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Synthesis and Characterization of Alkaline-Earth Metal (Ca, Sr, and Ba) Doped Nanodimensional LaMnO_(3) Rare-Earth Manganites

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Chinese Physics Letters 2013年第7期30卷 217-220页

作者： Asma Khalid saadat anwar siddiqi Affia Aslam School of Physics University of MelbourneParkville VIC 3010Australia Interdisciplinary Research Centre in Biomedical Materials COMSATS Institute of Information TechnologyDefence RoadOff Raiwind RoadLahore-54700Pakistan Department of Physics University of HailHail-30055Saudi Arabia

The substitution of divalent cations of alkaline-earth elements in nanodimensional structures of rare-earth manganites produces advanced materials with potential electrical and magnetic functionalities.A systematic investigation of La_(0.65)A_(0.35)MnO_(3)(A=Ca,Sr,Ba)materials synthesized with a modified citrate route adopting ethanol dehydration has been *** structural and morphological analyses are carried out by using x-ray diffraction and scanning electron microscopy,*** measurements are performed in variation with temperature to study the electrical transport properties which are found to vary with the size of the A-site cationic *** temperature magnetic measurements are carried out to investigate the type of magnetic phase present in *** stability of the magnetic phase and coercivity are found to be dependent on the size of nanocrystallites.

关键词： materials. earth dimensional

Structural and Magnetic Studies of Zn_(0.95)Co_(0.05)O and Zn_(0.90)Co_(0.05)Al_(0.05)O

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Chinese Physics Letters 2011年第11期28卷 178-181页

作者： Murtaza Saleem saadat A.siddiqi Shahid Atiq M.Sabieh anwar Centre of Excellence in Solid State Physics University of the PunjabQuaid-e-Azam CampusLahore-54590Pakistan Interdisciplinary Research Centre in Biomedical Materials(IRCBM) COMSATS Institute of Information TechnologyDefence RoadOff Raiwind RoadLahorePakistan School of Science and Engineering(SSE) Lahore University of Management Sciences(LUMS)Opposite Sector UD.H.A.Lahore-54792Pakistan

Single-phase Zn_(0.95)Co_(0.05)O and Zn_(0.90)Co_(0.05)Al_(0.05)O samples were prepared by a novel combustion *** diffraction studies exhibit the pure phase wurtzite structure of doped *** dispersive x-ray analysis confirms the incorporation of dopants into the host *** electron microscopy shows the ordered morphology in both of the ***-dependent resistivity analysis describes the expected semiconducting behavior that is similar to the parent ZnO ***-temperature magnetic measurements reveal the absence of ferromagnetism in Co-doped ZnO,while the Co and Al co-doped sample displays apparent room-temperature ferromagnetic *** decrease of resistivity and presence of ferromagnetic behavior in Al-doped ZnCoO system corroborate the significant role of free carriers.

关键词： resistivity ferromagnetic behavior

Effect of Temperature on Structural and Magnetic Properties of Laser Ablated Iron Oxide Deposited on Si（100）

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Chinese Physics Letters 2009年第11期26卷 211-214页

作者： Shahid M. Ramay saadat A. siddiqi M. Sabieh anwar S. C. Shin Centre for Solid State Physics University of Punjab Lahore-54590 Pakistan School of Science and Engineering Lahore University of Management Sciences (LUMS) Opposite Sector U D.H.A Lahore 54972 Pakistan Department of Physics KAIST 373-1 Guseong-dong Yuseong-gu Daejeon 305-701 Republic of Korea

We fabricate Fe3O4 thin films on Si（100） substrates at different temperatures using pulsed laser deposition, and study the effect of annealing and deposition temperature on the structural and magnetic properties of Fe3O4 thin films. Subsequently, the films are characterized by x-ray diffraction （XRD）, scanning electron microscopy （SEM） and vibrating sample magnetometery （VSM）. The XRD results of these films confirm the presence of the Fe3O4 phase and show room-temperature ferromagnetism, as observed with VSM. We demonstrate the optimized deposition and annealing conditions for an enhanced magnetization of 854 emu/cm3 that is very high when compared to the bulk sample.

