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Accumulation of dysprosium,samarium,terbium,lanthanum,neodymium and ytterbium by Arthrospira platensis and their effects on biomass biochemical composition

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Journal of Rare Earths 2021年第9期39卷 1133-1143页

作者： Inga Zinicovscaia Liliana Cepoi Ludmila Rudi Tatiana Chiriac Dmitrii grozdov sergey pavlov Svetlana Djur Joint Institute for Nuclear Research 6 Joliot-Curie Str.1419890DubnaRussia Horia Hulubei National Institute for R&D in Physics and Nuclear Engineering 30 Reactorului Str.MG-6BucharestMagureleRomania Institute of Microbiology and Biotechnology 1 Academiei Str.202&ChisinauMoldova State University "Dimitrie Cantemir"3/2 Academiei Str.2028ChisinauMoldova

The growth of Arthrospira platensis and physiological changes in biomass under the effects of six rare earth elements Dy,Sm,Tb,La,Nd and Yb were *** were tested by three concentrations of 10,20 and 30 mg/*** to neutron activation analysis data ***’s accumulation capacity toward studied elements changes in the following order of La>Dy>Nd>Sm>Yb>*** results show that Dy and La ions stimulate biomass growth and Yb ions inhibit it,while Sm,Tb and Nd ions do not affect biomass *** contents of proteins and chlorophyll a are not affected by the presence of rare earth elements in the cultivation *** elements affect to different extents carbohydrates,phycobilins,β-carotene,lipids and MDA contents in spirulina *** in the antioxidant activity under applied metal loads reveal a moderate stress in exposed *** *** can be successfully used for bioremediation of natural water contaminated with REEs as well as REEs recovery from low polluted industrial effluents.

关键词： Rare earth elements Arthrospira platensis Biochemical composition Antioxidant activity Neutron activation analysis

growth of carbon nanotube arrays on various CtxMey alloy films by chemical vapour deposition method

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Journal of Materials Science & Technology 2018年第3期34卷 472-480页

作者： Pawel Mierczynski sergey V.Dubkov sergey V.Bulyarskii Alexander A.pavlov sergey N.Skorik Alexey Yu Trifonov Agnieszka Mierczynska Eugene P.Kitsyuk sergey A.gavrilov Tomasz P.Maniecki Dmitry g.gromov Institute of general and Ecological Chemistry Lodz University of TechnologyZeromskiego 116Lodz 90-924Poland National Research University of Electronic Technology Shokin SquareZelenogradMoscow 124498Russia Institute of Nanotechnology of Microelectronics of the RAS INMEMoscow 11-9991Russia Scientific-Manufacturing Complex'Technological Center' ZelenogradMoscow 124498Russia Scientific Research Institute of Physical Problems named after F V.Lukin Proezd 4806.6ZelenogradMoscow 124460Russia The Australian Wine Research Institute Waite PrecinctHartley Grove cnr Paratoo RoadUrrbrae AdelaideSA 5064Australia

Carbon nanotube （CNT） arrays were fabricated on Ct-Me-N-（O） alloys with content of Ct in the range of 6-40 at.% by chemical vapour deposition. The Ct was a catalytic metal from the group of the following elements： Ni, Co, Fe, Pd, while Me was a transition metal from the group of IV-VII of the periodic table （where Me=Ti, V, Cr, Zr, Nb, Mo, Ta, W, Re）. Carbon nanotubes were found to grow efficiently on the alloy surface with its composition containing Ti, V, Cr, Zr, Hf, Nb or Ta. The growth of CNTs was not observed when the alloy contained W or Re. Additions of oxygen and nitrogen in the alloy facilitated the formation of oxynitrides and catalyst extrusion on the alloy surface. Replacement of the metals in alloy composition affected the diameter of the resulting CNTs. The obtained results showed that the alloy films of varying thickness （10-500 nm） may be used for the CNTs growth. The resulting CNT material was highly homogenous and its synthesis reproducible.

关键词： Carbon nanotubes Amorphous alloys Chemical vapour deposition Catalytic processes Thin films

Assessment of Factors Influencing Trace Element Content of the Basidiomycetes in the European Part of Russia

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Advances in Microbiology 2013年第8期3卷 37-46页

作者： Anatoly gorbunov sergey Lyapunov Elizaveta Mochalova Marina Frontasyeva sergey pavlov geological Institute of Russian Academy of Sciences Moscow Joint Institute for Nuclear Research Dubna Russia

The article presents concentrations of 29 trace elements in different groups of basidiomycetes: saprotrophic, parasitic and symbiotic. The potential of using the concentration factor (Kc) is shown for the assessment of trace element accumulation by the fungi. The variations of trace element concentrations in different ecological and geochemical environment are presented. The data obtained in this research made it possible to mark out the group of trace elements that are mainly accumulated by fungi. This information helped to assess the correlation between the trace element concentrations in the mycothalluses of fungi and their mobile forms in the soil. The expected patterns of the trace element accumulation in fungi are described.

