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In situ XRD and electrochemical investigation on a new intercalation-type anode for high-rate lithium ion capacitor

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Journal of Energy Chemistry 2021年第6期30卷 109-117,I0004页

作者： Bobo Zou Ting Wang Shengyuan Li Rong Kang Guochun Li sherif Ael-khodary Dickon HLNg Xianhu Liu Jingxia Qiu Yan Zhao Jiabiao Lian Huaming Li Institute for Energy Research Jiangsu UniversityZhenjiang 212013JiangsuChina Nanyang Environment and Water Research Institute(NEWRI) Interdisciplinary Graduate School(IGS)Nanyang Technological University50 Nanyang Avenue639798Singapore Department of Physics The Chinese University of Hong KongShatinHong KongChina Key Laboratory of Materials Processing&Mold(Zhengzhou University) Ministry of EducationZhengzhou UniversityZhengzhou 450002HenanChina

A new intercalation-type anode material is reported herein to improve the lithium storage kinetics for high-rate lithium ion *** crystal structure of orthorhombic NaNbO3 indicates two possible tunnels for lithium ions insertion into NaNbO3 host along theand***,in situ XRD is conducted to investigate the lithium storage mechanism and structural evolution of the NaNb O_(3) anode,demonstrating its intercalation behavior through(101)and(141)***,the rGO nanosheets are introduced to facilitate the charge transfer,which also effectively prevent the aggregation of NaNbO3 *** expected,the NaNbO_(3)/rGO nanocomposites possess remarkable reversible capacity(465 mA h g^(-1) at 0.1 A g^(-1)),superior rate capability(325 mA h g^(-1) at 1.0 A g^(-1))and cycling stability,attributed to their synergistic effect and high Li+diffusion coefficient DLi[D(NaNbO_(3)/rGO)/D(NaNbO_(3))≈31.54].Remarkably,the NaNbO3/rGO-based LIC delivers a high energy density of 166.7 W h kg^(-1) at 112.4 W kg^(-1) and remains 24.1 W h kg^(-1) at an ultrahigh power density of26621.2 W kg^(-1),with an outstanding cycling durability(90%retention over 3000 cycles at 1.0 A g^(-1)).This study provides new insights on novel intercalation-type anode material to enrich the materials system of LICs.

关键词： Lithium ion capacitor Intercalation-type anode NaNbO3 nanocubes In situ XRD High energy/power densities

Synthesis, spectral, optical and anti-inflammatory activity of complexes derived from 2-aminobenzohydrazide with some rare earths

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Journal of Rare Earths 2015年第7期33卷 758-764页

作者： Nasser Mohammed Hosny el Sayed a.el Morsy Yousery E.sherif Chemistry Department Faculty of Science Port-Said University Clinical Pharmacology Department Faculty of Medicine Mansoura University Pharmacology and Therapeutics Department Qassim College of Medicine Qassim University Department of Chemistry Faculty of Science and Arts Taibah University

Three new metal complexes derived from Er（Ⅲ）, Dy（Ⅲ） and Zr（Ⅳ） with 2-aminobenzohydrazide （ABH） were synthesized and characterized by elemental analyses, IR, ^1H-NMR, ES-MS and transmission electron microscopy （TEM）. The morphology and the particle size were determined by TEM. The results showed that the ligand acted as neutral bi-dentate coordinating to the metal ions through the carbonyl oxygen and amidic amino nitrogen. The aromatic amine group remained inert towards coordination. The optical band gap was measured and found to be 3.3, 3.5 and 4.3 eV for Er（Ⅲ）, Dy（Ⅲ） and Zr（Ⅳ）, respectively. The optical band gap values indicated a semi-conducting nature of the investigated complexes. The anti-inflammatory and analgesic activities of the tested compounds were determined and compared with standard meloxicam.