关键词： Condensed matter: electrical magnetic and optical Surfaces interfaces and thin films Condensed matter: structural mechanical & thermal

Effect of Co substitution on the structural,electrical,and magnetic properties of Bi_(0.9)La_(0.1)FeO_3 by sol-gel synthesis

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International Journal of Minerals,Metallurgy and Materials 2013年第2期20卷 166-171页

作者： Ghulam Ali saadat A.siddiqi Shahid M.Ramay Shahid Atiq Murtaza Saleem Centre of Excellence in Solid State Physics University of the Punjab Interdisciplinary Research Centre in Biomedical Materials COMSATS Institute of Information Technology Chemical Engineering Department College of EngineeringKing Saud University

Cobalt （Co）-doped ***3 multiferroics were synthesized by a sol-gel method based on the auto- combustion technique. As-synthesized powder was examined using various characterization techniques to explore the effect of Co substitution on the properties of Bi0.9La0.1FeO3. X-ray diffraction reveals that Co-doped Bi0.9La0.1FeO3 preserves the perovskite-type rhombohedral structure of BiFeO3, and the composition without Co preserves the original structure of the phase; however, a second-phase Bi2Fe409 has been identified in all other compositions. Surface morphological studies were performed by scanning electron microscopy. Temperature-dependent resistivity of the samples reveals the characteristic insulating behavior of the multiferroic material. The resistivity is found to decrease with the increase both in temperature and Co content. Room temperature frequency-dependent dielectric measurements were also reported. Magnetic measurements show the enhancement in magnetization with the increase in Co content.

关键词： multiferroics cobalt doping microstructure electric properties magnetic properties sol-gel process

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Origin of Ferromagnetism in Al and Ni Co-doped ZnO Based DMS Materials

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Chinese Physics Letters 2012年第10期29卷 155-157页

作者： Murtaza Saleem saadat A.siddiqi Shahid M.Ramay Shahid Atiq Shahzad Naseem Centre for Solid State Physics University of the PunjabQuaid-e-Azam CampusLahore 54590Pakistan 2Interdisciplinary Research Centre in Biomedical MaterialsCOMSATS Institute of Information TechnologyDefence RoadOff Raiwind RoadLahorePakistan 3Department of Chemical EngineeringCollege of EngineeringKing Saud UniversityP.O.Box 800Riyadh 11421Saudi Arabia

Zn0.95Ni0.05O and Zn0.90Ni0.05Al0.05O compositions of nanocrystallites are synthesised using the well recognised auto-combustion *** x-ray diffraction patterns demonstrate the phase pure characteristic wurtzite-type crystal structure with space group P63mc in both the *** elemental incorporation of Ni and Al contents into the ZnO structure is confirmed by energy dispersive x-ray *** micrographs of scanning electron microscopy show an approximate ordered *** electrical resistivity is observed to decrease with the rising temperature,depicting the characteristic semiconductor behaviour of the *** lower values of resistivity and ferromagnetic interactions in the Al-doped sample correspond to an increase of carrier's *** is observed that the carrier mediated mechanism is mainly responsible for ferromagnetism in ZnO-based diluted magnetic semiconductors.

关键词： resistivity diluted Origin

Room Temperature Magnetic Behavior of Sol-Gel Synthesized Mn Doped ZnO

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Chinese Journal of Chemical Physics 2010年第4期23卷 469-472,I0002页

作者： Murtaza Saleem saadat A. siddiqi Shahid Atiq M. Sabieh anwar Saira Riaz 旁通普大学固态物理中心拉赫尔54590 拉赫尔管理科学大学科学与工程学院拉赫尔54792

Mn doped ZnO nano-crystallites were synthesized by state of the art sol-gel derived auto- combustion technique. As-burnt powder was investigated with different characterization techniques to explore the properties of Mn doped ZnO dilute magnetic semiconductor. X- ray diffraction measurements indicate that Mn doped ZnO retain wurtzite type hexagonal crystal structure like ZnO. Compositional and morphological studies were carried out by energy dispersive X-ray analysis and scanning electron microscopy, respectively. Temperature dependent resistivity of the sample exhibited the semiconducting behavior of the DMS material. Room temperature magnetic properties determined by vibrating sample magnetometer, revealed the presence of ferromagnetic and diamagnetic contributions in Mn doped ZnO.

