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HEAT-RESISTANT PYRIDINE-BASED POLY(ETHER-ESTER)S: SYNTHESIS, CHARACTERIZATION AND PROPERTIES

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Chinese Journal of Polymer Science 2013年第1期31卷 171-178页

作者： shahram mehdipour-ataei Ali Mahmoodi Department of Chemistry Islamic Azad University

A pyridine-based diacid was synthesized via nucleophilic substitution reaction of 4-hydroxy benzoic acid with 2,6- dichloropyridine in the presence of potassium carbonate. The diacid was characterized using FT-IR and 1H-NMR spectroscopic methods and also with elemental analysis. Polycondensation reaction of the diacid with different diols including 1,4-dihydroxy benzene, 1,5-dihydroxy naphthalene, bis-phenol A and bis-phenol-P resulted in preparation of pyridine-based poly（ether-ester）s. The polymers were characterized and their physical and thermal properties including inherent viscosity, molecular weight, solubility, thermal stability, thermal behavior and crystallinity were studied. They revealed high heat-resistance and improved solubility in polar solvents. Structure-property relations for the prepared polyester were also studied.

关键词： Polyester Polymer synthesis and characterization Thermal properties Structure-property relations.

SOLUBLE POLYIMIDES FROM A SEMI-ALIPHATIC DIAMINE CONTAINING ESTER,AMIDE AND ETHER GROUPS

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Chinese Journal of Polymer Science 2011年第1期29卷 93-100页

作者： shahram mehdipour-ataei Leila Akbarian-Feizi Iran Polymer and Petrochemical Institute P.O.Box 14965/115TehranIran

A diamine was synthesized by two successive reactions. Nucleophilic reaction of 4-hydroxybenzoic acid with terephthaloyl chloride yielded terephthaloyl bis（4-oxybenzoic） acid. Then reaction of this compound with 1,8-diamino-3,6- dioxaoctane via Yamazaki method resulted in preparation of diamine named terephthalic acid bis（4-{2-[2-（2-amino ethoxy）ethoxy]ethyl carbamoyl}phenyl） ester. After fully characterization it was used to prepare new polyimides through polycondensation with different dianhydrides using trimethylchlorosilane. Characterization of polymers was achieved by common methods and their physical properties including inherent viscosity, thermal behavior, thermal stability, crystallinity and solubility were studied. Prepared polyimides showed improved solubility and good thermal stability.

关键词： Polyimide Polycondensation Synthesis Thermal properties

ORGANOSOLUBLE,THERMALLY STABLE POLYAMIDES CONTAINING SULFONE AND SULFIDE UNITS

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Chinese Journal of Polymer Science 2009年第6期27卷 781-787页

作者： shahram mehdipour-ataei Mehdi Hatami Mohammad Hossein Mosslemin Iran Polymer and Petrochemical Institute Department of Chemistry Isfahan University of Technology Department of Chemistry Islamic Azad University

A new diamine containing sulfone,sulfide and amide groups was synthesized via a three-step reaction process. The nucleophilic substitution reaction of 4-aminothiophenol with 4-nitrobenzoyl chloride in the presence of propylene oxide (PO) afforded N-(4-mercaptophenyl)-4-nitrobenzamide(MPNB).The catalytic reduction of the nitro group in MPNB to amino group was accomplished by using Pd/C and hydrazine monohydrate to produce 4-amino-N-(4-mercapto phenyl)benzamide(AMPB).Reaction of two moles of AMPB with bis(4-c...

关键词： Polymerizations Polycondensation Nucleophilic substitution Polyamides Thermal properties