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chinese Science Bulletin 2006年第14期51卷 1736-1740页

作者： song zhiguang1,2.& wang cuiping1,3.. state key laboratory of organic geochemistry,{3.. chinese academy of sciences, guangzhou 51064., china 2. guangzhou Research Center of Gas Hydrate, chinese academy of sciences, guangzhou 51064., china 3..Graduate School of chinese academy of sciences, Beijing 10003.. china state key laboratory of organic geochemistry Guangzhou Institute of Geochemistry Chinese Academy of Sciences Guangzhou 510640 China guangzhou Research Center of Gas Hydrate Chinese Academy of Sciences Guangzhou 510640 China Graduate School of chinese academy of sciences Beijing 100039 China

A group of 2,6,10,15,19-pentamethyli- cosenes (PMIΔ) containing 1―5 unsaturated double bonds has been identified in the sea floor sediments from the Gulf of Mexico at the Green Canyon 23..*** PMIΔ compounds are distributed between nC22 and nC24 on the mass chromatogram of aliphatic fraction. Their δ 13..values are very much depleted in 13..and in the range of ?86.7‰ to ?115.5‰, whereas the δ 13..values of companion n-alkanes range from ?28.4‰ to ?3..6‰. These unsaturated PMIΔ com-pounds are typical biomarkers derived from the an-aerobic oxidation of methane mediated by meth-ane-oxidizing archaeal bacteria and indicative of the gas seeps or even the occurrence of gas hydrates in the deep sea sediments.

关键词：生物标志墨西哥湾沉积物 PMIA 天然气水化物

SYNTHESIS AND CHARACTERIZATION OF NOVEL BIPOLAR PPV-BASED COPOLYMER CONTAINING TRIAZOLE AND CARBAZOLE UNITS

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chinese Journal of Polymer Science 2001年第6期19卷 615-621页

作者： Ze Liu Li-xiang wang Xia-bin Jing Fo-song wang The {3..key laboratory of Polymer Physics and Chemistry Changchun institute of Applied Chemistry chinese academy of sciences, Changchun 13..22, china chinese Acad Sci Changchun Inst Appl Chem State Key Lab Polymer Phys & Chem Changchun 130022 Peoples R China

Two new blue light-emitting PPV-based conjugated copolymers containing both an electron-withdrawing unit (triazole-TAZ) and electron-rich moieties (carbazole-CAR and bicarbazole-BCAR) were prepared by Wittig condensation polymerization between the triazole diphosphonium salt and the corresponding dialdehyde monomers. Their structures and properties were characterized by FT-IR, TGA, DSC, UV-Vis, PL spectroscopy and electrochemical measurements. The resulting copolymers are soluble in common organic solvents and thermally stable with a T-g of 147degreesC for TAZ-CAR-PPV and of 157degreesC for TAZ-BCAR-PPV. The maximum photoluminescence wavelengths of TAZ-CAR-PPV and TAZ-BCAR-PPV film appear at 460 nm and 480 nm, respectively. Cyclic voltammetry measurement demonstrates that TAZ-BCAR-PPV has good electrochemical reversibility, while TAZ-CAR-PPV exhibits the irreversible redox process. The triazole unit was found to be an effective pi-conjugation interrupter and can play the rigid spacer role in determining the emission colour of the resulting copolymer.

关键词： light-emitting polymer PPV-based bipolar polymer triazole-containing polymer carbazole-containing polymer

The distribution of phenylalkanes in the modern sediment associated with gas hydrate from the Gulf of Mexico

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Acta Oceanologica Sinica 2008年第6期27卷 71-82页

作者： wang cuiping SUN Hongwen song {3..ZHANG Tao College of Environmental Science and Engineering Nankai University Tianjin 300071 China state key laboratory of organic geochemistry Guangzhou Institute of Geochemistry Chinese Academy of Sciences Guangzhou 510640 China

