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Enhanced removal of sulfonamide antibiotics from water by phosphogypsum modified biochar composite

Journal of Environmental Sciences 2023年第8期130卷 174-186页

作者： Zonghong Jiang Miao Chen Xinqing Lee Qianwei Feng Ning Cheng Xueyang Zhang shengsen wang Bing wang College of Resources and Environmental Engineering Guizhou UniversityGuiyang 50025China Key Laboratory of Karst Georesources and Environment Ministry of EducationGuiyang 550025China State Key Laboratory of Environmental Geochemistry Institute of GeochemistryChinese Academy of SciencesGuiyang 550081China School of Environmental Engineering Xuzhou University of TechnologyXuzhou 221018China College of Environmental Science and Engineering Yangzhou UniversityYangzhou 225127China

Antibiotic pollution has become a global eco-environmental issue.To reduce sulfonamide antibiotics in water and improve resource utilization of solid wastes,phosphogypsummodified biochar composite(PMBC)was prepared via facile one-step from distillers grains,wood chips,and phosphogypsum.The physicochemical properties of PMBCwere characterized by scanning electron microscope(SEM),Fourier transform infrared spectroscopy(FTIR),Zeta potential,X-ray diffraction(XRD),etc.The influencing factors,adsorption behaviors,and mechanisms of sulfadiazine(SD)and sulfamethazine(SMT)onto PMBC were studied by batch and fixed bed column adsorption experiments.The results showed that the removal rates of SD and SMT increased with the increase of phosphogypsum proportion,while decreased with the increase of solution pH.The maximum adsorption capacities of modified distillers grain and wood chips biochars for SD were 2.98 and 4.18 mg/g,and for SMT were 4.40 and 8.91mg/g,respectively,which was 9.0–22.3 times that of pristine biochar.Fixed bed column results demonstrated that PMBC had good adsorption capacities for SD and SMT.When the solution flow rate was 2.0 mL/min and the dosage of PMBC was 5.0 g,the removal rates of SD and SMT by modified wood chips biochar were both higher than 50%in 4 hr.The main mechanisms of SD and SMT removal by PMBC are hydrogen bonding,π-πdonor-acceptor,electrostatic interaction,and hydrophobic interaction.This study provides an effective method for the removal of antibiotics in water and the resource utilization of phosphogypsum.

关键词： Modified biochar Solid waste Antibiotics Phosphogypsum Fixed-bed adsorption

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One-step preparation of a novel graphitic biochar/Cu^(0)/Fe_(3)O_(4) composite using CO_(2)-ambiance pyrolysis to activate peroxydisulfate for dye degradation

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Journal of Environmental Sciences 2023年第3期125卷 26-36页

作者： Yangfan Yuan Changai Zhang Chenhao Zhao Bingwang Xiaozhi wang Bin Gao shengsen wang Jorg Rinklebe College of Environmental Science and Engineering Yangzhou UniversityYangzhou 225127China Joint International Research Laboratory of Agriculture and Agri-Product Safety of Ministry of Education of China Yangzhou UniversityYangzhou 225127China Jiangsu Collaborative Innovation Center for Solid Organic Waste Resource Utilization Yangzhou 225127China School of Environmental and Natural Resources Zhejiang University of Science and TechnologyHangzhou 310023China School of Resources and Environmental Engineering Guizhou UniversityGuiyang 550025China Department of Agricultural and Biological Engineering University of FloridaGainesville FL32611USA University of Wuppertal School of Architecture and Civil EngineeringInstitute of Foundation EngineeringWaterand Waste-ManagementLaboratory of Soil-and Groundwater-ManagementWuppertal 42285Germany Department of Environment Energy and GeoinformaticsSejong UniversityGuangjin-GuSeoul 05006South Korea

