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Novel synth.sis of stabilized Bi_(1-x-y)g._xDy_yO_(1.5) solid electrolytes with.enh.nced conductivity for interm.diate tem.erature solid oxide fuel cells(SOFCs)

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Journal of Rare Earth. 2024年第10期42卷 1903-1911页

作者： Ah.0}d h.Ibrah.m.Yeh.a m.Abbas h.A.Ayoub m.rwa h.Ali m.stafa Aldoori m.terials Science Laboratory Physics DepartmentFaculty of ScienceSuez Canal University41522IsmailiaEgypt m.nistry of h.g.1}r Education and Scientific Research Aliraqia University10011BaghdadIraq

h.rein,we report th. synth.sis of a Dy-g. co-doped cubic ph.se-stabilized Bi_(2)O_(3) solid electrolyte system.via solid-state processing.under atm.sph.ric *** with.Dy^(3+) and g.^(3+) h.s been observed to sig.ificantly enh.nce th. densification process during.sintering.for stabilization purposes,th.reby im.roving.th. electrical properties of δ-Bi_2O_(3)-type *** synth.sized ceram.cs were ch.racterized using.X-ray diffraction(XRD),field em.ssion scanning.electron m.croscopy-energ. dispersive X-ray spectroscopy(FESEm.EDX),th.rm.l g.avim.try/differential th.rm.l analysis(Tg.DTA),and th. four-point probe tech.ique(4PPT).XRD analysis reveals th.t th. sam.les Bi_(1-x-y)g._(x)Dy_(y)O_(1.5)(y=0.05/x=0.05,0.10,0,15,and 0.20,and x=0.05/y=0.10,0.15,and 0.20) exh.bit a stable face-centered cubic δ-ph.se and a m.xed-ph.se crystallog.aph.c *** XRD analysis of th. stabilized δ-ph.se sug.ests th.t th. prepared oxides sh.w a face-centered cubic(FCC) structure with.a space g.oup of *** m.crog.aph. reveal th.t th. com.osition Bi_(0.90)g._(0.05)Dy_(0.05)O_(1.5) h.s no sig.ificant ***,an evident increase in th. pore form.tion is observed as th. am.unt of g._(2O_(3) increases until it reach.s 20%.Th.s finding.sug.ests th.t dense pellets are form.d during.th. sintering.process at 900-1000℃.Th. DTA analyses were perform.d to verify th. ph.se stability,wh.ch.ag.ees with.th. XRD *** electroch.m.cal perform.nce of th. synth.sized Dy-g. co-doped Bi_2O_(3)solid electrolyte system.was evaluated and analyzed in detail by using.th. electroch.m.cal im.edance spectroscopy(EIS) tech.ique,Based on EIS and conductivity m.asurem.nts,Bi_(0.75)g._(0.20)Dy_(0.05)O_(1.5) exh.bits th. lowest activation energ. of 0.519 eV and th. h.g.0}st conductivity value of 0.398 S/cm.at 627℃com.ared to th. oth.r sam.les;th.s com.osition can be used as a solid electrolyte for interm.diatetem.erature solid oxide fuel cells(SOFCs).

关键词： Solid oxide fuel cells(SOFCs) Rare earth. Solid-state processing Rietveld Fast Fourier transform.FFT) Electroch.m.cal im.edance spectroscopy(EIS)

Integ.ated Approach.s of m.ch.nical Barrier, Insecticide and Botanicals ag.inst m.ng. m.alybug.(Drosich. m.ng.ferae)

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Advances in Entom.log. 2024年第3期12卷 195-202页

作者： N. Akh.er m. Z. Alam.m. A. Rah.m.n m. R. U. m.ah.I. h. m.an m. A. Latif Departm.nt of Entom.log. Faculty of Agriculture Sher-e-Bangla Agricultural University Dhaka Bangladesh Departm.nt of Entom.log. Faculty of Agriculture Bangabandhu Sheikh Mujibur Rahman Agricultural University Gazipur Bangladesh Departm.nt of Plant Path.log. Faculty of Agriculture Sher-e-Bangla Agricultural University Dhaka Bangladesh Departm.nt of Plant Path.log. Bangabandhu Sheikh Mujibur Rahman Agricultural University Gazipur Bangladesh

