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Chinese Journal of chemistry 1996年第3期14卷 228-234页

作者： song, ming liang,{2., Chinese Academy of Sciences, beijing 100080, china institute of chemistry Chinese Academy of Sciences Beijing 100080 China

An extraction-free spectrophotometric method for the determination of cationic surfactants, such as cetylpyridinium chloride, cetyltrimethylammonium bromide and zephiramine is proposed, which is based on the formation of ternary complexes with Fe(Ⅲ) and chrome azurol S. The molar ratio of the complex is 2.1:1 (Fe(Ⅲ):chrome azurol S:cationic surfactant). The method is simple, rapid and sensitive, giving an apparent molar absorptivity of 4.5×104 ***-1 and a linear range of 0.1-6.0 umol/L cationic surfactants. The total cationic surfactant content can be determined directly in aqueous solutions by measuring the absorbance at 680 nm (pH 5.8). The method has been successfully applied to water samples.

关键词： Cationic surfactant determination spectrophotometry ternary complex Fe(Ⅲ) chrome azurol S

Regulating Melting Process in the Energy Storage of Solid-Liquid PCM based on Double MRT-LBM Simulation

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Journal of Thermal Science 2024年第5期33卷 1688-1700页

作者： CHEN Weiqi song Zhichao quan Dong{2. HE Yurong School of Energy Science&Engineering Harbin Institute of TechnologyHarbin 150001China Heilongjiang Key Laboratory of New Energy Storage Materials and Processes Harbin 150001China Zhengzhou Research institute of Harbin institute of Technology Zhengzhou 450000China Innovation&Research institute of Hiwing Technology Academy Beijing 100074China

The melting process of solid-liquid phase change materials(PCM)has a significant impact on their energy storage *** more effectively apply solid-liquid PCM for energy storage,it is crucial to study the regulation of melting process of solid-liquid PCM,which is numerically investigated based on double multiple relaxation time lattice Boltzmann method(MRT-LBM)in this *** this work we pay more attention to the effects of different Stefan numbers(Ste)and Rayleigh numbers(Ra)on the melting *** results indicate that the PCM melting is greatly influenced by the Ste number and Ra number,which can be divided into the heat conduction dominant stage and the convection dominant stage,according to the onset time of convection Fo_(C).In order to describe the contribution of the heat conduction dominant stage to the whole melting process quantitatively,we firstly propose the ratio of the heat conduction dominant stage R_(pc),which can be defined as the ratio of Fo_(C)to the complete melting time Fo_(M).R_(pc)gradually decreases as the Ra number increases,and when the Ste number rises:R_(pc)=90.0%when Ste=1.0 and Ra=1×10^(5),R_(pc)=39.6%when Ste=0.1 and Ra=1×10^(5),and R_(pc)=14.0%when Ste=1.0 and Ra=1×10~7.A regime map about the effects of different Ste numbers and Ra numbers on R_(pc)has been further *** discovered findings would be helpful in regulating melting process in the energy storage of solid-liquid PCM.

关键词： latent thermal energy storage solid-liquid phase change double MRT-LBM dominant melting mechanism

Thermal-force control ability under variation of electromagnetic stick structure parameters in RPECT

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Journal of Iron and Steel Research International 2024年第1期31卷 224-236页

作者： Ting-song Yang Wen-quan Sun Feng-shan Du An-rui He quan Yang National Engineering Research Center of Advanced Rolling and Intelligent Manufacturing University of Science and Technology BeijingBeijing100083China institute of Engineering and Technology University of Science and Technology BeijingBeijing100083China College of Mechanical Engineering Yanshan UniversityQinhuangdao066004HebeiChina

Thermal-force driving of roll profile electromagnetic control technology(RPECT),which can be used to adjust the roll profile,can be affected by the sequential temperature rise between the electromagnetic stick(ES)and electromagnetic control *** to the limited space of ES and induction coil,the cross-sectional area of induction coil can be inevitably affected by changing the size of the ES induction zone,which can further change the energy input under the same electromagnetic parameters,the temperature rising effect and the bulging *** investigate this phenomenon,the effects of the radius of the induction zone on the thermal-force contribution ratio,the heating ability of ES and the temperature distribution were analyzed through an electromagnetic-thermal-structural finite element *** ensure that the results are applicable to RPECT,the thermal energy conversion ability and thermal-force roll crown control ability under different lengths of the induction zone were *** was found that whether the current density regulation mode or the current frequency regulation mode is adopted,the cases with 2. or 2. mm radius of the induction zone have the great thermal energy conversion ability and the good thermal-force roll crown control *** reasonable adjustment of the length of the induction zone can reduce the radius required for the maximum energy efficiency *** with the results of the simulation analysis,the optimization of ES based on the control ability maximization requirement is achieved,which provides the base for the design and configuration of ES in RPECT.