Herein,a one-step co-pyrolysis protocol was adopted for the first time to prepare a novel pyrogenic carbon-Cu^(0)/Fe_(3)O_(4)heteroatoms (FCBC) in CO_(2)ambiance to discern the roles of each component in PDS activation.During co-pyrolysis,CO_(2)catalyzed formation of reducing gases by biomass which facilitated reductive transformation of Fe^(3+)and Cu^(2+)to Cu^(0)and Fe_(3)O_(4),respectively.According to the analysis,the resulting metal (oxide) catalyzed graphitization of biocharand decomposition of volatile substances resulting in an unprecedented surface area (1240 m^(2)/g).The resulting FCBC showed greater structural defects and less electrical impedance.Batch experiments indicated that Rhodamine B (RhB) degradation by FCBC (100%) was superior to Fe_(3)O_(4)(50%) and Cu^(0)/Fe_(3)O_(4)(76.4%) in persulfate (PDS) system,which maintained reasonable efficiency (75.6%-63.6%) within three cycles.The reactive oxygen species (ROS) associated with RhB degradation was identified by an electron paramagnetic resonance and confirmed by scavenging experiments.RhB degradation invoked both(sulfate and dominantly hydroxyl) radical and non-radical (singlet oxygen,^(1)O_(2)) pathways.Regarding FCBC,Cu^(0)can continuously react with Fe^(3+)in Fe_(3)O_(4)to generate larger quantities of Fe^(2+),and both Cu^(0)and Fe^(2+)activated PDS to yield sulfate radicals which was quickly converted to hydroxyl radical.Besides,Cu^(0)/Cu^(2+)could complex with PDS to form a metastable complex,which particularly contributed to1O_(2)generation.These cascade reactions by FCBC were reinforced by carbonyl group of biochar and favorable electron transfer ability.This work highlighted a new approach to prepare a magnetic and environment-benign heterogonous catalyst to remove organic pollutants in water.

关键词： Biochar Singlet oxygen Persulfate Water pollution Waste biomass

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基于茶渣的生物炭负载零价铁对水体和土壤中Cr(Ⅵ)的修复及机理研究

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环境污染与防治 2024年第5期46卷 638-644页

作者：徐玥徐学敏时悦赵晨浩王圣森扬州大学环境科学与工程学院江苏扬州225127 五莲县叩官镇应急管理事务服务中心山东日照262305

利用茶渣中的残余多酚类物质,通过绿色合成法制得零价铁(ZVI),并以茶渣烧制的生物炭(BC)作为载体负载ZVI,将制得的ZVI/BC材料用于去除水体中Cr(Ⅵ)及修复Cr(Ⅵ)污染土壤。结果表明,茶渣中提取的多酚可以成功还原Fe(Ⅱ)制备ZVI,且制得的Z... 详细信息

利用茶渣中的残余多酚类物质,通过绿色合成法制得零价铁(ZVI),并以茶渣烧制的生物炭(BC)作为载体负载ZVI,将制得的ZVI/BC材料用于去除水体中Cr(Ⅵ)及修复Cr(Ⅵ)污染土壤。结果表明,茶渣中提取的多酚可以成功还原Fe(Ⅱ)制备ZVI,且制得的ZVI/BC复合材料具有优秀的Cr(Ⅵ)去除能力;ZVI/BC对Cr(Ⅵ)的吸附过程为单分子层化学吸附,ZVI为反应中心,其对Cr(Ⅵ)的吸附等温线符合Langmuir模型,在溶液初始pH为3时对Cr(Ⅵ)吸附性能最佳。与BC相比,ZVI/BC更能促进土壤中的铬从易被利用的可交换态、碳酸盐结合态向较难被利用的铁锰氧化态、有机态转化。ZVI/BC主要通过还原反应修复土壤和水体中的Cr(Ⅵ),同时也伴随着表面络合过程。

关键词：茶渣生物炭 Cr(Ⅵ) 零价铁吸附

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A Rapid Technique for Prediction of Nutrient Release from Polymer Coated Controlled Release Fertilizers

