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In-situ embedded ultrafine Bi_(12)O_(17)Br_(2)nanotubes in MOF-derived hierarchical porous carbon for enhanced photocatalytic CO_(2)conversion to CO

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Journal of Materials Science & Technology 2024年第4期171卷 47-53页

作者： Xing Sun Mengxia Ji Yi Zhang Qingzeng Xing Zihan Liu Nianhua Liu Emmanuel Nkudede Huaming Li sheng yin Jiexiang Xia School of Chemistry and Chemical Engineering Institute for Energy ResearchJiangsu UniversityZhenjiang 212013China Key Laboratory of Comprehensive and Highly Efficient Utilization of Salt Lake Resources Qinghai Provincial Key Laboratory of Resources Chemistry of Salt LakesQinghai Institute of Salt LakesChinese Academy of SciencesXining 81008China

Increasing the utilization efficiency of photogenerated electrons is highly recognized as one of the ef-ficient approaches to boost the photocatalytic CO_(2)conversion efficiency.Herein,ZIF-67-derived porous carbon(PC)material was employed for the construction of PC@ultrafine Bi_(12)O_(17)Br_(2)nanotubes(PC@BOB NTs)composites through a facile solvothermal synthesis in order to optimize the use of excited elec-trons in the BOB NTs.Photoelectrochemical characterization results revealed that the introduction of PC material achieved a faster charge separation rate in the PC@BOB composites,ensuring more photogener-ated electrons participate in the CO_(2)adsorption and activation process.Moreover,the pore structures of ZIF-67-derived PC material provided abundant confined spaces for the enrichment of CO_(2)molecules.Af-ter 5 h of Xenon lamp irradiation,PC@BOB composites exhibited obviously increased photocatalytic CO_(2)reduction activity in the pure water.When the addition amount of PC was 5 wt%,the PC@BOB-2 com-posite showed the highest CO evolution rate of 359.70μmol/g,which was 2.95 times higher than that of the pure BOB NTs.This work provides some independent insights into the applications of Metal-Organic Framework(MOF)-derived hierarchical porous structures to strengthen the CO_(2)enrichment,as well as the excited charge utilization efficiency,thus achieving a high solar-to-fuel conversion efficiency.

关键词： Bi_(12)O_(17)Br_(2)nanotubes Hierarchical porous structure CO_(2)enrichment Charge separation CO_(2)photoreduction

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Long-term functional maintenance of primary hepatocytes in vitro using macroporous hydrogels engineered through liquid-liquid phase separation

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Nano Research 2024年第3期17卷 1725-1736页

作者： Yang Sun sheng yin Jian Cui Zhongxia Wang Yueying Han Ding Ma Shuo Wang Junhua Wu Yi Cao Chunping Jiang Xiaosong Gu Jinan Microecological Biomedicine Shandong Laboratory Jinan 250021China Collaborative Innovation Center of Advanced Microstructures National Laboratory of Solid State MicrostructureKey Laboratory of Intelligent Optical Sensing and ManipulationMinistry of EducationDepartment of PhysicsNanjing UniversityNanjing 210093China Department of Hepatobiliary Surgery The Affiliated Drum Tower Hospital of Nanjing University Medical SchoolNanjing 210093China National Institute of Healthcare Data Science at Nanjing University Nanjing UniversityNanjing 210093China

Preserving the functionality of hepatocytes in vitro poses a significant challenge in liver tissue engineering and bioartificial liver,as these cells rapidly lose their metabolic and functional characteristics after isolation.Inspired by the macroporous structures found in native liver tissues,here we develop synthetic hydrogel scaffolds that closely mimic the liver’s structural organization through the phase separation between polyethylene glycol(PEG)and polysaccharides.Our hydrogels exhibit interconnected macroporous structures and appropriate mechanical properties,providing an optimal microenvironment conducive to hepatocyte adhesion and the formation of sizable aggregates.Compared to two-dimensional hepatocyte cultures,enhanced functionalities of hepatocytes cultured in our macroporous hydrogels were observed for 14 days,as evidenced by quantitative reverse-transcription–polymerase chain reactions(qRT-PCR),immunofluorescence,and enzyme linked immunosorbent assay(ELISA)analyses.Protein sequencing data further confirmed the establishment of cell–cell interactions among hepatocytes when cultured in our hydrogels.Notably,these hepatocytes maintained a protein expression lineage that closely resembled freshly isolated hepatocytes,particularly in the Notch and tumor necrosis factor(TNF)signaling pathways.These results suggest that the macroporous hydrogels are attractive scaffolds for liver tissue engineering.

