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Mineral chemistry,P-T-t paths and exhumation processes of mafic granulites in Dinggye,Southern Tibet

Science China Earth Sciences 2005年第11期48卷 1870-1881页

作者： LIU shuwen ZHANG Jinjiang shu guiming LI Qiugen The Key Laboratory of Orogenic Belts and Crustal Evolution Ministry of EducationSchool of Earth and Space SciencesPeking UniversityBeijing 100871China

The mafic granulites in Dinggye,as various scale lense-shaped enclaves within the high Himalayan crystalline rock series,occur along mylonitic foliations at the junction between the Southern Tibetan Detachment System(STDS)and the Xainza-Dinggye normal fault *** main lithological assemblage comprises garnet plagioclase pyroxenite,garnet two-pyroxene granulite,pyroxene garnet amphibolite and so *** detailed petrological analyses show that these mafic granulites underwent at least four-stage metamorphic *** first metamor-phic stage,the garnet+clinopyroxene+quart mineral assemblage(M1)was probably formed un-der eclogite facies,the second stage,the plagioclase+clinopyroxene symplectite mineral as-semblage(M2)was produced under high-pressure granulite facies by the early decompressive breakdown of M1 mineral assemblage,the third stage,the plagioclase+clinopyroxene+hypersthene symplectite mineral assemblage(M3)was formed at granulite facies by the late period decompressive breakdown of M1 and M2 mineral assemblages and the final stage,pla-gioclase+hornblende mineral assemblage(M4)was formed by hydrolysis of earlier mineral as-semblages during late *** detailed mineral composition analyses suggest that garnets and clinopyroxenes within M1 and M2 mineral assemblages display similar compositions to the equivalents in the B and C types of eclogites,whereas the M3 clinopyroxenes are akin to these of the same kind of minerals in the *** mineral chemistry features and P-T estimates calculated by mineral thermometers and barometers indicate that the early stage relic porphyro-blasts(M1)could be formed at the eclogite facies,the early decompressive breakdown(M2)occurred at the high-pressures granulite facies of 1.35―1.48 GPa and 625―675℃,the M3 mineral assemblage recorded the granulite facies of 0.7―0.95 GPa and 775―900℃and M4 plagioglase+hornblende retrograde mineral assemblage was produced under the amphibolite facies metamorphism with pr

关键词： mafic granulites garnet and clinopyroxene metamorphic P-T conditions eclogite facies metamorphism three-stage exhumation Dinggye in Southern Tibet.

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The facile method developed for preparing polyvinylidene fluoride plasma separation membrane via macromolecular interaction

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Chinese Journal of Chemical Engineering 2022年第9期35卷 140-149页

作者： Juanjuan Liu Xiaolong Lu guiming shu Ke Li shuyun Zheng Xiao Kong Tao Li Jun Yang Tianjin Key Laboratory of Extracorporeal Life Support for Critical Diseases Tianjin Artificial Cell Engineering Technology Research CenterInstitute of Hepatobiliary DiseaseThe Third Central Hospital Affiliated to Nankai UniversityTianjin Third Central HospitalTianjin 300170China State Key Laboratory of Separation Membrane and Membrane Processes School of Material Science and EngineeringInstitute of Biological and Chemical EngineeringTiangong UniversityTianjin 300387China Clinical Laboratory Tianjin Children’s HospitalTianjin 300074China State Key Laboratory of Membrane Materials and Membrane Applications Tianjin Motimo Membrane Tech.Co.LtdTianjin 300457China The Key Laboratory of Bioactive Materials College of Life ScienceNankai UniversityTianjin 300000China

The design of membrane pore is critical for membrane preparation. Polyvinylidene fluoride(PVDF) membrane exhibits outstanding properties in the water-treatment field. However, it is a huge challenge to prepare PVDF macro-pore plasma separation membrane by non-solvent induced phase separation(NIPS). Herein, a facile strategy is proposed to prepare PVDF macro-pore plasma separation membrane via macromolecular interaction. ATR-FTIR and ^(1)H NMR showed that the intermolecular interaction existed between polyethylene oxide(PEO) and polyvinylpyrrolidone(PVP). It could significantly affect the PVDF macro-pore membrane structure. The maximum pore of the PVDF membrane could be effectively adjusted from small-pore/medium-pore to macro-pore by changing the molecular weight of PEO. The PVDF macro-pore membrane was obtained successfully when PEO-200 k existed with PVP. It exhibited higher plasma separation properties than the currently used plasma separation ***, it had excellent hemocompatibility due to the similar plasma effect, hemolysis, prothrombin time, blood effect and complement C_(3a) effect with the current utilized plasma separation membrane,implying its great potential application. The proposed facile strategy in this work provides a new method to prepare PVDF macro-pore plasma separation membrane by NIPS.

