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多储能逆变器并联系统在微网孤岛条件下的稳定性分析及其控制策略

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高电压技术 2015年第10期41卷 3266-3273页

作者：徐少华李建林惠东中国电力科学研究院北京100192

多台储能逆变器在微网孤岛条件下并联运行时,需要为整个微网系统提供稳定的电压频率支撑,但逆变器等效输出阻抗和线路阻抗的差异会造成功率分配不均以及环流过大等问题,从而导致整个微网系统的不稳定。为了解决上述问题,可以在传统P-U、... 详细信息

多台储能逆变器在微网孤岛条件下并联运行时,需要为整个微网系统提供稳定的电压频率支撑,但逆变器等效输出阻抗和线路阻抗的差异会造成功率分配不均以及环流过大等问题,从而导致整个微网系统的不稳定。为了解决上述问题,可以在传统P-U、Q-f(调整有功功率来稳定微网电压、调整无功功率来稳定微网频率)下垂控制策略的基础上采用虚拟阻抗技术,通过对虚拟阻抗的设计将所有逆变器的等效输出阻抗设计为阻性,从而实现负荷功率的均分。从多储能逆变器并联系统的拓扑结构入手,分析了储能逆变器并联系统的功率流动特性并建立其输出阻抗模型;对整个系统的控制策略进行详细的介绍,包括引入虚拟阻抗的下垂控制策略以及储能逆变器的双闭环控制策略;根据阻抗稳定性分析法,分析了逆变器滤波参数和控制参数对整个系统稳定性能的影响,基于该工况可以发现当滤波电感L增加到5 m H时,逆变器并联系统趋于不稳定;虚拟阻抗系数kL增大到3时,系统阻抗比乃奎斯特曲线越过拒绝域,同时也会使系统的等效输出阻抗由偏阻容性变成感性,不利于高次谐波的抑制;而虚拟阻抗系数RD增大可以加强功率均分效果且对系统的稳定性影响较小。仿真结果说明,在该工况条件下,通过合理的设计逆变器输出阻抗,可以使多逆变器间的环流最大值由30 A降低到3 A以内,从而保证光储微网在孤岛条件下的稳定运行。

关键词：逆变器并联功率均分阻抗稳定性下垂控制虚拟阻抗光储微网

大容量级联式电池储能功率调节系统中多脉冲驱动技术研究

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高电压技术 2015年第7期41卷 2121-2126页

作者：李建林樊辉徐少华中国电力科学研究院北京100192 北京理工大学自动化学院北京100081

出于高压隔离目的,大容量级联式电池储能系统中,一般采用光纤传输驱动脉冲信号。由于H桥单元个数众多,驱动脉冲数量庞大,为减少光纤使用数量,降低系统成本,提高工作可靠性,采用编解码技术,对多路脉冲驱动信号进行编码后通过一条光纤信... 详细信息

出于高压隔离目的,大容量级联式电池储能系统中,一般采用光纤传输驱动脉冲信号。由于H桥单元个数众多,驱动脉冲数量庞大,为减少光纤使用数量,降低系统成本,提高工作可靠性,采用编解码技术,对多路脉冲驱动信号进行编码后通过一条光纤信号进行串行传输成为一种可行的解决方案。首先分析了PWM脉冲信号的产生算法,在此之上提出针对多路PWM脉冲进行编解码的算法,指定通信协议,采用光纤信号进行串行通信,并将该方案成功应用于一台6 k V,600 k W电池储能功率调节系统(PCS)中,实验结果表明采用该编解码方案使用一条光纤即可完成传统多路光纤传输任务,功率调节系统输出与理论分析一致,电压谐波含量低,并网电流正弦度高,验证了所提的脉冲编解码方案的正确性与可行性。

关键词：功率调节系统级联H桥光纤通信串行信号脉宽调制电池储能

Techniques to Quantify the Size of Protein Colloids in Amyloid Fiber Formation

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Open Journal of Biophysics 2013年第1期3卷 22-32页