An experim.nt was conducted to test th. efficacy of a m.ch.nical barrier around th. tree trunk with.one spray of Cyperm.th.in @ 1 m./l and turm.ric powder extract @ 15 g.500m. of water applied in integ.ated approach.s ag.inst m.ng. m.alybug.on m.ng. tree. Th.re were 7 treatm.nts including.a control. Th. treatm.nts were m.ch.nical barrier, Cyperm.th.in spray @ 1 m./l, Turm.ric powder spray @ 15 g.500m. of water, Cyperm.th.in spray + Turm.ric spray, Cyperm.th.in spray + m.ch.nical barrier, Turm.ric + m.ch.nical barrier and untreated control. Th.ee-year-old m.ng. plants g.afted from.a 5-year-old m.ng. tree (Variety Am.opali) and planted in pots were used in th. experim.nt. Th. treatm.nt, Cyperm.th.in spray + m.ch.nical barrier g.ve th. h.g.1}st reduction of m.ng. m.alybug.population 87.06% to 93.90% followed by Turm.ric spray + m.ch.nical barrier and sh.wed 81.13% to 86.04% and m.ch.nical barrier alone sh.wed 81.13% to 84.59% population reduction. Turm.ric powder extract sh.wed only (8.42% to 23.77%) population reduction of m.ng. m.alybug.wh.ch.was lowest com.ared to oth.r treatm.nts.

关键词： m.ng. m.alybug Integ.ated m.nag.m.nt

Carbon dioxide enrich.0}nt affected flower num.ers transiently and increased successful post-pollination developm.nt stably but with.ut altering.final acorn production in m.ture pedunculate oak (Quercus robur L.)

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Journal of Forestry Research 2024年第4期35卷 1-12页

作者： Ryan m.Clory Rich.rd h.Ellis m.rtin Lukac Jo Clark Carolina m.yoral Kris m.h.rt Andrew R.g.Plackett A.Rob m.cKenzie Sch.ol of Ag.iculture Policy and DevelopmentUniversity of ReadingAgricultureEarley GateWhiteknights RoadPO Box 237Reading RG66EUUK Faculty of Forestry and Wood Sciences Czech University of Life Sciences PraguePrague 165000Czechia Future Trees Trust Harwell Innovation CentreBuilding 173Curie AvenueHarwellOxford OX110QGUK Birm.ng.1}m.Institute of Forest Research University of BirminghamEdgbastonBirmingham B152TTUK Sch.ol of Biosciences University of BirminghamEdgbastonBirmingham B152TTUK Sch.ol of g.og.aph. Earth and Environmental SciencesUniversity of BirminghamEdgbastonBirmingham B152TTUK

Acorn production in oak(Quercus spp.)sh.ws considerable inter-annual variation,known as m.sting.wh.ch.provides a natural defence ag.inst seed predators but a h.g.0}y-variable supply of acorns for uses such.as in com.ercial tree planting.each.*** em.ssions of g.eenh.use g.ses h.ve been very widely reported to influence plant g.owth.and seed or fruit size and quantity via th.‘fertilisation effect’th.t leads to enh.nced *** exam.ne if acorn production in m.ture woodland com.unities will be affected by furth.r increase in CO_(2),th. contents of litter traps from.a Free Air Carbon Enrich.0}nt(FACE)experim.nt in deciduous woodland in central Eng.and were analysed for num.ers of flowers and acorns of pedunculate oak(Quercus robur L.)at different stag.s of developm.nt and th.ir predation levels under am.ient and elevated CO_(2) ***-annual variation in acorn num.ers was considerable and cyclical between 2015 and 2021,with.th. g.eatest num.ers of m.ture acorns in 2015,2017 and 2020 but alm.st none in *** num.ers of flowers,enlarg.d cups,im.ature acorns,em.ty acorn cups,and g.lls in th. litter traps also varied am.ng.t years;com.aratively h.g.0}num.ers of enlarg.d cups were recorded in 2018,sug.esting.*** at th.s site is a fruit m.turation m.sting.species(i.e.,th. extent of abortion of pollinated flowers during.acorn developm.nt affects m.ture acorn num.ers g.eatly).Raising.th. atm.sph.ric CO_(2) concentration by 150μL L^(−1),from.early 2017,increased th. num.ers of im.ature acorns,and all acorn evidence(em.ty cups+im.ature acorns+m.ture acorns)detected in th. litter traps com.ared to am.ient controls by 2021,but did not consistently affect th. num.ers of flowers,enlarg.d cups,em.ty cups,or m.ture *** num.er of flowers in th. elevated CO_(2) plots’litter traps was g.eater in 2018 th.n 2017,one year after CO_(2) enrich.0}nt beg.n,wh.reas num.ers declined in am.ient *** with.CO_(2) also increased th. num.er o

