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Nonlinear electronic and ultrafast optical signatures in chemical vapor-deposited ultrathin PtS_(2) ribbons

Nano Research 2022年第5期15卷 4366-4373页

作者： shaolong jiang Jin Yang Liang Zhu Jiafeng Xie Weiteng Guo Erding Zhao Chaoyu Chen Tianwu Wang Fuhai Su Yanfeng Zhang Junhao Lin Shenzhen Key Laboratory of Advanced Quantum Functional Materials and Devices and Department of Physics Southern University of Science and TechnologyShenzhen 518055China Key Laboratory of Materials Physics Institute of Solid State PhysicsHFIPSChinese Academy of SciencesHefei 230031China University of Science and Technology of China Hefei 230026China Great Bay Area Research Institute Aerospace Information Research Institute(AIR)of Chinese Academy of Science(CAS)Guangzhou 510700China Shenzhen Institute for Quantum Science and Engineering and Department of Physics Southern University of Science and TechnologyShenzhen 518055China International Quantum Academy and Shenzhen BranchHefei National LaboratoryFutian DistrictShenzhen 518048China School of Materials Science and Engineering Peking UniversityBeijing 100871China

The emerging two-dimensional(2D)platinum disulfide(PtS_(2))has driven increasing attentions due to its high electron mobility,good air-stability,and strong interlayer interaction which leads to a widely tunable electronic structure.However,a detailed study on its covalent-like layer-dependent properties remains infant.Herein,we demonstrate the successful production of ultrathin 1T-PtS_(2) ribbons with thickness centralized almost at monolayer 1L-4L and large domain size up to 210 μm on Au foils using chemical vapor deposition(CVD)technique,which enables macro-and microscopic study of its extraordinary layer-dependent features with precise control of the number of layers.Using electron energy loss spectroscopy(EELS)and optical pump-probe spectroscopy(OPPS),we reveal that both the electron and ultrafast optical absorption signals of the as-grown 2D PtS_(2) show strong nonlinear layer-dependent responses which manifest discriminated transition in 1L-4L PtS_(2) ribbons.The layer-dependent nonlinear response of 2D PtS_(2) can be well interpreted in the frame of calculated electron and phonon structures.These achievements offer a platform for successfully fabricating large-sized ultrathin 2D PtS_(2) and facilitating our knowledge about its electronic and optoelectronic properties.

关键词： platinum disulfide(PtS_(2)) chemical vapor deposition electronic transition saturable absorption optical pump-probe spectroscopy

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Salt-assisted growth and ultrafast photocarrier dynamics of large-sized monolayer ReSe2

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Nano Research 2020年第3期13卷 667-675页

作者： shaolong jiang Jin Yang Yuping Shi Jing Zhao Chunyu Xie Liyun Zhao Jiatian Fu Pengfei Yang Yahuan Huan Qin Xie Huachao jiang Qing Zhang Xianlong Wang Fuhai Su Yanfeng Zhang Department of Materials Science and Engineering College of EngineeringPeking UniversityBeijing100871China Key Laboratory of Materials Physics Institute of Solid State PhysicsChinese Academy of SciencesHefei230031China University of Science and Technology of China Hefei230026China Center for Nanochemistry(CNC) Beijing National Laboratory for Molecular SciencesCollege of Chemistry and Molecular EngineeringPeking UniversityBeijing100871China

Owing to its anisotropic optical and electrical properties,rhenium diselenide(ReSe2)has garnered considerable attention recently as a candidate material for polarization-sensitive photodetectors.However,the direct and controllable synthesis of large-sized ReSe2 with a uniform thickness is still a great challenge.Herein,we have refined the synthesis method to obtain uniform monolayer ReSe2 flakes with a size of up to^106μm on sapphire via an ambient-pressure chemical vapor deposition technique using Na promoter from sodium chloride.Interestingly,optical pump-probe spectroscopy revealed a fast switching from saturable absorption(SA)to absorption enhancement(AE)in subpicosecond time scale,followed by a slower decay induced by exciton recombination.Furthermore,both AE and SA signals exhibited clear angular dependence with a periodicity of 180°,which reflected the dichroism in nonlinear absorption dynamics.In addition,the photocarrier dynamics including free-carrier transport and subpicosecond relaxation due to exciton formation or surface trapping was probed using time resolved terahertz spectroscopy.We believe that our study serves as a reference for atomically controlled synthesis of large-sized ReSe2 and provides useful insights on its optoelectronic properties for novel device applications.

