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Suppression of gold nanoparticle agglomeration and its separation via nylon membranes

Chinese Journal of Chemical Engineering 2017年第7期25卷 931-937页

作者： Ayyavoo Jayalakshmi In-Chul Kim Young-Nam kwon School of Urban and Environmental Engineering Ulsan National Institute of Sdence and TechnologyUlsan 689-798Korea KIST-UNIST UIsan Center for Convergent Materials UNIST(Ulsan National Institute of Science and Technology)Korea Environment and Resources Research Center Korea Research Institute Chemical TechnologyDaejeon 305-606Korea

Use of ultraporous nylon membrane is one of the most widely employed techniques for removal of hard and soft nanoparticles in the semiconductor industry, and the accurate determination of membrane pore size is necessary in order to avoid manufacturing defects caused by contamination. The gold nanoparticle has several benefits for the evaluation of polymeric membranes; however, the nanoparticles agglomerate easily on the nylon membrane and make it difficult to evaluate the membrane precisely. The properties of 2-amino-2-hydroxymethyl-1,3-propanediol(ADP) ligand in gold nanoparticle solution were systematically investigated, and ADP was utilized for improved evaluation of the nylon membranes. Nylon membrane used in this study was prepared by phase inversion techniques. Ultrathin dense layer on top of the membrane surface and Darcy structures in the microporous membrane support were observed. The gold particle rejection was carried out at various p H values from 4 to14 and higher rejection was observed at p H 4 and 8. The suppression of gold colloid agglomeration using ADP and monodispersity of gold colloids was also analyzed by confocal laser scanning microscopy(CLSM), transmission electron microscopy(TEM), and scanning electron microscopy(SEM). van der Waals interaction energy of the particles was reduced in the addition of ADP. The presence of ADP ligand in the gold solutions prevented the agglomeration of gold nanoparticles and reduced the adsorption of the particles on the nylon membrane surface,leading to precise evaluation of membrane pore sizes.

关键词： Particle size Electron microscopy Gold colloid flock Semiconductor

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VQT:value cardinality and query pattern based R-schema to XML schema translation with implicit referential integrity

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Journal of Zhejiang University-Science A(Applied Physics & Engineering) 2008年第12期9卷 1694-1707页

作者： Jinhyung KIM Dongwon JEONG Doo-kwon BAIK Department of Computer Science and Engineering Korea UniversitySeoul 136-713Korea Department of Informatics and Statistics Kunsan National UniversityKunsan 573-701Korea

In this paper,we propose a new relational schema (R-schema) to XML schema translation algorithm, VQT, which analyzes the value cardinality and user query patterns and extracts the implicit referential integrities by using the cardinality property of foreign key constraints between columns and the equi-join characteristic in user queries. The VQT algorithm can apply the extracted implied referential integrity relation information to the R-schema and create an XML schema as the final result. Therefore, the VQT algorithm prevents the R-schema from being incorrectly converted into the XML schema, and it richly and powerfully represents all the information in the R-schema by creating an XML schema as the translation result on behalf of the XML DTD.

关键词： Value cardinality Query pattern Relational schema XML schema Implicit referential integrity relations Explicit referential integrity

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Effect of the protection layer formed by cross-linked gelatin on the stability and performance of glucose and oxygen fuel cells

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Journal of Energy Chemistry 2021年第10期30卷 155-162,I0005页

作者： Kyuhwan Hyun Joonyoung Lee Suhyeon Kang Yongchai kwon Graduate School of Energy and Environment Seoul National University of Science and Technology232 Gongneung-roNowon-guSeoul 01811Republic of Korea Department of Chemical and Biomolecular Engineering Seoul National University of Science and Technology232 Gongneung-roNowon-guSeoul 01811Republic of Korea

A glucose oxidation catalyst comprising carbon nanotube,tetrathiafulvalene(TTF),gelatin,glutaraldehyde(GA)and glucose oxidase(GOx)(CNT/[TTF-GOx]/Gelatin+GA)is suggested to enhance the reactivity of glucose oxidation reaction(GOR),and the performance and stability of enzymatic biofuel cells(EBCs)using this *** this catalyst,TTF is used as mediator to transfer electron effectively,while GA is crosslinked to gelatin to form non-soluble *** structure prevents the dissolution of gelatin from aqueous electrolyte and reduces the leaching-out of GOx and TTF *** confirm the crosslinking effect of GA and gelatin,Fourier-transform infrared spectroscopy(FT-IR)and electrochemical evaluations are *** to FT-IR analysis,it was observed that the amide I peak shifted after *** is evidence showing the appropriate network formation and the reactivity of CNT/[TTFGOx]/Gelatin+GA is well preserved even after multiple potential *** addition,its GOx activity is regularly monitored for one month and the measurements prove that the structure prevents the leaching out of GOx *** on that,EBC using the anodic catalyst shows excellent performances,such as open circuit voltage of 0.75 V and maximum power density of 184μW/cm^(2).