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Open Journal of Soil Science 2011年第2期1卷 40-44页

作者： shengsen wang Ashok K. Alva Yuncong Li Min Zhang 不详

Controlled release fertilizers (CRF) are produced with different rates and durations of nutrient release to cater to different crops with wide ranges of nutrient requirements. A rapid technique is needed to verify the label specifications of nutrient release rate and duration. Polymer-coated urea (PCU) (43% nitrogen [N]) and polymer-coated N, phosphorus (P), potassium (K) (PC_NPK;14-14-14) fertilizer products were used in this study. Soil incubation of the above CRF products at 25℃ showed that 63.6% to 70.8% of total N was released over 220 days (d). At 100℃ in water 100% of N release occurred in about 168 to 216 hours (h). Regression equations were developed for cumulative nutrient release as a function of release time separately at 25℃ and 100℃. Using the above regressions, the release duration for a given percent nutrient release at each temperature was calculated. These values were then used to establish a relationship between the release duration at 25℃ as a function of that at 100℃. This relationship is useful to predict the release duration at 25℃ of an unknown CRF product by conducting a rapid release test in water at 100℃. This study demonstrated that a rapid nutrient release test at 100℃ successfully predicted nutrient release rate and duration at 25℃, for polymer coated fertilizers. Therefore, this rapid test can be used to verify the label release rate and duration of most CRF products.

关键词： Nutrient Requirement Nutrient Management polymer Coated Fertilizer Slow Release Fertilizer

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Carboxymethyl cellulose stabilized Zn O/biochar nanocomposites: enhanced adso rption and inhibited photocatalytic degradation of methylene blue

Carboxymethyl cellulose stabilized Zn O/biochar nanocomposit...

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中国土壤学会土壤环境专业委员会第十九次会议暨“农田土壤...

作者： shengsen wang Xiaozhi wang College of Environmental Science and Engineering Yangzhou University

Biochar（BC） supported nanoscaled zinc oxide（nZO） was encapsulated eit her with（nZORc/BC） or with no（nZOR/BC） sodium carboxymethyl cellulose（CMC）. The X-ray diffraction and ultraviolet（UV）-visible-near infrared spectrophotometry revealed that nZO of 16, 10, and 20 nm with energy band gaps of 2.79, 3.68 and 2.62 e V were synthesized for nZOR/BC, nZORc/BC and nZO/BC（nZO precipitated on B C）. The Langmuir isotherm predicted saturated sorption of methylene blue（MB） was 17.01 g kg-1 for nZORc/BC, over 20 times greater than nZOR/BC. Under UV irradiat ion, 10.9, 61.6, 83.1, and 41.6% of MB were degraded for nZORc/BC, nZO/BC, nZO R/BC and BC. The scavenging experiment revealed that hydroxyl radical dominated CMC degradation. Exogenous CMC（2 g L-1） increased MB sorption from 10.6% to 73.1%, but decreased MB degradation from 80.7% to 41.1%, relative to nZOR/BC. T his suggested CMC was attributed to increased MB sorption and compromised MB de gradation by quenching free radicals.

关键词： Sodium carboxymethyl cellulose nanoscaled zinc oxide methylene blue sorption degradation

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磁性HAP/Fe_(3)O_(4)材料去除水土环境中Cd的效果研究

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农业环境科学学报 2022年第7期41卷 1537-1543页

作者：尹文华刘迎春王杰王圣森王小治尹微琴扬州大学环境科学与工程学院江苏扬州225127

为探究磁性羟基磷灰石/四氧化三铁(HAP/Fe_(3)O_(4))纳米材料对水土环境中Cd的去除效果,以米糠为原料,采用水热法制备纳米材料,通过水中吸附实验和土壤培养实验对Cd去除效果进行研究。结果表明:pH为8时,HAP/Fe_(3)O_(4)对Cd的吸附更符... 详细信息

