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Rare Metals 2024年第9期43卷 4628-4635页

作者： Yu-Ning Fan Yun-Qiu Zhang san-shuang gao Zeng-Hui Bi Yin Wang Shu-Xing Zhou Qian Liu Tian-Ping Lv Guang-Zhi Hu Institute for Ecological Research and Pollution Control of Plateau Lakes School of Ecology and Environmental ScienceYunnan University Hubei Key Laboratory of Low Dimensional Optoelectronic Materials and Devices Hubei University of Arts and Science Institute for Advanced Study Chengdu University

The use of transition metal-activated peroxymonosulfate（PMS） as an advanced oxidation technology has gained recognition. This study developed a catalyst using cobaltDlanthanum bimetallic oxide supported on layered molybdenum disulfide （Mo S2） as a carrier. The CoDLa/Mo S2catalyst was synthesised through coprecipitation, followed by calcination with an optimised metal ratio of Co:La=2:1 to activate PMS and degrade trace chloramphenicol（CAP） in water. The chemical composition of the catalyst was confirmed using X-ray diffraction （XRD） and X-ray photoelectron spectroscopy （XPS）. At catalyst and PMS dosages of 0.1 and 0.5 g·L-1, respectively, the degradation rate of CAP was 95% with in 30 min. The catalyst exhibitedstrong resistance to most interfering anions and maintained a high degradation rate at p H 3D11. Liquid chromatographyDmass spectrometry analysis revealed the potential degradation pathways of CAP in the CoDLa/Mo S2（2:1）/PMS system. For other pollutants, such as oxytetracycline,complete degradation was achieved within 20 min,demonstrating the broad applicability of the CoDLa/Mo S2（2:1）/PMS system for the degradation and removal of antibiotic organic contaminants. This study offers a feasible approach for the degradation of antibiotic organic pollutants, including CAP, in natural water bodies.

关键词： Catalysts

Method of improving pedestrian navigation performance based on chest card

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Journal of Systems Engineering and Electronics 2024年第4期35卷 987-998页

作者： CHENG Hao gao shuang CAI Xiaowen WANG Yuxuan WANG Jie School of Instrumentation and Optoelectronic Engineering Beihang UniversityBeijing 100191China School of Automation and Electronic Information Xiangtan UniversityXiangtan 411105China Navigation Guidance and Control Graduate School of the Second Institute of China Aerospace Science and Industry CorporationBeijing 100854China

With the development of positioning technology,loca-tion services are constantly in demand by *** a primary location service pedestrian navigation has two main approaches based on radio and inertial *** pedestrian naviga-tion based on radio is subject to environmental occlusion lead-ing to the degradation of positioning *** pedestrian navigation based on micro-electro-mechanical system inertial measurement unit(MIMU)is less susceptible to environmental interference,but its errors dissipate over *** this paper,a chest card pedestrian navigation improvement method based on complementary correction is proposed in order to suppress the error divergence of inertial navigation *** suppress atti-tude errors,optimal feedback coefficients are established by pedestrian motion *** extend navigation time and improve positioning accuracy,the step length in subsequent movements is compensated by the first step *** experi-mental results show that the positioning accuracy of the pro-posed method is improved by more than 47%and 44%com-pared with the pure inertia-based method combined with step compensation and the traditional complementary filtering com-bined method with step *** proposed method can effectively suppress the error dispersion and improve the positioning accuracy.

关键词： pedestrian navigation micro-electro-mechanical sy-stem(MEMS) inertial navigation complementary filtering

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Aero-Hydro-Elastic-Servo Modeling and Dynamic Response Analysis of A Monopile Offshore Wind Turbine Under Different Operating Scenarios

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China Ocean Engineering 2024年第3期38卷 379-393页

作者： XIE shuang-yi gao Jian LI Yong-ran JIANG Shu-xin ZHANG Cheng-lin HE Jiao College of Mechanical Engineering Chongqing University of TechnologyChongqing 400044China Beijing Institute of Precision Mechatronics and Controls Beijing 100076China College of Mechanical and Vehicle Engineering Chongqing UniversityChongqing 400044China Fishery Machinery and Instrument Research Institute Chinese Academy of Fishery SciencesShanghai 200092China School of Mechanical and Power Engineering Chongqing University of Science&TechnologyChongqing 401331China