关键词： Roll profile electromagnetic control technology Electromagnetic stick Electromagnetic control roll Induction area Thermal-force driving

Adsorptive Stripping Voltammetric Study of the Enhancement of Copper(Ⅱ) in Phosphate and Carbonate media and in the Presence of Silicate

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Chinese Chemical Letters 1997年第6期8卷 61-64页

作者： ming song Hui Min MA Yue Xian HUANG and {2. {2. liang(institute of chemistry Chinese Academy of Sciences beijing 100080) institute of chemistry Academia Sinica Beijing 100080 Taiwan china institute of Atomic Energy P.O. Box 275-26 Beijing 102413 China

Adsorptive enhancements of several inorganic salts on copper(II) were studied by adsorptive stripping voltammetry with a hanging mercury drop electrode Increase in peak curren of cu(II) were observed in alkaline phosphate or media owing to adsorption Silicate can also enhance the peak current of Cu(II). The enhancing power phosphate,carbonate, and silicate is 33, 2., and 8.9 times, respectively.

关键词： in Phosphate and Carbonate media and in the Presence of Silicate II Adsorptive Stripping Voltammetric Study of the Enhancement of Copper

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Buried interface management via bifunctional NH_(4)BF_(4)towards efficient CsPbI_(2.Br solar cells with a V_(oc)over 1.4 V

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Journal of Energy chemistry 2024年第2期89卷 364-370,I0009页

作者： Fazheng Qiu ming-Hua Li Jinpeng Wu Jin-song Hu School of Materials Science and Engineering NingboTech UniversityNingbo 315100ZhejiangChina beijing National Laboratory for Molecular Sciences(BNLMS) Institute of ChemistryChinese Academy of SciencesBeijing 100190China College of Chemical Engineering Beijing Advanced Innovation Center for Soft Matter Science and EngineeringBeijing University of Chemical TechnologyBeijing 100029China School of Chemical Sciences University of Chinese Academy of SciencesBeijing 100049China

CsPbI_(2.Br perovskite solar cells(PSCs)have drawn tremendous attention due to their suitable bandgap,excellent photothermal stability,and great potential as an ideal candidate for top cells in tandem solar ***,the abundant defects at the buried interface and perovskite layer induce severe charge recombination,resulting in the open-circuit voltage(V_(oc))output and stability much lower than ***,a novel buried interface management strategy is developed to regulate interfacial carrier dynamics and CsPbI_(2.Br defects by introducing ammonium tetrafluoroborate(NH_(4)BF_(4)),thereby resulting in both high CsPbI_(2.Br crystallization and minimized interfacial energy ***,NH_(4)^(+)ions could preferentially heal hydroxyl groups on the SnO_(2.surface and balance energy level alignment between SnO_(2.and CsPbI_(2.Br,enhancing charge transport efficiency,while BF_(4)^(-)anions as a quasi-halogen regulate crystal growth of CsPbI_(2.Br,thus reducing perovskite ***,it is proved that eliminating hydroxyl groups at the buried interface enhances the iodide migration activation energy of CsPbI_(2.Br for strengthening the phase *** a result,the optimized CsPbI_(2.Br PSCs realize a remarkable efficiency of 17.09%and an ultrahigh V_(oc)output of 1.43 V,which is one of the highest values for CsPbI_(2.Br PSCs.

关键词： Inorganic perovskite Buried interface Defect Stability Open-circuit voltage loss

Engineering hydrophobic protective layers on zinc anodes for enhanced performance in aqueous zinc-ion batteries

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Journal of Energy chemistry 2024年第10期97卷 1-11页

作者： Taofeng Li Suxia Yan Hongyu Dong Yang Zheng Kun ming Ying Chen Haitao Li Guochun Li Zhixia He Weimin Li quan Wang Xiaohui {2. Junfeng Liu Edison Huixiang Ang Yong Wang institute for Energy Research Jiangsu University School of Mechanical Engineering Jiangsu University Shenzhen College of Advanced Technology University of Chinese Academy of Sciences Shandong Zhongke Advanced Technology Co. Ltd School of Materials Science and Engineering Hefei University of Technology Natural Sciences and Science Education National Institute of Education Nanyang Technological University

