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A new dimeric furanocoumarin from Notopterygium incisum

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Chinese Chemical Letters 2008年第8期19卷 940-942页

作者： shi biao wu Yi Hua Yu Ying He Hu Jin Feng Hu Department of Natural Products for Chemical Genetic Research Key Laboratory of Brain Functional Genomics Ministry of Education ＆ Shanghai Key Laboratory of Brain Functional Genomics （MOE ＆ SBFG） East China Normal University Shanghai 200062 China Shanghai Key Laboratory of Functional Magnetic Resonance Imaging East China Normal University Shanghai 200062 China

A new dimeric psoralen-type furanocoumarin, notopterol-（18-O-20＇）-notopol （1）, was isolated from Notopterygium incisum for the first time and its structure was elucidated by spectroscopic methods.

关键词： Notopterygium incisum Umbelliferae Dimeric furanocoumarin Structure elucidation

Polyphenols from Jaboticaba Wood and Their Antioxidant and Anti-inflammatory Effects

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Polyphenols from Jaboticaba Wood and Their Antioxidant and A...

Mechanistic insight into the synergy between nickel single atoms and nanoparticles on N-doped carbon for electroreduction of CO2

第十四届全国中药和天然药物学术研讨会

作者： shi-biao wu Edward J.Kennelly Lehman College

Jaboticaba(Myrciaria cauliflora)are pleasant-tasting,dark-colored fruits,native to *** fruits are reported to be rich source of phenolic compounds,including anthocyanins,flavonoids,phenolic acids,tannins,as well as less well known polyphenols like *** to now,however,the metabolic profile of jaboticaba woods was *** our study,we

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Journal of Energy Chemistry 2025年第1期100卷 327-336页

作者： Mingdong Sun Wenwen Guan Cailing Chen Chao wu Xiaoling Liu biao Meng Tao Chen Yu Han Jun Wang shibo Xi Yu Zhou State Key Laboratory of Materials-Oriented Chemical Engineering College of Chemical Engineering Nanjing Tech University Advanced Membranes and Porous Materials Center Physical Sciences and Engineering Division King Abdullah University of Science and Technology Institute of Sustainability for Chemicals Energy and Environment A*STAR (Agency for Science Technology and Research) College of Materials Science and Engineering Sichuan University

The synergy of single atoms （SAs） and nanoparticles （NPs） has demonstrated great potential in promoting the electrocatalytic carbon dioxide reduction reaction （CO2RR）;however,the rationalization of the SAs/NPs proportion remains one challenge for the catalyst ***,a Ni2+-loaded porous poly（ionic liquids）(PIL) precursor synthesized through the free radical self-polymerization of the ionic liquid monomer,1-allyl-3-vinylimidazolium chloride,was pyrolyzed to prepare the Ni,N co-doped carbon materials,in which the proportion of Ni SAs and NPs could be facilely modulated by controlling the annealing *** catalyst Ni-NC-1000 with a moderate proportion of Ni SAs and NPs exhibited high efficiency in the electrocatalytic conversion of CO2into *** Ni K-edge X-ray absorption near-edge structure （XANES） spectra and theoretical calculations were conducted to gain insight into the synergy of Ni SAs and *** charge transfer from Ni NPs to the surrounding carbon layer and then to the Ni SAs resulted in the electron-enriched Ni SAs active *** the electroreduction of CO2,the coexistence of Ni SAs and NPs strengthened the CO2activation and the affinity towards the key intermediate of*COOH,lowering the free energy for the potential-determining*CO2→*COOH step,and therefore promoted the catalysis efficiency.

关键词： Single atom catalyst Synergy effect Carbon catalyst Electrocatalysis

Identifying the dynamic behaviors in complete reconstruction of Co-based complex precatalysts during electrocatalytic oxygen evolution

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Journal of Energy Chemistry 2025年第1期100卷 226-233页

作者： Jingfang Zhang Danyang wu Linke Cai Youluan Lu Fanpeng Cheng Lijuan shi Qun Yi Yao Liu Yi Huang Key Laboratory of Green Chemical Engineering Process of Ministry of Education Engineering Research Center of Phosphorus Resources Development and Utilization of Ministry of Education Hubei Key Laboratory of Novel Reactor and Green Chemical Technology School of Chemical Engineering & Pharmacy Wuhan Institute of Technology Key Laboratory of Pesticide & Chemical Biology of Ministry of Education Engineering Research Center of Photoenergy Utilization for Pollution Control and Carbon Reduction of Ministry of Education College of Chemistry Central China Normal University College of Materials Science and Engineering Fuzhou University