Phenylalkanes with carbon numbers between 16 and 19, characterized by the main carbon-18, have been identified in the modern sediments collected from gas hydrate area from the Gulf of Mexico. The structure of phenylalkanes with four isomers for every carbon number was determined by means of their mass spectra and previous studies. The distribution of the series characterized by a low molecular mass was similar to the distribution of n-alkane, alkylcyclohexanes and alkylbenzenes in each sample. There were differences in the distribution of the phenylalkane series between the S - 1, S - 4, S - 7, S - 9 samples and the S - 8, S - 10 and S - 11 samples. The phenylalkanes might be derived from Archaea associated with anaerobic oxidation of methane （AOM） processes in S - 1, S -4, S -7 and S -9 samples according to their distribution resembled with the distribution of the extract from a type of Archaea. The distribution of alkylcyclohexanes and alkylbenzenes in S - 1, S - 4, S - 7 and S - 9 sample was found to be similar to each other. The odd-over-even predominance of alkylcyclohexanes was seen as the input of some bac- terial.

关键词： phenylalkane gas hydrate Gulf of Mexico

珠三角城乡大气有机气溶胶来源、生成机制及吸入沉积通量

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环境科学学报 2024年第1期44卷 15-28页

作者：伍莉娜黄山刘袁宋奇聪胡伟伟陈卫旷烨王小月李伟彭钰雯陈多宏岳玎利宋伟袁斌王新明邵敏暨南大学环境与气候研究院广州511443 粤港澳环境质量协同创新联合实验室广州511443 中国科学院广州地球化学研究所有机地球化学国家重点实验室广州510640 广东省生态环境监测中心国家环境保护区域空气质量部检测重点实验室广州510308

为探究珠三角地区秋季亚微米有机气溶胶(OA)的污染特征、健康风险及其城乡差异,本研究对基于黑碳高分辨率飞行时间气溶胶质谱仪(SP-AMS)观测的广州(城市)及鹤山(乡村)气溶胶数据进行了分析.结果显示,在城乡的两次秋季观测期间,PM,平均... 详细信息

为探究珠三角地区秋季亚微米有机气溶胶(OA)的污染特征、健康风险及其城乡差异,本研究对基于黑碳高分辨率飞行时间气溶胶质谱仪(SP-AMS)观测的广州(城市)及鹤山(乡村)气溶胶数据进行了分析.结果显示,在城乡的两次秋季观测期间,PM,平均质量浓度分别为(29.87±20.11)μg·m^(-3..(40.08±16.05)μg·m^(-3..其中OA占比最高,分别为57.4%和52.1%.基于正交矩阵因子分析法(PMF)进行来源解析,发现在珠三角城乡两地二次有机气溶胶都是OA的首要组分,分别占64.0%和66.7%.城市地区OA受日间光氧化反应贡献明显,而乡村地区OA在夜间至清晨出现显著抬升,可能与夜间二次生成相关.相对湿度(RH)升高指示的液相反应及日间光氧化对城市低氧化态OA生成均有促进作用,光氧化也能促进乡村低氧化态OA的日间生成,而夜间SOA(Night-OA)则主要在高RH的条件下贡献更为显著.基于模型计算了亚微米级OA在人体呼吸系统中的分粒径沉积通量,发现其在肺泡区域沉积通量最大,两地沉积通量的粒径分布呈现双峰分布,但城区OA在小粒径(120 nm)的沉积峰值更加突出,因此可能具有更大的健康风险.