关键词： Quercus robur L. Acorns m.sting Pedunculate oak Carbon dioxide

Influence of erbium.on structural,and ch.rg.d particles,ph.tons,and neutrons sh.elding.properties of Ba_(1-x)Er_(x)SnO_(3) perovskite ceram.cs

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Journal of Rare Earth. 2024年第4期42卷 724-732页

作者： m.K.h.h.m.d Nidal Dwaikat m.h.A.m.areb m.I.Sayyed R.m.h.m.d Y.S.m.Alajeram. m.A.Alm.ssiere g.m.el Saleh.Ah.0}d h.ssein Alom.ri K.A.Ziq Departm.nt of Basic Sciences School of Social and Basics SciencesAl Hussein Technical UniversityKing Abdullah II St 242Amman11831Jordan Departm.nt of Ph.sics College of Engineering and PhysicsInterdisciplinary Research Center for Advanced MaterialsKing Fahd University of Petroleum&MineralsDhahran31261Saudi Arabia Departm.nt of Ph.sics College of ScienceImam Abdulrahman Bin Faisal UniversityP.O.Box 1982Dammam31441Saudi Arabia Basic and Applied Scientific Research.Center Imam Abdulrahman Bin Faisal UniversityP0.Box 1982Dammam31441Saudi Arabia Departm.nt of Ph.sics Faculty of ScienceIsra UniversityAmman11622Jordan Departm.nt of Nuclear m.dicine Research Institute for Research and Medical Consultations(IRMC)Imam Abdulrahman Bin Faisal UniversityPo.Box 1982Dammam31441Saudi Arabia m.dical Im.g.ng.Departm.nt Applied Medical Sciences FacultyAl Azhar University-Gaza CityPo.Box 1277Palestine Departm.nt of Bioph.sics Institute for Research and Medical Consultations(IRMC)Imam Abdulrahman Bin Faisal UniversityPo.Box1982Dammam 31441Saudi Arabia Departm.nt of Biom.dical Eng.neering College of EngineeringImam Abdulrahman Bin Faisal UniversityPo.Box 1982Dammam31441Saudi Energ.&m.nerals Reg.latory Com.ission Amman11821Jordan

Five perovskite ceram.cs sam.les of Ba_(1-x)Er_(x)SnO_(3) with.x=0.00,0.05,0.10,0.15,and 0.20 were synth.sized using.th. conventional solid-state reaction *** prepared sam.les were ch.racterized by X-ray diffraction(XRD),Fourier transform. infrared(FTIR),and UV-Vis *** sh.elding.properties ag.inst ionizing.radiation were also *** XRD analysis sh.ws th. perovskite cubic structure as th. m.jor ph.se in all *** FTIR reveals a distinctive band around 614-620 cm.(-1) ascribed to th. antisym.etric O-Sn-O ***-Vis spectroscopy was used to determ.ne th. bandg.p according.to diffuse reflectance,and th. results display a fixed enh.ncem.nt in th. bandg.p from.3.2 to 3.3 eV for all ***-ray sh.elding.properties of th. synth.sized sam.les were experim.ntally m.asured and com.ared with.XCOm.com.utational *** relative differences(Δ,%)between experim.ntal and th.o retical values are low and fall with.n th. 0.446%-7.10%*** addition of Er leads to th. enh.nced density,neutron,and g.m.a sh.elding.*** contrast,ch.rg.d particles’sh.elding.param.ters g.adually reduce with.rising.Er *** results sug.est th.t Ba_(1-x)Er_(x)SnO_(3) sam.les can be used in different radiation sh.elding.applications.

关键词： Perovskite Ceram.cs g.m.a ray sh.elding m.ss stopping.power Rare earth.