关键词： Er(Ⅲ) Dy(Ⅲ) Zr(Ⅳ) metal complexes optical band gap rare earths

Course Evaluation Based on Deep Learning and SSA Hyperparameters Optimization

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Computers, Materials & Continua 2022年第4期71卷 941-959页

作者： Alaa a.el-Demerdash sherif E.Hussein John FW Zaki Department of Computer and Systems Faculty of EngineeringMansoura UniversityMansoura35516Egypt

Sentiment analysis attracts the attention of Egyptian Decisionmakers in the education *** offers a viable method to assess education quality services based on the students’feedback as well as that provides an understanding of their *** machine learning techniques offer automated strategies to process big data derived from social media and other digital channels,this research uses a dataset for tweets’sentiments to assess a few machine learning *** dataset preprocessing to remove symbols,necessary stemming and lemmatization is performed for features *** is followed by several machine learning techniques and a proposed Long Short-Term Memory(LSTM)classifier optimized by the Salp Swarm Algorithm(SSA)and measured the corresponding ***,the validity and accuracy of commonly used classifiers,such as Support Vector Machine,Logistic Regression Classifier,and Naive Bayes classifier,were ***,LSTM based on the SSA classification model was compared with Support Vector Machine(SVM),Logistic Regression(LR),and Naive Bayes(NB).Finally,as LSTM based SSA achieved the highest accuracy,it was applied to predict the sentiments of students’feedback and evaluate their association with the course outcome evaluations for education quality purposes.

关键词： Sentiment analysis course evaluation deep learning Bi-LSTM opinion mining students feedback natural language processing machine learning tweets analysis SSA

A comparative study of liquid and solid inner contact roxatidine acetate ion-selective electrode membranes

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Chinese Chemical Letters 2015年第6期26卷 714-720页

作者： Mohamed K.Abd el-Rahman Hala E.Zaazaa Samah S.Abbas Badr el-Zeany Zeinab a.el-sherif Dalia a.el-Haddad Analytical Chemistry Department Faculty of PharmacyCairo University National Organization for Drug Control and Research

A comparative study was conducted using two designs of a roxatidine acetate （ROX）-selective electrode; a conventional liquid inner contact called electrode A and a graphite-coated solid contact called electrode 13. The fabrication of electrodes was based on roxatidine-tetraphenylborate （ROX-TPB） as an ion-association complex in a PVC matrix using different plasticizers. electrode A has a linear dynamic range of 2.2 ×10^-5 mol/L to 1.0 ×10^-2 mol/L, with a Nernstian slope of 54.7 mV/decade and a detection limit of 1.4 ×10^-6 mol/L. electrode B shows linearity over the concentration range of 1.0×10^-6 mol/L to 1.0×10^-2 tool/L, with a Nernstian slope of 51.2 mV/decade and a limit of detection of 1.1×10^7 mol/L which is remarkably improved as a result of diminishing ion fluxes in this solid contact, ion-selective electrode. The proposed sensors display useful analytical characteristics for the determination of ROX in bulk powder and its pharmaceutical formulation. The present electrodes show clear discrimination of ROX from several inorganic, organic ions, sugars, some common drug excipients and the degradation product （3-[3-（1-piperidinyl methyl） phenoxy] propyl amine） of ROX. Furthermore, the proposed electrodes were utilized for the determination of ROX in human plasma, where electrode B covers drug Cmax which indicated its applicability to pharmacokinetic, bioavailability and bioequivalent studies. The results obtained by the proposed electrodes were statistically analyzed and compared with those obtained by a reported HPLC method. No significant difference for either accuracy or precision was observed.

关键词： Comparative study Roxatidine acetate Liquid inner contact electrode Solid contact electrode Degradation product Plasma

Promising supercapacitor electrodes based immobilization of proteins onto macroporous Ni foam materials

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Journal of Energy Chemistry 2015年第1期24卷 31-38页

作者： Mohamed Khairy sherif a.el-Safty National Institute for Materials Science (NIMS) 1-2-1 Sengen Tsukubalshi Ibaraki-ken 305-0047 Japan Chemistry Department Faculty of Science Sohag UniversityEgypt Graduate School for Advanced Science and Engineering Waseda University 3-4-1 Okubo Shinjuku-ku Tokyo 169-8555 Japan

Immobilizing biocomponents on solid surfaces is a critical step in the development of new devices for future biological, medical, and elec- tronic applications. Therefore, numerous integrated films were recently developed by immobilizing different proteins or enzymes on electrode surfaces. In this work, hemeproteins were sa.ely immobilized onto macroporous nickel-based electrodes while maintaining their functionality. Such modified electrodes showed interesting pseudo-capacitive behavior. Among hemeproteins, hemoglobin （Hb） film has a higher electro- chemical performance and greater charge/discharge cycling stability than myoglobin （Mb） and cytochrome C （CytC）. The heme group in an alkaline medium could induce the formation of superoxides on the electrode surface. These capacitive features of hemeprotein-Ni electrode were related to strong binding sites between hemeproteins and porous Ni electrode, the accumulation of superoxide or radicals on the Ni sur- face, and facile electron transfer and electrolyte diffusion through the three-dimensional macroporous network. Thus, these new protein-based supercapacitors have potential use in free-standing platform technology for the development of implantable energy-storage devices.

