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Defects and morphology engineering for constructing V_(s)-Ni_(3)S_(2)@V_(s)-Cu_(2)S nanotube heterojunction arrays toward efficient bifunctional electrocatalyst for overall water splitting

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Journal of Energy Chemistry 2024年第7期94卷 29-40页

作者： Wenyuan sun Alan Meng Lei Wang Guicun Li Jinfeng Cui Yongkai sun zhenjiang Li College of Materials Science and Engineering Qingdao University of Science and TechnologyQingdao 266042ShandongChina Key Laboratory of Optic-electric Sensing and Analytical Chemistryfor Life Science MOE College of Chemistry and Molecular EngineeringQingdao Universityof Science and TechnologyQingdao 266042ShandongChina College of Environment and Safety Engineering Qingdao University of Science and TechnologyQingdao 266042ShandongChina Qingdao Huanghai University Qingdao 266000ShandongChina College of Electromechanical Engineering Qingdao University of Science and TechnologyQingdao 266061ShandongChina

The development of highly active,stable and inexpensive electrocatalysts for hydrogen production by defects and morphology engineering remains a great ***,S vacancies-rich Ni_(3)S_(2)@Cu_(2)S nan-otube heterojunction arrays were in-situ grown on copper foam(V_(s)-Ni_(3)S_(2)@V_(s)-Cu_(2)S NHAs/CF)for efficient electrocatalytic overall water *** the merits of nanotube arrays and efficient electronic mod-ulation drived by the OD vacancy defect and 2D heterojunction defect,the resultant V_(s)-Ni_(3)S_(2)@V_(s)-Cu_(2)S NHAs/CF electrocatalyst exhibits excellent electrocatalytic activity with a low overpotential of 47 mV for the hydrogen evolution reaction(HER)at 10 mA cm^(-2) current density,and 263 mV for the oxygen evolution reaction(OER)at 50 mA cm^(-2) current density,as well as a cell voltage of 1.48 V at 10 mA cm^(-2).Moreover,the nanotube heterojunction arrays endows V_(s)-Ni_(3)S_(2)@V_(s)-Cu_(2)S NHAs/CF with outstanding stability in long-term catalytic processes,as confirmed by the continuous chronopotentiom-etry tests at current densities of 10 mA cm^(-2) for 100 h.

关键词： Nanotubearrays Heterojunction Vacancy Bifunctional electrocatalyst Overall water splitting

MXRA7 is involved in megakaryocyte differentiation and platelet production

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Blood Science 2023年第3期5卷 160-169页

作者： zhenjiang sun Benfang Wang Ying Shen Kunpeng Ma Ting Wang Yiqiang Wang Dandan Lin Institute of Blood and Marrow Transplantation National Clinical Research Center for Hematologic DiseasesCollaborative Innovation Center of HematologyJiangsu Institute of HematologyThe First Affiliated Hospital of Soochow UniversitySuzhou Medical CollegeSoochow UniversitySuzhou 215006China Department of Clinical Laboratory The Affiliated Jiangyin Hospital of Southeast UniversityJiangyin 214400China Wisdom Lake Academy of Pharmacy Xi’an Jiaotong-Liverpool UniversitySuzhou 215123China

Matrix remodeling is a critical process in *** biology of MXRA7,as a matrix remodeling associated gene,has still not been reported in hematopoietic *** databases showed that MXRA7 expressed in hematopoietic stem cells,suggesting that it may be involved in *** found that the amounts of megakaryocytes were lower in bone marrow and spleen from Mxra7−/−mice compared with that from wild-type ***-out of MXRA7 also reduced the amount of platelet in peripheral blood and affected the function of ***-out of MXRA7 inhibited hematopoietic stem/progenitor cells differentiate to megakaryocytes possibly through down-regulating the expression of GATA-1 and ***,knockdown of MXRA7 in MEG-01 cells could inhibit the cell proliferation and cell *** of MXRA7 inhibited the differentiation of MEG-01 cells and proplatelet formation through suppressing the ERK/MAPK signaling pathway and the expression ofβ-*** conclusion,the current study demonstrated the potential significance of MXRA7 in megakaryocyte differentiation and platelet *** novel findings proposed a new target for the treatment of platelet-related diseases,and much more investigations are guaranteed to dissect the mechanisms of MXRA7 in megakaryocyte differentiation and platelet production.