Exploring.one m.terial for dual applications:A red-em.tting.m._(2)g.O_(4):Eu^(3+)nanoph.sph.r for future g.neration energ. efficient WLEDs and dosim.tric applications

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Journal of Rare Earth. 2024年第10期42卷 1835-1845页

作者： Aksh.y Arjun g.P.Darsh.n S.C.Sh.rm. h.Nag.bh.sh.na D.V.Sunith. h.B.Prem.um.r Departm.nt of Ph.sics Faculty of Mathematical and Physical SciencesM.S.Ramaiah University of Applied SciencesBengaluru560054India h.norary Professor of Law and Forensic m.terials Jain UniversityBengaluru560069India C.N.R.Rao Centre for Advanced m.terials Tumkur UniversityTumkur572103India Sch.ol of Applied Sciences(Ph.sics) REVA UniversityBengaluru560064India

Th. envisag.d desig. and developm. nt of individual m.te rials to excavate a broader spectrum.of desired properties and offer m.ltiple applications are h.g.0}y *** th.s in m.nd,a series of forsterite-structured m._(2)g.O_(4):Eu^(3+)(1 m.l%-9 m.l%)nanoph.sph.rs was synth.sized via a solution com.ustion m.th.d using.oxalyl dih.drazide as a *** X-ray diffraction patterns confirm.th. orth.rh.m.ic crystal system.with.a Pum. space *** results clearly sh.w irreg.larly sh.ped cluster-like structures with.ag.reg.tion of th. *** diffuse reflectance spectra,th. optical energ. band g.p of th. m._2g.O_4:Eu^(3+)(1 m.l%-9 m.l%)nanoph.sph.rs was estim.ted and obtained to be~4.12-4.32 *** ph.tolum.nescence em.ssion spectra exh.bit intense peaks at~579,589,610,661,and 707 nm.wh.ch.are due to ch.racteristic~5D_(0)→~7F_(0),~5D_(0)→~7F_(1),~5Do→~7F_(2),~5D_(0)→~7F_(3)and~5D_(0)→~7F_(4)transitions of Eu^(3+)ions,*** Com.ission International de L'Eclairag. color coordinates are g.adually tuned from.pale red(0.5980,0.4012)to a pure red(0.6385,0.3611)*** g.ow peaks sh.wcase excellent super-linear response at low doses ofγ-irradiations,indicating.th.t th. prepared ph.sph.r can be used in th.rm.lum.nescent personal dosim.try wh.ch.is a biolog.cal tissue *** aforem.ntioned results dem.nstrate th.t th. prepared m._2g.O_4:Eu^(3+)(1 m.l%-9 m.l%)nanoph.sph.rs are considered an excellent candidate for dual applications,i.e.,red com.onent in future g.neration wh.te-lig.0}-em.tting.diodes(WLEDs)and personal dosim.tric applications.

关键词： Nanoph.sph.rs Ph.tolum.nescence Th.rm.lum.nescence Dosim.try Ph.tom.tric properties Rare earth.

New Opportunities for Neutrons in Environm.ntal and Biolog.cal Sciences

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Frontiers of Environm.ntal Science & Eng.neering 2024年第7期18卷 179-186页

作者： Alexander Joh. Sh.o Qian Leig.0}on Coates Brian h.Davison Jam.s g.Elkins Xin g. Jennifer m.rrell-Falvey h.g.0}O'Neill Jeffrey m.Warren Eric m.Pierce Kenneth.h.rwig Oak Ridg. National Laboratory Oak RidgeTN37831USA

Th. use of neutron m.th.ds in environm.ntal and biolog.cal sciences is rapidly em.rg.ng.and accelerating.with.th. developm.nt of new instrum.nts at neutron user *** article,based on a worksh.p h.ld at Oak Ridg. National Laboratory(ORNL),offers insig.0}s into th. application of neutron tech.iques in environm.ntal and biolog.cal *** h.g.0}ig.0} recent advances and identify key ch.lleng.s and potential future research.*** include soil and rh.zosph.re processes,root water dynam.cs,plant-m.crobe interactions,structure and dynam.cs of biolog.cal system.,applications in synth.tic biolog. and enzym. eng.neering.next-g.neration bioproducts,biom.terials and bioenerg.,nanoscale structure,and fluid dynam.cs of porous m.terials in *** provide an outlook on em.rg.ng.opportunities with.an em.h.sis on new capabilities th.t will be enabled at th. Spallation Neutron Source Second Targ.t Station currently under desig. at *** m.ssion of scientific neutron user facilities worldwide is to enable science using.state-of-th.-art neutron *** aim.to encourag. research.rs in th. environm.ntal and biolog.cal research.com.unity to explore th. unique capability afforded by neutrons at th.se facilities.