关键词： whemeprotein nickel foam pseudocapacitor macroporous peroxide alkaline medium

Strain engineering in electrocatalysis:Strategies,characterization,and insights

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Nano Research 2024年第5期17卷 3603-3621页

作者： Qibo Deng Peng Xu Hassanien Gomaa Mohamed A.Shenashen sherif a.el-Safty Cuihua An Li-Hua Shao Ning Hu School of Mechanical Engineering Hebei University of TechnologyTianjin 300401China Department of Chemistry Faculty of ScienceAl-Azhar University71524AssiutEgypt Department of Petrochemical Egyptian Petroleum Research Institute(EPRI)Nasr City11727CairoEgypt Center for Functional Materials National Institute for Materials Science(NIMS)1-2-1 SengenTsukubaIbaraki-ken305-0047Japan State Key Laboratory of Reliability and Intelligence electrical Equipment Key Laboratory of Advanced Intelligent Protective Equipment TechnologyMinistry of Educationand School of Mechanical EngineeringHebei University of TechnologyTianjin 300401China National Key Laboratory of Strength and Structural Integrity Institute of Solid MechanicsSchool of Aeronautic Science and EngineeringBeihang UniversityBeijing100191China Advanced Equipment Research Institute Co. Ltd.of HEBUTTianjin 300401China

Strain engineering,as a cutting-edge method for modulating the electronic structure of catalysts,plays a crucial role in regulating the interaction between the catalytic surface and the adsorbed *** electrocatalytic performance is influenced by the electronic structure,which can be achieved by introducing the external forces or stresses to adjust interatomic spacing between surface *** challenges in strain engineering research lie in accura.ely understanding the mechanical impact of strain on *** paper first introduces the basic strategy for generating the strain,summarizes the different strain generation forms and their advantages and *** progress in researching the characterization means for the lattice strains and their applications in the field of electrocatalysis is also ***,the challenges of strain engineering are introduced,and an outlook on the future research directions is provided.

关键词： strain electrocatalysis characterization chemical reaction kinetics lattice mismatch

Comparative study between three carbonaceous nanoblades and nanodarts for antimicrobial applications

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Journal of Environmental Sciences 2024年第2期136卷 594-605页

作者： Mohamed S.Selim Ahmed M.Azzam Mohamed A.Shenashen Shimaa A.Higazy Bayaumy B.Mostafa sherif a.el-Safty National Institute for Materials Science(NIMS) 1-2-1 SengenTsukuba-ShiIbaraki-Ken 305-0047Japan Petroleum Application Department Egyptian Petroleum Research InstituteNasr City 11727Egypt Department of Environmental Research Theodor Bilharz Research InstituteGizaEgypt

The design of nanostructured materials occupies a privileged position in the development and management of affordable and effective technology in the antibacterial ***,we discuss the antimicrobial properties of three carbonaceous nanoblades and nanodarts materials of graphene oxide(GO),reduced graphene oxide(RGO),and single-wall carbon nanotubes(SWCNTs)that have a mechano-bactericidal effect,and the ability to piercing or slicing bacterial *** demonstrate the significance of size,morphology and composition on the antibacterial activity mechanism,the designed nanomaterials have been *** minimum inhibitory concentration(MIC),standard agar well diffusion,and transmission electron microscopy were utilized to evaluate the antibacterial activity of GO,RGO,and *** on the evidence obtained,the three carbonaceous materials exhibit activity against all microbial strains tested by completely encapsulating bacterial cells and causing morphological disruption by degrading the microbial cell membrane in the order of RGO>GO>*** of the external cell wall structure and outer membrane proteins,the synthesized carbonaceous nanomaterials exhibited higher antibacterial activity against Gram-positive bacterial strains than Gram-negative and fungal *** had the lowest MIC values(0.062,0.125,and 0.25 mg/mL against ***,***,and ***,respectively),as well as minimum fungal concentrations(0.5 mg/mL for both *** and ***).At 12 hr,the cell viability values against tested microbial strains were completely *** lysis and death occurred as a result of severe membrane damage caused by microorganisms perched on RGO *** work gives an insight into the design of effective graphene-based antimicrobial materials for water treatment and remediation.