This paper constructs a coupled aero-hydro-elastic-servo simulation framework for a monopile offshore wind turbine(OWT).In this framework,a detailed multi-body dynamics model of the monopile OWT including the gearbox,blades,tower and other components(nacelle,hub,bedplate,etc.)has been explicitly *** effects of pile−soil interaction,controller and operational conditions on the turbine dynamic responses are studied systematically in time domain and frequency *** results show that(1)a comprehensive drivetrain model has the capability to provide a more precise representation of the complex dynamic characteristics exhibited by drivetrain components,which can be used as the basis for further study on the dynamic characteristics of the drivetrain.(2)The pile−soil interaction can influence the wind turbine dynamic responses,particularly under the parked condition.(3)The effect of the pile−soil interaction on tower responses is more significant than that on blade responses.(4)The use of the controller can substantially affect the rotor characteristics,which in turn influences the turbine dynamic responses.(5)The tower and blade displacements under the operational condition are much larger than those under the parked *** model and methodology presented in this study demonstrate potential for examining complex dynamic behaviors of the monopile *** ensure accuracy and precision,it is imperative to construct a detailed model of the wind turbine system,while also taking into account simulation efficiency.

关键词： offshore wind turbine(OWT) pile−soil interaction dynamic response parked condition operating condition

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Dynamic shielding of bacterial outer membrane vesicles for safe and efficient chemo-immunotherapy against tumors

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Nano Research 2024年第2期17卷 836-847页

作者： Shuping Li Xin Li Jiaqi Meng Weier Bao shuang Wang Peng Ye Xiao-Dong gao Wei Wei Key Laboratory of Carbohydrate Chemistry and Biotechnology Ministry of Education School of BiotechnologyJiangnan UniversityWuxi 214122China State Key Laboratory of Biochemical Engineering Institute of Process EngineeringChinese Academy of SciencesBeijing 100190China School of Chemical Engineering University of Chinese Academy of SciencesBeijing 100049China

Bacterial outer membrane vesicles(OMVs)are potent immunostimulants of regulating the tumor microenvironment(TME)for immunotherapy,and can be used to deliver ***,the severe systemic inflammatory response triggered by OMVs upon intravenous(i.v.)injection has limited their ***,we developed a safe and effective strategy by conjugating doxorubicin-loaded serum albumin(SA-DOX,AD)onto the surface of OMVs using a matrix metalloproteinase(MMP)-cleavable peptide linker(cL).This approach enabled the dynamic shielding of OMVs to reduce the systemic side effects while simultaneously enhancing the anti-tumor effects through ***,the resulting OMV-cL-AD formulation exhibited significantly enhanced accumulation at the tumor site after ***,facilitated by the SA decoration on the OMVs ***,the shield on the OMV-cL-AD was cleaved by the over-expressed MMP in the TME,leading to the release of both OMVs and *** process provided OMV-induced immunotherapy and DOX-induced chemotherapy,resulting in synergistic tumor *** conclusion,our work demonstrated the potential of OMV-cL-AD as an effective immunochemotherapy strategy that can prolong the survival time of mice without inducing side effects.

关键词： outer membrane vesicles doxorubicin tumor microenvironment immunotherapy chemotherapy

Boson star superradiance

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Science China(Physics,Mechanics & Astronomy) 2024年第6期67卷 69-78页

作者： He-Yu gao Paul M.Saffin Yi-Jie Wang Qi-Xin Xie shuang-Yong Zhou School of Physical Sciences University of Science and Technology of ChinaHefei 230026China School of Physics and Astronomy University of NottinghamUniversity ParkNottingham NG72RDUK Interdisciplinary Center for Theoretical Study University of Science and Technology of ChinaHefei 230026China Peng Huanwu Center for Fundamental Theory Hefei 230026China

Recently,it has been realized that in some systems internal space rotation can induce energy amplification for scattered waves,similar to rotation in real *** particularly,it has been shown that energy extraction is possible for a Q-ball,a stationary non-topological soliton that is coherently rotating in its field *** this paper,we generalize the analysis to the case of boson stars,and show that the same energy extraction mechanism still works for boson stars.

关键词： superradiance boson star field space rotation

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Construction of MoP/MoS_(2) Core-shell Structure Electrocatalyst for Boosting Hydrogen Evolution Reaction

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Chemical Research in Chinese Universities 2024年第3期40卷 490-498页

作者： MENG Dan RAN Shunjiang gao Ling ZHANG Yue san Xiaoguang ZHANG Lei LI Ruixiang JIN Quan College of Chemical Engineering Shenyang University of Chemical TechnologyShenyang 110142P.R.China Key Laboratory of Automobile Materials(Ministry of Education) School of Materials Science and EngineeringJilin UniversityChangchun 130022P.R.China

