MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage School of Chemistry and Chemical EngineeringHarbin Institute of TechnologyHarbin 150001China Chongqing Research Institute Harbin Institute of TechnologyChongqing 401151China School of Mechanical Engineering Chengdu UniversityChengdu 610106China

High-temperature proton exchange membranes(HT-PEMs) possess excellent thermal and outstanding electrochemical stability, providing an avenue to realize high-temperature proton exchange membranes fuel cells(HT-PEMFCs) with both superior power density and long-term durability. Unfortunately, polybenzimidazole(PBI), a typical material for conventional HT-PEMs, fails to compromise the high nonaqueous proton conductivity and high mechanical properties, thus hindering their practical applications.Achieving efficient nonaqueous proton conduction is crucial for HT-PEMFC, and many insightful research works have been done in this area. However, there still lacks a report that integrates the host-guest interactions of phosphoric acid doping and the structural stability of polymers to systematically illustrate modification strategies. Here, we summarize recent advancements in enhancing the nonaqueous proton conduction of HT-PEMs. Various polymer structure modification strategies, including main chain and side group modification, cross-linking, blocking, and branching, are reviewed. Composite approaches of polymer, including compounding with organic porous polymers, filling the inorganic components and modifying with ionic liquids, etc., are also covered in this work. These strategies endow the HT-PEMs with more free volume, nanophase-separated structure, and multi-stage proton transfer channels, which can facilitate the proton transportation and improve their performance. Finally, current challenges and future directions for further enhancements are also outlined.

关键词： Benzimidazole Nonaqueous proton conduction Free volume Nanophase-separated structure Structure modification

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Novel CoP/CoMoP_(2) heterojunction with nanoporous structure as an efficient electrocatalyst for hydrogen evolution

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Nano Research 2024年第5期17卷 3693-3699页

作者： Lili Zhang Xinxing Shi Aijiao Xu Wenwu zhong Jitang Zhang shijie Shen Zhejiang Provincial Key Laboratory for Cutting Tools Taizhou UniversityJiaojiang 318000China

The exploration of new heterojunction materials is of great significance in reducing the cost of existing noble metal catalysts and thus realizing the large-scale application of electrocatalytic hydrolysis technology.Herein,a novel CoP/CoMoP_(2) heterojunction was synthesized and served as a hydrogen evolution reaction(HER)electrocatalyst.The heterojunction has morphology of nanoporous structure,which is conducive to exposing more active sites and facilitating bubbles transport.The charge distribution is optimized by a strong interface interaction between CoP and CoMoP_(2).The catalyst’s conductivity and the adsorption properties of the intermediates have both been enhanced.CoP/CoMoP_(2) demonstrates excellent HER activity with an overpotential of 93.6 mV at 10 mA∙cm^(-2),which is competitive with the reported performance of analogous electrocatalysts.This work provides insights into the development of innovative phosphide-based heterojunction electrocatalysts.

关键词： nanoporous CoP CoMoP_(2) heterojunction hydrogen evolution reaction

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Electrolyte Engineering for High-Voltage Lithium Metal Batteries

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Research 2022年第4期2022卷 781-832页

作者： LiweiDong shijie zhong Botao Yuan Yuanpeng Ji Jipeng Liu Yuanpeng Liu Chunhui Yang Jiecai Han Weidong He MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage School of Chemistry and Chemical EngineeringHarbin Institute of TechnologyHarbin 150080China National Key Laboratory of Science and Technology on Advanced Composites in Special Environments and Center for Composite Materials and Structures Harbin Institute of TechnologyHarbin 150080China State Key Laboratory of Urban Water Resource and Environment Harbin Institute of TechnologyHarbin 150080China Chongqing Research Institute Harbin Institute of TechnologyChongqing 401151China School of Mechanical Engineering Chengdu UniversityChengdu610106China