Transition metal-based nanomaterials have emerged as promising electrocatalysts for oxygen evolution reaction（OER）. Considerable research efforts have shown that self-reconstruction occurs on these nanomaterials under operating conditions of OER process. However, most of them undergo incomplete reconstruction with limited thickness of reconstruction layer, leading to low component utilization and arduous exploration of real catalytic mechanism. Herein, we identify the dynamic behaviors in complete reconstruction of Co-based complexes during OER. The hollow phytic acid（PA） cross-linked CoFe-based complex nanoboxes with porous nanowalls are designed because of their good electrolyte penetration and mass transport ability, in favor of the fast and complete reconstruction. A series of experiment characterizations demonstrate that the reconstruction process includes the fast substitution of PA by OH-to form Co（Fe）(OH)xand subsequent potential-driven oxidation to Co（Fe）OOH. The obtained CoFeOOH delivers a low overpotential of 290 mV at a current density of 10 mA cm-2and a long-term *** experiment results together with theory calculations reveal that the Fe incorporation can result in the electron rearrangement of reconstructed CoFeOOH and optimization of their electronic structure,accounting for the enhanced OER activity. The work provides new insights into complete reconstruction of metal-based complexes during OER and offers guidelines for rational design of high-performance electrocatalysts.

关键词： Complete reconstruction Co-based complex Precatalysts Oxygen evolution reaction

Regulation and function of endoplasmic reticulum autophagy in neurodegenerative diseases

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Neural Regeneration Research 2025年第1期20卷 6-20页

作者： Xiu-Yun Zhao De-En Xu Ming-Lei wu Ji-Chuan Liu Zi-Ling shi Quan-Hong Ma Department of Neurology and Clinical Research Center of Neurological Disease the Second Affiliated Hospital of Soochow UniversitySuzhouJiangsu ProvinceChina Institute of Neuroscience&Jiangsu Key Laboratory of Translational Research and Therapy for Neuro-Psycho-Diseases Soochow UniversitySuzhouJiangsu ProvinceChina Department of Neurology Jiangnan University Medical CenterWuxiJiangsu ProvinceChina

The endoplasmic reticulum,a key cellular organelle,regulates a wide variety of cellular *** reticulum autophagy,one of the quality control systems of the endoplasmic reticulum,plays a pivotal role in maintaining endoplasmic reticulum homeostasis by controlling endoplasmic reticulum turnover,remodeling,and *** this review,we briefly describe the endoplasmic reticulum quality control system,and subsequently focus on the role of endoplasmic reticulum autophagy,emphasizing the spatial and temporal mechanisms underlying the regulation of endoplasmic reticulum autophagy according to cellular *** also summarize the evidence relating to how defective or abnormal endoplasmic reticulum autophagy contributes to the pathogenesis of neurodegenerative *** summary,this review highlights the mechanisms associated with the regulation of endoplasmic reticulum autophagy and how they influence the pathophysiology of degenerative nerve *** review would help researchers to understand the roles and regulatory mechanisms of endoplasmic reticulum-phagy in neurodegenerative disorders.

关键词： autophagy endoplasmic reticulum endoplasmic reticulum autophagy endoplasmic reticulum quality control system endoplasmic reticulum receptors endoplasmic reticulum-associated degradation neurodegeneration neurodegenerative disease selective autophagy unfolded protein response

Multiple Tin Compounds Modified Carbon Fibers to Construct Heterogeneous Interfaces for Corrosion Prevention and Electromagnetic Wave Absorption

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Nano-Micro Letters 2025年第1期17卷 507-527页

作者： Zhiqiang Guo Di Lan Zirui Jia Zhenguo Gao Xuetao shi Mukun He Hua Guo Guanglei wu Pengfei Yin College of Science Sichuan Agricultural UniversityYa’an 625014People’s Republic of China School of Materials Science and Engineering Hubei University of Automotive TechnologyShiyan 442002People’s Republic of China Institute of Materials for Energy and Environment State Key Laboratory of Bio‑Fibers and Eco‑TextilesCollege of Materials Science and EngineeringQingdao UniversityQingdao 266071People’s Republic of China Shaanxi Key Laboratory of Macromolecular Science and Technology School of Chemistry and Chemical EngineeringNorthwestern Polytechnical UniversityXi’anShaanxi 710072People’s Republic of China

Currently,the demand for electromagnetic wave(EMW)absorbing materials with specific functions and capable of withstanding harsh environments is becoming increasingly ***-component interface engineering is considered an effective means to achieve high-efficiency EMW ***,interface modulation engineering has not been fully discussed and has great potential in the field of EMW *** this study,multi-component tin compound fiber composites based on carbon fiber(CF)substrate were prepared by electrospinning,hydrothermal synthesis,and high-temperature thermal *** utilizing the different properties of different substances,rich heterogeneous interfaces are *** effectively promotes charge transfer and enhances interfacial polarization and conduction *** prepared SnS/SnS_(2)/SnO_(2)/CF composites with abundant heterogeneous interfaces have and exhibit excellent EMW absorption properties at a loading of 50 wt%in epoxy *** minimum reflection loss(RL)is−46.74 dB and the maximum effective absorption bandwidth is 5.28 ***,SnS/SnS_(2)/SnO_(2)/CF epoxy composite coatings exhibited long-term corrosion resistance on Q235 steel ***,this study provides an effective strategy for the design of high-efficiency EMW absorbing materials in complex and harsh environments.