关键词： Nanocrystal Diluted magnetic semiconductor Auto-combustion Room temperature ferromagnetism

Induced modifications in the properties of Sr doped BiFeO3 multiferroics

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Progress in Natural Science:Materials International 2013年第5期23卷 487-492页

作者： Tanvir Hussain saadat A.siddiqi Shahid Atiq M.S.Awan Centre of Excellence in Solid State Physics Quaid-e-Azam CampusUniversity of the Punjab Interdisciplinary Research Centre in Biomedical Materials (IRCBM) COMSATS Institute of Information Technology Department of Physics COMSATS Institute of Information Technology

Multiferroics exhibit unique combination of ferroic properties,*** instance,in BiFeO3,magnetic and electric properties *** this work,BiFeO3 and Sr-doped BiFeO3 samples with general formula,Bi1-x Srx FeO3(x=0.00,0.05,0.10,0.20,and 0.30) were synthesized by sol-gel auto-combustion technique,in order to investigate these ferroic *** samples were confrmed to have perovskite type rhombohedral structure,characteristic of BiFeO3.A dilute phase of Bi2Fe4O9was also found in all the Sr-doped *** micrographs of the palletized samples revealed that minutely doped Sr might not have any effect on the morphology of the *** dependent dielectric measurements were carried out at room temperature for all the samples from 100 Hz to 1 *** dielectric constant of un-doped sample at low frequency was 52 which decreased with increasing Sr *** enhancement of magnetic properties was observed with increasing the Sr *** BiFeO3 material was observed to have the least value of remanent *** the Sr2+ tions were doped in BiFeO3,its magnetization and remanence were increased to 0.867 emu/g and 0.175 emu/g,respectively,at x=0.30.

关键词： Bismuth ferrite Ferroelectricity Ferromagnetism Nanomaterials Magnetically ordered materials

Comparative Study on Various Strength Parameters of Structural Elements Made from Cross-Laminated Timber

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Journal of Renewable Materials 2022年第6期10卷 1575-1606页

作者： Mohammad anwar-Us-saadat Janeshka Goonewardena Bidur Kafle Mahmud Ashraf Mahbube Subhani School of Engineering Technology-Civil Melbourne PolytechnicEpping3076Australia School of Engineering Deakin UniversityWaurn Ponds3216Australia

Cross laminated timber(CLT)is an innovative and environment friendly engineered timber product with superior structural *** offers strong resistance against both in-plane and out-of-plane ***,it is widely used as floors,roofs or wall *** experimental research on CLT under various loading conditions has been done in the recent *** article presents a comprehensive review of various design methods to determine basic mechanical properties such as tension,compression and rolling shear strength of CLT with primary focus on Norway *** relevant experimental data available from existing literature were collated and consequently been used to evaluate the performance of various methods to design CLT *** comparison revealed that different methods show considerable variance in predicting the capacity of CLT panels due to the variation in timber species,which affects the corresponding mechanical properties of the *** addition to species,rolling shear properties can also vary considerably depending on the type of experimental technique used for testing.A predictive model has also been proposed to correlate rolling shear strength obtained from shear analogy method to that obtained using planar shear.

关键词： Cross-laminated timber mass timber mechanical strength rolling shear strength planar shear test short span bending test

Magnetron sputtered Dy2O3 with chromium and copper contents for antireflective thin films with enhanced absorption

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Journal of Rare Earths 2019年第9期37卷 989-994,I0004页

作者： Shahid M. Ramay Asif Mahmood Hamid M. Ghaithan Nasser S. Al-Zayed Adnan Aslam Abdullah Murtaza Nisar Ahmad saadat A. siddiqi Murtaza Saleem Physics and Astronomy Department College of ScienceKing Saud University RiyadhSaudi Arabia Chemical Engineering Department College of EngineeringKing Saud University RiyadhSaudi Arabia Department of Physics The University of Lahore1-KM Raiwind RoadLahore. Pakistan Interdisciplinary Research Centre in Biomedical Materials COMSATS Institute of Information TechnologyDefence RoadOff Raiwind RoadLahore Pukiston Department of Physics SBASSELahore University of Management Sciences (LUMS)Lahore 4792Pakisran

Dy2O3 is a rare earth oxide having a number of advanced applications in various fields including protective or antireflective coatings,Main objective of this novel research work is to check the effect of Cr and Cu addition on different properties of Dy2O3 and achievement of antireflective thin films with enhanced abso *** films of these materials we re deposited using DC magnetron with reactive *** studies reveals the crystalline nature of thin films having Dy2O3(222)reflection in all samples with Cr2O3(116)and CuO(111)reflections in Cr and Cu containing *** emission scanning electron microscopy demonstrates the homogeneous deposition of thin films with uniform shape,size and distribution of *** index,extinction coefficient and absorption coefficient significantly increase while optical reflectance decreases with Cr and Cu mediation corroborating an improved antireflective *** imaginary part of dielectric constant is found to increase slightly with low tangent loss for Cr containing composition co nsidered favorable for energy storage applications.

关键词： Thin films Dysprosium oxide X-ray diffraction FESEM Optical properties Anti-reflective

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