作者： Jonathan R. Anson Chia-Hung Lu Lingwen Cui Xiaojing Yang shaohua xu Florida Institute of Technology Melbourne USA NASA Kennedy Space Center Cape Canaveral USA

A new method for the analysis of protein colloidal diameter has been developed using three existing protein concentration quantification techniques, absorption at 280 nm, colloidal gold assay, and DC protein assay. Protein colloids are formed in the process of aggregation and are thought to be intermediates in protein self-assembly and formation of amyloid fiber. Deposition of the protein fibers in tissues leads to numerous human diseases including Alzheimer’s. Lysozyme was incubated at pH 2.0, 55°C, an environment conducive to amyloid fiber formation. The protein colloids present in the supernatant of the samples after centrifugation were studied over a time course of 30 days. The OD 280 assay detects total protein concentration based on absorption of radiation in the near UV. The colloidal gold assay and DC protein assay only measure colloidal sphere surface protein concentration. Due to the surface plasmon resonance, the light absorption spectrum changes when proteins bind to colloidal gold particles. Using the measured protein concentration on the surface of protein colloids along with the total measured protein concentration in the entire protein colloidal spheres, an interior protein concentration for all colloids is obtained. The protein colloidal sphere size can be calculated by using the ratio between the interior protein concentration and total protein concentration. Results indicate that the colloidal gold assay, DC protein assay, and OD 280 assay can be used to quantify the size of the protein colloids. The colloidal gold assay and DC protein assay are both independently effective in analysis of surface protein concentration in protein colloids. The DC protein assay was found to be much quicker in data production as it only requires 15 minutes of incubation time. The DC protein assay was also more reliable than the colloidal gold assay in accuracy and precision of results.

关键词： Aggregation Atomic Force Microscopy Nanoparticles Gold Surface Plasmon Resonance Protein Analysis Spectrophotometry

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含白云石微粉水泥砂浆的抗硫酸盐侵蚀性能

硅酸盐学报 2018年第2期46卷 224-229页

作者：凌康卢都友徐江涛张少华许仲梓南京工业大学材料科学与工程学院

为评估白云石微粉对水泥抗硫酸盐侵蚀性能的影响,以石灰石微粉为参照,研究了白云石微粉掺量（质量分数）分别为10%、20%、30%时,水泥砂浆在质量浓度为5%硫酸钠溶液中的变形和强度发展规律,并讨论了基于抗蚀系数的含碳酸盐岩微粉水泥抗... 详细信息

为评估白云石微粉对水泥抗硫酸盐侵蚀性能的影响,以石灰石微粉为参照,研究了白云石微粉掺量（质量分数）分别为10%、20%、30%时,水泥砂浆在质量浓度为5%硫酸钠溶液中的变形和强度发展规律,并讨论了基于抗蚀系数的含碳酸盐岩微粉水泥抗硫酸盐侵蚀性能评价方法。结果表明：砂浆试体在Na_2SO_4溶液中的变形过程可分为稳定期、缓慢膨胀期和加速膨胀期3个阶段。除掺10%白云石微粉试体外,其余含碳酸盐岩微粉砂浆的膨胀率均大于空白样（PC）。与掺石灰石微粉试体相比,含白云石微粉试体起始膨胀的龄期滞后,同期膨胀小,且两者膨胀差异随龄期延长和掺量增加呈增大趋势。无论在水中还是在Na_2SO_4溶液中,掺碳酸盐岩微粉砂浆抗压和抗折强度发展趋势均与PC类似,但强度均降低,且掺量越大,强度降幅越大。与在水中养护时强度持续缓慢增长不同,掺碳酸盐岩微粉砂浆强度在Na_2SO_4溶液中经历先快速增长至峰值,而后降低的过程。与含石灰石微粉试体相比,含白云石微粉砂浆强度达到峰值的龄期滞后且后期强度高。标准规定的28 d抗蚀系数K_（28）不能确切反映含碳酸盐岩微粉水泥抗硫酸盐侵蚀性能。采用试体起始膨胀或强度达峰值龄期的抗蚀系数可提高判定结果的准确性和可靠性。