High-voltage lithium metal batteries(HVLMBs)have been arguably regarded as the most prospective solution to ultrahigh-density energy storage devices beyond the reach of current technologies.Electrolyte,the only component inside the HVLMBs in contact with both aggressive cathode and Li anode,is expected to maintain stable electrode/electrolyte interfaces(EEIs)and facilitate reversible Li+transference.Unfortunately,traditional electrolytes with narrow electrochemical windows fail to compromise the catalysis of high-voltage cathodes and infamous reactivity of the Li metal anode,which serves as a major contributor to detrimental electrochemical performance fading and thus impedes their practical applications.Developing stable electrolytes is vital for the further development of HVLMBs.However,optimization principles,design strategies,and future perspectives for the electrolytes of the HVLMBs have not been summarized in detail.This review first gives a systematical overview of recent progress in the improvement of traditional electrolytes and the design of novel electrolytes for the HVLMBs.Different strategies of conventional electrolyte modification,including high concentration electrolytes and CEI and SEI formation with additives,are covered.Novel electrolytes including fluorinated,ionic-liquid,sulfone,nitrile,and solid-state electrolytes are also outlined.In addition,theoretical studies and advanced characterization methods based on the electrolytes of the HVLMBs are probed to study the internal mechanism for ultrahigh stability at an extreme potential.It also foresees future research directions and perspectives for further development of electrolytes in the HVLMBs.

关键词： electrolyte maintain summarized

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Corrosion behavior of HVOF Inconel 625 coating in the simulated marine environment

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China Welding 2024年第1期33卷 46-51页

作者：彭超钟丰平袁梦谢世杰王学斌 National Quality Inspection and Testing Center of Special Metal Structural Materials Zhejiang Academy of Special Equipment ScienceHangzhou 310020China Key Laboratory of Special Equipment Safety Testing Technology of Zhejiang Province Hangzhou 310020China Zhejiang-Ukraine Joint Laboratory for Materials and Welding Testing Technology Hangzhou 310020China

High velocity oxygen fuel(HVOF)spraying process is commonly used to produce superalloy coatings.Inconel 625 coating was prepared on Q235B low carbon steel by HVOF.A series of experiments were conducted to examine the surface and corrosion resistance properties of Inconel 625 HVOF coating.In this paper,potentiodynamic polarization tests and electrochemical impedance spectroscopy(EIS)tests were carried out to evaluate the corrosion resistance of Inconel 625 coating under simulated marine environment.The experiment-al results showed that Inconel 625 coating revealed low porosity and desired coating thickness.Shift in the corrosion potential(E_(corr))to-wards the noble direction combined with much low corrosion current density(i_(corr))indicating a significant improvement of HVOF Inconel 625 coating compared with the substrate.

关键词： high velocity oxygen fuel(HVOF) Inconel 625 coating marine environment corrosion

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从废旧电池中直接提取锂实现锂的高效回收

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Science Bulletin 2024年第11期69卷 1697-1705页

作者：刘威刘猛闯马纷纷覃明盛钟伟陈忻曾子琪程时杰谢佳 State Key Laboratory of Advanced Electromagnetic Technology School of Electrical and Electronic EngineeringHuazhong University of Science and TechnologyWuhan 430074China State Key Laboratory of Materials Processing and Die&Mould Technology School of Materials Science and EngineeringHuazhong University of Science and TechnologyWuhan 430074China School of Chemistry and Chemical Engineering Huazhong University of Science and TechnologyWuhan 430074China GuSu Laboratory of Materials Suzhou 215123China Suzhou Laboratory Suzhou 215123China

The flourishing expansion of the lithium-ion batteries(LIBs) market has led to a surge in the demand for lithium resources. Developing efficient recycling technologies for imminent large-scale retired LIBs can significantly facilitate the sustainable utilization of lithium resources. Here, we successfully extract active lithium from spent LIBs through a simple, efficient, and low-energy-consumption chemical leaching process at room temperature, using a solution comprised of polycyclic aromatic hydrocarbons and ether solvents. The mechanism of lithium extraction is elucidated by clarifying the relationship between the redox potential and extraction efficiency. More importantly, the reclaimed active lithium is directly employed to fabricate LiFePO_(4) cathode with performance comparable to commercial materials. When implemented in 56 Ah prismatic cells, the cells deliver stable cycling properties with a capacity retention of ~90% after 1200 cycles. Compared with the other strategies, this technical approach shows superior economic benefits and practical promise. It is anticipated that this method may redefine the recycling paradigm for retired LIBs and drive the sustainable development of industries.