关键词： Enzymatic biofuel cell Tetrathiafulvalene Crosslinking of glutaraldehyde and gelatin Hemi-acetal bond group

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An alternative interpretation for the map expression of "abrupt" changes in lateral stratigraphic level near transverse zones in fold-thrust belts

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Geoscience Frontiers 2012年第4期3卷 401-406页

作者： Sanghoon kwon Gautam Mitra Department of Earth System Sciences Yonsei UniversitySeoul 120-749Republic of Korea Department of Earth and Environmental Sciences University of RochesterRochesterNY 14627USA

The map expression of ＂abrupt＂ changes in lateral stratigraphic level of a thrust fault has been traditionally interpreted to be a result of the presence of （1） a lateral （or oblique） thrust-ramp, or （2） a frontal ramp with displacement gradient, and/or （3） a combination of these geometries. These geometries have been used to interpret the structures near transverse zones in fold-thrust belts （FTB）. This contribution outlines an alternative explanation that can result in the same map pattern by lateral variations in stratigraphy along the strike of a low angle thrust fault. We describe the natural example of the Leamington transverse zone, which marks the southern margin of the Pennsylvanian-Permian Oquirrh basin with genetically related lateral stratigraphic variations in the North American Sevier FTB. Thus, the observed map pattern at this zone is closely related to lateral stratigraphic variations along the strike of a horizontal fault. Even though the present-day erosional level shows the map pattern that could be interpreted as a lateral ramp, the observed structures along the Leamington zone most likely share the effects of the presence of a lateral （or oblique） ramp, lateral stratigraphic variations along the fault trace, and the displacement gradient.

关键词： Lateral stratigraphic changes Fold-thrust belt Transverse zone Frontal ramp Lateral ramp Displacement gradient

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Spatial Multi-Presence System to Increase Security Awareness for Remote Collaboration in an Extended Reality Environment

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Intelligent Automation & Soft Computing 2023年第7期37卷 369-384页

作者： Jun Lee Hyun kwon Department of Game Software Hoseo UniversityAsan-siKorea Department of Artificial Intelligence and Data Science Korea Military AcademySeoulKorea

Enhancing the sense of presence of participants is an important issue in terms of security awareness for remote collaboration in extended ***,conventional methods are insufficient to be aware of remote situations and to search for and control remote *** study pro-poses a spatial multi-presence system that simultaneously provides multiple spaces while rapidly exploring these spaces as users perform collaborative work in an extended reality *** proposed system provides methods for arranging and manipulating remote and personal spaces by creating an annular screen that is invisible to the *** user can freely arrange remote participants and their workspaces on the annular *** users can simultaneously view various spaces arranged on the annular screen,they can perform collaborative work while simultaneously feeling the presence of multiple spaces and can be fully immersed in a specific *** addition,the personal spaces where users work can also be arranged through the annular *** to the results of the performance evaluations,users participating in remote collaborative works can visualize the spaces of multiple users simultaneously and feel their presence,thereby increasing their understanding of the ***,the proposed system reduces the time to perform tasks and gain awareness of the emergency in remote workspaces.

关键词： Extended reality spatial presence multi presence security awareness

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Development and Application of a Production Data Analysis Model for a Shale Gas Production Well

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Fluid Dynamics & Materials Processing 2020年第3期16卷 411-424页

作者： Dongkwon Han Sunil kwon Department of Energy and Mineral Resources Dong-A UniversityBusan49315Korea

This paper presents the development and application of a production data analysis software that can analyze and forecast the production performance and reservoir properties of shale gas *** theories used in the study were based on the analytical and empirical *** reliability has been confirmed through comparisons with a commercial *** transient data relating to multi-stage hydraulic fractured horizontal wells,it was confirmed that the accuracy of the modified hyperbolic method showed an error of approximately 4%compared to the actual estimated ultimate recovery(EUR).On the basis of the developed model,reliable productivity forecasts have been obtained by analyzing field production data relating to wells in *** EUR was computed as 9.6 Bcf using the modified hyperbolic *** the Pow Law Exponential method,the EUR would be 9.4 *** models developed in this study will allow in the future integration of new analytical and empirical theories in a relatively readily than commercial models.

关键词： Production data analysis shale gas multi-stage hydraulic fractured horizontal wells estimated ultimate recovery

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Vat-based photopolymerization 3D printing:From materials to topical and transdermal applications

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Asian Journal of Pharmaceutical Sciences 2024年第4期19卷 1-19页

作者： Angélica Gra Sara bom Ana M.Martins Helena M.Ribeiro Joana Marto Research Institute for Medicine(iMed.ULisboa) Faculty of PharmacyUniversidade de LisboaLisbonPortugal

Three-dimensional(3D)printing is an innovative manufacturingmethod with the potential to revolutionize topical and transdermal dosage ***,it is established that Vatbased photopolymerization(VP)3D printing technologies offer superior printing efficiency and versatility compared to other 3D printing technologies available on the ***,there are some limitations that impair their full application in pharmaceutical contexts,such as the lack of a range of biocompatiblematerials for topical and transdermal *** reviewarticle explores all types of VP-based 3D printing and discusses the relevance of implementing this kind of *** start with a detailed description of the printing process,focusing on the commercial materials available and lab-made resins proposed by different *** also review recent studies in this field,which mainly focus on the fabrication of transdermal devices based on microneedle *** the future,it is expected that the manufacturers of 3D printers invest in modifications to the printing apparatus to allow the simultaneous printing of different resins and/or compound types,which will open frontiers to the personalization of treatment approaches.