关键词： Neutrons Environm.nt Biolog. Neutron im.g.ng Neutron scattering Second Targ.t Station(STS)

Th. m.lti-im.urity system.in CdSe nanoplatelets:electronic structure and th.rm.dynam.c properties

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Com.unications in Th.oretical Ph.sics 2024年第3期76卷 165-173页

作者： D A Bag.0}asaryan V A h.rutynyan E m.Kazaryan h.A Sarkisyan Russian-Arm.nian University H Emin 1230051YerevanArmenia Institute of Applied Problem. of Ph.sics 25 Nersisyan St0014YerevanArmenia

Th.s paper th.oretically studies th. im.urity states and th. effects of im.urity concentration and config.ration on th. optical,electrical,and statistical properties of CdSe nanoplatelets(NPLs).An im.g. ch.rg.-based m.del of electron-im.urity interaction is *** ch.rg.-carrier energ. spectra and corresponding.wave functions depending.on th. im.urity num.er and config.ration are *** electron binding.energ.es are calculated for different NPL *** is sh.wn th.t th. im.g. ch.rg.-based interaction potential th.t arises due to th. dielectric constants m.sm.tch.is m.ch.strong.r th.n th. interaction potential th.t does not take such.a m.sm.tch.into ***,it is dem.nstrated th.t th. binding.energ.es are increasing.with.th. num.er of *** calculate th. canonical partition function using.th. energ. levels of th. electron,wh.ch.in turn is used to obtain th. m.an energ.,h.at capacity,and entropy of th. non-interacting.electron *** th.rm.dynam.c properties of th. non-interacting.electron g.s th.t depend on th. g.om.tric param.ters of th. NPL,im.urity num.er,config.ration,and tem.erature are studied.

关键词： nanoplateletes th.rm.dynam.c properties im.urity states

CD8+T cell m.tabolic flexibility elicited by CD28-ARS2 axisdriven alternative splicing.of PKm.supports antitum.r im.unity

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Cellular & m.lecular Im.unolog. 2024年第3期21卷 260-274页

作者： g.Aaron h.lling.Colin A.Ch.vel Anand P.Sh.rda m.ckenzie m.Lieberm.n Caitlin m.Jam.s Sh.vana m.Lig.0}m.n Jason h.Tong.g.anxi Qiao Tiffany R.Em.ons Th.jaswini g.ridh.ran Sh.ng.i h.u Andrew m.Intlekofer Rich.rd m.h.g.sh. Teresa W.m.Fan Andrew N.Lane Kevin h.Eng.Brah.0}h.Seg.l Elizabeth.A.Repasky Kelvin P.Lee Scott h.Olejniczak Departm.nt of Im.unolog. Roswell Park Comprehensive Cancer CenterBuffaloNY 14263USA Departm.nt of m.dicine Roswell Park Comprehensive Cancer CenterBuffaloNY 14263USA h.m.n Oncolog. and Path.g.nesis Prog.am Memorial Sloan Kettering Cancer CenterNew YorkNY 10065USA Center for Environm.ntal System. Bioch.m.stry Department of Toxicology and Cancer Biology and Markey Cancer CenterLexingtonKY 40536USA Departm.nt of Cancer g.netics and g.nom.cs Roswell Park Comprehensive Cancer CenterBuffaloNY 14263USA Present address:University of Colorado Boulder BoulderCO 80309USA Present address:Dana Farber Cancer Institute BostonMA 02215USA Present address:m.ssach.setts Institute of Tech.olog. BostonMA 02139USA Present address:m.lvin and Bren Sim.n Com.reh.nsive Cancer Center Indiana University School of MedicineIndianapolisIN 46202USA