关键词： ReSe2 chemical vapor deposition sodium chloride large size ultrafast photocarrier dynamics

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Scalable salt-templated directed synthesis of high-quality MoS_(2) nanosheets powders towards energetic and environmental applications

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Nano Research 2020年第11期13卷 3098-3104页

作者： Lijie Zhu Pengfei Yang Yahuan Huan Shuangyuan Pan Zhaoqian Zhang Fangfang Cui Yuping Shi shaolong jiang Chunyu Xie Min Hong Jiatian Fu Jingyi Hu Yanfeng Zhang Department of Materials Science and Engineering College of EngineeringPeking UniversityBeijing100871China

Two-dimensional(2D)transition metal dichalcogenides(TMDCs)have emerged as perfect platforms for developing applications in nano-electronics,catalysis,energy storage and environmental-related fields due to their superior properties.However,the low-cost,batch production of high-quality 2D TMDCs remains a huge challenge with the existing synthetic strategies.Herein,we present a scalable chemical vapor deposition(CVD)approach for the batch production of high-quality MoS_(2) nanosheet powders,by using naturally abundant,water-soluble and recyclable NaCl crystal powders as templates.The high-quality MoS_(2) nanosheets powders are achieved by a facile water dissolution-filtration process,by virtue of the excellent dispersibility of the as-grown products in water.The internal mechanism for the scalable synthesis strategy is explored.The applications of the MoS_(2) nanosheets powders are also demonstrated as catalysts or adsorbents in hydrogen evolution reaction(HER)and organic dyes adsorption,respectively.This work should hereby pave ways for the mass production and application of powdery TMDCs in energetic and environmental related fields.

关键词： mass production salt-templated molybdenum disulfide chemical vapor deposition green transfer

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Application of chemical vapor-deposited monolayer ReSe2 in the electrocatalytic hydrogen evolution reaction

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Nano Research 2018年第4期11卷 1787-1797页

作者： shaolong jiang Zhepeng Zhang Na Zhang Yahuan Huan Yue Gong Mengxing Sun Jianping Shi Chunyu Xie Pengfei Yang Qiyi Fang He Li Lianming Tong Dan Xie Lin Gu Porun Liu Yanfeng Zhang Department of Materials Science and Engineering College of Engineering Peking University Beijing 100871 China Center for Nanochemistry (CNC) Beijing National Laboratory for Molecular Sciences College of Chemistry and Molecular Engineering Peking University Beijing 100871 China Beijing National Laboratory for Condensed Matter Physics Institute of Physics Chinese Academy of Sciences Beijing 100190 China School of Physical Sciences University of Chinese Academy of Sciences Beijing 100190 China Institute of Microelectronics Tsinghua National Laboratory for Information Science and Technology (TNList) Tsinghua University Beijing 100084 China Collaborative Innovation Center of Quantum Matter Beijing 100190 China Centre for Clean Environment and Energy Griffith University Gold Coast 4222 Australia

Controlled synthesis of structurally anisotropic rhenium diselenide （ReSe2） with macroscopically uniform and strictly monolayer thickness as well as tunable domain shape/size is of great interest for electronics-, optoelectronics-, and electrocatalysis-related applications. Herein, we describe the controlled synthesis of uniform monolayer ReSe2 flakes with variable morphology （sunflower- or truncated-triangle-shaped） on SiO2/Si substrates using different ambient-pressure chemical vapor deposition （CVD） setups. The prepared polycrystalline ReSe2 flakes were transferred intact onto Au foil electrodes and tested for activity in the hydrogen evolution reaction （HER）. Interestingly, compared to the compact truncated-triangle-shaped ReSe2 flakes, their edge-abundant sunflower-shaped counterparts exhibited superior electrocatalytic HER activity, featuring a relatively low Tafel slope of - 76 mV/dec and an exchange current density of 10.5 μA/cm2. Thus, our work demonstrates that CVD-grown ReSe2 is a promising two- dimensional anisotropic material for applications in the electrocatalytic HER.