Aqueous zinc-ion batteries possess substantial potential for energy storage applications;however,they are hampered by challenges such as dendrite formation and uncontrolled side reactions occurring at the zinc *** our investigation,we sought to mitigate these issues through the utilization of in situ zinc complex formation reactions to engineer hydrophobic protective layers on the zinc anode *** robust interfacial layers serve as effective barriers,isolating the zinc anode from the electrolyte and active water molecules and thereby preventing hydrogen evolution and the generation of undesirable ***,the presence of numerous zincophilic sites within these protective layers facilitates uniform zinc deposition while concurrently inhibiting dendrite *** comprehensive evaluation of functional anodes featuring diverse functional groups and alkyl chain lengths,we meticulously scrutinized the underlying mechanisms influencing performance *** analysis involved precise modulation of interfacial hydrophobicity,rapid Zn2.ion transport,and ordered deposition of Zn2.***,the optimized anode,fabricated with octadecylphosphate（OPA）,demonstrated exceptional performance *** Zn//Zn symmetric cell exhibited remarkable longevity,exceeding 4000 h under a current density of 2.mA cm-2.nd a capacity density of 2.mA h cm-2.Furthermore,when integrated with a VOH cathode,the complete cell exhibited superior capacity retention compared to anodes modified with alternative organic molecules.

关键词： Aqueous zinc-ion batteries Dendrite growth inhibition Energy storage Hydrophobic protective layers Zinc anode stability

Dramatic Difference Between Cu_(2.)H_(8)and Cu_(2.)H_(9)Clusters in Catalysis

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CCS chemistry 2024年第6期6卷 1581-1590页

作者： Chun-Yu Liu Tong-Yu Liu Zong-Jie Guan song Wang Yuan-Yuan Dong Feng Hu De-en Jiang quan-{2. Wang Department of chemistry Engineering Research Center of Advanced Rare Earth Materials(Ministry of Education)Tsinghua UniversityBeijing 100084 Jiangsu Engineering Research Centre for Digital Textile Inkjet Printing Key Laboratory of Eco-Textile Jiangnan UniversityMinistry of EducationWuxiJiangsu 214122 Department of Chemical and Biomolecular Engineering Vanderbilt UniversityNashvilleTennessee 37235 Department of chemistry Vanderbilt UniversityNashvilleTennessee 37235 College of chemistry and Chemical Engineering Hunan UniversityChangsha 410082 Hefei National Research Center for Physical Sciences at the Microscale School of Chemistry and Materials ScienceUniversity of Science and Technology of ChinaHefeiAnhui 230026

Sensitivity to structure and composition is very challenging to establish in nanocatalysis due to inadequate definition of structures that are very close in *** synthesized a pair of atomically precise copper clusters that are very close in composition,[Cu_(2.)H_(9)(Tf-dpf)_(10)]·BF4(Cu_(2.)H_(9))and[Cu_(2.)H_(8)(Tf-dpf)_(10)]·(BF_(4))_(2.(Cu_(2.)H_(8)),by using a pyridyl-functionalized flexible amidinate ligand,N,N′-di(5-trifluoromethyl-2.pyridyl)*** one-hydride difference in their composition leads to significant variation in geometric and electronic structures and,consequently,distinctly different optical and catalytic ***_(2.)H_(8)exhibits 2. times higher catalytic activity than Cu_(2.)H_(9)(96.7%vs 3.7%in yield)in the selective hydrogenation of anα,β-unsaturated aldehyde(cinnamaldehyde)to saturated aldehyde(3-phenylpropanal).Electrospray ionization mass spectrometry combined with density functional theory calculations reveal that the greater ease of dissociation of one Tf-dpf ligand compared to Cu_(2.)H_(8)is the key to its higher *** work demonstrates a clear case of structure and composition sensitivity in nanocatalysis and that one hydride,out of∼330 atoms in the nanoclusters,can make a huge difference in the catalytic *** insights will be useful in the design and synthesis of atomically precise nanocatalysts.

关键词： copper cluster hydride amidinate ligand structural transformation hydrogenation catalysis

SYNTHESIS AND CHARACTERIZATION OF NEW STABILIZERS WITH OPTIMAL MOLECULAR WEIGHT

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Chinese Journal of Polymer Science 2001年第4期19卷 341-350页

作者： Jiang-qing Pan institute of chemistry Chinese Academy of Sciences,{2. china 中科院化学所北京

Over 2.x 10(8) tons of polymers are produced every year, and a large portion of polymers faces the degradation problem. There are many effective methods to protect polymers against degradation and the addition of stabilizers to polymer remains the most convenient and effective way of enhancing polymer life and performance. In this article, a series of effective stabilizers with optimal molecular weight (MW), including common, monomeric and polymeric stabilizers (antioxidant and light stabilizer) were synthesized using isocyanation, controlled isocyanation, hydrosilylation, epoxide addition, macroreaction of stabilizing functional compounds and polymerization of monomeric stabilizers. The structure and performance of these new stabilizers were characterized by using IR, NMR, MS, UV-spectra, XPS and elemental analysis. The current development of stabilizer synthesis was also reviewed.

