检索结果-南通市图书馆

Bio-Based Waterborne Poly(Vanillin-Butyl Acrylate)/MXene Coatings for Leather with Desired Warmth Retention and Antibacterial Properties

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Engineering 2024年第5期36卷 250-263页

作者： Jianzhong ma Li ma Lei Zhang Wenbo Zhang Qianqian fan Buxing Han College of Bioresources Chemical and materials Engineering Shaanxi University of Science and TechnologyXi’an 710021China Xi’an Key Laboratory of Green Chemicals and Functional materials Xi’an 710021China College of Chemistry and Chemical Engineering Shaanxi University of Science and TechnologyXi’an 710021China Shaanxi Collaborative Innovation Center of Industrial Auxiliary Chemistry and Technology Shaanxi University of Science and TechnologyXi’an 710021China Institute of Chemistry Chinese Academy of SciencesBeijing 100190China

This study presents a solvent-free,facile synthesis of a bio-based green antibacterial agent and aromatic monomer methacrylated vanillin(MV)using *** resulting MV not only imparted antibacterial properties to coatings layered on leather,but could also be employed as a green alternative to petroleum-based carcinogen styrene(St).Herein,MV was copolymerized with butyl acrylate(BA)to obtain waterborne bio-based P(MV-BA)miniemulsion via miniemulsion ***,MXene nanosheets with excellent photothermal conversion performance and antibacterial properties,were introduced into the P(MV-BA)miniemulsion by ultrasonic *** the gradual solidification of P(MV-BA)/MXene nanocomposite miniemulsion on the leather surface,MXene gradually migrated to the surface of leather coatings due to the cavitation effect of ultrasonication and amphiphilicity of MXene,which prompted its full exposure to light and bacteria,exerting the maximum photothermal conversion efficiency and significant antibacterial *** particular,when the dosage of MXene nanosheets was 1.4 wt%,the surface temperature of P(MV-BA)/MXene nanocomposite miniemulsioncoated leather(PML)increased by about 15℃ in an outdoor environment during winter,and the antibacterial rate against Escherichia coli and Staphylococcus aureus was nearly 100%under the simulated sunlight treatment for 30 ***,the introduction of MXene nanosheets increased the air permeability,water vapor permeability,and thermal stability of these *** study provides a new insight into the preparation of novel,green,and waterborne bio-based nanocomposite coatings for leather,with desired warmth retention and antibacterial *** can not only realize zerocarbon heating based on sunlight in winter,reducing the use of fossil fuels and greenhouse gas emissions,but also improve ability to fight off invasion by harmful bacteria,viruses,and other microorganisms.

关键词： MXene nanosheets Vanillin Styrene substitute Leather coating Photothermal conversion Warmth retention Antibacterial properties

Supertetragonal BaZrS_(3):A promising perovskite sulphide with giant ferroelectricity and low band gap

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Science China(Physics,Mechanics & Astronomy) 2024年第8期67卷 126-133页

作者： Menglu Li sa Zhang Chenhan Liu Xiaotao Zu Liang Qiao Haiyan Xiao School of Physics University of Electronic Science and Technology of ChinaChengdu 611731China College of mathematics and Physics Chengdu University of TechnologyChengdu 610059China Micro-and Nano-scale Thermal Measurement and Thermal management Laboratory Ministry of Education Key Laboratory of Numerical Simulation of Large-Scale Complex SystemsSchool of Energy and Mechanical EngineeringNanjing Normal UniversityNanjing 210023China

Over the past century,ferroelectricity has offered exciting opportunities for fundamental research and device ***,most of the discovered excellent ferroelectrics are oxide materials with large band gaps,limiting their potential for optoelectronics *** using first-principles calculations we identify a new narrow-gap ferroelectric beyond oxides,i.e.,ferroelectric perovskite sulphide BaZrS_(3).Under large compressive strains,BaZrS_(3)can be stabilized into a unique supertetragonal phase with an extraordinary polarization of 67.16μC/cm^(2),which is even stronger than that of conventional oxide ***,the supertetragonal BaZrS_(3)exhibits a direct narrow band gap of 1.2 eV and excellent electronic *** on the chemical bonding analysis,we attribute the formation of supertetragonal phase to charge re-ordering in which theπbond overlap along the long〈Zr-S〉bond completely vanishes and the antibonding states of theσbond appear below the Fermi *** work provides a conceptual strategy for designing new ferroelectrics for electronic and photovoltaic applications.