关键词： liver tissue engineering phase separation hepatocytes macroporous hydrogel

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CdBiO2Br nanosheets in situ strong coupling to carbonized polymer dots and improved photocatalytic activity for organic pollutants degradation

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Chinese Chemical Letters 2022年第12期33卷 5189-5195页

作者： Zhiyuan Pang Bin Wang Xingwang Yan Chongtai Wang sheng yin Huaming Li Jiexiang Xia School of Chemistry and Chemical Engineering Institute for Energy ResearchJiangsu UniversityZhenjiang 212013China School of Chemistry and Chemical Engineering the Key Laboratory of Electrochemical Energy Storage and Energy Conversion of Hainan ProvinceHainan Normal UniversityHaikou 571158China

Carbonized polymer dots(CPDs)modified layer-structured CdBiO_(2)Br(CPDs/CdBiO_(2)Br)Z-scheme heterojunction hybrid material has been synthesized via simple solvothermal method.The hybrid material with Z-scheme heterojunction can effectively maintain the original highly oxidizing holes of CdBiO_(2)Br and the highly reducing electrons of CPDs.In addition,the construction of heterostructure is beneficial to the migration and separation of photogenerated carriers.Under visible light irradiation,6 wt%CPDs/CdBiO_(2)Br showed the best catalytic activity for degradation of organic pollutants.Free radical capture experiments and ESR analysis confirmed that the main active species are·O_(2)^(-)and h^(+).The decomposition process of organic pollutants was analyzed by LC-MS.Finally,the probable visible light mechanism performance of CPDs/CdBiO_(2)Br as direct Z-scheme heterojunction photocatalytic materials was proposed.

关键词： Carbonized polymer dots CdBiO_(2)Br Direct Z-scheme heterojunction Pollutant degradation Photocatalytic activity

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Mulberry Diels-Alder-type adducts:isolation,structure,bioactivity,and synthesis

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Natural Products and Bioprospecting 2022年第1期12卷 442-504页

作者： Si-Yuan Luo Jun-Yu Zhu Ming-Feng Zou sheng yin Gui-Hua Tang School of Pharmaceutical Sciences Sun Yat-Sen UniversityGuangzhouGuangdong 510006People’s Republic of China

Mulberry Diels-Alder-type adducts(MDAAs)are unique phenolic natural products biosynthetically derived from the intermolecular[4+2]-cycloaddition of dienophiles(mainly chalcones)and dehydroprenylphenol dienes,which are exclusively distributed in moraceous plants.A total of 166 MDAAs with diverse skeletons have been isolated and identified since 1980.Structurally,the classic MDAAs characterized by the chalcone-skeleton dienophiles can be divided into eight groups(Types A−H),while others with non-chalcone dienophiles or some variations of classic MDAAs are non-classic MDAAs(Type I).These compounds have attracted significant attention of natural products and synthetic chemists due to their complex architectures,remarkable biological activities,and synthetic challenges.The present review provides a comprehensive summary of the structural properties,bioactivities,and syntheses of MDAAs.Cited references were collected between 1980 and 2021 from the SciFinder,Web of Science,and China National Knowledge Internet(CNKI).

关键词： Mulberry Diels-Alder-type adducts MDAAs Natural products Bioactivity Synthesis

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Euphorstranoids A and B,two highly rearranged ingenane diterpenoids from Euphorbia stracheyi:structural elucidation,chemical transformation,and lipid-lowering activity

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Organic Chemistry Frontiers 2022年第3期9卷 775-780页

作者： Fang-Yu Yuan Yue-Hua Pan Ai-Ping yin Wei Li Dong Huang Xue-Long Yan Shu-Qi Wu Gui-Hua Tang Rong Pu sheng yin School of Pharmaceutical Sciences Sun Yat-sen UniversityGuangzhouGuangdong 510006People’s Republic of China Department of Clinical Laboratory the Third People’s Hospital of DongguanDongguan 523326People’s Republic of China

Euphorstranoids A(1)and B(2),two highly rearranged ingenane diterpenoids with an unusual 5/6/7/3 carbon ring system,were isolated from Euphorbia stracheyi.Their structures were determined by a combination of spectral,chemical,and X-ray diffraction methods.The plausible biosynthetic pathway of 1 and 2 was proposed and chemically mimicked.Compounds 1 and 2 significantly inhibited the triglyceride(TG)level in 3T3-L1 adipocytes via retarding cell adipogenesis at the early stage.

