检索结果-南通市图书馆

Preferential adsorption control: Ca-based LDO for regenerating used lubricating oil

在线全文

学校读者我要写书评

暂无评论

Progress in Natural Science:Materials International 2024年第1期34卷 155-161页

作者： Xiao-lei Zhang Jian-zhong Wu Yun Liu Zai-wu Zhang Chao Hu yong-sheng lu School of Environmental and Chemical Engineering Shanghai University Shanghai Chengtou Wastewater Treatment CO. LTD Shanghai Shangsheng Ecological Engineering Co. Ltd. Shencai Technology Co. Ltd

Different Ca-based layered double oxides（LDO） were applied in the removal of contaminants in used lubricating oil as an alternative decolorant. CaAl-LDO and CaFeAl-LDO achieved much greater decoloration efficiency than the traditional decolorants, where 0.93 and 0.91 of the decoloration efficiency under the optimum conditions were obtained, respectively. The decoloration activity with CaFeAl-LDO > CaAl-LDO >> CaFe-LDO was revealed by both Density Functional Theory（DFT） calculations and experimental analysis. Ca12Al14O33was shown to be the active component for decoloration. Fe3+doped into CaAl-LDO could improve decoloration activity via a changed charge distribution of decolorant. High preferential adsorption activity, which originated from different charge distribution for contaminants instead of the oil components, contributed to outstanding decoloration performance. The activity depended on the adsorption intensity of contaminants, where the most of the active decolorant neither too strongly or weakly bound with the contaminants. The results of this study suggested the Cabased LDOs could be a potentially alternative decolorants for regenerating the used lubricating oil.

关键词： Used lubrication oil Adsorption Ca-LDO Decoloration DFT calculation

Effects of SO_2 and SO_3 on the formation of polychlorinated dibenzo-p-dioxins and dibenzofurans by de novo synthesis

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Journal of Zhejiang University-Science A(Applied Physics & Engineering) 2010年第5期11卷 363-369页

作者： Ke SHAO Jian-hua YAN Xiao-dong LI sheng-yong lu Mu-xing FU Ying-lei WEI State Key Laboratory of Clean Energy Utilization Zhejiang University Hangzhou 310027 China

The effects of SO2,SO3 on de novo synthesis of polychlorinated dibenzo-p-dioxins (PCDDs) and dibenzofurans (PCDFs) were studied using model fly ashes incorporating copper oxide and activated carbon. It was found that the inhibitive effect of SO2 on PCDD/Fs formation is similar to that of SO3. To investigate the inhibition mechanism,CuSO4 formations from both CuO and CuCl2 were examined. The ability of SO3 to convert CuCl2 and CuO on a silica support into sulfate is much stronger than that of SO2. However,replacing silica by activated carbon leads to a much high conversion of CuCl2 to CuSO4 in the presence of SO2. The promotion by activated carbon is explained by the reduction of CuCl2 to Cu2Cl2 and the eventual conversion of Cu2Cl2 into CuSO4 is the main inhibition mechanism of SO2 on de novo synthesis of PCDD/Fs.

关键词： Cuprous chloride Model fly ash Sulfation Cupric chloride

Polychlorinated dibenzo-p-dioxins and dibenzofurans in flue gas emissions from municipal solid waste incinerators in China

在线全文

学校读者我要写书评

暂无评论

Journal of Zhejiang University-Science A(Applied Physics & Engineering) 2008年第9期9卷 1296-1303页

作者： Tong CHEN Yue-ling GU Jian-hua YAN Xiao-dong LI sheng-yong lu Hui-fen DAI Ke-fa CEN State Key Laboratory of Clean Energy Utilization Zhejiang University Hangzhou 310027 China School of Medicine Zhejiang University Hangzhou 310058 China

Polychlorinated dibenzo-p-dioxins and furans （PCDD/Fs） emissions in flue gas from two types of municipal solid waste incinerators （MSWIs） most commonly used in China were investigated in this study. The selected incinerators include two grate-type MSWIs： MSWI-A （350 t/d） and MSWI-B 050 t/d）, and two fluidized bed MSWIs： MSWI-C （400 t/d） and MSWI-D （400 t/d）, which are all equipped with semi-dry lime scrubber and bag filter except MSWI-D equipped with cyclone and wet scrubber （WS） as air pollutant control device （APCD）. Results indicated that the emission concentration and the international toxic equivalents （I-TEQs） of the PCDD/Fs from the stacks were in the range of 1.210-10.273 ng/Nm^3 and 0.019-0.201 ng I-TEQ/Nm^3, respectively. They were greatly lower than the emission regulation standard of PCDD/Fs in China （1.0 ng I-TEQ/Nm^3）. However, only the PCDD/Fs emission level from MSWI-C was below 0.1 ng I-TEQ/Nm^3. Although the homologue profiles were distinct, the contributions of the 2,3,7,8-subsituted congeners to the total I-TEQ were similar among all the investigated MSWIs. Two major 2,3,7,8-substituted congeners, 2,3,4,7,8-PeCDF and 1,2,3,7,8-PeCDD, account for 47% and 9% （average values） of the total I-TEQ values, respectively. The correlation between PCDD/Fs levels and composition of flue gas was also discussed.