Hydrogen energy stands out as one of the most promising alternative energy sources due to its cleanliness and *** water splitting offers a sustainable pathway for hydrogen ***,the kinetic rate of the hydrogen evolution reaction(HER)is sluggish,emphasizing the critical need for stable and highly active electrocatalysts to facilitate HER and enhance reaction *** metal-based catalysts have garnered attention for their favorable catalytic activity in electrochemical hydrogen evolution in alkaline *** this investigation,flower-like nanorods of MoS_(2) were directly synthesized in situ on a nickel foam substrate,followed by the formation of MoP/MoS_(2)-nickel foam(NF)heterostructures through high-temperature phosphating in a tube furnace *** findings reveal that MoP/MoS_(2)-NF-450 exhibits outstanding electrocatalytic performance in an alkaline milieu,demonstrating a low overpotential(90 mV)and remarkable durability at a current density of 10 mA/cm^(2).Comprehensive analysis indicates that the introduction of phosphorus(P)atoms enhances the synergistic effect with MoS_(2),while the distinctive flower-like nanorod structure of MoS_(2) exposes more active ***,the interface between the MoP/MoS_(2) heterostructure and NF facilitates electron transfer during hydrogen evolution,thereby enhancing electrocatalytic *** design and synthesis of such catalysts offer a valuable approach for the development of high-performance hydrogen evolution electrocatalysts.

关键词： MoP/MoS_(2) Core-shell structure Heterostructure Synergistic effect Hydrogen evolution reaction

A novel fracture-cavity reservoir outcrop geological knowledge base construction method considering parameter collection and processing, mutual transformation of data-knowledge, application and update

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Petroleum Science 2024年第4期21卷 2184-2202页

作者： Qi-Qiang Ren Jin-Liang gao Peng Zhu Meng-Ping Li Jian-Wei Feng Qiang Jin san Zhang Institute of Sedimentary Geology Chengdu University of Technology PetroChina Research Institute of Petroleum Exploration and Development School of Energy Chengdu University of Technology School of Resources and Geosciences China University of Mining and Technology School of Geosciences China University of Petroleum (East China) School of Geosciences Yangtze University

This study endeavors to formulate a comprehensive methodology for establishing a Geological Knowledge Base(GKB) tailored to fracture-cavity reservoir outcrops within the North Tarim Basin. The acquisition of quantitative geological parameters was accomplished through diverse means such as outcrop observations, thin section studies, unmanned aerial vehicle scanning, and high-resolution cameras. Subsequently, a three-dimensional digital outcrop model was generated, and the parameters were standardized. An assessment of traditional geological knowledge was conducted to delineate the knowledge framework, content, and system of the GKB. The basic parameter knowledge was extracted using multiscale fine characterization techniques, including core statistics, field observations, and microscopic thin section analysis. Key mechanism knowledge was identified by integrating trace elements from filling, isotope geochemical tests, and water-rock simulation experiments. Significant representational knowledge was then extracted by employing various methods such as multiple linear regression, neural network technology, and discriminant classification. Subsequently, an analogy study was performed on the karst fracture-cavity system(KFCS) in both outcrop and underground reservoir settings. The results underscored several key findings:(1) Utilization of a diverse range of techniques,including outcrop observations, core statistics, unmanned aerial vehicle scanning, high-resolution cameras, thin section analysis, and electron scanning imaging, enabled the acquisition and standardization of data. This facilitated effective management and integration of geological parameter data from multiple sources and scales.(2) The GKB for fracture-cavity reservoir outcrops, encompassing basic parameter knowledge, key mechanism knowledge, and significant representational knowledge, provides robust data support and systematic geological insights for the intricate and in-depth examination of the genetic

关键词： Geological knowledge base Karst fracture-cavity system Mutual transformation of data-knowledge Knowledge base content and application Tarim basin

Experimental demonstration of a photonic spiking neuron based on a DFB laser subject to side-mode optical pulse injection

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Science China(Information Sciences) 2024年第3期67卷 271-280页

作者： Shuiying XIANG shuang gao Yuechun SHI Yuna ZHANG Ziwei SONG Xingxing GUO Yahui ZHANG Yuxin MA Xiangfei CHEN State Key Laboratory of Integrated Service Networks Xidian University Yongjiang Laboratory 3. College of Engineering and Applied Sciences Nanjing University

We proposed and experimentally demonstrated a simple and novel photonic spiking neuron based on a distributed feedback(DFB) laser subject to side-mode optical pulse injection(SMOPI). The DFB laser chip is designed and fabricated based on asymmetric equivalent π phase shift(π-EPS) with the reconstruction-equivalent-chirp(REC) technique. Under side-mode continuous-wave(CW) optical injection,excitability pulse was experimentally observed during the dominant mode switching process due to the injection-locked effect. Based on the transition between the excitability regime and the side-mode injection locking effect, the controllable and repeatable neuron-like spiking response can be realized when external stimulus pulses are electro-optically modulated on the CW optical carrier. The experimental results show that the spike threshold, temporal integration, and refractory period, which are important spike processing mechanisms in biological neurons, can all be achieved in the optically-injected DFB laser. The experimental findings are also verified numerically with a rate equation model that considers the SMOPI. To the best of our knowledge, this is the first experimental demonstration of a photonic spiking neuron based on a DFB laser subject to SMOPI, which holds promise for realizing large-scale photonic spiking neuron arrays for hardware photonic spiking neural network chips.