关键词： differentiation megakaryocytes MXRA7 platelet

Spacecraft rendezvous trajectory safety quantitative performance index eliminating probability dilution

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Science China(Technological Sciences) 2014年第6期57卷 1219-1228页

作者： sun zhenjiang LUO YaZhong NIU ZhiYong College of Aerospace Science and Engineering National University of Defense Technology

In view of the probability dilution problem of the existing quantitative indexes of rendezvous trajectory safety performance using collision probability,this paper proposes a new quantitative index of rendezvous trajectory safety performance by well combining collision probability with warning *** proposed new index increases monotonously as the position errors of the chaser spacecraft increase,therefore it can effectively overcome the problems of the reduction in the largest performance value and the advancement in the most dangerous time induced by the probability *** proposed new index is applied to the safety design of close range rendezvous *** mission’s safety requirements for initial navigation precision and the safe region of initial and final keeping points’positions with a certain navigation precision are analyzed,and several valuable conclusions about the relation between position navigation precision and velocity navigation precision as well as the relation between keeping points’positions and navigation precision are obtained.

关键词：碰撞概率安全性能量化指标航天器交会稀释绩效指标导航精度安全设计

Stable multi-electron reaction stimulated by W doping VS_(4)for enhancing magnesium storage performance

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Journal of Energy Chemistry 2024年第2期89卷 89-98,I0004页

作者： Yuxin Tian Jiankang Chen Guofeng Wang Bing sun Alan Meng Lei Wang Guicun Li Jianfeng Huang Shiqi Ding zhenjiang Li College of Materials Science and Engineering Qingdao University of Science and TechnologyQingdao 266042ShandongChina Key Laboratory of Optic-electric Sensing and Analytical Chemistry for Life Science MOEShandong Key Laboratory of Biochemical AnalysisCollege of Chemistry and Molecular EngineeringQingdao University of Science and TechnologyQingdao 266042ShandongChina School of Material Science and Engineering International S&T Cooperation Foundation of Shaanxi ProvinceXi’an Key Laboratory of Green Manufacture of Ceramic MaterialsShaanxi University of Science and TechnologyXi’an 710021ShaanxiChina

Rechargeable magnesium batteries(RMBs)hold promise for offering higher volumetric energy density and safety features,attracting increasing research interest as the next post lithium-ion *** high performance cathode material by inducing multi-electron reaction process as well as maintaining structural stability is the key to the development and application of ***,multielectron reaction occurred in VS_(4)by simple W doping strategy.W doping induces valence of partial V as V^(2+)and V^(3+)in VS_(4)structure,and then stimulates electrochemical reaction involving multi-electrons in 0.5%*** flower-like microsphere morphology as well as rich S vacancies is also modulated by W doping to neutralize structure change in such multi-electron reaction *** fabricated 0.5%W-V-S delivers higher specific capacity(149.3 m A h g^(-1)at 50 m A g^(-1),which is 1.6 times higher than that of VS_(4)),superior rate capability(76 mA h g^(-1)at 1000 mA g^(-1)),and stable cycling performance(1500cycles with capacity retention ratio of 93.8%).Besides that,pesudocapaticance-like contribution analysis as well as galvanostatic intermittent titration technique(GITT)further confirms the enhanced Mg^(2+)storage kinetics during such multi-electron involved electrochemical reaction *** discovery provides new insights into the designing of multi-electron reaction process in cathode as well as neutralizing structural change during such reaction for realizing superior electrochemical performance in energy storage devices.

关键词： Multi-electron reaction W doping Stable structure Cathode Rechargeable magnesium batteries

Establishment of an indirect immunofluorescence assay for the detection of African swine fever virus antibodies

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Journal of Integrative Agriculture 2024年第1期23卷 228-238页

作者： Wan Wang zhenjiang Zhang Weldu Tesfagaber Jiwen Zhang Fang Li Encheng sun Lijie Tang Zhigao Bu Yuanmao Zhu Dongming Zhao State Key Laboratory for Animal Disease Control and Prevention National African Swine Fever Para-reference LaboratoryNational High Containment Facilities for Animal Diseases Control and PreventionHarbin Veterinary Research InstituteChinese Academy of Agricultural SciencesHarbin 150069China College of Veterinary Medicine Northeast Agricultural UniversityHarbin 150069China