m.tabolic flexibility h.s em.rg.d as a critical determ.nant of CD8+T-cell antitum.r activity,yet th. m.ch.nism. driving.th. m.tabolic flexibility of T cells h.ve not been *** th.s study,we investig.ted th. influence of th. nuclear cap-binding.com.lex(CBC)adaptor protein ARS2 on m.ture T *** doing.so,we discovered a novel sig.aling.axis th.t endows activated CD8+T cells with.flexibility of g.ucose ***2 upreg.lation driven by CD28 sig.aling.reinforced splicing.factor recruitm.nt to pre-m.NAs and affected approxim.tely one-th.rd of T-cell activation-induced alternative splicing.*** th.se effects,th. CD28-ARS2 axis suppressed th. expression of th. m. isoform.of pyruvate kinase in favor of PKm.,a key determ.nant of CD8+T-cell g.ucose utilization,interferon g.m.a production,and antitum.r effector ***,PKm.alternative splicing.occurred independently of CD28-driven PI3K path.ay activation,revealing.a novel m.ans by wh.ch.costim.lation reprog.am. g.ucose m.tabolism.in CD8+T cells.

关键词： Im.unom.tabolism m.NA splicing CD8 T cells ARS2 PKm.

Im.act of carbim.zole com.ined with.vitam.n E on testicular injury induced by experim.ntal h.perth.roidism.in adult albino rats:oxidative/inflam.atory/apoptotic path.ays

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Asian Journal of Androlog. 2024年第4期26卷 396-401页

作者： Ram.dan S h.ssein m.ustafa m.Eyada Rash.d m.m.stafa Sam.h.m.Elaidy Sh.reen h.Elsayed h.ny m.Saad Departm.nt of Derm.tolog. College of Medicine Prince Sattam Bin Abdulaziz UniversityAl-Kharj 16242Saudi Arabia Departm.nt of Derm.tolog. Andrology and STDsAssiut Police HospitalAssiut 71525Egypt Departm.nt of Derm.tolog. Venereology and AndrologyFaculty of MedicineSuez Canal UniversityIsmailia 41522Egypt Departm.nt of Androlog. and Sexolog. Faculty of MedicineSuez Canal UniversityIsmailia 41511Egypt Departm.nt of Clinical Ph.rm.colog. Faculty of MedicineSuez Canal UniversityIsmailia 41511Egypt Departm.nt of Reh.bilitation Sciences Faculty of Health and Rehabilitation SciencesPrincess Nourah bint Abdulrahman UniversityRiyadh 12271Saudi Arabia.

Th.roid h.rm.nes play essential roles in sperm.tog.nesis,but th.ir effects on infertile m.les rem.in poorly *** study aim.d to evaluate th. im.act of com.ining.carbim.zole(CBZ)with.vitam.n E(VE)on testicular injury induced by experim.ntal h.perth.roidism.in adult albino rats,focusing.on oxidative,inflam.atory,and apoptotic *** th.s experim.ntal study,64 adult m.le albino Wistar rats were divided into eig.0} g.oups:g.oup I(control-untreated),g.oup II(CBZ-control),g.oup III(VE-control),g.oup IV(CBZ+VE-control),g.oup V(levoth.roxine-induced testicular injury),g.oup VI(levoth.roxine+CBZ-treated),g.oup VII(levoth.roxine+VE-treated),and g.oup VIII(levoth.roxine+CBZ+VE-treated).Th. study was conducted in th. Faculty of m.dicine,Suez Canal University(Ism.ilia,Eg.pt).After cervical decapitation,both.testes and epididym.s were exam.ned h.stopath.log.cally and *** differences were observed am.ng.g.oups concerning.m.londialdeh.de(m.A),g.utath.one(g.h.,superoxide dism.tase(SOD),and catalase(CAT;all Pm.rase ch.in reaction analysis sh.wed sig.ificant differences in tum.r necrosis factor-α(TNF-α),interleukin-10(IL-10),Bcl-2-associated X protein(BAX),B-cell lym.h.m. 2 protein(Bcl2),p53,Caspase-3,Caspase-8,Caspase-9,and nuclear factor-kappa B(NF-κB)m.NA levels(all Ph.perth.roid g.oup treated with.CBZ alone(g.oup VI)exh.bited testicular side effects,affecting.sem.niferous tubules and ***,th. g.oup VIII sh.wed im.roved sperm.tog.nesis and a decrease in testicular side *** addition of VE to th. treatm.nt of h.perth.roid rats with.CBZ reduced testicular side effects and sem.niferous tubular affection wh.n potentially im.roving.*** research.is needed to elucidate th. underlying.m.ch.nism. fully.

关键词： antith.roid drug. testicular injury th.roid g.and vitam.n E