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Nanoelectronics:Molecular Metal Wires and Related Molecular Materials

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Nanoelectronics:Molecular Metal Wires and Related Molecular ...

FROM METAL STRING COMPLEXES TO METAL WIRES

第十三届固态化学与无机合成学术会议

作者： shie-ming peng Department of Chemistry National Taiwan University

＜正＞We have designed a series of new ligands such as oligo-α-pyridylamines,and used them to construct an unique class of quadruple helix of metal *** achievement leads to a new direction to the application of molec...

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FROM METAL STRING COMPLEXES TO METAL WIRES

Optimal Timing of Business Conversion for Solvency Improvement

第五届尖端科学研讨会

作者： shie-ming peng Department of Chemistry National Taiwan UniversityTaipeiTaiwan

＜正＞ Owing to their fascinating bonding nature, the metal-metal （M-M） multiple bonds in dinuclear metal complexes have been an interesting and vital research topic. During the past decade, our seminal and systematic approaches on the all-syn oligo-（a-pyridyl）amido ligands coordinated metal ions have successfully opened up a new chapter, extending this territory from dinuclear to linear oligonuclear metal complexes. Their unique features in structures and bonding characterization have been thoroughly investigated, which, according to the M-M bonding strength, can be classified into two categories, namely the oligonickel（Ⅱ） complexes lacking an M-M bond and the oligochromium（Ⅱ） complexes with a strong M-M bonding formation. Depending on the specificity and number of metal ions, structures and magnetic behaviors of the corresponding metal complexes are systematically analyzed. Their potential application as a molecular metal wire is conveyed on the basis of the band structures calculated from hypothetical one-dimensional metal strings. Moreover, self-assembled monolayers of n-alkanethiols are employed as a two-dimensional matrix to isolate the metal string complexes, of which the scanning tunneling microscopy （STM） image exhibits remarkable protrusion characteristics. For tricobalt and trichromium complexes, the topographic STM images reveal that the protruding features are, respectively, 0.3 nm and 0.6 nm higher than that of the trinickel complexes. The trend of increasing conductivity correlates well with their associated bond orders, and is also in consistence with qualitative EHMO approaches.

关键词： Metal String Complex Molecular Metalwire STM Spectroscopy

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Acta Mathematicae Applicatae Sinica 2024年第3期40卷 744-757页

作者： peng LI ming ZHOU School of Finance Nanjing University of Finance and EconomicsNanjing 210023China Center for Applied Statistics and School of Statistics Renmin University of ChinaBeijing 100872China

In this paper,we study the optimal timing to convert the risk of business for an insurance company in order to improve its *** cash flow of company evolves according to a jump-diffusion *** conversion option offers the company an opportunity to transfer the jump risk business *** exchange for this option,the company needs to pay both fixed and proportional transaction *** proportional cost can also be seen as the profit loading of the jump risk *** formulated this problem as an optimal stopping *** solving this stopping problem,we find that the optimal timing of business conversion mainly depends on the profit loading of the jump risk business.A larger profit loading would make the conversion option *** fixed cost,however,only delays the optimal timing of business *** the end,numerical results are provided to illustrate the impacts of transaction costs and environmental parameters to the optimal strategies.

关键词： optimal stopping jump-diffusion process conversion option

Emerging materials and transistors for integrated circuits

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National Science Review 2024年第3期11卷 7-8页

作者： ming Liu Lian-Mao peng Lab of Nanofabrication and Novel Device Integration Institute of Microelectronics Chinese Academy of Sciences Key Laboratory for the Physics and Chemistry of Nanodevices and Center for Carbon-based Electronics School of Electronics Peking University

The device technology for integrated circuits(ICs) has received a great deal of attention in the past decade since the mainstream silicon-based complementary metal-oxide-semiconductor(CMOS) field-effect transistor(FET) for modern ICs had been encountering development bottlenecks due to the combination of power constraints, physics, cost and fabrication processes.