关键词： Electrostatic spinning Component regulation Heterogeneous interfaces Electromagnetic wave absorption Corrosion protection

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黑液木质素制备活性炭及其电化学性能研究

现代化工 2018年第3期38卷 114-118页

作者：于华阳孙国钰周帆高诚汤士标吴燕曹景沛中国矿业大学煤炭加工与高效洁净利用教育部重点实验室江苏徐州221116

以造纸黑液中提取的木质素为原料,采用碳化-活化法制备活性炭并作为双电层电容器电极材料研究其电化学性能。考察了碳化温度与活化温度对活性炭电化学性能的影响,分析了其比表面积、孔径分布与比电容之间的关系。结果表明,以KOH为活化剂... 详细信息

以造纸黑液中提取的木质素为原料,采用碳化-活化法制备活性炭并作为双电层电容器电极材料研究其电化学性能。考察了碳化温度与活化温度对活性炭电化学性能的影响,分析了其比表面积、孔径分布与比电容之间的关系。结果表明,以KOH为活化剂,活化剂与焦的质量比为1∶1、活化时间为1 h、碳化温度为600℃,活化温度为700℃制备的活性炭比电容达到最大,为158 F/g,其比表面积为948 m^2/g。经对比发现,在KOH水系电解液体系下,1~2 nm的微孔孔径分布情况对比电容值具有较显著的影响。此外,恒电流充放电、循环伏安、交流阻抗等电化学测试显示所制备的活性炭电极具有较好的双电层电容器性能。

关键词：造纸黑液木质素活性炭双电层电容器

Flow structure and unsteady fluctuation with separation over a two-dimensional backward-facing step

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Journal of Hydrodynamics 2019年第6期31卷 1204-1217页

作者： Fang-fang Wang shi-qiang wu biao Huang State Key Laboratory of Hydrology-Water Resources and Hydraulic Engineering Nanjing Hydraulic Research InstituteNanjing 210029China Smart Cities Institute Zhengzhou UniversityZhengzhou 450001China

The flow over a backward-facing step(BFS)is a typical separation and reattachment *** flow structures and unsteady mechanisms are still not well *** this paper,the global velocity fields of a BFS are obtained by a synchronous particle image velocimetry(PIV)system with Reh=5345(Reynolds number)and Er=2(expansion ratio).Flow structures are distinguished and defined by the fraction of the negative velocity(upn).The reattachment zone(Lr)is quantitatively defined as(u0.9,u/0.1)on the bottom *** distribution of the large-scale vortices couples well with the divided flow structures and their temporal evolution presenting four stages(forming,developing,shedding and redeveloping)when travel *** unsteady motions with various low frequencies are well explained by the coherent vortices and flow *** the unsteady low frequency motions,the Kelvin Helmholtz(KH)vortices and the oscillation of Xr(OX)come likely from the free shear *** KH vortices contribute to the unsteadiness of the temporal flow,and the OX is the primary response to the vortical fluctuations.

关键词： Backward-facing step flow structure large-scale vortices unsteady motion free shear layer

Tuning the Johari-Goldstein β-Relaxation and Its Separation from α-Relaxation of Poly(n-alkyl methacrylate)s by Small Molecule-bridged Hydrogen Bonds

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Chinese Journal of Polymer Science 2021年第11期39卷 1459-1469页

作者： Yuan-biao Liu Gao-Peng shi Guo-Zhang wu Shanghai Key Laboratory of Advanced Polymeric Materials School of Materials Science&EngineeringEast China University of Science&TechnologyShanghai 200237China

Introducing small molecule-bridged hydrogen bonds(HBs)between polymer chains has been reported to effectively reduce the interchain cooperativity despite of strengthening the intermolecular ***,a systematic investigation on tuning the Johari-Goldsteinβ(βJG)relaxation by adding various low-molecular-weight phenols in poly(n-alkyl methacrylate)s is carried out to further clarify the anomalous *** these small molecules capable of coupling the motion with pendent groups of host polymers due to forming at least two HBs per molecule,poly(n-alkyl methacrylate)mixtures exhibit rich dynamic changes in theβJG-properties andα,βJG *** increased loading of phenols with a small size and strong inter-HB strength(Δυi)clearly benefits for significant retardation and suppression of theβJG-relaxation,narrows theα,βJG separation and converges theβJG-peak with theα-peak,which demonstrates the alleviation of inter-chain topological ***,small molecules with a relatively big size and weakΔυi are found to amplify the magnitude of theα,βJG separation of poly(butyl methacrylate),even though experimental results of changes inα-dispersion and dynamic fragility confirm a reduction of the coupling factor n in all of these *** counterintuitive phenomenon suggests that the crossover time tc in the Coupling Model is no longer a universal quantity if the inter-chain interaction of polymers is strengthened by *** compelling findings shed vital insights into the HBinduced anomalous dynamics,and provide essential guidance for tailoring theβJG behavior and designing glassy polymeric materials.

关键词： Johari-Goldsteinβ-relaxation Hydrogen bond Glass transition Poly(n-alkyl methacrylate) Small molecule