关键词： Vat-based photopolymerization 3D printing Topical delivery Transdermal delivery Resins Photoinitiators

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Towards high-performance and robust anion exchange membranes(AEMs)for water electrolysis:Super-acid-catalyzed synthesis of AEMs

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Journal of Energy Chemistry 2024年第6期93卷 478-510,I0012页

作者： Geun Woong Ryoo Sun Hwa Park Ki Chang kwon Jong Hun Kang Ho Won Jang Min Sang kwon Department of Materials Science and Engineering Research Institute of Advanced Materials(RIAM)Seoul National UniversitySeoul 08826Republic of Korea Interdisciplinary Materials Measurement Institute Korea Research Institute of Standards and Science(KRISS)Daejeon 34113Republic of Korea Department of Chemical and Biological Engineering and Institute of Chemical ProcessSeoul National UniversitySeoul 08826Republic of Korea Department of Applied Measurement Science University of Science and TechnologyDaejeon 34113Republic of Korea

The increasing demand for hydrogen energy to address environmental issues and achieve carbon neutrality has elevated interest in green hydrogen production,which does not rely on fossil *** various hydrogen production technologies,anion exchange membrane water electrolyzer(AEMWE)has emerged as a next-generation technology known for its high hydrogen production efficiency and its ability to use non-metal ***,this technology faces significant challenges,particularly in terms of the membrane durability and low ionic *** address these challenges,research efforts have focused on developing membranes with a new backbone structure and anion exchange groups to enhance durability and ionic ***,the super-acid-catalyzed condensation(SACC)synthesis method stands out due to its user convenience,the ability to create high molecular weight(MW)polymers,and the use of oxygen-tolerant organic *** the synthesis of anion exchange membranes(AEMs)using the SACC method began in 2015,and despite growing interest in this synthesis approach,there remains a scarcity of review papers focusing on AEMs synthesized using the SACC *** review covers the basics of SACC synthesis,presents various polymers synthesized using this method,and summarizes the development of these polymers,particularly their building blocks including aryl,ketone,and anion exchange *** systematically describe the effects of changes in the molecular structure of each polymer component,conducted by various research groups,on the mechanical properties,conductivity,and operational stability of the *** review will provide insights into the development of AEMs with superior performance and operational stability suitable for water electrolysis applications.

关键词： Green hydrogen production Water electrolysis Anion exchange membrane water electrolyzer(AEMWE) Anion exchange membranes(AEMs) Super-acid-catalyzed condensation(SACC)

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On the Classification of Positive Quaternionic Khler Manifolds with b_4=1

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Acta Mathematica Sinica,English Series 2010年第5期26卷 875-884页

作者： Jin Hong KIM Hee kwon LEE Department of Mathematical Sciences Korea Advanced Institute of Science and Technology Guseong-dong

Let M be a positive quaternionic Kahler manifold of dimension 4m. We already showed that if the symmetry rank is greater than or equal to [m/2] ＋ 2 and the fourth Betti number b4 is equal to one, then M is isometric to HPm. The goal of this paper is to report that we can improve the lower bound of the symmetry rank by one for higher even-dimensional positive quaternionic Kahler manifolds. Namely, it is shown in this paper that if the symmetry rank of M with b4（M） = 1 is greater than or equal to m/2 ＋ 1 for m ≥ 10, then M is isometric to HPm. One of the main strategies of this paper is to apply a more delicate argument of Frankel type to positive quaternionic Kahler manifolds with certain symmetry rank.

关键词： positive quaternionic Kahler symmetry

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Genetic algorithm tuned PI controller on PMSM simplified vector control

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Journal of Central South University 2013年第11期20卷 3042-3048页

作者： WIBOWO Wahyu Kunto JEONG Seok-kwon Mechatronics Engineering Pukyong National University Refrigeration and Air-Conditioning Engineering Pukyong National University

A simple control structure in servo system is occasionally needed for simple industrial application which precise and high control performance is not exessively important so that the cost production can be reduced efficiently. Simplified vector control, which has simple control structure, is utilized as the permanent magnet synchronous motor control algorithm and genetic algorithm is used to tune three PI controllers used in simplified vector control. The control performance is obtained from simulation and investigated to verify the feasibility of the algorithm to be applied in the real application. Simulation results show that the speed and torque responses of the system in both continuous time and discrete time can achieve good performances. Furthermore, simplified vector control combined with genetic algorithm has a similar perfofmance with conventional field oriented control algorithm and possible to be realized into the real simple application in the future.

关键词： simplified vector control conventional field oriented control permanent magnet synchronous motor genetic algorithm PI controller

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