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How the enhanced East Asian summer monsoon regulates total gross primary production in eastern China

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Advances in Climate Change Research 2024年第2期15卷 244-252页

作者： ming-Yu HAN Yong ZHANG Jing peng China State Key Laboratory of Severe Weather Chinese Academy of Meteorological SciencesBeijing 100081China China Meteorological Administration Institute for Development and Programme Design Beijing 100081China CAS Key Laboratory of Regional Climate-Environment for Temperate East Asia Institute of Atmospheric PhysicsChinese Academy of Sciences(CAS)Beijing 100029China

Recognizing the relationship between gross primary production(GPP)and precipitation in eastern China,the East Asian Summer Monsoon(EASM)plays a crucial role in shaping *** confirmation of the strong link between EASM and GPP,there remains a notable research gap in understanding the specific impact of the EASM on GPP in different regions of eastern *** we used simulations from Trends in Net Land-Atmosphere Carbon Exchanges(TRENDY)models from 1951 to 2010 and divided eastern China into five subregions for the *** also used the New East Asian Summer Monsoon Index(NEWI)as a quantitative metric to distinguish between periods of strong and weak *** on this,this study aims to investigate the response of GPP in different subregions of eastern ***,under strengthened EASM years(1954,1957,1965,1969,1977,1980,1983,1987,1993 and 1998),East China experienced the most pronounced increase in GPP at 12±21(mean±1 sigma)gC m^(-2) mon^(-1) compared to the weak EASM years(1958,1961,1972,1973,1978,1981,1985,1994,1997 and 2004).In contrast,Southwest China showed a decline in GPP at-4±10 gC m^(-2) mon^(-1).Moreover,GPP also increased in Northeast and North China when EASM strengthened,while South China showed a decline in *** indicated that GPP changed with monsoon *** to the mechanism analysis,during strong EASM,there was intense moisture convergence through alterations in the atmospheric circulation field over East China and abundant precipitation,which further contributed to the increase in *** solar radiation in Southwest China decreased with EASM enhancement,which suppressed GPP and hindered vegetation ***,the results highlight the importance of accurately predicting the impact of different EASM intensities of regional carbon fluxes.

关键词： Gross primary production Surface air temperature Precipitation Solar radiation Eastern China Carbon cycle

Enhanced potassium storage of carbon nanofibers as binderfree anodes enabled by coupling ultra-small amorphous Sb_(2)O_(3),graphene modification and sulfur doping

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Rare Metals 2024年第1期43卷 51-64页

作者： Zhao Huang Yu-Kang Lou Lin peng Yuan peng Meng-Meng Wang ming Zhang College of Railway Transportation Hunan University of TechnologyZhuzhou 412007China College of Semiconductors(College of Integrated Circuits) Changsha Semiconductor Technology and Application Innovation Research InstituteHunan UniversityChangsha 410082China Key Laboratory for Micro-Nano Optoelectronic Devices of Ministry of Education College of Semiconductors(College of Integrated Circuits)Hunan UniversityChangsha 410082China

Considering the intrinsic advantages of natural copiousness and cost-effectiveness of potassium resource,potassium-ion batteries(KIBs) are booming as prospective alternatives to lithium-ion batteries(LIBs) in large-scale energy storage scenarios. Nevertheless, lacking desirable electrodes for reversibly hosting the bulky K+hinders the widespread application of KIBs, and it needs to be urgently solved. Hereon, the porous S-doped Sb_(2)O_(3)-graphene-carbon(SAGC) nanofibers are manufactured through an adjustable and facile approach, which involves electrospinning, in situ etching and sulfuration. The synthesized SAGC is featured by the ultra-small amorphous Sb_(2)O_(3) homogeneously wrapped inside the carbon matrix, as well as the co-incorporation of graphene and sulfur. Tentatively,the SAGC nanofiber sheets are applied as binder-free anodes for KIBs, exhibiting a prominent cycling life(256.72 m Ah·g^(-1) over 150 cycles at 100 m A·g^(-1)) and rate·g^(-1) over 100 cycles at 1 A·g^(-1)). The positive synergy among all the active components accounts for the distinguished performances of the SAGC. By reinforcing the tolerability to the swelling stress, producing the valid electrochemical active sites, and promoting the charge transferring for reversible K+uptake, the SAGC finally renders the excellent cyclability, capacity, and rate capability. Moreover, the extrinsic electrochemical pseudocapacitance characteristics induced by the porous carbon substrate elevate the K-storage capacity of the SAGC as well. It is hoped that the conclusions drawn may offer new insights into a direction for the high-performance binderfree KIB anodes.

关键词： S-doped Sb_(2)O_(3)-graphene-carbon Nanofibers Binder-free Anodes Potassium-ion batteries

Swelling of Spherical Polyelectrolyte Gels

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Chinese Journal of Polymer Science 2024年第9期42卷 1386-1392,I0009页

作者： ming-Yu Duan Jia-Dong Chen Yi-ming Liu Zhao-Feng peng Guang Chen Department of Advanced Manufacturing and Robotics College of EngineeringPeking UniversityBeijing 100871China

Polyelectrolyte(PE)gels,distinguished by their unique stimuli-responsive swelling behavior,serve as the basis of broad applications,such as artificial muscles and drug *** this work,we present a theoretical model to analyze the electrostatics and its contribution to the swelling behavior of PE gels in salt *** minimizing the free energy of PE gels,we obtain two distinct scaling regimes for the swelling ratio at equilibrium with respect to the salt *** compare our predictions for the swelling ratio with experimental measurements,which show excellent *** addition,we employ a finite element method to assess the applicability range of our theoretical model and *** anticipate that our model will also provide valuable insights into drug adsorption and release,deformation of red blood cells,4D printing and soft robotics,where the underlying mechanism of swelling remains enigmatic.