关键词：白云石微粉石灰石微粉硫酸盐侵蚀膨胀率强度抗蚀系数

The origin,diversification and adaptation of a major mangrove clade(Rhizophoreae) revealed by whole-genome sequencing

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National Science Review 2017年第5期4卷 721-734页

作者： shaohua xu Ziwen He Zhang Zhang Zixiao Guo Wuxia Guo Haomin Lyu Jianfang Li Ming Yang Zhenglin Du Yelin Huang Renchao Zhou Cairong Zhong David E.Boufford Manuel Lerdau Chung-I Wu Norman C.Duke Suhua Shi State Key Laboratory of Biocontrol Guangdong Provincial Key Laboratory of Plant ResourcesKey Laboratory of Biodiversity Dynamics and Conservation of Guangdong Higher Education Institutes School of Life Sciences Sun Yat-Sen University Core Genomic Facility Beijing Institute of Genomics Chinese Academy of Sciences Hainan Dongzhai Harbor National Nature Reserve Harvard University Herbaria Departments of Environmental Sciences and of Biology University of Virginia Department of Ecology and Evolution University of Chicago Centre for Tropical Water and Aquatic Ecosystem Research James Cook University The International Mangrove Consortium

Mangroves invade some very marginal habitats for woody plants—at the interface between land and *** mangroves anchor tropical coastal communities globally, their origin, diversification and adaptation are of scientific significance, particularly at a time of global climate change. In this study, a combination of single-molecule long reads and the more conventional short reads are generated from Rhizophora apiculata for the de novo assembly of its genome to a near chromosome level. The longest scaffold, N50 and N90 for the R. apiculata genome, are 13.3 Mb, 5.4 Mb and 1.0 Mb, respectively. Short reads for the genomes and transcriptomes of eight related species are also generated. We find that the ancestor of Rhizophoreae experienced a whole-genome duplication70 Myrs ago, which is followed rather quickly by colonization and species diversification. Mangroves exhibit pan-exome modifications of amino acid（AA） usage as well as unusual AA substitutions among closely related species. The usage and substitution of AAs, unique among plants surveyed, is correlated with the rapid evolution of proteins in mangroves. A small subset of these substitutions is associated with mangroves' highly specialized traits（vivipary and red bark） thought to be adaptive in the intertidal habitats. Despite the many adaptive features, mangroves are among the least genetically diverse plants, likely the result of continual habitat turnovers caused by repeated rises and falls of sea level in the geologically recent past. Mangrove genomes thus inform about their past evolutionary success as well as portend a possibly difficult future.

关键词： mangrove whole-genome sequencing adaptive evolution protein evolution genetic diversity sea-level changes

基于协调学术权力与行政权力的管理体制和运行机制设计

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中国高教研究 2010年第11期 64-66页

作者：章兢徐少华湖南大学湖南大学学术委员会秘书长教授长沙410082 湖南大学研究生院副研究员湖南长沙410082

学术权力和行政权力共存是大学组织的主要特征。建立和完善学术委员会管理体制和运行机制,能有效地促进学术权力和行政权力的协调。学术委员会的结构设计和保障其有效运行的制度设计是本文重点探讨的内容。

关键词：学术权力行政权力学术委员会管理体制运行机制

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激光焊接镁/铝异种金属的显微组织与性能

稀有金属材料与工程 2015年第10期44卷 2440-2444页

作者：周惦武田伟徐少华刘金水湖南大学汽车车身先进设计制造国家重点实验室湖南长沙410082

对1.8 mm厚AZ91镁合金和1.2 mm厚6016铝合金平板试件进行激光搭接焊试验,利用体视显微镜、卧式金相显微镜、扫描电镜、X射线衍射仪、电子显微硬度仪、微机控制电子万能试验机等手段研究镁/铝焊缝的表面成形性、接头区域的金相组织、界... 详细信息

