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Energy & Environmental Materials 2024年第1期7卷 68-76页

作者： Yusi Lei Liang Yue Yuruo Qi Yubin Niu Shujuan Bao jie song Maowen Xu Faculty of Materials and Energy Institute for Clean Energy&Advanced MaterialsSouthwest UniversityChongqing 400715China Shandong Zero-One-Four Advanced Materials Co. Ltd.Feicheng 271099China

Sodium dentrite formed by uneven plating/stripping can reduce the utilization of active sodium with poor cyclic stability and,more importantly,cause internal short circuit and lead to thermal runaway and ***,sodium dendrites and their related problems seriously hinder the practical application of sodium metal batteries(SMBs).Herein,a design concept for the incorporation of metal-organic framework(MOF)in polymer matrix(polyvinylidene fluoride-hexafluoropropylene)is practiced to prepare a novel gel polymer electrolyte(PH@MOF polymer-based electrolyte[GPE])and thus to achieve high-performance *** addition of the MOF particles can not only reduce the movement hindrance of polymer chains to promote the transfer of Na^(+)but also anchor anions by virtue of their negative charge to reduce polarization during electrochemical reaction.A stable cycling performance with tiny overpotential for over 800 h at a current density of 5 mA cm^(-2)with areal capacity of 5 mA h cm^(-2)is achieved by symmetric cells based on the resulted GPE while the Na_(3)V_(2)O_(2)(PO_(4))_(2)F@rGO(NVOPF)|PH@MOF|Nacell also displays impressive specific cycling capacity(113.3 mA h g^(-1)at 1 C)and rate capability with considerable capacity retention.

关键词： dendrite-free gel polymer electrolyte metal organic framework sodium batteries

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Identification of FIR systems under difference-driven scheduled quantized observations

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Control Theory and Technology 2024年第2期22卷 163-172页

作者： Dong Liang Ruizhe Jia Fengwei jing Yong song jin Guo School of Automation and Electrical Engineering University of Science and Technology BeijingBeijing100083China Key Laboratory of Knowledge Automation for Industrial Processes Ministry of EducationBeijing100083China National Engineering Research Center for Advanced Rolling and Intelligent Manufacturing University of Science and Technology BeijingBeijing100083China

In networked system identification,how to effectively use communication resources and improve convergence speed is the focus of ***,there is an inherent contradiction between the two *** this paper,the event-driven communication is used to save communication resources for the identification of finite impulse response systems,and the input design is carried out to meet the requirements of convergence ***,a difference-driven communication is ***,the performance of the communication mechanism is analyzed,and the calculation method of its communication rate is *** that,according to the communication rate and the convergence rate of the identification algorithm,the input design problem is transformed into a constrained optimization problem,and the algorithm for finding the optimal solution is *** addition,considering the case that the output is quantized by multiple thresholds,the way to calculate its communication rate is given and the influence of threshold number on communication rate is ***,the effectiveness of the algorithm is verified by simulation.

关键词： System identification FIR system Difference-driven Quantized observation

Buried interface management via bifunctional NH_(4)BF_(4)towards efficient CsPbI_(2)Br solar cells with a V_(oc)over 1.4 V

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Journal of Energy Chemistry 2024年第2期89卷 364-370,I0009页

作者： Fazheng Qiu Ming-Hua Li jinpeng Wu jin-song Hu School of Materials Science and Engineering NingboTech UniversityNingbo 315100ZhejiangChina Beijing National Laboratory for Molecular Sciences(BNLMS) Institute of ChemistryChinese Academy of SciencesBeijing 100190China College of Chemical Engineering Beijing Advanced Innovation Center for Soft Matter Science and EngineeringBeijing University of Chemical TechnologyBeijing 100029China School of Chemical Sciences University of Chinese Academy of SciencesBeijing 100049China