为探究磁性羟基磷灰石/四氧化三铁(HAP/Fe_(3)O_(4))纳米材料对水土环境中Cd的去除效果,以米糠为原料,采用水热法制备纳米材料,通过水中吸附实验和土壤培养实验对Cd去除效果进行研究。结果表明:pH为8时,HAP/Fe_(3)O_(4)对Cd的吸附更符合伪二阶动力学模型,吸附过程以化学吸附为主。溶液为酸性时,HAP/Fe_(3)O_(4)对Cd^(2+)的吸附机制可能为表面吸附和生成沉淀,溶液为中碱性时,对Cd^(2+)的去除以表面吸附以及离子交换为主。此外,HAP/Fe_(3)O_(4)在5次循环后吸附能力仍保持在较高水平,说明其作为吸附剂具有较高的可重复利用性。在土壤实验中,土壤pH随培养时间的延长和HAP/Fe_(3)O_(4)投加量的增加,总体呈上升趋势。与对照组相比,HAP/Fe_(3)O_(4)添加量为0.5%的处理显著降低了土壤CaCl_(2)提取态Cd含量,降幅为62%;浸出实验证明HAP/Fe_(3)O_(4)增强了土壤中重金属的滞留能力。HAP/Fe_(3)O_(4)纳米材料作为一种原料价格低廉且环境友好的吸附剂在处理水污染和修复土壤方面应用前景广阔。

关键词：米糠羟基磷灰石(HAP) Fe_(3)O_(4) 纳米材料

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Assessment of tree-ring mercury radial translocation and age effect in Masson pine:Implications for historical atmospheric mercury reconstruction

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Journal of Environmental Sciences 2024年第4期138卷 266-276页

作者： Xu Liu Xun wang Dingyong wang College of Resources and Environment Southwest UniversityChongqing 400715China State Key Laboratory of Environmental Geochemistry Institute of GeochemistryChinese Academy of SciencesGuiyang 550081China

The tree ring has been regarded as an emerging archive to reconstruct historical atmospheric mercury(Hg)trends,but with the large knowledge gaps in the reliability.In this study,we comprehensively evaluated the Hg source,radial translocation and age effect of Masson pine(Pinus massoniana)tree ring at Mt.Jinyun in Chongqing,to assess the suitability of such tree ring as the archive of atmospheric Hg.Results showed that distinct variabilities among Masson pine tree-ring Hg concentration profiles.The Hg concentration significantly increased along with stem height(P<0.05),indicating the Hg in tree rings mainly derived from foliage uptake atmospheric Hg.We found a distinct age effect that the tree ring of young trees had the higher Hg concentration.Besides,we used the advection-diffusion model to demonstrate how Hg concentration shifted by the advection or/and diffusion in tree rings.The modeling results showed that the advection induced radial translocation during the young growth period of tree was a plausible mechanism to result in the tree-ring Hg record largely different from the trend of anthropogenic Hg emissions in Chongqing.We finally suggest that in further Hg dendrochemistry,better discarding the tree-ring Hg profile of the young growth period to reduce impacts of the radial translocation and age effect.

关键词： Masson pine Tree-ring mercury Radial translocation Tree age effect

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利用不同无机和有机固体废物配制技术新成土的研究

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农业资源与环境学报 2023年第2期40卷 445-454页

作者：周洋刘迎春郁山王琛源尹微琴徐乔王圣森王小治扬州大学环境科学与工程学院江苏扬州225127 江苏省有机固体废弃物资源化协同创新中心南京210095

为拓展固体废物的利用途径,以生活污泥、蚯蚓粪、秸秆、粉煤灰、煤渣为原料通过为期3个月的室内恒温培养来制备技术新成土,研究不同原料配比对技术新成土理化性质的影响。结果表明:制备的技术新成土pH在7.08~7.69之间,水稳性团聚体总量... 详细信息