关键词： Retired lithium-ion batteries Lithium recycling Chemical leaching Active lithium Lithium iron phosphate

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川渝地区青花椒的麻感特性分析

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食品科学 2024年第12期45卷 187-193页

作者：高露赵镭史波林汪厚银钟葵闫师杰中国标准化研究院农业食品标准化研究所北京102200 天津农学院食品科学与生物工程学院天津市主要农作物智能育种重点实验室天津300392

采用感官时间-强度法和高效液相色谱法对川渝地区7种青花椒原料的椒麻感官特征以及主要麻味物质组成及含量进行测定,并通过偏最小二乘回归(partial least squares regression,PLSR)对麻味物质组成含量及感官特性进行关联性分析。结果表... 详细信息

采用感官时间-强度法和高效液相色谱法对川渝地区7种青花椒原料的椒麻感官特征以及主要麻味物质组成及含量进行测定,并通过偏最小二乘回归(partial least squares regression,PLSR)对麻味物质组成含量及感官特性进行关联性分析。结果表明:青花椒的麻感具有先快速上升后缓慢下降的特征,100 s左右达到最大麻感强度。不同样品之间酰胺含量差异较大,含量分布范围为5505.77~8639.30 mg/100 g。PLSR结果表明青花椒麻感特性与酰胺物质组成关联密切,最大感官强度、持续时间(T_(tot))、曲线下面积与羟基-α-山椒素呈强正相关性,T_(tot)与羟基-ε-山椒素和羟基-β-山椒素呈强正相关性。不同产地青花椒在麻感特性和酰胺组成上存在差异,羟基-α-山椒素和花椒油素是不同青花椒样品麻感特性差异的关键物质。本研究旨在为后期川渝地区青花椒麻感品质评价提供基础数据参考和科学依据。

关键词：川渝地区青花椒麻味物质感官特性

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基于网络效率的城市轨道交通网络抗震韧性评估

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清华大学学报（自然科学版） 2024年第3期64卷 509-519页

作者：侯本伟游丹范世杰许成顺钟紫蓝北京工业大学城市建设学部北京100124

该文基于震后轨道交通网络主体结构的破坏场景,以恢复震后通行能力为目标,分析了地震灾害作用下城市轨道交通网络的韧性。采用Space L方法构建轨道交通网络模型,选用客流加权的网络平均效率表示网络连通性能。采用地震易损性模型计算网... 详细信息

该文基于震后轨道交通网络主体结构的破坏场景,以恢复震后通行能力为目标,分析了地震灾害作用下城市轨道交通网络的韧性。采用Space L方法构建轨道交通网络模型,选用客流加权的网络平均效率表示网络连通性能。采用地震易损性模型计算网络主要结构单元(车站、隧道和桥梁)的破坏概率,采用Monte Carlo方法模拟网络主体结构单元的震后状态;考虑破坏单元修复时间存在不确定性,模拟了破坏单元的震后修复过程;根据震后不同时刻网络性能曲线和韧性三角形,定量化评估轨道交通网络抗震韧性指数和韧性损失。以北京地区城市轨道交通网络为例,分析了地震烈度、恢复策略和修复队伍数量对网络连通性能、恢复过程和韧性指标的影响。结果表明:轨道交通网络在遭受地震破坏、蓄意攻击和随机破坏后的韧性特征存在差异;震前提升少量重要单元的可靠度可提升网络灾前抵抗能力,但对网络灾后恢复能力和韧性指数的提升效果不明显。该研究可为城市轨道交通系统抗震安全性评估提供理论支撑和参考。

关键词：城市轨道交通网络地震灾害网络效率震后恢复韧性评估

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基于人工智能技术的轻量级网络入侵检测系统设计

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现代电子技术 2024年第5期47卷 108-111页

作者：董卫魏王曦钟昕辉冯世杰王美虹海南大学信息科学技术学院海南海口570100 中国传媒大学信息与通信工程学院北京100024 重庆大学微电子与通信工程学院重庆400044 华北电力大学计算机科学与技术学院北京100000 海南大学网络空间安全学院(密码学院) 海南海口570100

以提升网络入侵检测技术水平为目的,设计基于人工智能技术的轻量级网络入侵检测系统。该系统数据采集层利用若干个用户探针连接IDS检测服务器后,使用网络数据包捕获模块捕获用户网络运行数据,再通过传输层内防火墙、核心交换机和MQTT/C... 详细信息

以提升网络入侵检测技术水平为目的,设计基于人工智能技术的轻量级网络入侵检测系统。该系统数据采集层利用若干个用户探针连接IDS检测服务器后,使用网络数据包捕获模块捕获用户网络运行数据,再通过传输层内防火墙、核心交换机和MQTT/CoAP通信协议将用户网络运行数据发送到逻辑运算层内,该层利用数据预处理模块对用户网络运行数据进行去噪预处理后,将其输入到基于人工智能的网络入侵检测模块内,通过该模块输出轻量级网络入侵检测结果,然后将检测结果发送到展示层,通过入侵告警信息、数据可视化展示等模块实现人机交互。实验表明:该系统运行较为稳定,可有效检测不同类型网络入侵的同时,其检测及时性和入侵告警能力较好,应用效果良好。

