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9,10-Bis(diphenylmethylene)-9,10-dihydroanthracene-based metal-organic assemblies with aggregation-induced emission for multiple sensing

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Chinese Chemical Letters 2023年第12期34卷 215-219页

作者： Qian Feng Nan Li Zeyuan Zhang Kai Gao Kai Wang sanliang ling Hongye Yuan Yanmin Zhang Mingming Zhang State Key Laboratory for Mechanical Behavior of Materials Shaanxi International Research Center for Soft MatterSchool of Materials Science and EngineeringXian Jiaotong UniversityXi'an 710049China School of Pharmacy Health Science CenterXi'an Jjiaotong UniversityXi'an 710061China State Key Laboratory of Superhard Materials College of PhysicsJilin UniversityChangchun 130012China Advanced Materials Research Group Faculty of EngineeringUniversity of NottinghamNottingham NG72RDUnited Kingdom

Developing novel emissive supramolecular assemblies with elegant architectures and tunable perfor-mance remains highly desirable yet ***,we report the design and synthesis of several 9.10-bis(diphenylmethylene)-9.10-dihydroanthracene-based metal organic assembles with aggregation-induced emission *** assemblies feature intriguing thermochromic and mechanochromic properties,ie.,distinguishable fuorescence responses in terms of emission wavelength and intensity un-der variable temperatures and ***,these assemblies can serve as excellent fluorescent sensors for the detection of polysaccharide *** to the differentiated charge type and den-sity,the assembles display distinct sensing mechanisms toward different polysaccharide *** study provides novel perspectives for the synthesis of buttrfly-like platinum(I)supramolecular coordi-nation complexes with multistimuli-responsiveness for polysaccharide *** will facllitate the development of stimuli-responsive materials.

关键词： Light-emitting materials Butterfly-like assembles Aggregation-induced emission Multiple sensing

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Perylene Diimide-Based Multicomponent Metallacages as Photosensitizers for Visible Light-Driven Photocatalytic Oxidation Reaction

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CCS Chemistry 2022年第8期4卷 2604-2611页

作者： Yali Hou Zeyuan Zhang lingzhi Ma Ruping Shi sanliang ling Xiaopeng Li Gang He Mingming Zhang State Key Laboratory for Mechanical Behavior of Materials Shaanxi International Research Center for Soft MatterSchool of Materials Science and EngineeringXi’an Jiaotong UniversityXi’an 710049 Advanced Materials Research Group Faculty of EngineeringUniversity of NottinghamNottingham NG72RD College of Chemistry and Environmental Engineering Shenzhen UniversityShenzhen 518055 Frontier Institute of Science and Technology(FIST) Xi’an Jiaotong UniversityXi’an 710049 State Key Laboratory of Luminescent Materials and Devices Guangdong Provincial Key Laboratory of Luminescence from Molecular AggregatesSouth China University of TechnologyGuangzhou 510640

Self-assembled supramolecular structures with efficient singlet oxygen(1O2)-generation ability are expected to enable photocatalytic oxidation ***,we use two photosensitizers,perylene diimide and benzothiadiazole deri... 详细信息

关键词： metallacages singlet oxygen photocatalytic oxidation reaction self-assembly

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