关键词： Antimicrobial properties Nanoblades Mechano-bactericidal effect RGO nanosheets Gram-positive bacteria Cell viability

Thermochemical Aspects of Activated Ammonium Perchlorates with Superior Thermal Stability,Decomposition Enthalpy,Propagation Index,and Decomposition Kinetic Parameters

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Journal of Thermal Science 2021年第6期30卷 2196-2201页

作者： sherif elbasuney M.Yehia SHUKRI Ismael sherif Farag AHMED Saleh GHARIEB S.el-Sayyad Head of Nanotechnology Research Center Military Technical College(MTC)Cairo 11646Egypt School of Chemical Engineering Military Technical College(MTC)Cairo 11646Egypt Science and Technology Center of Excellence Cairo 11646Egypt Drug Radiation Research Department National Center for Radiation Research and Technology(NCRRT)Egyptian Atomic Energy Authority(EAEA)Cairo 11646Egypt

Ammonium perchlorate(AP)includes oxidizing and reducing elements on the same *** can act as an efficient oxidizer and mono-propellant as *** this study,AP experienced crystallographic phase change from orthorhombic centrosymmetric to non-centrosymmetric under controlled isothermal heat *** diffractograms confirmed this crystallographic phase *** thermal behaviour of activated AP had been investigated using *** AP demonstrated high chemical stability with an increase in endothermic phase transition enthalpy by 170%.The enthalpy of the subsequent two main exothermic decomposition reactions was increased by 250%.Whereas AP demonstrated total decomposition enthalpy of 733 J/g,activated AP showed 2614 J/*** AP can secure self-sustained response at a high *** index(combustion enthalpy/ignition temperature)was employed to assess self-sustained reaction *** AP demonstrated high propagation index of 8.7 compared with 2.5 for un-activated *** decomposition kinetic parameters had investigated using Kissinger and KAS *** AP showed an increase in activation energy by 89%using the Kissinger method;kinetic parameters using the KAS method were in good agreement with the Kissinger *** can have concluded that AP with novel kinetic decomposition parameters for enhanced safety storage and high combustion characteristics has evolved.

关键词： solid propellants oxidizers thermal behavior Kinetic parameters activation energy

Removal of trace arsenic(V) and phosphate from water by a highly selective ligand exchange adsorbent

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Journal of Environmental Sciences 2011年第12期23卷 1947-1954页

作者： Md. Rabiul Awual sherif A. el-Safty Akinori Jyo National Institute for Materials Science Exploratory Materials Research Laboratory for Energy and Environment 1-2-1 Sengen TsukubaIbaraki 305-0047 Japan Department of Applied Chemistry and Biochemistry Kumamoto University Kurokami 2-39-1 Kumamoto 860-8555 Japan

A highly selective ligand exchange type adsorbent was developed for the removal of trace arsenic（V）（As（V）） and phosphate from water. This adsorbent was prepared by loading zirconium（IV） on monophosphonic acid resin. This adsorbent was able to remove toxic anions efficiently at wide pH ranges. However, low pH was preferable for maximum breakthrough capacity in an adsorption operation. The effiect of a large amount of competing anions such as chloride, bicarbonate, and sulfate on the adsorption systems of As（V） and phosphate anions was investigated. The experimental findings revealed that the As（V） and phosphate uptakes were not affiected by these competing anions despite the enhancement of the breakthrough points and total adsorption. Phosphate anion was slightly preferable than As（V） in their competitive adsorption by the adsorbent. The adsorbed As（V） and phosphate on the Zr（IV）-loaded resin were quantitatively eluted with 0.1 mol/L sodium hydroxide solution, and the adsorbent was regenerated by 0.5 mol/L sulfuric acid. During several cycles of adsorption-elution-regeneration operations, no Zr（IV） was detected in the column efiuents. Therefore, the Zr（IV）- loaded monophosphonic acid resin is an efiective ligand exchange adsorbent for removing trace concentrations of As（V） and phosphate from water.

关键词： arsenic(V) phosphate ligand exchange adsorbent common anions regeneration