关键词：有机气溶胶(OA) 来源解析污染特征沉积通量黑碳气溶胶质谱仪珠三角地区

Visible-light driven room-temperature coupling of methane to ethane by atomically dispersed Au on WO_(3)

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Journal of Energy Chemistry 2021年第10期30卷 195-202,I0006页

作者： Xing Yang Wu Zhiyuan Tang Xiaoxu Zhao Xin Luo Stephen John Pennycook song Ling wang china-UK Low Carbon College Shanghai Jiao Tong UniversityShanghai 201306China School of Environmental Science and Engineering Shanghai Jiao Tong UniversityShanghai 200240China state key laboratory of Optoelectronic Materials and Technologies Centre for Physical Mechanics and BiophysicsSchool of PhysicsSun Yat-sen UniversityGuangzhou 510275GuangdongChina institute Department of Materials Science and Engineering National University of SingaporeSingapore 117575Singapore Shanghai institute of Pollution Control and Ecological Security Shanghai 200092China

Gold(Au)as co-catalyst is remarkable for activating methane(CH4),especially atomically dispersed Au with maximized exposing active sites and specific electronic ***,singlet oxygen(^(1)O_(2))typically manifests a mild redox capacity with a high selectivity to attack organic ***(PMS)favors to produce oxidative species 102 during the photocatalytic ***,combining atomic Au as co-catalyst and ^(1)O_(2) as oxidant is an effective strategy to selectively convert ***,we synthesized atomically dispersed Au on WO_(3..Au/WO_(3..,where Au was in the forms of single atoms and *** room temperature,such Au/WO_(3..exhibited enhanced photocata lytic conversion of CH4 to CH3..H3..ith a selectivity,up to 94%,under visible *** radicals-pathway mechanism of CH4 coupling has also been investigated through detection and trapping experiment of active *** calculations further interpret the electronic structure of Au/WO_(3..and tip-enhanced local electric field at the Au sites for promoting CH4 conversion.

关键词： Photocatalysis Single-atom Au Methane Ethane Visible light

Emerging contaminants:A One Health perspective

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The Innovation 2024年第4期5卷 140-170,139页

作者： Fang wang Leilei Xiang Kelvin Sze-Yin Leung Martin Elsner Ying Zhang Yuming Guo Bo Pan Hongwen Sun Taicheng An Guangguo Ying Bryan WBrooks Deyi Hou Damian EHelbling Jianqiang Sun Hao Qiu Timothy MVogel Wei Zhang Yanzheng Gao Myrna JSimpson Yi Luo Scott XChang Guanyong Su Bryan MWong Tzung-May Fu Dong Zhu Karl JJobst Chengjun Ge Frederic Coulon Jean Damascene Harindintwali Xiankui Zeng Haijun wang Yuhao Fu Zhong Wei Rainer Lohmann Changer Chen Yang song Concepcion Sanchez-Cid Yu wang Ali El-Naggar Yiming Yao Yanran Huang Japhet Cheuk-Fung Law Chenggang Gu Huizhong Shen Yanpeng Gao Chao Qin Hao Li Tong Zhang Natàlia Corcoll Min Liu Daniel SAlessi Hui Li Kristian KBrandt Yolanda Pico Cheng Gu Jianhua Guo Jianqiang Su Philippe Corvini Mao Ye Teresa Rocha-Santos Huan He Yi Yang Meiping Tong Weina Zhang Fidèle Suanon Ferdi Brahushi Zhenyu wang Syed AHashsham Marko Virta Qingbin Yuan Gaofei Jiang Louis A.Tremblay Qingwei Bu Jichun Wu Willie Peijnenburg Edward Topp Xinde Cao Xin Jiang Minghui Zheng Taolin Zhang Yongming Luo Lizhong Zhu Xiangdong Li DamiàBarceló Jianmin Chen Baoshan Xing Wulf Amelung Zongwei Cai Ravi Naidu Qirong Shen Janusz Pawliszyn Yong-guan Zhu Andreas Schaeffer Matthias C.Rillig Fengchang Wu Gang Yu James M.Tiedje state key laboratory of Soil and Sustainable Agriculture Institute of Soil ScienceChinese Academy of SciencesNanjing 210008China University of chinese academy of sciences Beijing 100049China Department of Chemistry Hong Kong Baptist UniversityHong KongChina HKBU institute of Research and Continuing Education Shenzhen Virtual University ParkShenzhenChina Technical University of Munich TUM School of Natural SciencesInstitute of Hydrochemistry85748 GarchingGermany School of Resources&Environment Northeast Agricultural UniversityHarbin 150030China Climate Air Quality Research UnitSchool of Public Health and Preventive MedicineMonash UniversityMelbourneVICAustralia Faculty of Environmental Science&Engineering Kunming University of Science&TechnologyKunming 650500China Ministry of Education key laboratory of Pollution Processes and Environmental Criteria College of Environmental Science and EngineeringNankai UniversityTianjin 300350China Guangdong key laboratory of Environmental Catalysis and Health Risk Control School of Environmental Science and EngineeringInstitute of Environmental Health and Pollution ControlGuangdong University of TechnologyGuangzhou 510006China Ministry of Education key laboratory of Environmental Theoretical Chemistry South China Normal UniversityGuangzhouGuangdong 510006China Department of Environmental Science Baylor UniversityWacoTXUSA Center for Reservoir and Aquatic Systems Research(CRASR) Baylor UniversityWacoTXUSA School of Environment Tsinghua UniversityBeijing 100084China School of Civil and Environmental Engineering Cornell UniversityIthacaNY 14853USA key laboratory of Microbial Technology for Industrial Pollution Control of Zhejiang Province Zhejiang University of TechnologyHangzhou 310014China School of Environmental Science and Engineering Shanghai Jiao Tong UniversityShanghai 200240China Laboratoire d’Ecologie Microbienne Universite Claude Bernard Lyon 1UMR CNRS 5557UMR INRAE 1418VetAgro Sup69622 VilleurbanneFrance Department of Pla