关键词： Polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/Fs) Municipal solid waste incinerator (MSWI) Grate Fluidized bed

Application of the ISCST3 model for predicting PCDD/F concentrations in agricultural soil in the vicinity of a MSWI plant in China

在线全文

学校读者我要写书评

暂无评论

Journal of Zhejiang University-Science A(Applied Physics & Engineering) 2008年第3期9卷 373-380页

作者： Meng-xia XU Jian-hua YAN sheng-yong lu Xiao-dong LI Tong CHEN Ming-jiang NI Hui-fen DAI Ke-fa CEN State Key Laboratory of Clean Energy Utilization Institute for Thermal Power Engineering Zhejiang University Hangzhou 310027 China School of Medicine Zhejiang University Hangzhou 310058 China

Based on the Industrial Source Complex Short-Term Version 3 （ISCST3） model, a simplified modeling approach was developed to predict concentrations of congeners of polychlorinated-p-dioxins and dibenzofurans （PCDD/Fs） of agricultural soil, within a radius of 3 kin from a municipal solid waste incinerator （MSWI） plant after its 4-year operation in Hangzhou, China. Comparisons were made between the measured and estimated congener-specific concentrations and the international-toxic equivalent （I-TEQ） values of soil samples with respect to distance from the stack. The results indicate that the predictions of soil PCDD/F concentrations and K-TEQ values were generally lower than their observations, and that the higher the degree of underestimation seems, the greater the further downwind one gets. Nevertheless, most of the predictions were in good agreement with the trend of measured ones and were within a factor of ten for samples located within 1 kin of the plant. Besides, analysis of contributions of various deposition pathways confirms that in addition to wet particle deposition, the dry gaseous deposition is essential for realistic prediction of PCDD/F depositions to soil, especially for tetra- and penta-chlorinated dioxins.

关键词： Agricultural soil Dispersion model ISCST3 Municipal solid waste incinerator (MSWI) Polychlorinated-p-dioxins and dibenzofurans (PCDD/Fs)

生活垃圾焚烧残灰中有毒成分的排放特性（英文）

在线全文

学校读者我要写书评

暂无评论

Journal of Zhejiang University-Science A(Applied Physics & Engineering) 2015年第4期16卷 316-325页

作者： Xiao-dong LI yong REN Sha-sha JI Xia-li HOU Tong CHEN sheng-yong lu Jian-hua YAN State Key Laboratory of Clean Energy Utilization Zhejiang University

目的:探索中国生活垃圾焚烧残灰中重金属、氯苯、多环芳烃等有毒成分的排放特性、排放水平及相互之间的关联特性,并认识其产生、排放与焚烧炉型、焚烧条件的关联,以探索控制其危害的有效方法。方法:1.对中国几个典型的生活垃圾焚烧炉现... 详细信息

目的:探索中国生活垃圾焚烧残灰中重金属、氯苯、多环芳烃等有毒成分的排放特性、排放水平及相互之间的关联特性,并认识其产生、排放与焚烧炉型、焚烧条件的关联,以探索控制其危害的有效方法。方法:1.对中国几个典型的生活垃圾焚烧炉现场采样,获得多个飞灰和底渣的样品;2.通过多种不同的检测手段和方法,分别检测残灰的基本物理化学特性、氯苯、多环芳烃和主要金属元素的浓度;3.结合焚烧炉型和焚烧特性等条件,分析各有毒成分的排放特性和相互之间的关联特性。结论:1.氯苯、多环芳烃和重金属受焚烧因素影响,在残灰中的排放特性各不相同,流化床焚烧炉能消除焚烧和原始垃圾的扰动,能控制氯苯在残灰中的排放,但多环芳烃排放控制不如炉排焚烧炉;2.残灰中主要的有机有毒成分为高氯代氯苯和2至4环等少环类多环芳烃;3.氯苯和多环芳烃在残灰中的含量可能因为不同的产生机理而表现出一定的负关联特点;4.残灰中的金属主要为铝和铁等轻金属,浓度远高于重金属元素,而无毒重金属(主要为Mn、Ni、As和Zn)浓度高于有毒重金属元素(Cu、Pb和Cr),且不同金属表现出不同的对氯苯和多环芳烃的催化促进或抑制作用。

关键词：残灰氯苯多环芳烃重金属生活垃圾焚烧

Surface Plasmon Resonance Sensors Based on Polymer Optical Fiber

在线全文

学校读者我要写书评

暂无评论

Journal of Electronic Science and Technology of China 2008年第4期6卷 357-360页

作者： Rong-sheng Zheng yong-Hua lu Zhi-Guo Xie Jun Tao Kai-Qun Lin Hai Ming The authors are with Department of Physics University of Science and Technology of China Anhui Key Laboratory of Optoelectronic Science and Technology Hefei 230026 China

Surface Plasmon Resonance （SPR） is a powerful technique for directly sensing in biological studies, chemical detection and environmental pollution monitoring. In this paper, we present polymer optical fiber application in SPR sensors, including wavelength interrogation surface enhanced Raman scattering SPR sensor and surface enhanced Raman scattering （SERS） probe. Long-period fiber gratings are fabricated on single mode polymer optical fiber （POF） with 120 μm period and 50% duty cycle. The polarization characteristic of this kind of birefringent grating is studied. Theoretical analysis shows it will be advantageous in SPR sensing applications.