关键词： neuromorphic photonics photonic spiking neuron DFB laser side-mode optical pulse injections

Inducing piezoelectricity in distorted rutile TiO_(2)for enhanced tetracycline hydrochloride degradation through photopiezocatalysis

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Journal of Advanced Ceramics 2024年第3期13卷 323-331页

作者： Taotao Xia Lizhen Lu Haoyu Zhang Jinghui Wang Zonghe Huang Hongyang Wang Weiyi Yang shuang gao Qi Li Key Laboratory of Advanced Technologies of Materials(Ministry of Education) School of Materials Science and EngineeringSouthwest Jiaotong UniversityChengdu 610031China Shenyang National Laboratory for Materials Science Institute of Metal ResearchChinese Academy of SciencesShenyang 110016China

Various material design strategies have been developed to enhance photocatalytic performance of TiO_(2).However,no report is available on applications of the photopiezocatalysis strategy on TiO_(2)due to its lack of *** we developed a low-temperature molten salt etching process to create rutile TiO_(2)nanoparticles by etching[MgO_(6)]octahedrons away from MgTiO_(3)by molten NH_(4)Cl,during which a lattice distortion occurred in TiO_(2).The lattice distortion broke the structure symmetry of rutile TiO_(2)and subsequently endowed these rutile TiO_(2)nanoparticles with an unusual piezoelectric response with the maximum effective piezoelectric coefficient(d_(33))of~41.6 pm/V,which had not previously been found in TiO_(2)***,the photopiezocatalysis strategy was applied for the first time to enhance the photocatalytic performance of these TiO_(2)*** creation of lattice distortion to induce piezoelectricity could be extended to other photocatalysts that the photopiezocatalysis strategy has not been applied to and may generate novel functionalities for various technical applications.

关键词： photocatalysis TiO_(2) piezocatalysis molten salt etching process photopiezocatalysis

PACS gene family-related neurological diseases: limited genotypes and diverse phenotypes

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World Journal of Pediatrics 2024年第1期20卷 82-91页

作者： Han Zhang Kai gao shuang Wang Yue-Hua Zhang Zhi-Xian Yang Ye Wu Yu-Wu Jiang Department of Pediatrics Peking University First Hospital.No.1 Xi'an Men StreetWest DistrictBeijing 100034China Bejing Key Laboratory of Molecular Diagnosis and Study on Pediatric Genetic Diseases BeijingChina Children Epilepsy Center Peking University First HospitalBeijingChina Key Laboratory for Neuroscience Ministry of Education/National Health and Family Planning CommissionPeking UniversityBeijingChina Center of Epilepsy Beijing Institute for Brain DisordersBeijingChina

Background The PACS gene family has been demonstrated to be related to intracellular vesicular *** phenotypic manifestations caused by the pathogenic variants of PACS include epilepsy,intellectual disability/developmental delay,and malformations,such as facial *** We identified seven new cases with pathogenic or likely pathogenic PACS variants using next-generation *** information obtained from these patients was analyzed along with that obtained from previously reported *** With the inclusion of the newly diagnosed cases in this study,103 cases with PACS gene family-related neurological diseases were reported,of which 43 were PACS2-related cases and the remaining were PACSI-related *** patients had seizures,which have been reported to be effectively controlled by several types of anti-seizure medications(ASMs).The most efficacious and frequently prescribed ASMs included sodium valproate(43.3%,13/30),oxcarbazepine/carbamazepine(26.7%,8/30),and levetiracetam(20%,6/30).Almost all patients had intellectual disability/developmental *** most common pathogenic missense variants were PACSI ***203Trp and PACS2 *** addition,we report a patient carrying a likely pathogenic copy number variation(CNV)(de novo heterozygous deletion of chr14:105821380-106107443,286 kilobase,destroyed part of the furin-binding region domain and the protein structure after it)with more severe and refractory late-onset *** The clinical phenotypes of the different PACS heterozygous missense variants were *** pathogenic variant sites of PACSI and PACS2 were quite limited but located in different regions.A CNV destroying part of the PACS2 gene might also be *** findings may provide an important clue for further functional studies on the pathogenic mechanism of neurological disorders related to the PACS gene family.

关键词： Developmental delay Epilepsy Intellectual disability PACSI PACS2