关键词： methods chemical elucidation

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In-Situ Synthesis of CQDs/BiOBr Material via Mechanical Ball Milling with Enhanced Photocatalytic Performances

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Chinese Journal of Structural Chemistry 2022年第8期41卷 44-51页

作者： Xingwang Yan Bin Wang Mengxia Ji Qi Jiang Gaopeng Liu Pengjun Liu sheng yin Huaming Li Jiexiang Xia Key Laboratory of Medicinal and Edible Plants Resources of Hainan Province Hainan Vocational University of Science and TechnologyHaikou 571126China School of Chemistry and Chemical Engineering Institute for Energy ResearchJiangsu UniversityZhenjiang 212013China

Designing simple, efficient, and environmentally friendly methods to construct high-efficient photocatalysts is an important strategy to promote the further development of the field of photocatalysis. Herein, flower-like carbon quantum dots(CQDs)/Bi OBr composite photocatalysts have been prepared via in-situ synthesis by mechanical ball milling in the existence of ionic liquid. The CQDs/Bi OBr composites exhibit higher photo-degradation performance for tetracycline(TC) than Bi OBr monomer and the commercial Bi_(2)O_(3) under visible light irradiation. For comparison, the different Br sources and synthetic methods are chosen to prepare Bi OBr and CQDs/Bi OBr composites. Photocatalysts prepared by ball milling and ionic liquid present significantly enhanced photocatalytic performance for removing TC. In addition, the introduction of CQDs could distinctly enhance the photocatalytic performances of pure Bi OBr. The reason is that CQDs as electron acceptor effectively separate electrons and holes and inhibit their recombination. The intermediates during photocatalytic degradation were tested using liquid chromatography-mass spectrometry(LC-MS) and possible degradation pathways were given. During degradation, ·OH, O_(2)^(·-)and h^(+) were identified to be the main active species based on electron spin resonance(ESR) spectra and free radical trapping experiments. A possible mechanism of CQDs/Bi OBr with enhanced photocatalytic performances was further proposed.

关键词： CQDs BiOBr photocatalysis pollutant degradation

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Simulation study on the active layer thickness and the interface of a-IGZO-TFT with double active layers

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Frontiers of Optoelectronics 2015年第4期8卷 445-450页

作者： Xiaoyue LI sheng yin Dong XU School of Optical and Electronic Information Huazhong University of Science and Technology Wuhan 430074 China

In this paper, ATLAS 2D device simulator of SILVACO was used for device simulation of inverted- staggered thin film transistor using amorphous indium gallium zinc oxide as active layer （a-IGZO-TFT） with double active layers, based on the density of states （DOS） model of amorphous material. The change of device performance induced by the thickness variation of each active layer was studied, and the interface between double active layers was analyzed. The best performance was found when the interface was near the edge of the channel, by optimizing the thickness of each active layers, the high performance device of threshold voltage （Vth） = -0.89 V, sub-threshold swing （SS）= 0.27, on/off current ratio （IoN/IoFF） = 6.98 × 10^14 was obtained.