关键词： preparation of stabilizer antioxidant hindered amine light stabilizer isocyanation hydrosilylation

High-resolution remote thermometry based on Bi^(3+)-doped 0D zinc halide hybrids

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Science china chemistry 2024年第8期67卷 2599-2605页

作者： Cui-Mi Shi shu-Hua Xue Jin-Yun Wang liang-Jin Xu Zhong-Ning Chen State Key Laboratory of Structural chemistry Fujian Institute of Research on the Structure of MatterChinese Academy of SciencesFuzhou 350002China Fujian Science Technology Innovation Laboratory for Optoelectronic Information of ChinaFuzhou 350108China University of Chinese Academy of Sciences Beijing 100049China

Developing highly sensitive optical thermometers is of great significance due to their capability to enable remote and non-contact temperature measurements, rendering them highly applicable in diverse and harsh environments. Herein we report a temperature-dependent phosphor of 0D metal halide hybrid by incorporating Bi^(3+)into the(MePPh_(3))_(2.ZnCl_(4) matrix. Through Bi^(3+)doping,the initially non-luminescent(MePPh_(3))_(2. ZnCl_(4) matrix exhibits a deep-blue emission centered at 453 nm, with a photoluminescence quantum yield(PLQY) of 5.71% and a Stokes shift of 75 nm at room temperature. Experimental characterization demonstrates that exciton-like luminescence of Bi^(3+)is mainly responsible for the blue emission. Single crystals of Bi^(3+)-doped(MePPh_(3))_(2.ZnCl_(4) show an unusual correlation between photoluminescence(PL) lifetime and temperature. Particularly, the dependence of luminescence lifetime on temperature is most remarkable in the temperature range of 80 to 100 K with an exceptional sensitivity up to 0.09 K^(-1), representing one of the best levels for thermometry based on PL decay lifetime. Our work not only provides a viable strategy for designing a novel, environmentally friendly, and stable blue emitter, but also paves the way for precise thermometric application at low temperature.

关键词： lead-free hybrids Bi^(3+)doping blue emission temperature sensing

Design study of charge-stripping scheme of heavy ion beams for HIAF-BRing

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Nuclear Science and Techniques 2024年第5期35卷 30-41页

作者： Jun-Jie Zhang Zhi-You Xu Jin-quan Zhang Wen-Wen Ge liang-Ting Sun Huan-Yu Zhao institute of Modern Physics Chinese Academy of SciencesLanzhou 730000China School of Nuclear Science and Technology University of Chinese Academy of SciencesBeijing 100049China

Charge strippers play an essential role in heavy-ion accelerators by stripping the projectile ions to higher charge states to enhance the acceleration efficiency downstream of the *** the high-energy mode of the booster ring(BRing)of the high-intensity heavy-ion accelerator facility,the pre-accelerated ions from the iLinac will be stripped by a carbon foil to higher charge states and then injected into the *** key parameters of the stripper and stripped ions were calculated,and the influence of stripping on the beam quality was *** get high stripping efficiencies,the foil thicknesses and resultant charge state distributions for the typical ions were determined by the code *** equilibrium thickness was obtained for the U beam,while the stripper thicknesses for the Xe and Kr beams were determined based on a compromise between the stripped charge states and the stripping *** energy loss,energy straggling,and emittance growth due to stripping have a non-negligible impact on the transport of the stripped beams and the injection of the ***,these parameters were simulated by *** addition,the foil’s temperature evolution,which greatly affects the foil lifetime,was simulated by *** maximum temperature of the foil bombarded by the U and Xe beams with the nominal parameters will exceed the safe value in terms of the impact of evaporation on the foil’s *** the foil temperature constraint,the highest tolerable beam intensity and the injected ion number into the ring were derived for different beam *** results of this paper will present important reference data for the optimization design and commissioning of the beamline and injection to the BRing for the stripped ions.

关键词： High-intensity heavy-ion accelerator facility Charge stripper Energy spread Thermal analysis Emittance growth Injection turns