Environmental pollution is escalating due to rapid global development that often prioritizes human needs over planetary *** global efforts to mitigate legacy pollutants,the continuous introduction of new substances remains a major threat to both people and the *** response,global initiatives are focusing on risk assessment and regulation of emerging contaminants,as demonstrated by the ongoing efforts to establish the UN’s Intergovernmental Science-Policy Panel on Chemicals,Waste,and Pollution *** review identifies the sources and impacts of emerging contaminants on planetary health,emphasizing the importance of adopting a One Health *** for monitoring and addressing these pollutants are discussed,underscoring the need for robust and socially equitable environmental policies at both regional and international *** actions are needed to transition toward sustainable pollution management practices to safeguard our planet for future generations.

关键词： pollution planet contaminants

Fast screening compositions of PM2.5 by ATR-FTIR： Comparison with results from IC and OC/EC analyzers

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Journal of Environmental sciences 2018年第9期30卷 76-88页

作者： Xu Yu Wei song Qingqing Yu Sheng Li Ming Zhu Yanli Zhang Wei Deng Weiqiang Yang Zhonghui Huang Xinhui Bi Xinming wang state key laboratory of organic {3..and Guangdong key laboratory of Environmental Protection and Resources Utilization Guangzhou Institute of Geochemistry Chinese Academy of Sciences Guangzhou 510640 China Center for Excellence in Regional Atmospheric Environment Institute of Urban Environment Chinese Academy of SciencesXiamen 361021 China Uniuersity of chinese academy of sciences Beijing 100049 China Department of Chemistry Hong Kong University of Science and Technology Kowloon Hong Kong China