关键词： Optical fiber gratings polymer optical fiber surface plasmon resonance surface plasmon wave(SPW) surface enhanced Raman scattering.

Enhancing m^(6)A modification in the motor cortex facilitates corticospinal tract remodeling after spinal cord injury

在线全文

学校读者我要写书评

暂无评论

Neural Regeneration Research 2025年第6期20卷 1749-1763页

作者： Tian Qin Yuxin Jin Yiming Qin Feifei Yuan Hongbin lu Jianzhong Hu yong Cao Chengjun Li Department of Spine Surgery and Orthopedics Xiangya HospitalCentral South UniversityChangshaHunan ProvinceChina Key Laboratory of Organ Injury Aging and Regenerative Medicine of Hunan ProvinceChangshaHunan ProvinceChina National Clinical Research Center for Geriatric Disorders Xiangya HospitalCentral South UniversityChangshaHunan ProvinceChina Department of Sports Medicine Xiangya HospitalCentral South UniversityChangshaHunan ProvinceChina

Spinal cord injury typically causes corticospinal tract disruption. Although the disrupted corticospinal tract can self-regenerate to a certain degree, the underlying mechanism of this process is still unclear. N6-methyladenosine(m^(6)A) modifications are the most common form of epigenetic regulation at the RNA level and play an essential role in biological processes. However, whether m^(6)A modifications participate in corticospinal tract regeneration after spinal cord injury remains unknown. We found that expression of methyltransferase 14 protein(METTL14) in the locomotor cortex was high after spinal cord injury and accompanied by elevated m^(6)A levels. Knockdown of Mettl14 in the locomotor cortex was not favorable for corticospinal tract regeneration and neurological recovery after spinal cord injury. Through bioinformatics analysis and methylated RNA immunoprecipitation-quantitative polymerase chain reaction, we found that METTL14 regulated Trib2 expression in an m^(6)A-regulated manner, thereby activating the mitogen-activated protein kinase pathway and promoting corticospinal tract regeneration. Finally, we administered syringin, a stabilizer of METTL14, using molecular docking. Results confirmed that syringin can promote corticospinal tract regeneration and facilitate neurological recovery by stabilizing METTL14. Findings from this study reveal that m^(6)A modification is involved in the regulation of corticospinal tract regeneration after spinal cord injury.

关键词： corticospinal tract remodeling epigenetic regulations locomotor cortex m^(6)A modification methyltransferase 14 protein(METTL14) mitogen-activated protein kinase neural regeneration spinal cord injury syringin TRIB2

De novo synthesis of atropisomeric benzofurans via Cu/SPDO complex catalyzed asymmetric formal [3 + 2] annulation

在线全文

学校读者我要写书评

暂无评论

Science China Chemistry 2025年第1期68卷 174-180页

作者： Fan-Xiao Meng Xing-Yu Wang Ka lu Ju-Song Yang Fu-Min Zhang Ai-Jun Ma Bao Du yong-Qiang Tu State Key Laboratory of Applied Organic Chemistry College of Chemistry and Chemical Engineering Lanzhou University School of Chemistry and Chemical Engineering Shanghai Jiao Tong University School of Biotechnology and Health Sciences Wuyi University

Herein, the de novo synthesis of atropisomeric benzofurans through the Cu/spirocyclic-pyrrolidine-oxazoline(SPDO) complex catalyze asymmetric formal [3 + 2] cycloaddition between quinones and ynamides is explored, producing a range of structurally diverse axially chiral benzofurans in satisfactory yields with good to excellent enantioselectivities. Furthermore, density functional theory calculations were applied to explain the possible reaction mechanism.

关键词： benzofuran atropisomers novel de novo synthetic strategy asymmetric formal [3 + 2] cycladdition Cu/SPDO complex DFT calculations

Erratum to:Emission characteristics of hazardous components in municipal solid waste incinerator residual ash

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Journal of Zhejiang University-Science A(Applied Physics & Engineering) 2015年第7期16卷 596-596页

作者： Xiao-dong LI yong REN Sha-sha JI Xia-li HOU Tong CHEN sheng-yong lu Jian-hua YAN State Key Laboratory of Clean Energy Utilization Zhejiang University

Erratum to:J Zhejiang Univ-Sci A(Appl Phys&Eng)2015 16(4):316-325doi:10.1631/jzus.A1400142The original version of this article unfortunately contained some *** p.318,the column of "Pore size(nm)" in Table 2 was incorrect,and the correct unit is ? instead of *** p.322,the numerical values of metal concentrations in the test were incorrectly used,because one batch of the detection values was incorrectly used instead of the average values.

关键词： In nm Erratum to