关键词： rhenium diselenide,chemical vapor deposition（CVD）,monolayer,morphology control,hydrogen evolution reaction （HER）

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Space-confined growth of monolayer ReSe2 under a graphene layer on Au foils

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Nano Research 2019年第1期12卷 149-157页

作者： Chunyu Xie shaolong jiang Xiaolong Zou Yuanwei Sun Liyun Zhao Min Hong Shulin Chen Yahuan Huan Jianping Shi Xiebo Zhou Zhepeng Zhang Pengfei Yang Yuping Shi Porun Liu Qing Zhang Peng Gao Yanfeng Zhang Department of Materials Science and Engineering College of EngineeringPeking UniversityBeijing 100871China Center far Nanochemistry(CNC) Beijing National Laboratory for Molecular SciencesCollege of Chemistry and Molecular EngineeringPeking UniversityBeijing 100871China Tsinghua-Berkeley Shenzhen Institute(TBSI) Tsinghua UniversityShenzhen 518055China Electron Microscopy Laboratory School of PhysicsPeking UniversityBeijing 100871China International Center for Quantum Materials School of PhysicsPeking UniversityBeijing 100871China State Key Laboratory of Advanced Welding and Joining Harbin Institute of TechnologyHarbin 150001China Centre for Clean Environment and Energy Griffith UniversityGold Coast 4222Australia Collaborative Innovation Center of Quantum Matter Beijing 100871China

Vertical heterostructures based on two-dimensional(2D)materials have attracted widespread interest for their numerous applications in electronic and optoelectronic devices.Herein,we report the direct construct!on of an abnormal graphene/ReSe2 stack on Au foils by a two-step chemical vapor deposition(CVD)strategy.During the second growth stage,mono layer ReSe2 is found to prefere ntially evolve at the irUerface between the first-grown graphene layer and the Au substrate.The unusual stacking behavior is unraveled by in-situ"cutting open"the upper graphene from the defects to expose the lower ReSe2 using scanning tunneling microscopy(STM).From combination of these results with density functional theory calculations,the domain boundaries and edge sites of graphene are proposed to be adsorption sites for Re and Se precursors,further facilitating the growth of ReSe2 at the van der Waals gap of graphene/Au.This work hereby offers an intriguing strategy for obtaining vertical 2D heterostructures featured with an ultra-clean interface and a designed stacking geometry.

关键词： graphene rhenium selenide chemical vapor deposition seanning tunneling microscopy two-dimensional(2D)heterostructure

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高效光催化二氧化碳还原钻单原子催化剂的多尺度结构工程

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Science China Materials 2024年第4期67卷 1292-1300页

作者：王榆惠郑天宇金昱丞孙婷婷丁旭王萧徐清梅李彤轩张少龙姜建壮 Beijing Advanced Innovation Center for Materials Genome Engineering Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline MaterialsDepartment of Chemistry and Chemical EngineeringSchool of Chemistry and Biological EngineeringUniversity of Science and Technology BeijingBeijing 100083China College of Chemistry and Environmental Engineering Shenzhen UniversityShenzhen 518060China

人工光合作用将二氧化碳转化为增值化学品和燃料,在克服全球环境能源危机方面具有巨大潜力.然而,由于CO_(2)的热力学稳定性和动力学滞后性,开发高效的CO_(2)RR光催化剂是一个巨大的挑战.本文在微介孔氮掺杂碳(0.8-Co-ISAS/MMNC-900)上... 详细信息

人工光合作用将二氧化碳转化为增值化学品和燃料,在克服全球环境能源危机方面具有巨大潜力.然而,由于CO_(2)的热力学稳定性和动力学滞后性,开发高效的CO_(2)RR光催化剂是一个巨大的挑战.本文在微介孔氮掺杂碳(0.8-Co-ISAS/MMNC-900)上制备了一种具有高度分散Co单原子位的分级多孔钴单原子光催化剂,该催化剂显著促进了CO_(2)-to-CO的光还原.0.8-Co-ISAS/MMNC-900催化剂的CO生成速率高达7261μmol g^(-1)h^(-1),CO选择性高达90.1%,并且在四次循环测试中表现出良好的稳定性.实验数据和理论结果表明,分层多孔结构可以促进电荷分离引起的外部局部电场的形成,Co隔离的单原子位和微介孔构型协同作用,促进光激发电子积累、CO_(2)吸附活化和*COOH中间体的形成.本研究通过多尺度多孔结构工程,提出了一种合成CO_(2)还原光催化剂的新策略.