Chemical speciation of fine particles or PM2.5 collected on filters is still a cosily and time- consuming task. In this study, filter-based PM2.5 samples were collected during November-December 2013..t four sites in guangzhou, and the major components were fast screened （~ 7 rain per filter sample） by Attenuated Total Reflectance （ATR）-Fourier Transform Infrared Spectroscopic （FTIR） in comparison with that measured by organic carbon/Element carbon （OC/ EC） analyzer and Ion Chromatography （IC）. The concentrations of nitrate, ammonium, sulfate, primary organic carbon （POC） and secondary organic carbon （SOC） measured by OC/EC and IC analyzers were better correlated with their infrared absorption peak heights at 13.. cm 1 for nitrate, 143.. 3..5 and 3..5 cm^-1 for ammonium, 615 cm^-1 for sulfate, 690, 760 and 890 cm^-1 for POC and 1640 and 1660 cm^-1 for SOC respectively, during polluted days （PM2.5 〉 75 μg/m^3..than during clean days （PM2.5〈 75 μg/m^3.. With the evolution of a haze episode during our field campaign, the concentrations of the major PM2.5 components displayed consistent variations with their infrared absorption peak heights, suggesting ATR-FTIR could be a fast and useful technique to characterize filter-based PM2.5 compositions particularly during pollution events although cautions should be taken when PM2.5 levels are low. Notably, elevated PM2.5 mass concentrations occurred with enhanced ratios of [NO^-3..SO^2-4] and [NH^＋4]/[SO^2-4], implying that nitrogenous components play vital roles in the PM2.5 pollution events in the study region.

关键词： ATR-FTIR Fine particles (PM2.5) Haze episode Sulfate Nitrate Ammonium organic carbon

Vertical profiles of biogenic volatile organic compounds as observed online at a tower in Beijing

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Journal of Environmental sciences 2020年第9期32卷 33-42页

作者： Huina Zhang Yanli Zhang Zhonghui Huang WJoe FActon Zhaoyi wang Eiko Nemitz Ben Langford Neil Mullinger Brian Davison Zongbo Shi Di Liu Wei song Weiqiang Yang Jianqiang Zeng Zhenfeng Wu Pingqing Fu Qiang Zhang Xinming wang state key laboratory of organic {3..and Guangdong key laboratory of Environmental Protection and Resources Utilization Guangzhou Institute of GeochemistryChinese Academy of SciencesGuangzhou 510640China Center for Excellence in Regional Atmospheric Environment institute of Urban Environment Chinese Academy of SciencesXiamen 361021China University of chinese academy of sciences Beijing 100049China state Environmental Protection key laboratory of Environmental Pollution Health Risk Assessment and Guangdong key laboratory of Water and Air Pollution Control South China Institute of Environmental ScienceMinistry of Ecology and EnvironmentGuangzhou 510655China Lancaster Environment Centre Lancaster UniversityLancaster LA14YQUK Centre for Ecology and Hydrology Edinburgh EH260QBUK School of Geography Earth and Environmental sciences University of BirminghamBirmingham B152TTUK institute of Surface-Earth System Science Tianjin UniversityTianjin 300072China institute of Atmospheric Physics Chinese Academy of SciencesBeijing 100029China Beijing key laboratory of Green Chemical Reaction Engineering and Technology Department of Chemical EngineeringTsinghua UniversityBeijing 100084China

Vertical profiles of isoprene and monoterpenes were measured by a proton transfer reactiontime of flight-mass spectrometry(PTR-ToF-MS) at heights of 3..5,3..64,and 102 m above the ground on the institute of Atmospheric Physics(IAP) tower in central Beijing during the winter of 2016 and the summer of *** mixing ratios were larger in summer due to much stronger local emissions whereas monoterpenes were lower in summer due largely to their consumption by much higher levels of *** mixing ratios were the highest at the 3..m in summer(1.64±0.66 ppbV) and at 15 m in winter(1.41±0.64 ppbV) with decreasing concentrations to the ground and to the 102 m,indicating emission from the tree canopy of the surrounding *** mixing ratios were the highest at the 3.. height in both the winter(0.71±0.42 ppbV) and summer(0.16±0.10 ppbV) with a gradual decreasing trend to 102 m,indicting an emission from near the ground *** lowest isoprene and monoterpene mixing ratios all occurred at 102 m,which were 0.71±0.42 ppbV(winter) and 1.3..0.51 ppbV(summer) for isoprene,and 0.42±0.22 ppbV(winter) and0.07±0.06 ppbV(summer) for *** in the summer and monoterpenes in the winter,as observed at the five heights,showed significant mutual *** the winter monoterpenes were positively correlated with combustion tracers CO and acetonitrile at 3..,suggesting possible anthropogenic sources.