关键词： Basidiomycetes Mycelium Microelements Storage Mobile Forms

Hidden stage of intracranial hemorrhage in newborn rats studied with laser speckle contrast imaging and wavelets

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Journal of Innovative Optical Health Sciences 2015年第5期8卷 99-106页

作者： Alexey N.pavlov Arkady S.Abdurashitov Olga N.pavlova Valery V.Tuchin Olga S.Sindeeva sergey S.Sindeev Oxana V.Semyachkina-glushkovskaya Department of Physics Saratov State University 83 Astrakhanskaya Str.Saratov 410012Russia Department of Biology Saratov State University 83 Astrakhanskaya Str.Saratov 410012Russia

Using the laser speckle contrast imaging and wavelet-based analyses,we investigate a latent("hidden")stage of the development of intracranial hemorrhages(ICHs)in newborn *** apply two measures based on the continuous wavelet-transform of blood flow velocity in the sagittal sinus,namely,the spectral energy in distinct frequency ranges and a multiscality degree characterizing complexity of experimental *** show that the wavelet-based multifractal formalism reveals changes in the cerebrovascular blood flow at the development of ICH.

关键词： Cerebral blood flow laser speckle contrast imaging stress wavelet-analysis complexity

Intake of Cl, Br, I, Se in Human Body with Food in Central Regions of the European Part of Russia

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Food and Nutrition Sciences 2015年第1期6卷 168-178页

作者： Anatoly V. gorbunov sergey M. Lyapunov Marina Frontasyeva sergey S. pavlov geological Institute of the Russian Academy of Sciences Moscow Russia Frank Laboratory of Neutron Physics Joint Institute for Nuclear Research Dubna Russia

Since most of the central regions of the European part of Russia are considered selenium and iodine deficient, the assessment of modern real consumption of chlorine, bromine, iodine and selenium by population of these regions with different diets is an important constituent part of medical monitoring. In this paper, a brief analysis of the impact of these elements on the human body is given. A number of consumed foodstuffs in different food rations (diets) were assessed. Six selected basic food rations, which most fully reflect the specific features of nutrition in the Russian Federation, were chosen. The analysis of the concentration of chlorine, bromine, iodine and selenium in a wide range of food and agricultural products was carried out. The daily intake of these elements in the human body from the selected diets was calculated. A comparison of the real income of chlorine, bromine, iodine and selenium in the human body with a physiologically needed intake was performed. It is proposed to use the coefficient of Kr, which is the ratio of actual intake of the element in the human body to physiologically needed intake. Based on this analysis assessed insufficient or excess supply of chlorine, bromine, iodine and selenium in the human body with these diets in the central regions of the European part of Russia was evaluated.

关键词： Trace Elements Intake Chlorine Bromine Selenium Iodine Foodstuffs Diets

Trapping the Short-Chain Odd Carbon Number Olefins Using Nickel(Ⅱ)-Catalyzed Tandem Ethylene Oligomerization and Friedel-Crafts Alkylation of Toluene

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Chinese Journal of Chemistry 2023年第21期41卷 2855-2865页

作者： sergey V.Zubkevich Vladislav A.Tuskaev Svetlana Ch.gagieva Alexander A.pavlov Victor N.Khrustalev Fei Wang Li Pan Yuesheng Li Daniele Saracheno Anton A.Vikhrov Dmitry N.Zarubin Boris M.Bulychev Department of Chemistry Lomonosov Moscow State UniversityLeninskie Gory 1Moscow119991 Russian Federation Materials Research and Technology Department Luxembourg Institute of Science and Technology5Avenue des Hauts-FourneauxL-4362 Esch-sur-AlzetteLuxembourg A N Nesmeyanov Institute of Organoelement Compounds Russian Academy of SciencesVavilova st.28Moscow119991 Russian Federation BMSTU Center of National Technological Initiative“Digital Material Science:New Material and Substances” Bauman MoscowState Technical University2nd Baumanskaya st.5MoscowRussian Federation Peoples’Friendship University of Russia(RUDN University) Miklukho-Maklay St.6Moscow117198 Russian Federation Zelinsky Institute of Organic Chemistry Russian Academy of SciencesLeninsky Prospekt 47Moscow119991 Russian Federation Institute of Advanced Polymer Materials School of Materials Science and EngineeringTianjin UniversityTianjin300350 China