关键词： supertetragonal phase perovskite sulphide ferroelectricity

Supported Recyclable Metal-free Frustrated Lewis Pair Catalyst for Catalytic Hydrogenation of Substituted Pyridines to Piperidines

在线全文

学校读者我要写书评

暂无评论

Chemical Research in Chinese Universities 2024年第4期40卷 682-689页

作者： ma Shaohua TANG Zhiyong CAS Key Laboratory for Nanosystem and Hierarchical fabrication CAS Center for Excellence in NanoscienceNational Center for Nanoscience and TechnologyBeijing100190P.R.China University of Chinese Academy of Sciences Beijing100049P.R.China

The construction of heterogeneous frustrated Lewis pairs(FLPs)catalysts is crucial for realizing highly efficient and recyclable pyridines catalytic *** this work,we prepared a recyclable heterogenous FLPs catalyst CMP-BF with conjugated microporous polymer CMP-ethynyl as the support via self-catalyzed 1,1-carboboration reaction with commercial Lewis acid B(C_(6)F_(5))_(3).The as-synthesized CMP-BF demonstrates superior heterogenous catalytic hydrogenation performance(conversion>99%),and considerable stability(84%conversion after three cycles)in recyclable hydrogenation of 2,*** work provides insights into the fabrication and catalytic application of recyclable heterogenous FLP catalysts.

关键词： Pyridine hydrogenation Frustrated Lewis pair Conjugated microporous polymer

A new gravitational theory and dark matter problem

维普期刊数据库评论

在线全文

维普期刊数据库

学校读者我要写书评

暂无评论

Communications in Theoretical Physics 2024年第6期76卷 129-136页

作者： Xiong Zhao Yongge ma Department of Physics Beijing Normal UniversityBeijing 100875China

We propose a new gravitational theory with torsion based on Riemann-Cartan geometry,in which all physical quantities are *** addition to the spacetime metric,the gravitational degrees of freedom in this theory also include the torsion and two scalar *** energy-momentum tensor of the matter fields in this theory is also proposed.A spherically symmetric static vacuum solution of the theory is *** turns out that this solution can fit the observational data of the rotation curve outside the stellar disk in the Milky ***,the galactic dark matter may just be the gravitational effect of the theory with torsion.

关键词： gravity torsion dark matter

Enhancing the Electrocatalytic Oxidation of 5-Hydroxymethylfurfural Through Cascade Structure Tuning for Highly Stable Biomass Upgrading

在线全文

学校读者我要写书评

暂无评论

Nano-Micro Letters 2024年第12期 457-475页

作者： Xiaoli Jiang Xianhui ma Yuanteng Yang Yang Liu Yanxia Liu Lin Zhao Penglei Wang Yagang Zhang Yue Lin yen Wei School of materials and Energy University of Electronic Science and Technology of China Hefei National Research Center for Physical Sciences at the Microscale University of Science and Technology of China The Key Laboratory of Bioorganic Phosphorus Chemistry and Chemical Biology(Ministry of Education) Department of Chemistry Tsinghua University School of materials Science and Engineering North Minzu University

Electrocatalytic 5-hydroxymethylfurfural oxidation reaction（HMFOR） provides a promising strategy to convert biomass derivative to highvalue-added chemicals. Herein, a cascade strategy is proposed to construct Pd-Ni Co2O4electrocatalyst by Pd loading on Ni-doped Co3O4and for highly active and stable synergistic HMF oxidation. An elevated current density of 800 m A cm-2can be achieved at 1.5 V, and both faradaic efficiency and yield of 2,5-furandicarboxylic acid remained close to 100% over 10 consecutive electrolysis. Experimental and theoretical results unveil that the introduction of Pd atoms can modulate the local electronic structure of Ni/Co, which not only balances the competitive adsorption of HMF and OH- species, but also promote the active Ni3+species formation, inducing high indirect oxidation activity. We have also discovered that Ni incorporation facilitates the Co2+pre-oxidation and electrophilic OH*generation to contribute direct oxidation process. This work provides a new approach to design advanced electrocatalyst for biomass upgrading.

关键词：

In silico optimization of actuation performance in dielectric elastomercomposites via integrated finite element modeling and deep learning

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Theoretical & Applied Mechanics Letters 2024年第1期14卷 48-56页

作者： Jiaxuan ma Sheng Sun materials Genome Institute Shanghai UniversityShanghai 200444China Zhejiang Laboratory Hangzhou 311100China Shanghai Frontier Science Center of Mechanoinformatics Shanghai UniversityShanghai 200444China

Dielectric elastomers(DEs)require balanced electric actuation performance and mechanical integrity under applied *** high dielectric particles as fillers provides extensive design space to optimize concentration,morphology,and distribution for improved actuation performance and material *** study presents an integrated framework combining finite element modeling(FEM)and deep learning to optimize the microstructure of DE *** first calculates actuation performance and the effective modulus across varied filler combinations,with these data used to train a convolutional neural network(CNN).Integrating the CNN into a multi-objective genetic algorithm generates designs with enhanced actuation performance and material modulus compared to the conventional optimization approach based on FEM approach within the same *** framework harnesses artificial intelligence to navigate vast design possibilities,enabling optimized microstructures for high-performance DE composites.