关键词：单原子热力学稳定性激发电子光还原多尺度结构人工光合作用多孔结构电荷分离

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中蕉9号和巴西蕉果穗营养特性的差异性评价

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中国南方果树 2024年第2期53卷 123-128页

作者：张晓龙李中华张立丹何维弟江家泉江舒婷孙少龙樊小林华南农业大学/广东省环境友好型肥料工程技术研究中心广州510642 五洲丰农业科技有限公司山东烟台264000 广东省农业科学院果树研究所广州510645

矿质营养元素对果实品质的提升发挥着重要作用。为探究中蕉9号果品较差的营养学原因,以大田正常管理条件下的中蕉9号和巴西蕉为试材,在成熟期对二者果穗进行破坏性取样,重点检测了对果实品质有重要影响的6种元素(氮、磷、钾、、钙镁、... 详细信息

矿质营养元素对果实品质的提升发挥着重要作用。为探究中蕉9号果品较差的营养学原因,以大田正常管理条件下的中蕉9号和巴西蕉为试材,在成熟期对二者果穗进行破坏性取样,重点检测了对果实品质有重要影响的6种元素(氮、磷、钾、、钙镁、硼),探讨中蕉9号和巴西蕉果穗养分累积和分配的差异。结果表明,中蕉9号果穗的鲜质量和干质量分别为33.38 kg/株和6.73 kg/株,分别比巴西蕉果穗重16.39%和30.16%,但是其总养分累积量和含量却比巴西蕉分别低10.12%和34.78%,主要原因是中蕉9号果穗中的氮、钙、镁含量较低,分别比巴西蕉减少了54.59%、28.18%和88.81%。其次,中蕉9号果轴中较高养分分配比例也对果实养分含量不利,中蕉9号果轴中18%的养分分配比例显著大于巴西蕉的12%。综合可得,中蕉9号果实中的养分含量较低,为提高中蕉9号的养分含量,以品质优良的巴西蕉养分含量为参考标准,建议中蕉9号生长发育后期的N∶P_(2)O_(5)∶K_(2)O施肥配比为1∶0.12∶1.71,同时还需加强钙镁肥的施用,以提高中蕉9号果实中养分含量,改善品质。

关键词：中蕉9号巴西蕉果实品质矿质元素累积与分配养分管理

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基于半月板MRI的3D卷积神经网络模型预测膝骨关节炎发生的研究

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磁共振成像 2024年第2期15卷 103-107,121页

作者：蒋可欣谢雨含李勉文张志勇陈少龙丘昌镇张晓东南方医科大学第三附属医院(广东省骨科研究院)影像科广州510630 中山大学电子与通信工程学院广州510275

目的探究基于自动分割半月板MRI的3D卷积神经网络(convolutional neural network,CNN)模型预测膝骨关节炎(knee osteoarthritis,KOA)发生的潜在价值。材料与方法本回顾性研究数据均来自于公开数据库骨关节炎倡议(Osteoarthritis Initiat... 详细信息

目的探究基于自动分割半月板MRI的3D卷积神经网络(convolutional neural network,CNN)模型预测膝骨关节炎(knee osteoarthritis,KOA)发生的潜在价值。材料与方法本回顾性研究数据均来自于公开数据库骨关节炎倡议(Osteoarthritis Initiative,OAI)。随机选择基线时的130例膝关节MRI图像,由经过训练的肌骨诊断医师手动勾画半月板感兴趣区,训练半月板MRI分割模型。采用OAI骨关节炎发生队列的MRI图像分割半月板,并基于3D CNN构建KOA预测模型。该关节炎发生队列共纳入710例膝关节,基线时均无放射学KOA,即Kellgren-Lawrence(KL)分级均≤1。在48个月的随访期间,发生放射学KOA(KL分级≥2)为病例组,未发生放射学KOA为对照组。病例组与对照组以1∶1的比例进行匹配。分别利用基线和确定放射学KOA前1年随访时间点(P-1)的膝关节MRI图像构建KOA预测模型。采用Dice系数评估半月板MRI分割模型性能。采用受试者工作特征曲线下面积(area under the curve,AUC)评估基于半月板MRI、临床信息和MRI骨关节炎膝关节评分(MRI Osteoarthritis Knee Score,MOAKS)构建的预测模型的预测价值。结果本研究半月板分割模型在测试集的Dice系数达90.32%。在基线和P-1时间点,3D CNN KOA预测模型(基线时AUC:0.60;P-1时AUC:0.71)比基于临床信息的模型(基线时AUC:0.55;P-1时AUC:0.63)及MOAKS(基线时AUC:0.52~0.56;P-1时AUC:0.51~0.64)在测试集中表现出更好的预测能力,且差异存在统计学意义(P<0.05)。结论基于自动分割半月板MRI构建的3D CNN KOA预测模型较临床信息或MRI半定量评分能更好地预测放射学KOA的发生。