关键词： amorphous indium gallium zinc oxide （a-IGZO） double active layers interface density of states（DOS） ATLAS

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Structural, optical and electrical properties of ZnO： B thin films with different thickness for bifacial a-Si：H/c-Si heterojunction solar cells

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Frontiers of Optoelectronics 2017年第1期10卷 31-37页

作者： Dong XU sheng yin Xiangbin ZENG Song YANG Xixing WEN School of Optical and Electronic Information Huazhong University of Science and Technology Wuhan 430074 China

Textured surface boron-doped zinc oxide （BZO） thin films were fabricated by metal organic chemical vapor deposition as transparent conductive oxide （TCO） for solar cells. The surface microstructure was characterized by X-ray diffraction spectrum and scan- ning electron microscope. The optical transmittance was shown by optical transmittance microscope and the electrical properties were tested by Hall measurements. The thickness of the BZO film has crucial impact on the surface morphology, optical transmittance, and resistivity. The electrical and optical properties as well as surface microstructure varied inconsistently with the increase of the film thickness. The grain size and the surface roughness increased with the increase of the film thickness. The conductivity increased from 0.96x 103 tO 6.94x 103 S/cm while the optical transmittance decreased from above 85% to nearly 80% with the increase of film thickness from 195 to 1021 nm. The BZO films deposited as both front and back transparent electrodes were applied to the bifacial p- type a-Si：H/i-type a-Si：H/n-type c-Si/i-type a-Si：H/n＋-type a-Si：H heterojunction solar cells to obtain the optimized parameter of thickness. The highest efficiency of all the samples was 17.8% obtained with the BZO film thickness of 829 nm. Meanwhile, the fill factor was 0.676, the open- circuit voltage was 0.63 Vand the short-circuit density was 41.79 mA/cm2. The properties of the solar cells changing with the thickness were also investigated.

关键词： boron-doped zinc oxide （BZO） metal organicchemical vapor deposition （MOCVD） heterojunction solarcell thickness textured surface transparent conductive oxide （TCO）

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基于深度学习的医院海量档案特征快速查询算法研究

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自动化技术与应用 2024年第5期43卷 114-117页

作者：尹声声汕头大学医学院第二附属医院广东汕头515041

为提高档案特征查询结果的查全率和查准率,提出基于深度学习的医院海量档案特征快速查询算法。通过深度学习,建立深度卷积神经网络,采用文本聚类算法,划分档案文本类别,利用图搜图的方式,通过神经网络,提取指定档案的图像特征,得到图像... 详细信息

为提高档案特征查询结果的查全率和查准率,提出基于深度学习的医院海量档案特征快速查询算法。通过深度学习,建立深度卷积神经网络,采用文本聚类算法,划分档案文本类别,利用图搜图的方式,通过神经网络,提取指定档案的图像特征,得到图像内容对应的文本注释,搜索该文本归属簇集,将簇集内所有文本的特征词和主题作为文本特征,将文本数据匹配到的图像作为图形特征。选取医学领域公共数据集作为实验数据,实验结果表明,针对海量档案文本特征和图像特征,设计算法提高了特征查询查全率和查准率,档案特征快速查询精度更优。

关键词：深度学习档案特征查询算法神经网络文本聚类特征词

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Ab initio modeling of the energy landscape for screw dislocations in body-centered cubic high-entropy alloys

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npj Computational Materials 2020年第1期6卷 754-764页

作者： sheng yin Jun Ding Mark Asta Robert O.Ritchie Department of Materials Science and Engineering University of CaliforniaBerkeleyCA 94720USA Materials Sciences Division Lawrence Berkeley National LaboratoryBerkeleyCA 94720USA

In traditional body-centered cubic(bcc)metals,the core properties of screw dislocations play a critical role in plastic deformation at low temperatures.Recently,much attention has been focused on refractory high-entropy alloys(RHEAs),which also possess bcc crystal structures.However,unlike face-centered cubic high-entropy alloys(HEAs),there have been far fewer investigations into bcc HEAs,specifically on the possible effects of chemical short-range order(SRO)in these multiple principal element alloys on dislocation mobility.Here,using density functional theory,we investigate the distribution of dislocation core properties in MoNbTaW RHEAs alloys,and how they are influenced by SRO.The average values of the core energies in the RHEA are found to be larger than those in the corresponding pure constituent bcc metals,and are relatively insensitive to the degree of SRO.However,the presence of SRO is shown to have a large effect on narrowing the distribution of dislocation core energies and decreasing the spatial heterogeneity of dislocation core energies in the RHEA.It is argued that the consequences of the mechanical behavior of HEAs is a change in the energy landscape of the dislocations,which would likely heterogeneously inhibit their motion.

关键词： alloys deformation cubic

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