关键词： Membranes Macro-pore plasma separation membrane Hemocompatibility Purification Biomedical engineering

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EMP chemical ages of monazites from Central Zone of the eastern Kunlun Orogen:Records of multi-tectonometamorphic events

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Chinese Science Bulletin 2007年第16期52卷 2252-2263页

作者： CHEN NengSong SUN Min WANG QingYan ZHAO GuoChun CHEN Qiang shu guiming Faculty of Earth Sciences China University of Geosciences Wuhan 430074 China Department of Earth Sciences the University of Hong Kong Poflam Road Hong Kong China School of Earth and Space Sciences Peking University Beijing 100871 China

Two generations of monazite were identified in one mica schist sample from the central zone of the eastern Kunlun Orogen at the northern margin of the Qinghai-Tibet Plateau. The first generation was found in the cores of garnet porphyroblasts with relatively high Y2O3 contents (averaging 1.012±0.088 wt%). The second generation occurs either as inclusions in the rims of garnet porphyroblasts,matrix kyanite,plagioclase and quartz,or as separate crystals associated with matrix biotite and muscovite mostly having a relatively low Y2O3 content (averaging 0.479±0.100 wt%). Electron microprobe (EMP) Th-U-Pbtotal chemical dating for two grains of the first generation monazite yields average ages of 455 ± 18 Ma and 420 ± 20 Ma,respectively; six grains of the second generation gave an average age of 246.1 ± 3.8 Ma. These ages suggest that the core and rim of the garnet porphyroblasts and their associated assemblages record two events of significant tectonometamorphism. The formation of the Ordovician monazite is related to the tectonometamorphic event responsible for continuous amalgamation of the Gondwanaland in the Late Pan-African period or for consumption of the Proto-Tethys,whereas the development of the Triassic monazite is related to the tectonometamorphic event for consumption of the Paleo-Tethys.

关键词：独居石昆仑造山带变质岩电子探针测年石榴石

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Electron microprobe chemical ages of monazite from Qinling Group in the Qinling Orogen: Evidence for Late Pan-African metamorphism?

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Chinese Science Bulletin 2006年第21期51卷 2645-2650页

作者： CHEN Qiang CHEN Nengsong WANG Qinyan SUN Min WANG Xinyu LI Xiaoyan shu guiming Faculty of Earth Sciences China University of Geosciences Wuhan 430074 China Department of Earth Sciences The University of Hong Kong HongKong SAR China Guangxi Institute of Geological Survey Nanning 5300.23 China School of Earth and Space Sciences Peking University Beijing 100871 China

Electron microprobe chemical dating was carried out on monazites enclosed in two gen-erations of mineral paragenesis of St + Ky + Grt and Sil + And + Grt + St, respectively, from the Qinling Group. Two different ages, 520±23 Ma and 435±9 Ma, were obtained from these monazites. This indicates that the Qinling Group experienced a metamorphism during the Early Cambrian, which is probably in response to the Late Pan-African subduction-accretion tectonothermal event.

关键词：化学年龄电子显微探针独居石秦岭造山带

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Post-Entrainment Mineral-Magma Interaction in Mantle Xenoliths from Inner Mongolia,Western North China Craton

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Journal of Earth Science 2012年第1期23卷 54-76页

作者： Yamei Wang Baofu Han William L Griffin Lei Zhang guiming shu Key Laboratory of Orogenic Belts and Crustal Evolution Ministry of EducationPeking UniversityBeijing 100871China School of Earth and Space Sciences Peking UniversityBeijing 100871China GEMOC ARC National Key Centre Department of Earth and Planetary SciencesMacquarie UniversityNSW 2109Australia CSIRO Exploration and Mining North RydeNSW 2113Australia

In order to distinguish the primary microstructures developed under mantle conditions from the secondary phenomena after xenolith entrainment in the host magma, this study intends to discuss the genesis of spongy, sieve-textured, and reaction rims on mineral grains of mantle xenoliths in the Cenozoic basalts from the western North China craton. The spongy rims on primary clinopyroxene show neither obvious compositional zoning nor preferential development towards the host basalt and probably suggest an origin via partial melting within the lithospheric mantle or pressure release as the xenoliths were carried upwards. The sieve-textured rims on primary spinel show clear chemical zoning with increasing Cr# and decreasing AI towards the host basalt. They are interpreted as the result of partial melting due to heating of the host basaltic magma and decreasing pressure during ascent proc- ess. Post-entrainment reaction mainly generated secondary minerals at contacts between the host ba- saltic melt and xenoliths. The secondary clinopyroxene in reaction rims develops on primary clinopy- roxene and has higher Ti, Ca, and Fe contents and lower Mg# and Si contents than primary one, while the secondary spinel on primary Cr-AI spinel is titanomagnetite. The secondary olivine and clinopy- roxene in the reaction rims on primary orthopyroxene are enriched in Fe, Al, and Ti. The occurrence of reaction rims in mantle xenoliths reflects disequilibrium processes after xenolith entrainment in the basaltic melt. The spongy rims on primary clinopyroxene may not be related to the interaction with thehost basaltic melt, while the sieve-textured rims on primary spinel and reactions rims on primary clinopyroxene, spinel, and orthopyroxene may result from post-entrainment reaction between the host basaltic melt and xenolith minerals.