对1.8 mm厚AZ91镁合金和1.2 mm厚6016铝合金平板试件进行激光搭接焊试验,利用体视显微镜、卧式金相显微镜、扫描电镜、X射线衍射仪、电子显微硬度仪、微机控制电子万能试验机等手段研究镁/铝焊缝的表面成形性、接头区域的金相组织、界面元素分布、断口形貌、主要物相、显微硬度与接头力学性能。结果表明:激光功率1900 W,焊接速度50 mm/s,离焦量f为0,Ar气保护气体流量为15 L/min时,焊缝表面成形性良好,热影响区窄,晶粒细化;焊接接头平均抗拉强度和抗剪强度分别为13.99和12.79 MPa,镁侧和铝侧焊缝硬度均高于母材;剪切断口较平坦、光滑,出现相互平行的疲劳条纹;拉伸断口存在较多高度不一致的解理台阶,呈脆性断裂特征;镁/铝焊缝界面存在Mg17Al12、Mg2Al3主要物相,其中Mg17Al12脆性相高温下比Mg2Al3延性相结构稳定,是镁/铝焊接接头呈现脆性特征和较难实现焊接的主要原因。

关键词：镁/铝异种金属激光焊接金属间化合物力学性能

Crystal and Molecular Structure of Copper (Ⅱ) Dimeric Complex of S-Methyl-β-N-(Pyridine N-Oxide-2-ylmethylidene) Dithiocarbazate with Acetonitrile

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Chemical Research in Chinese Universities 1990年第4期6卷 262-265页

作者： Yu Kaibei and Zhou Zhongyuan (Chengdu Center of Analysis and Determination, Academia Sinica, Chengdu)Gou shaohua, You Xiaozeng and xu Zheng (Coordination Chemistry Institute, Nanjing University, Nanjing)

The crystal and molecular structure of copper(Ⅱ) dimeric complex of S-methyl-B-N-(pyridine N-oxide-2-ylmethylidene) dithiocarbazate with acetonitrile, [CuL (CH3CN)]2 (ClO4)2, was determined by X-ray diffraction. The complex crystalizes in monoclinic system with space group P21/n, a= 7. 685(2), 6=20.160(6), c= 10. 847(5) A ,B = 107.89(3), Z=2,Dc=1.788 g/cm3, F(000) = 835. 8, u= 18. 17 cm-1(Moka,R= 0. *** Cu(Ⅱ) ion in the complex is surrounded by a distorted square pyramidal. The basal plane is comprised of S, N and O atoms of one ligand together with a N atom of the solvent--acetonitrile, while the axial position is occupied by the S atom of the other ligand. The bond length of Cu-S(bridging) is 3. 038A . and Cu-Cu distance is 3. 700A.

关键词： Complex of Cu (Ⅱ) Crystal and molecular structure Dimeric complex S-methyl-β-N-(pyridine N-oxide-2-ylmethyndene)dithiocarbazate

Synthesis and Magnetic Properties of Copper (Ⅱ) Complexes with Pyridine N-Oxide-2-ylmethy-lidenedithiocarbazate as Ligands

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Chemical Research in Chinese Universities 1990年第4期6卷 255-261页

作者： Gou shaohua , You Xiaozeng and xu Zheng (Coordination Chemistry Institute, Nanjing University, Nanjing)Zhu Duolin and Yu Yunpen (Department of Chemistry, Zhenjiang Teacher’ s College, Zhenjiang)

A series of copper (Ⅱ) complexes with pyridine N- oxide- 2- ylmethylidened-ithiocarbazates as ligands were synthesized and characterized by IR spectra, electronic spectra and magnetic moments measurement at room temperature. Variable temperature magnetic susceptibilites (3-300K) of four complexs were measured and fitted with the Bleaney-Bowers dimer equation by considering the magnetic interaction between molecules. The fitting results show the existence of intramolecular ferromagnetic interactions and intermolecu-lar anti-ferromagnetic interactions in these copper( Ⅱ) complexes.

关键词： Pyridine N-oxide-2-ylmethylidenedithiocarbazate Copper(Ⅱ) complex Magnetic susceptibility