African swine fever(ASF)continues to cause enormous economic loss to the global pig *** there is no safe and effective vaccine,accurate and timely diagnosis of ASF is essential to implement control *** immunofluorescence assay(IFA)is a gold standard serological method recommended by the World Organization for Animal Health(WOAH).In this study,we used primary fetal kidney cells to establish a wild boar cell line(BK2258)that supported the efficient replication of ASF virus(ASFV)SD/DY-I/21 and showed visible cytopathic effect(CPE).Moreover,using BK2258,we established a sensitive and specific IFA for ASFV antibody *** standardize and evaluate the performance of this assay,we used serum samples from pigs infected with the low virulent genotype I SD/DY-I/21 and genotype II HLJ/HRB1/20,and immunized with the vaccine candidate HLJ/18-7GD,field samples,and negative serum *** IFA reacted with the ASFV-positive sera and displayed bright fluorescence *** was no non-specific green fluorescence due to cellular senescence or other cell damage-causing *** to a commercial indirect enzyme-linked immunosorbent assay(iELISA),ASFV antibodies were detected 1–4 days earlier using our *** detection limits of the IFA and iELISA for the same ASFV-antibody positive serum samples were 1:25,600 and 1:6,400,respectively,indicating that the IFA is more sensitive than *** newly established IFA was highly specific and did not cross-react with sera positive for six other important porcine pathogens(i.e.,Classical swine fever virus(CSFV),Porcine reproductive and respiratory syndrome virus(PRRSV),Porcme circovirus type 2(PCV2),Pseudorabies virus(PRV),Foot-and-Mouth disease virus type O(FMDV/O),and Porcine epidemic diarrhea virus(PEDV)).This study thus provides a sensitive,specific,and reliable detection method that is suitable for the serological diagnosis of ASF.

关键词： African swine fever antibody IFA serological method

Zwitterionic ring-opening polymerization of macrocyclic ethyleneoxy-substituted carbonate:Access to cyclic PEG-like polycarbonate

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Chinese Chemical Letters 2024年第3期35卷 282-286页

作者： Jin Huang Jinwen Li Rui Yan Yuanyuan Qu Fengzhen Guo Lei Shen Can-liang Ma Jie sun zhenjiang Li Kai Guo State Key Laboratory of Materials-Oriented Chemical Engineering College of Biotechnology and Pharmaceutical EngineeringNanjing Tech UniversityNanjing 211816China Institute of Nanjing Advanced Biomaterials&Processing Equipment Lishui Economic Development ZoneNanjing 211299China

The innovation in polymer design to rival conventional polyethylene glycol(PEG)is an important approach to achieving a more sustainable ***,cyclic PEG-like polycarbonates having high molecular weight(4.4–49.5 kg/mol)were enabled through zwitterionic ring-opening polymerization(ZROP)of macrocyclic carbonates(MCs)mediated by N-heterocyclic carbene(NHC).The thermodynamic behavior of polymerization depends on the ring size of *** this process,the ZROP of 11-membered MC was driven by the change of enthalpy(ΔH_(p))which differed from the ZROP of 14-membered MC driven by the entropic change(ΔS_(p)).Cyclic polycarbonates depicted improved thermostability(T_(d5%)≥204℃)and higher glass transition temperatures(T_(g)>–40℃)in comparison to their linear analogues(T_(d5%)≤185℃,T_(g)~–50℃).In addition,the mechanism of ZROP of MC was addressed through computational study.A distinct mechanism of polymerization distinguishable from the well-known NHC-mediated ZROP of cyclic esters was revealed,where the zwitterion from nucleophilic addition to MC,*** intermediate,cannot be ring-opened probably due to the delocalization of negative charge on the carbonate group,but serves as an active center for the *** comparison to PEG,the attained polymer demonstrated comparable hydrophilic and biocompatible properties,as revealed by the results of contact angle and in vitro cytotoxicity studies,suggesting that cyclic polycarbonate hold the promise as the alternative of PEG.

关键词： Zwitterionic ring-opening polymerization Cyclic polycarbonate Macrocycles Tetrahedral intermediate NHC carbene

Correction:Incorporating mesopelagic fish into the evaluation of marine protected areas under climate change scenarios

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Marine Life Science & Technology 2024年第2期6卷 363-364页

作者： Shuhao Liu Yang Liu Katharina Teschke Mark A.Hindell Rachel Downey Briannyn Woods Bin Kang Shuyang Ma Chi Zhang Jianchao Li zhenjiang Ye Peng sun Jianfeng He Yongjun Tian Research Centre for Deep Sea and Polar Fisheries and Key Laboratory of MaricultureMinistry of EducationOcean University of ChinaQingdao 266003China Frontiers Science Center for Deep Ocean Multispheres and Earth System Ocean University of ChinaQingdao 266100China Alfred Wegener Institute Helmholtz Centre for Polar and Marine ResearchAm Handelshafen 1227570 BremerhavenGermany Helmholtz Institute for Functional Marine Biodiversity at the University Oldenburg Ammerländer Heerstraße 23123129 OldenburgGermany Institute for Marine and Antarctic Studies University of TasmaniaHobart 7004Australia Fenner School of Environment and Society Australian National UniversityCanberraACT 2602Australia College of Fisheries Ocean University of ChinaQingdao 266003China Polar Research Institute of China Shanghai 200136China