CsPbI_(2)Br perovskite solar cells(PSCs)have drawn tremendous attention due to their suitable bandgap,excellent photothermal stability,and great potential as an ideal candidate for top cells in tandem solar ***,the abundant defects at the buried interface and perovskite layer induce severe charge recombination,resulting in the open-circuit voltage(V_(oc))output and stability much lower than ***,a novel buried interface management strategy is developed to regulate interfacial carrier dynamics and CsPbI_(2)Br defects by introducing ammonium tetrafluoroborate(NH_(4)BF_(4)),thereby resulting in both high CsPbI_(2)Br crystallization and minimized interfacial energy ***,NH_(4)^(+)ions could preferentially heal hydroxyl groups on the SnO_(2)surface and balance energy level alignment between SnO_(2)and CsPbI_(2)Br,enhancing charge transport efficiency,while BF_(4)^(-)anions as a quasi-halogen regulate crystal growth of CsPbI_(2)Br,thus reducing perovskite ***,it is proved that eliminating hydroxyl groups at the buried interface enhances the iodide migration activation energy of CsPbI_(2)Br for strengthening the phase *** a result,the optimized CsPbI_(2)Br PSCs realize a remarkable efficiency of 17.09%and an ultrahigh V_(oc)output of 1.43 V,which is one of the highest values for CsPbI_(2)Br PSCs.

关键词： Inorganic perovskite Buried interface Defect Stability Open-circuit voltage loss

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Optimized nitrogen application for maximizing yield and minimizing nitrogen loss in film mulching spring maize production on the Loess Plateau,China

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Journal of Integrative Agriculture 2024年第5期23卷 1671-1684页

作者： Qilong song jie Zhang Fangfang Zhang Yufang Shen Shanchao Yue Shiqing Li State Key Laboratory of Soil Erosion and Dryland Farming on the Loess Plateau College of Natural Resources and EnvironmentNorthwestA&FUniversityYangling712100China Life Science Department Luoyang Normal UniversityLuoyang 471934China

Excessive use of N fertilizers(driven by high-yield goals)and its consequent environmental problems are becoming increasingly acute in agricultural systems.A 2-year field experiment was conducted to investigate the effects of three N application methods(application of solid granular urea once(OF)or twice(TF),application of solid granular urea mixed with controlled-release urea once(MF),and six N rates(0,60,120,180,240,and 300 kg N ha^(-1))on maize yield,economic benefits,N use efficiency,and soil N balance in the maize(Zea mays L.)film mulching system on the Loess Plateau,*** grain yield and economic return of maize were significantly affected by the N rate and application *** with the OF treatment,the MF treatment not only increased the maize yield(increased by 9.0-16.7%)but also improved the economic return(increased by 10.9-25.8%).The agronomic N use efficiency(NAE),N partial factor productivity(NPFP)and recovery N efficiency(NRE)were significantly improved by 19.3-66.7,9.0-16.7 and 40.2-71.5%,respectively,compared with the OF *** economic optimal N rate(EONR)of the OF,TF,and MF was 145.6,147.2,and 144.9 kg ha^(-1) in 2019,and 206.4,186.4,and 146.0 kg ha^(-1) in 2020,*** apparent soil N loss at EONR of the OF,TF,and MF were 97.1-100.5,78.5-79.3,and 50.5-68.1 kg ha^(-1),*** results support MF as a one-time N application method for delivering high yields and economic benefits,with low N input requirements within film mulching spring maize system on the Loess Plateau.

关键词： maize yield N management economic optimal N rate Loess Plateau

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Concomitant treatment of ureteral calculi and ipsilateral pelvic sciatic nerve schwannoma with transperitoneal laparoscopic approach: A case report

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World Journal of Clinical Cases 2024年第11期12卷 1947-1953页

作者： Yang Xiong jin Li Han-jie Yang Department of Urology Pingxiang People’s HospitalPingxiang 337000Jiangxi ProvinceChina

BACKGROUND Schwannomas are rare peripheral neural myelin sheath tumors that originate from Schwann *** the different types of schwannomas,pelvic sciatic nerve schwannoma is extremely *** preoperative diagnosis of pelvic schwannomas is difficult,and surgical resection is the gold standard for its definite diagnosis and *** SUMMARY We present a case of pelvic schwannoma arising from the sciatic nerve that was detected in a 40-year-old man who underwent computed tomography for intermittent right lower back pain caused exclusively by a right ureteral ***,successful transperitoneal laparoscopic surgery was performed for the intact removal of the stone and en bloc resection of the *** total operative time was 125 min,and the estimated blood loss was *** surgical procedure was *** patient was discharged on postoperative day 5 with the simultaneous removal of the urinary ***,the patient presented with motor and sensory disorders of the right lower limb,caused by partial damage to the right sciatic *** tumor recurrence was observed at the postoperative *** Histopathological examination of the specimen confirmed the diagnosis of a ***,laparoscopic surgery is safe and feasible for concomitant extirpation of pelvic schwannomas and other pelvic and abdominal diseases that require surgical treatment.