关键词： winter Vertical mixing

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Biomarkers of aging

Science china(Life sciences) 2023年第5期66卷 893-1066页

作者： Aging Biomarker Consortium Hainan Bao Jiani Cao Mengting Chen Min Chen Wei Chen Xiao Chen Yanhao Chen Yu Chen Yutian Chen Zhiyang Chen Jagadish K Chhetri Yingjie Ding Junlin Feng Jun Guo Mengmeng Guo Chuting He Yujuan Jia Haiping Jiang Ying Jing Dingfeng Li Jiaming Li Jingyi Li Qinhao Liang Rui Liang Feng Liu Xiaoqian Liu Zuojun Liu Oscar Junhong Luo Jianwei Lv Jingyi Ma Kehang Mao Jiawei Nie Xinhua Qiao Xinpei Sun Xiaoqiang Tang Jianfang wang Qiaoran wang Siyuan wang Xuan wang Yaning wang Yuhan wang Rimo Wu Kai Xia Fu-Hui Xiao Lingyan Xu Yingying Xu Haoteng Yan Liang Yang Ruici Yang Yuanxin Yang Yilin Ying Le Zhang Weiwei Zhang Wenwan Zhang Xing Zhang Zhuo Zhang Min Zhou Rui Zhou Qingchen Zhu Zhengmao Zhu Feng Cao Zhongwei Cao Piu Chan Chang Chen Guobing Chen Hou-Zao Chen Jun Chen Weimin Ci Bi-Sen Ding Qiurong Ding Feng Gao Jing-Dong JHan Kai Huang Zhenyu Ju Qing-Peng Kong Ji Li Jian Li Xin Li Baohua Liu Feng Liu Lin Liu Qiang Liu Qiang Liu Xingguo Liu Yong Liu Xianghang Luo Shuai Ma Xinran Ma Zhiyong Mao Jing Nie Yaojin Peng Jing Qu Jie Ren Ruibao Ren Moshi song Zhou songyang Yi Eve Sun Yu Sun Mei Tian Shusen wang Si wang Xia wang Xiaoning wang Yan-Jiang wang Yunfang wang Catherine CL Wong Andy Peng Xiang Yichuan Xiao Zhengwei Xie Daichao Xu Jing Ye Rui Yue Cuntai Zhang Hongbo Zhang Liang Zhang Weiqi Zhang Yong Zhang Yun-Wu Zhang Zhuohua Zhang Tongbiao Zhao Yuzheng Zhao Dahai Zhu Weiguo Zou Gang Pei Guang-Hui Liu Aging Biomarker Consortium(ABC) Beijing 100101China CAS key laboratory of Genomic and Precision Medicine Beijing Institute of GenomicsChinese Academy of Sciences and China National Center for BioinformationBeijing 100101China state key laboratory of Stem Cell and Reproductive Biology Institute of ZoologyChinese Academy of SciencesBeijing 100101China Department of Dermatology Xiangya HospitalCentral South UniversityChangsha 410008China Hunan key laboratory of Aging Biology Xiangya HospitalCentral South UniversityChangsha 410008China National Clinical Research Center for Geriatric Disorders Xiangya HospitalCentral South UniversityChangsha 410008China Clinic Center of Human Gene Research Union HospitalTongji Medical CollegeHuazhong University of Science and TechnologyWuhan 430022China Hubei Clinical Research Center of Metabolic and Cardiovascular Disease Huazhong University of Science and TechnologyWuhan 430022China Hubei key laboratory of Metabolic Abnormalities and Vascular Aging Huazhong University of Science and TechnologyWuhan 430022China Stem Cell Translational Research Center Tongji HospitalTongji University School of MedicineShanghai 200065China Department of Nuclear Medicine Daping HospitalThird Military Medical UniversityChongqing 400042China CAS key laboratory of Nutrition Metabolism and Food SafetyShanghai Institute of Nutrition and HealthUniversity of Chinese Academy of SciencesChinese Academy of SciencesShanghai 200031China Shanghai key laboratory of Maternal Fetal Medicine Clinical and Translational Research Center of Shanghai First Maternity and Infant HospitalFrontier Science Center for Stem Cell ResearchShanghai Key Laboratory of Signaling and Disease ResearchSchool of Life Sciences and TechnologyTongji UniversityShanghai 200092China The Department of Endovascular Surgery The First Affiliated Hospital of Zhengzhou UniversityZhengzhou 450052China key laboratory of Regenerative Medicine of Ministry of Education Institute of Ageing and Regenerative MedicineJ