The author wants to highlight the important role of mes-opelagic fish in the conservation of marine living ***,in order to further clarify and focus research point on the conservation of marine living resources,the authors replaced the MPA with the protected areas,and slightly modified several other vague *** these corrections,most of them are the replacement of the terms.

关键词： protected correction fish

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基于机器视觉的芯片检测系统的设计与实现

信息与电脑 2023年第11期35卷 15-19页

作者：孙镇江青岛职业技术学院信息学院山东青岛266555

为提高芯片检测的可靠性、实时性、检测效率,设计一个基于计算机视觉的芯片检测系统。首先,利用YOLOv5训练芯片识别模型,结合工业级相机实时采集芯片图像;其次,将芯片图像数据发送到检测服务器设备,判断芯片实物是否存在刮痕缺陷和引脚... 详细信息

为提高芯片检测的可靠性、实时性、检测效率,设计一个基于计算机视觉的芯片检测系统。首先,利用YOLOv5训练芯片识别模型,结合工业级相机实时采集芯片图像;其次,将芯片图像数据发送到检测服务器设备,判断芯片实物是否存在刮痕缺陷和引脚缺失的问题;最后,根据检测结果利用机械臂将芯片放置到不同的分区,实现检测与分拣的功能。测试结果表明,该系统的准确率高较高,能够满足工业生产的要求。

关键词：机器视觉芯片刮痕缺陷引脚缺失

Incorporating mesopelagic fish into the evaluation of conservation areas for marine living resources under climate change scenarios

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Marine Life Science & Technology 2024年第1期6卷 68-83页

作者： Shuhao Liu Yang Liu Katharina Teschke Mark AHindell Rachel Downey Briannyn Woods Bin Kang Shuyang Ma Chi Zhang Jianchao Li zhenjiang Ye Peng sun Jianfeng He Yongjun Tian Research Centre for Deep Sea and Polar Fisheries and Key Laboratory of MaricultureMinistry of EducationOcean University of ChinaQingdao 266003China Frontiers Science Center for Deep Ocean Multispheres and Earth System Ocean University of ChinaQingdao 266100China Alfred Wegener Institute Helmholtz Centre for Polar and Marine ResearchAm Handelshafen 1227570 BremerhavenGermany Helmholtz Institute for Functional Marine Biodiversity at the University Oldenburg Ammerländer Heerstraße 23123129 OldenburgGermany Institute for Marine and Antarctic Studies University of TasmaniaHobart 7004Australia Fenner School of Environment and Society Australian National UniversityCanberraACT 2602Australia College of Fisheries Ocean University of ChinaQingdao 266003China Polar Research Institute of China Shanghai 200136China

Mesopelagic fish(meso-fish)are central species within the Southern Ocean(SO).However,their ecosystem role and adaptive capacity to climate change are rarely integrated into protected areas *** is a pity given their importance as crucial prey and predators in food webs,coupled with the impacts of climate ***,we estimate the habitat distribution of nine meso-fish using an ensemble model approach(MAXENT,random forest,and boosted regression tree).Four climate model simulations were used to project their distribution under two representative concentration pathways(RCP4.5 and RCP8.5)for short-term(2006–2055)and long-term(2050–2099)*** addition,we assess the ecological representativeness of protected areas under climate change scenarios using meso-fish as indicator *** models show that all species shift poleward in the ***(family Myctophidae)are predicted to migrate poleward more than other families(Paralepididae,Nototheniidae,Bathylagidae,and Gonostomatidae).In comparison,lanternfishes were projected to increase habitat area in the eastern SO but lose area in the western SO;the opposite was projected for species in other *** areas(IAs)of meso-fish are mainly distributed near the Antarctic Peninsula and East *** protected area cover 23% of IAs at present and 38%of IAs in the future(RCP8.5,long-term future).Many IAs of meso-fish still need to be included in protected areas,such as the Prydz Bay and the seas around the Antarctic *** results provide a framework for evaluating protected areas incorporating climate change adaptation strategies for protected areas management.

关键词： Myctophids Mesopelagic fish Species distribution model Southern Ocean Antarctic Peninsula