关键词： Gels Polyelectrolytes Swelling Stimuli-responsive Electrostatic interaction Cell model

Bimetal MOF-derived NiFe-P nanocomposites coupled with Cu_(3)P nanoparticles to construct tandem electron transfer channels for photocatalytic hydrogen evolution

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Journal of Environmental Sciences 2024年第3期137卷 333-346页

作者： Haiyan Zhang Shitao Yang peng Zhu Senpei Tang ming Li College of Chemistry and Chemical Engineering Jishou UniversityJishou 416000China School of Account Hunan University of Technology and BusinessChangsha 410205China

Finely modulated light-induced charge separation and transfer is a central challenge to achieve efficient *** progress has been made in this field,most of the previous research works focused on the separation or migration of photogenerated carriers but did not build a bridge between the *** to realize the strong driving and precise migration of carriers has become the focus of our *** report an ingeniously designed ternary *** NiFe-MOF as the“parent material”,the FeP_(4)/Ni_(x)P_(y)heterojunction is derived in situ while maintaining the frame structure through gas-solid reaction,and finally the Z-type electron transfer is *** Cu_(3)P anchoring spindle matrix,an electron transport tunnel is opened up in Cu_(3)P/FeP_(4)/Ni_(x)P_(y)ternary heterojunction under the action of p-n heterojunction built-in electric field driving and accurate energy band *** strong driving force of the built-in electric field provides an inexhaustible power for the transmission of electrons,and the fine series of electron transmission channels realizes the precise transmission of *** above fine design makes the perfect fit between the built-in electric field and the electron transfer channel,which not only effectively improves the embarrassing situation of insufficient electron driving force of hydrogen evolution reaction in the previous research,but also makes up for the weakening of semi-conductor reduction ability caused by the construction of traditional p-n *** research work provides a new idea for the construction of multiple heterostructures and the design of fine interface engineering in the future.

关键词： Cu_(3)P/FeP_(4)/Ni_(x)P Built-in electric field Electron transfer channels Photocatalysis

Critical environmental factors affecting mountain geohazards in a warming climate in Southwest China

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Advances in Climate Change Research 2024年第4期15卷 695-707页

作者： Xiao-ming XU peng CUI Xue-Qin ZHANG Key Lab of Land Surface Pattern and Simulation Institute of Geographic Sciences and Natural Resources ResearchChinese Academy of SciencesBeijing 10010lChina University of Chinese Academy of Sciences Beijing 100049China China-Pakistan Joint Research Center on Earth Sciences Chinese Academy of Sciences and Higher Education CommissionIslamabad 45320Pakistan

Environmental factors are essential input variables for susceptibility assessment models of mountain ***,the existing literature provides a limited understanding of the relative contribution of these factors to the occurrence of geohazards with a warming climate,posing tremendous challenges for risk management in mountainous ***'an city is susceptible to hazards because of its steep terrain,abundant precipitation and active seismic *** this regard,we utilise the GeoDetector model to extract critical environmental factors affecting the spatial patterns of mountain geohazards(i.e.,landslide,debris flow and rockfall)in Southwest *** analysis indicates that the factors with the highest explanatory power for the spatial distribution of landslides,debris flows,and rockfalls are soil property,extreme precipitation and extreme temperature,***,we revealed the synergistic effects among factors given their larger q-value than individual *** further explored the responses of mountain geohazards to climate change,including the rising temperature and precipitation,because the frequent occurrence of mountain geohazards is closely related to a warming *** variation in snow water equivalent caused by antecedent snowfall and snowdrifts acts as a crucial indicator for geohazards,highlighting the significance of snow and wind observations in meteorological nowcasting and disaster *** disclose the phenomenon of the geohazard hysteresis to the precipitation peak resulting from the top-down(i.e.,precipitation-runoff and surface-deep soil moisture)peak *** work is expected to enhance the precision of susceptibility assessment models and the reliability of short-term forecasts for mountain geohazards.

关键词： Mountain geohazards Environmental factors Climate change GeoDetector Southwest China