为拓展固体废物的利用途径,以生活污泥、蚯蚓粪、秸秆、粉煤灰、煤渣为原料通过为期3个月的室内恒温培养来制备技术新成土,研究不同原料配比对技术新成土理化性质的影响。结果表明:制备的技术新成土pH在7.08~7.69之间,水稳性团聚体总量为49.83%~86.44%,团聚体破碎率为13.10%~32.20%,平均质量直径和几何平均直径分别为0.54~1.04 mm和0.54~0.89 mm。培养后技术新成土的氮、磷、钾速效养分分别下降了11.03%~38.08%、5.79%~25.06%、0.11%~10.52%,总有机碳含量在5.26%~8.74%之间,整体养分含量处于较高水平。DTPA提取态Zn含量升高了15.74%~102.40%,DTPA提取态Cd含量降低了17.39%~65.02%。生物毒性实验表明有9种处理不会对植物生长产生明显影响,有3种处理需要对配方进行调整。综合pH、团聚体总量及稳定性、养分含量来看,所制备的技术新成土的性质基本达到了自然土壤的正常范围,可以用于土壤复垦、改良或代替部分自然土壤。污泥会导致处理中重金属Zn含量较高,因此制备的技术新成土应避免种植蔬菜、粮食等农作物。

关键词：固体废弃物技术新成土养分土壤团聚体重金属

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Pushing the boundaries: an interview with Dae-Hyun Kim on terahertz devices

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National Science Review 2024年第3期11卷 42-45页

作者： Defu wang the Center for Carbon-based Electronics School of Electronics Peking University

Ⅲ–Ⅴ compound semiconductors, such as InGaAs/InAlAs, exhibit exceptional carrier transport properties, establishing them as fundamental elements in terahertz(THz) applications crucial for the development of 6G netwo...

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Enrichment of anammox biomass during mainstream wastewater treatment driven by achievement of partial denitrification through the addition of bio-carriers

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Journal of Environmental Sciences 2024年第3期137卷 181-194页

作者： Yuqing Ma Bo wang Xiaodi Li Shuo wang Wen wang Yongzhen Peng National Engineering Laboratory for Advanced Municipal Wastewater Treatment and Reuse Technology Engineering Research Center of BeijingBeijing University of TechnologyBeijing 100124China

Anammox is widely considered as the most cost-effective and sustainable process for nitrogen removal.However,how to achieve the enrichment of anammox biomass remains a challenge for its large-scale application,especially in mainstream wastewater treatment.In this study,the feasibility of enrichment of anammox biomass was explored through the realization of partial denitrification and the addition of bio-carriers.By using ordinary activated sludge,a sequencing batch reactor(SBR)followed by an up-fow anaerobic sludge bed(UASB)was operated at 25±2℃ for 214 days.The long-term operation was divided into five phases,in which SBR and UASB were started-up in Phases I and II,respectively.By eliminating oxygen and adjusting the infow ratios in Phases III-V,advanced nitrogen removal was achieved with the effuent total nitrogen being 4.7 mg/L and the nitrogen removal efficiency being 90.5%in Phase V.Both in-situ and ex-situ activity tests demonstrated the occurrence of partial denitrification and anammox.Moreover,16S rRNA high-throughput sequencing analysis revealed that Candidatus Brocadia was enriched from below the detection limit to in biofilms(0.4%in SBR,2.2%in UASB)and the foc sludge(0.2%in SBR,1.3%in UASB),while Thauera was mainly detected in the foc sludge(8.1%in SBR,8.8%in UASB),which might play a key role in partial denitrification.Overall,this study provides a novel strategy to enrich anammox biomass driven by rapid achievement of partial denitrification through the addition of bio-carriers,which will improve large-scale application of anammox processes in mainstream wastewater treatment.

关键词： Enrichment Anammox biomass Bio-carriers Partial denitrification Mainstream wastewater

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