Nickel(Ⅱ)complexes with pyrazole-based ligands are widely employed in catalysis of ethylene oligomerization and subsequent Friedel-Crafts alkylation of *** have prepared ten new nickel(Ⅱ)dibromide complexes with various substituted bis(azolyl)*** have been characterized using^(1)H NMR,IR,high resolution mass spectrometry and elemental *** structures of three complexes have been unambiguously established using X-ray *** was found that these complexes in the presence of Et2AlCl or Et_(3)Al_(2)Cl_(3)are active both in ethylene oligomerization and Friedel-Crafts alkylation processes(activity up to 3720 kgoligomer·mol[Ni]^(−1)·h^(−1)).The use of Et_(3)Al_(2)Cl_(3)results in a higher share of alkylated products(up to 60%).Moreover,catalytic systems activated with Et_(3)Al_(2)Cl_(3)produced small amounts of odd carbon number olefins(up to 0.8%).The Friedel-Crafts alkylation was used as a trap for previously undetected short-chain odd carbon number olefins(C_(3)and C_(5)).

关键词： Ethylene oligomerization Friedel-Crafts alkylation Nickel(Ⅱ)complexes N-ligands Odd carbon number olefins

Assessment of Mercury in Diagnostic Biomaterials of Different Population groups in Urban Areas of the Moscow Region

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Advances in Microbiology 2019年第7期9卷 571-580页

作者： Anatoly V. gorbunov sergey M. Lyapunov Irina N. Ilchenko Marina V. Frontasyeva sergey S. pavlov geological Institute of Russian Academy of Sciences Moscow Russian I. M. Sechenov First Moscow State Medical University (Sechenov University) Moscow Russian Frank Laboratory of Neutron Physics Joint Institute for Nuclear Research Dubna Russian

The results of a survey of different population groups in urban areas of the Moscow Region (industry workers, residents of areas with increased anthropogenic load of mercury and conditionally pristine areas, cohorts of pregnant women and children) to assess the contents of mercury in samples of various diagnostic biomaterials taken during the course of research are presented. Mercury concentrations in venous and umbilical cord blood, urine, hair, and nails were determined by means of instrumental neutron activation analysis and cold vapor atomic absorption spectrometry. Peculiarities of selection, transportation, storage, and preparation for analysis of samples of hair, nails, urine and umbilical venous blood are described. The determined concentrations of mercury in the studied diagnostic biomaterials are compared with normal and thresholds values. Although increased mercury concentrations were observed in some cases, no significant exposure of mercury was evident in general in the study towns. A positive correlation between the degree of consumption of seafood during pregnancy and a high content of mercury in the analyzed diagnostic biomaterials was shown.

关键词： Mercury Hair Nails Urine Venous and Umbilical Cord Blood The Impact The Human

Estimation of Mercury Intake from Consumption of Fish and Seafood in Russia

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Food and Nutrition Sciences 2016年第7期7卷 516-523页

作者： Anatoliy V. gorbunov Boris V. Ermolaev sergey M. Lyapunov Olga I. Okina sergey S. pavlov Marina V. Frontasyeva geological Institute Russian Academy of Sciences Moscow Russia Joint Institute for Nuclear Research Dubna Russia

Data on the mercury concentration in freshwater and marine fish and seafood on the territory of Russia are presented. The level and pattern of the fish and seafood consumption in various regions of Russia are found from the analysis of open statistics. Regions with the maximum and minimum consumption of fish products are established. Mercury intake from these products in a human organism is calculated. It is shown that at the current level and pattern of the diet in Russia fish cannot be a source of high mercury concentrations in a human organism.

关键词： Mercury Marine and Freshwater Fish Seafood Consumption Level Human Organism Intake

Nostoc Linckia as Biosorbent of Chromium and Nickel from Electroplating Industry Wastewaters

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材料科学与工程（中英文B版） 2014年第8期4卷 242-247页

作者： Inga Zinicovscaia Liliana Cepoi Ana Valuta Liudmila Rudi Otilia Ana Culicov Marina Vladimirovna Elena Ivanovna Kirkesali sergey Serghevich pavlov Tatiana Mitina Joint Institute for Nuclear Research Dubna 1419890 Russia Institute of Microbiology and Biotechnology of the Academy of Sciences of Moldova Chisinau 2028 R. Moldova The Institute of Chemistry of the Academy of Sciences of Moldova Chisinau 2028 R. Moldova National R&D Institute for Electrical Engineering ICPE-CA Bucharest 030138 Romania