关键词： Schwannoma Sciatic nerve Laparoscopy Ureteral calculi Pelvic neoplasms Case report

Precise immobilization of metal single atoms into a porphyrinic metal-organic framework for an efficient alkene hydrosilylation

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Nano Research 2024年第7期17卷 5914-5921页

作者： Chun-Ying Chen Qi-jie Mo Fu-Zhen Li Hai-Li song Li Zhang MOE Laboratory of Bioinorganic and Synthetic Chemistry Lehn Institute of Functional MaterialsSchool of ChemistrySun Yat-Sen UniversityGuangzhou 510006China

Alkene hydrosilylation is one of the most concise and atom-economical methods to synthesize organosilicon ***,we reported the precise immobilization of metal single atoms(M-SAs;M=Ru,Rh,Ir,Pd,Pt,and Au)into a porphyrinic metalorganic framework(MOF)of PCN-222(PCN=porous coordination network),and then applied the resultant MOF composites of M-SAs@PCN-222 to alkene *** solvent-free conditions,Pt-SAs@PCN-222 displayed an especially high catalytic efficiency with the turnover frequency up to 119 s−1 and the maximum turnover number of 906,250 at room *** and theoretical studies revealed that there existed strong interactions between Pt-SAs@PCN-222 and the substrates,which helped to condense the substrates in the cavities of the porous *** density functional theory calculations and molecular dynamics simulations disclosed that PCN-222 could transfer electrons to Pt-SAs to enhance the silane oxidative addition and drive the reaction to proceed smoothly via Chalk–Harrod pathway.

关键词： alkene hydrosilylation single atom catalysts metal-organic frameworks precision chemistry synergistic catalysis

Unsaturated bi-heterometal clusters in metal-vacancy sites of 2D MoS2 for efficient hydrogen evolution

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Carbon Energy 2024年第3期6卷 264-275页

作者： Gonglei Shao jie Xu Shasha Gao Zhang Zhang song Liu Xu Zhang Zhen Zhou Interdisciplinary Research Center for Sustainable Energy Science and Engineering(IRC4SE2) School of Chemical EngineeringZhengzhou UniversityZhengzhouHenanChina College of Chemistry and Materials Engineering Wenzhou UniversityWenzhouZhejiangChina Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education) College of ChemistryNankai UniversityTianjinChina State Key Laboratory of Chemo/Biosensing and Chemometrics Institute of Chemical Biology and Nanomedicine(ICBN)College of Chemistry and Chemical EngineeringHunan UniversityChangshaHunanChina Institute of New Energy Material Chemistry School of Materials Science and EngineeringNankai UniversityTianjinChina

The valence states and coordination structures of doped heterometal atoms in two-dimensional(2D)nanomaterials lack predictable regulation ***,a robust method is proposed to form unsaturated heteroatom clusters via the metal-vacancy restraint mechanism,which can precisely regulate the bonding and valence state of heterometal atoms doped in 2D molybdenum *** unsaturated valence state of heterometal Pt and Ru cluster atoms form a spatial coordination structure with Pt–S and Ru–O–S as catalytically active *** them,the strong binding energy of negatively charged suspended S and O sites for H+,as well as the weak adsorption of positively charged unsaturated heterometal atoms for H*,reduces the energy barrier of the hydrogen evolution reaction proved by theoretical ***,the electrocatalytic hydrogen evolution performance is markedly improved by the ensemble effect of unsaturated heterometal atoms and highlighted with an overpotential of 84 mV and Tafel slope of 68.5 mV dec^(−1).In brief,this metal vacancy-induced valence state regulation of heterometal can manipulate the coordination structure and catalytic activity of heterometal atoms doped in the 2D atomic lattice but not limited to 2D nanomaterials.