关键词： mantle xenolith interaction,spongy rim sieve-textured rim reaction rim.

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Progress in in-situ electrochemical nuclear magnetic resonance for battery research

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Magnetic Resonance Letters 2024年第2期4卷 13-21页

作者： Yong Jiang Mengmeng Zhao Zhangquan Peng guiming Zhong Laboratory of Advanced Spectro-electrochemistry and Li-ion Batteries Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalian116023China University of Chinese Academy of Sciences Beijing100049China Tianmu Lake Institute of Advanced Energy Storage Technologies Co. Ltd.Liyang213300China

A thorough understanding of the fundamental electrochemical and chemical processes in batteries is crucial to advancing energy density and power ***,the characterizations of such processes are ***-situ electrochemical nuclear magnetic resonance(EC-NMR)offers the capability to collect real-time data during battery operation,furnishing insights into the local structures and ionic dynamics of materials by monitoring changes in the chemical environment around the ***-NMR also has the advantages of being both quantitative and *** paper systematically reviews the design of EC-NMR approach,and delves into the applications and progress of EC-NMR concerning battery reaction mechanisms,failure mechanisms,and overall battery *** review culminates in a comprehensive summary of the perspective and challenges associated with EC-NMR.

关键词： In-situ NMR Reaction mechanism Failure mechanism Battery systems Ionic dynamics

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SEI/dead Li-turning capacity loss for high-performance anode-free solid-state lithium batteries

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Journal of Energy Chemistry 2024年第9期96卷 145-152页

作者： Qianwen Yin Tianyu Li Hongzhang Zhang guiming Zhong Xiaofei Yang Xianfeng Li Division of Energy Storage Dalian National Laboratory for Clean EnergyDalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023LiaoningChina University of Chinese Academy of Sciences Beijing 100049China Key Laboratory of Long-Duration and Large-Scale Energy Storage Dalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023LiaoningChina Laboratory of Advanced Spectro-Electrochemistry and Lithium-Ion Batteries Dalian National Laboratory for Clean EnergyDalian Institute of Chemical PhysicsChinese Academy of SciencesDalian 116023LiaoningChina

Anode-free solid-state lithium metal batteries(AF-SSLBs)have the potential to deliver higher energy density and improved safety beyond lithium-metal ***,the unclear mechanism for the fast capacity decay in AF-SSLBs,either determined by dead Li or solid electrolyte interface(SEI),limits the proposal of effective strategies to prolong cycling *** clarify the underlying mechanism,herein,the evolution of SEI and dead Li is quantitatively analyzed by a solid-state nuclear magnetic resonance(ss-NMR)technology in a typical LiPF6-based polymer *** results show that the initial capacity loss is attributed to the formation of SEI,while the dead Li dominates the following capacity loss and the growth rate is 0.141 mA h cm^(−2)cycle−*** reduce the active Li loss,the combination of inorganic-rich SEI and self-healing electrostatic shield effect is proposed to improve the reversibility of Li deposition/dissolution behavior,which reduces the capacity loss rate for the initial SEI and following dead Li generation by 2.3 and 20.1 folds,*** a result,the initial Coulombic efficiency(ICE)and stable CE increase by 15.1%and 15.3%in Li-Cu cells,which guides the rational design of high-performance AF-SSLBs.

关键词： Solid-state lithium batteries Solid-state NMR Anode-free SEI Dead Li

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河北康保地区花岗岩独居石电子探针定年

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岩石学报 2007年第4期23卷 817-822页

作者：王鑫琳张臣刘树文舒桂明北京大学造山带与地壳演化教育部重点实验室

已有年代学研究表明,康保地区西阿公单元含石榴二长花岗岩形成于中元古代。我们采用近年来新发展的独居石电子探针Th-U-总Pb定年方法对康保地区西阿公单元十硼地区变质细粒含石榴二长花岗岩样品中的独居石开展了电子探针进行测年分析,... 详细信息