关键词：人工智能轻量级网络入侵检测系统数据采集硬件结构无监督免疫优化

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瘢痕的激光治疗进展

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中南大学学报（医学版） 2024年第2期49卷 197-206页

作者：郭耿鸿陈嘉胜韩晓沙谢启胡陈婉娴耿德毅唐世杰钟晓平汕头大学医学院第二附属医院整形外科、烧伤外科广东汕头515000 汕头大学医学院整形外科研究所广东汕头515000 汕头市整形外科临床研究中心广东汕头515000

瘢痕主要包括浅表性瘢痕、增生性瘢痕、萎缩性瘢痕、凹陷性瘢痕和瘢痕疙瘩5种类型,以成纤维细胞和胶原蛋白的异常产生及结缔组织的排列紊乱等为特点。激光治疗瘢痕涉及多种信号转导通路和细胞因子的协调激活,然而瘢痕形成的确切病理机... 详细信息

瘢痕主要包括浅表性瘢痕、增生性瘢痕、萎缩性瘢痕、凹陷性瘢痕和瘢痕疙瘩5种类型,以成纤维细胞和胶原蛋白的异常产生及结缔组织的排列紊乱等为特点。激光治疗瘢痕涉及多种信号转导通路和细胞因子的协调激活,然而瘢痕形成的确切病理机制仍不清楚,导致缺乏根治性的治疗手段。近年来,激光治疗作为一种新的瘢痕微创治疗方法越来越受欢迎。点阵、皮秒激光及激光辅助药物传输等新理论的出现,使得激光治疗不断进步,并衍生出许多新颖的治疗方式,包括激光联合药物、物理治疗等,均显示出良好的治疗效果。另外,新型材料与术后护理的结合对优化激光治疗至关重要,这将有助于临床医生制订更完善的治疗策略。因此,探索适用性更广的治疗方案具有非常重要的意义。

关键词：瘢痕激光治疗作用机制联合治疗

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Fluorobenzene diluted low-density electrolyte for high-energy density and high-performance lithium-sulfur batteries

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Journal of Energy Chemistry 2022年第5期31卷 752-761页

作者： Zhilong Han Shuping Li Mengjun Sun Renjie He Wei zhong Chuang Yu shijie Cheng Jia Xie State Key Laboratory of Advanced Electromagnetic Engineering and Technology School of Electrical and Electronic EngineeringHuazhong University of Science and TechnologyWuhan 430074HubeiChina School of Physics Huazhong University of Science and TechnologyWuhan 430074HubeiChina State Key Laboratory of Materials Processing and Die&Mould Technology School of Materials Science and EngineeringHuazhong University of Science and TechnologyWuhan 430074HubeiChina

The mass fraction of electrolytes is the crucial factor affecting the energy density of lithium-sulfur(Li-S)batteries. Due to the high porosity within the C/S cathode, high concentration of polysulfides, and side reaction in lithiun metal anode under lean electrolyte, it is extremely challenging to improve performance while reducing the electrolyte volume. Here, we report a novel electrolyte with relatively low density(1.16 g cm^(-2)), low viscosity(1.84 m Pa s), and high ionic conductivity, which significantly promotes energy density and cyclability of Li-S batteries under practical conditions. Moreover, such electrolyte enables a hybrid cathode electrolyte interphase(CEI) and solid electrolyte interface(SEI) layer with plentiful Li F, which leads to fast kinetics of ions transport and stable cyclability even under low temperatures.Compared to Li-S batteries in electrolyte employing 1,1,2,2-tetrafluoroethyl 2,2,3,3-tetrafluoropropyl ether(TTE) diluent, the ultra-thick cathode(20 mg cm^(-2)) shows a high capacity of 9.48 m Ah cm^(-2)and excellent capacity retention of 80.3% over 191 cycles at a low electrolyte-to-sulfur ratio(E/S = 2) and negative-to-positive capacity ratio(N/P = 2.5), realizing a 19.2% improvement in energy density in coin cells(from 370 to 441 Wh kg^(-1)) and a high energy density up to 467 Wh kg^(-1) in pouch cells. This study not only provides guidance for the electrolyte design but also paves the way for the development of high performance Li-S batteries under practical conditions.

关键词： High energy density Lithium-sulfur battery Thick sulfur electrode Lean electrolyte Low-density electrolyte

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