关键词： clusters hydrogen evolution reaction metal vacancy MoS2 unsaturated heterometal

Li-ion Battery Failure Warning Methods for Energy-storage Systems

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Chinese Journal of Electrical Engineering 2024年第1期10卷 86-100页

作者： Peihao Wu Nawei Lyu Yuhang song Xin Jiang Yang jin School of Electrical and Information Engineering Zhengzhou UniversityZhengzhou 450001China

Energy-storage technologies based on lithium-ion batteries are advancing ***,the occurrence of thermal runaway in batteries under extreme operating conditions poses serious safety concerns and potentially leads to severe *** address the detection and early warning of battery thermal runaway faults,this study conducted a comprehensive review of recent advances in lithium battery fault monitoring and early warning in energy-storage systems from various physical *** focus was electrical,thermal,acoustic,and mechanical aspects,which provide effective insights for energy-storage system safety enhancement.

关键词： Lithium-ion batteries energy-storage systems thermal runaway characteristic signals fault warning

Surface plasmon-coupled radiative heat transfer between graphene-covered magnetic Weyl semimetals

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Science China Technological Sciences 2024年第11期67卷 3405-3412页

作者： song jinLin YAO Xinjie jin Lin CHEN Lei ZHAO HaiLong CHENG Qiang School of Electrical and Information Engineering Wuhan Institute of Technology State Key Laboratory of Coal Combustion School of Energy and Power EngineeringHuazhong University of Science and Technology

Weyl semimetals(WSMs) have recently attracted considerable research attention because of their remarkable optical and electrical properties. In this study, we investigate the near-field radiative heat transfer(NFRHT) between graphene-covered Weyl slabs, particularly focusing on the supported coupled surface plasmon polaritons(SPPs). Unlike bare Weyl slabs where the epsilon-near-zero(ENZ) effect contributes the most to the NFRHT, adding a monolayer graphene sheet yields coupled SPPs, i.e.,the coupling of graphene SPPs(GSPPs) and Weyl SPPs(WSPPs), which dominates the NFRHT. The graphene sheet greatly suppresses the ENZ effect by compressing the parallel wavevector, thereby enabling the heat transfer coefficient(HTC) to be significantly changed. Further, for the graphene-covered magnetic Weyl slab configuration, an increase in the number of Weyl nodes suppresses the SPP coupling and ENZ effect, thereby weakening the NFRHT with a regulation ratio of 4.4 whereas an increase in the Fermi level slightly influences the NFRHT. Several typical heterostructures are also proposed for comparison, and results show that a mono-cell structure has the largest total HTC. Our findings will facilitate the understanding of surface plasmon-coupled radiative heat transfer and enable opportunities in energy harvesting and thermal management at the nanoscale based on WSM-based systems.

关键词： near-field radiative heat transfer Weyl semimetal surface plasmon polariton epsilon-near-zero graphene

Enantioselective Construction of Polycyclic Chromanes through Organocatalytic Sequential Quintuple Reaction via One-Pot Step-Wise Procedure

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Chinese Journal of Chemistry 2024年第18期42卷 2197-2202页

作者： jie Wang Hang Qin Ya-Li song Fei Cao Zhi-Hao You Key Laboratory of Pharmaceutical Quality Controlof Hebei Province College of Pharmaceutical SciencesHebei UniversityBaodingHebei 071002China Key Laboratory of Medicinal Chemistry and Molecular Diagnosis of the Ministry of Education BaodingHebei 071002China

An efficient and highly stereoselective synthetic method to access polycyclic chromanes has been achieved through organocatalyzed one-pot step-wise reactions involving 2-hydroxycinnamaldehydes,2-aminochalcones,and malononitrile as *** reactions underwent a quintuple process by aza-Michael/Michael/Knoevenagel/oxa-Michael/aldol-type reaction in sequence to give products bearing 3 new generated rings and 5 chiral centers in moderate to quantitative yields with excellent stereoselectivities.

关键词： Asymmetric catalysis Organocatalysis Cyclization Quintuple reaction Polycycles Heterocycles Chromane One-pot reaction