关键词：膝骨关节炎半月板磁共振成像卷积神经网络分割预测

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Influence of liquid water content on wind turbine blade icing by numerical simulation

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排灌机械工程学报 2019年第6期37卷 513-520页

作者： LI Yan SUN Ce jiang Yu YI Xian GUO Wenfeng WANG shaolong FENG Fang Heilongjiang Provincial Key Laboratory of Technology and Equipment for Utilization of Agricultural Renewable Resources in Cold Region Northeast Agricultural University Harbin Heilongjiang 150030 China State Key Laboratory of Aerodynamics China Aerodynamics Research and Development Center Mianyang Sichuang 621000 China College of Metallurgy & Energy North China University of Science and Technology Tangshan Hebei 063009 China

In order to research the influence of liquid water content ( LWC ) on blade icing of wind turbine, a numerical simulation method for blade icing was established. The numerical simulation was based on low speed viscous N-S equation. The trajectory equation of water droplets was established by Lagrangian method. The mass and energy conservation equations of the water droplets impacting on the surface of the blade were solved based on control body theory. Three sections along blade span wise of a 1.5 MW wind turbine were decided to simulate icing. Five kinds of LWC were selected for simulation including 0.2,0.4,0.6,0.8 and 1.0 g/m^3 under two ambient temperatures of -10 ℃ and -20 ℃. The medium volume droplet diameter ( MVD ) was 30μm. The simulations included icing shape on blade surface, dimensionless icing area and dimensionless maximum stagnation thickness. Furthermore, the flow fields around both the iced blade airfoil and the original one were simulated and analyzed. Accor-ding to the results, the typical icing characteristics of icing shape, icing area and thickness were greatly affected by the difference of LWCs. This study can provide theoretical reference for the research on antiicing and deicing of wind turbine blade.

关键词： wind turbine icing airfoil numerical simulation liquid water content

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Transcriptome analysis of purple pigment formation in Colocasia esculenta

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BIOCELL 2021年第3期45卷 785-796页

作者： FANGLIAN HE WEIQING DONG shaolong WEI ZUYANG QIU JINGLI HUANG HUIPING jiang SHIYU HUANG LILI LIU Biotechnology Research Institute Guangxi Zhuang Nationality Autonomous Region Academy of Agricultural SciencesNanning530007China Guangxi Zhuang Nationality Autonomous Region Academy of Agricultural Sciences Nanning530007China Lipu Municipal Bureau of Agriculture and Rural Affairs Lipu546600China College of Agriculture Guangxi UniversityNanning530004China

Taro(Colocasia esculenta(L.)Schott)is an important crop in Africa,Southeast Asia,and subtropics and is used as a food and medicine.The purple color pigmentation is an appealing character in taro.We sampled taro corms of the cultivar‘Lipu Taro’at four developmental stages,including LPYS1(without purple pigment,50 days of development(DOD)),LPYS2(very few purple pigments,75 DOD),LPYS3(moderate purple pigments,115 DOD)and LPYS4(high purple pigments,205 DOD).The purpose of our study was to identify the key genes underpinning the purple pigmentation in taro based on RNA-sequencing.Through RNA-Seq,6453 differentially expressed transcripts(DETs)were identified between purple and non-purple pigmented samples.We identified 41 and 12 flavonoid and anthocyanin related DETs transcripts,respectively.These DETs were upregulated at LPYS2,LPYS3,and LPYS4 as compared to LPYS1,indicating their positive contribution to the color formation in taro.Moreover,we identified several DETs encoding for transcription factors,including MYB and bHLH,known to be major regulators of structural genes involved in the flavonoid-anthocyanin pathway.Finally,we reported several plant hormones(ethylene,auxin,gibberellin,jasmonic acid,and cytokinin)related DETs,which are predicted to play important roles in the corm coloration.Different regulation of transcripts representing the flavonoid-anthocyanin biosynthesis pathway,plant hormone transduction pathway,and transcription factors may have key roles in purple pigmentation in taro.Our findings will facilitate future research on improving the quality and appeal of taro.

关键词： Anthocyanin Colocasia esculenta Color formation Plant hormones Gene expression Transcription factors

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