已有年代学研究表明,康保地区西阿公单元含石榴二长花岗岩形成于中元古代。我们采用近年来新发展的独居石电子探针Th-U-总Pb定年方法对康保地区西阿公单元十硼地区变质细粒含石榴二长花岗岩样品中的独居石开展了电子探针进行测年分析,计算方法为Suzuki和Adachi等提出的方法。独居石年龄峰值分别为252Ma,265Ma,281Ma和322Ma,表明西阿公单元含石榴二长花岗岩形成时代不是中元古代,其侵位时间应为二叠纪。这一新的年代学结果与Sengor和王荃推测的华北板块与西伯利亚板块"晚二叠世碰撞"的模式一致。康保地区西阿公单元含石榴二长花岗岩具过铝花岗岩特征,代表古蒙古洋消失,是华北板块与西伯利亚板块碰撞造山阶段多期岩浆作用的结果,为确定古亚洲洋的闭合时间提供了重要依据。

关键词：电子探针独居石钍-铀-铅康保花岗岩

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柴北缘超高压变质带沙柳河蛇绿岩型地幔橄榄岩及其意义

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岩石学报 2005年第4期21卷 1049-1058页

作者：张贵宾宋述光张立飞牛耀龄舒桂明教育部造山带与地壳演化重点实验室 Department of Earth Sciences University of DurhamDurham DH1 3LEUK

本文报道了柴北缘大陆型超高压变质带沙柳河地区发现的蛇绿岩型地幔橄榄岩,其原始矿物组合为橄榄石+斜方辉石+铬铁矿。方辉橄榄岩中识别出两个世代的橄榄石,第一世代橄榄石(OI^1)残晶发育扭折带,化学成分与现代大洋地幔橄榄岩的橄榄石一... 详细信息

本文报道了柴北缘大陆型超高压变质带沙柳河地区发现的蛇绿岩型地幔橄榄岩,其原始矿物组合为橄榄石+斜方辉石+铬铁矿。方辉橄榄岩中识别出两个世代的橄榄石,第一世代橄榄石(OI^1)残晶发育扭折带,化学成分与现代大洋地幔橄榄岩的橄榄石一致,第二世代橄榄石(OI^2)Fo 值高达94～97,其内部含有细小的流体包裹体,是第一世代橄榄石蛇纹石化后再次变质的产物。斜方辉石残晶的成分具有高 Al 和 Ca 的特征,与大洋地幔橄榄岩中斜方辉石的成分一致。温压条件的估算反映该橄榄岩体属于典型的尖晶石相方辉橄榄岩。其围岩是由堆晶辉长岩变质的条带状蓝晶石榴辉岩,二者构成了大洋蛇绿岩套的下部层位,并且与区内具有 N-MORB 和 OIB 性质的榴辉岩共生。这些特征表明该方辉橄榄岩应代表洋壳下伏地幔橄榄岩,从而揭示大陆造山带从早期的大洋俯冲消亡到大陆俯冲碰撞的完整过程。

关键词：地幔橄榄岩蛇绿岩大陆型超高压变质带:柴北缘

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Sphingolipid inhibitor response gene GhMYB86 controls fiber elongation by regulating microtubule arrangement

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Journal of Integrative Plant Biology 2024年第9期66卷 1898-1914页

作者： Fan Xu guiming Li Shengyang He Zhifeng Zeng Qiaoling Wang Hongju Zhang Xingying Yan Yulin Hu Huidan Tian Ming Luo College of Agronomy and Biotechnology Southwest UniversityChongqing 400715China Engineering Research Center of South Upland Agriculture Ministry of EducationSouthwest UniversityChongqing 400715China Dianjiang No.1 Middle School of Chongqing Chongqing 408300China Yushan No.1 Senior High School Shangrao 334700China

Although the cell membrane and cytoskeleton play essential roles in cellular morphogenesis,the interaction between the membrane and cytoskeleton is poorly *** fibers are extremely elongated single cells,which makes them an ideal model for studying cell ***,we used the sphingolipid biosynthesis inhibitor,fumonisin B1(FB1),and found that it effectively suppressed the myeloblastosis(MYB)transcription factor GhMYB86,thereby negatively affecting fiber elongation.A direct target of GhMYB86 is GhTUB7,which encodes the tubulin protein,the major component of the microtubule ***,both the overexpression of GhMYB86 and GhTUB7 caused an ectopic microtubule arrangement at the fiber tips,and then leading to shortened ***,we found that GhMBE2 interacted with GhMYB86 and that FB1 and reactive oxygen species induced its transport into the nucleus,thereby enhancing the promotion of GhTUB7 by ***,we established a GhMBE2-GhMYB86-GhTUB7 regulation module for fiber elongation and revealed that membrane sphingolipids affect fiber elongation by altering microtubule arrangement.

关键词： cotton fiber membrane sphingolipid microtubule arrangement

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