关键词： Dielectric elastomer composites Multi-objective optimization Finite element modeling Convolutional neural network

Nuclear phylogenomics of angiosperms and insights into their relationships and evolution

在线全文

学校读者我要写书评

暂无评论

Journal of Integrative Plant Biology 2024年第3期66卷 546-578页

作者： Guojin Zhang Hong ma College of Life Sciences Hunan Normal UniversityChangsha 410081China Department of Biology 510 Mueller LaboratoryHuck Institutes of the Life SciencesThe Pennsylvania State UniversityUniversity ParkPA 16802USA

Angiosperms(flowering plants) are by far the most diverse land plant group with over 300,000 species. The sudden appearance of diverse angiosperms in the fossil record was referred to by Darwin as the “abominable mystery,”hence contributing to the heightened interest in angiosperm evolution. Angiosperms display wide ranges of morphological, physiological,and ecological characters, some of which have probably influenced their species richness. The evolutionary analyses of these characteristics help to address questions of angiosperm diversification and require well resolved phylogeny. Following the great successes of phylogenetic analyses using plastid sequences,dozens to thousands of nuclear genes from next-generation sequencing have been used in angiosperm phylogenomic analyses, providing well resolved phylogenies and new insights into the evolution of angiosperms. In this review we focus on recent nuclear phylogenomic analyses of large angiosperm clades, orders, families,and subdivisions of some families and provide a summarized Nuclear Phylogenetic Tree of Angiosperm families. The newly established nuclear phylogenetic relationships are highlighted and compared with previous phylogenetic results. The sequenced genomes of Amborella,Nymphaea, Chloranthus, Ceratophyllum, and species of monocots, magnoliids, and basal eudicots, have facilitated the phylogenomics of relationships among five major angiosperms clades. All but one of the 64 angiosperm orders were included in nuclear phylogenomics with well resolved relationships except the placements of several orders. Most families have been included with robust and highly supported placements, especially for relationships within several large and important orders and ***, we examine the divergence time estimation and biogeographic analyses of angiosperm on the basis of the nuclear phylogenomic frameworks and discuss the differences compared with previous analyses. Furthermore,we discuss the implicatio

关键词： angiosperms evolution flowering plants nuclear gene phylogenomics phylogeny

Catalysis by subsurface metal atoms in Al(001) through electron transfer

在线全文

学校读者我要写书评

暂无评论

National Science Review 2024年第4期11卷 12-13页

作者： Bo Sun Ding ma Beijing National Laboratory for Molecular Science New Cornerstone Science Laboratory College of Chemistry and Molecular Engineering Peking University

Heterogeneous catalysis plays a crucial role in the chemical industry, which has evolved from the investigation of chemisorption to an electronic structure[1]. Diverse strategies, such as alloying,doping, and confining, have been applied to enhance the catalytic properties of active sites through electronic modulation. The electron transfer between active sites and substrates profoundly influences catalytic activity [2].

关键词：

On the Security of Homomorphic Encryption Schemes with Restricted Decryption Oracles

在线全文

同方期刊数据库

学校读者我要写书评

暂无评论

Journal of Systems Science & Complexity 2024年第5期37卷 2240-2261页

作者： ma Guangsheng LI Hongbo School of mathematics and Physics North China Electric Power University Academy of mathematics and Systems Science Chinese Academy of Sciences University of Chinese Academy of Sciences

Fully homomorphic encryption（FHE） can be used for privacy-preserving aggregation of medical data. In this typical application, the security against passive attacks has been well studied by Li and Micciancio（2021）. In this paper, the authors further consider a “nearly passive” kind of attack, where the attacker may behave like a passive attacker in the view of the third-party *** capture the security against this hard-to-detect attack, the authors propose a new notion of IND-CPArDsecurity. The authors show that the standard LWE encryption and its related FHE schemes can not defend against IND-CPArDattack, even under a stricter rule limiting the content and number of queries made by the attacker. To make the application of FHE schemes more secure, the authors discuss some possible modifications that may serve as countermeasures to IND-CPArDattack.

关键词： Homomorphic encryption privacy secure cloud computing security