Aging biomarkers are a combination of biological parameters to(i)assess age-related changes,(ii)track the physiological aging process,and(iii)predict the transition into a pathological *** a broad spectrum of aging biomarkers has been developed,their potential uses and limitations remain poorly *** immediate goal of biomarkers is to help us answer the following three fundamental questions in aging research:How old are we?Why do we get old?And how can we age slower?This review aims to address this ***,we summarize our current knowledge of biomarkers developed for cellular,organ,and organismal levels of aging,comprising six pillars:physiological characteristics,medical imaging,histological features,cellular alterations,molecular changes,and secretory *** fulfill all these requisites,we propose that aging biomarkers should qualify for being specific,systemic,and clinically relevant.

关键词： aging senescence biomarker clock

神农架及其周缘地区五峰-龙马溪组页岩微观孔隙结构特征及其含气性评价

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地球化学 2019年第6期48卷 590-601页

作者：方新焰王鹏吴亮亮耿安松中国科学院广州地球化学研究所有机地球化学国家重点实验室广东广州510640 中国科学院大学北京100049 河南省发展和改革委员会河南郑州450018

近年来随着我国页岩气勘探领域从上扬子地区逐步扩展到中扬子地区,位于中扬子的宜昌、神农架地区由于广泛发育五峰-龙马溪组黑色页岩而受到了较多的关注。本次研究通过对比鄂西宜昌、神农架地区与川东焦石坝地区五峰-龙马溪组黑色页岩... 详细信息

近年来随着我国页岩气勘探领域从上扬子地区逐步扩展到中扬子地区,位于中扬子的宜昌、神农架地区由于广泛发育五峰-龙马溪组黑色页岩而受到了较多的关注。本次研究通过对比鄂西宜昌、神农架地区与川东焦石坝地区五峰-龙马溪组黑色页岩的地球化学特征、孔隙结构特征和构造保存条件等因素,综合评价宜昌、神农架地区五峰-龙马溪组富有机质页岩的含气性。结果表明,神农架背斜北翼八角庙剖面五峰-龙马溪组黑色页岩发育以微孔和介孔为主的有机质孔隙,与宜昌和焦石坝地区五峰-龙马溪组黑色页岩孔隙特征相似,具备良好的页岩气储集空间。宜昌、神农架地区与焦石坝地区的五峰-龙马溪组黑色页岩在厚度、热演化程度、矿物组成、页岩孔隙类型和分布特征上有很大的相似性,但在页岩的分布范围、有机质丰度及类型上均存在差异。另外,宜昌、神农架地区受宜昌上升运动等构造活动的影响,在古隆起中心部位的五峰-龙马溪组遭受严重剥蚀破坏,页岩气保存条件较差,仅在古隆起周缘地区还发育保存条件较好的富有机质页岩。综合认为位于黄陵隆起东缘的宜昌斜坡带是今后鄂西、渝东地区页岩气勘探开发的有利地区。

关键词：鄂红地1井孔体积保存条件比表面积 NLDFT模型