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Fabricating functionally graded Fe-Cr-Co permanent magnetic alloys via laser powder bed fusion

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Journal of Iron and Steel Research International 2024年第3期31卷 729-737页

作者： ya-zhou He ya-qing Hou Peng shen Hao Zhang Dong Zhou Hang Su Central Iron and Steel Research Institute Co. Ltd.Beijing 100081China Material Digital R&D Center China Iron and Steel Research Institute Group Co.Ltd.Beijing 100081China

Laser powder bed fusion(LPBF)in-situ alloying technology offers the possibility to construct gradient materials with varied structures and *** graded Fe-Cr-Co permanent magnetic alloys were fabricated by LPBF and in-situ alloying mixed powders of Fe,Cr,and Co *** effects of different Fe,Cr and Co contents on the microstructure,magnetic properties and hardness of Fe-Cr-Co alloys prepared by LPBF were *** as-built Fe-Cr-Co alloys present a single body-centered-cubic phase and have a homogeneous distribution of *** mechanical properties and magnetic properties of the compositionally graded sample show a gradient *** the increase in Cr content,the Vickers hardness of the sample increases,and the saturation magnetization of the sample *** optimal magnetic properties in an isotropic state are given as coercivity HcB=21.65 kA/m,remanence Br=0.70 T and energy product(BH)_(max)=5.35 kJ/m^(3),which are comparable to or higher than the reported magnetic properties in an isotropic state prepared by traditional powder *** in-situ alloying technology has the potential to further explore Fe-Cr-Co magnetic materials,such as those consisting of multiple or more constituent elements,and to maximize the compositional flexibility of magnetic materials.

关键词： Fe-Cr-Co alloy Laser powder bed fusion In-situ alloying Functional material Magnetic property

Numerical study on the effective thermal conductivity and thermal tortuosity of porous media with different morphologies

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Science China(Technological Sciences) 2024年第6期67卷 1685-1694页

作者： DU shen LI Dong LI Meng-Jie HE ya-Ling Key Laboratory of Thermo-Fluid Science and Engineering of Ministry of Education School of Energy and Power EngineeringXi’an Jiaotong UniversityXi’an710049China

Effective thermal conductivity and thermal tortuosity are crucial parameters for evaluating the effectiveness of heat conduction within porous *** direct pore-scale numerical simulation method is applied to investigate the heat conduction processes inside porous structures with different *** thermal conduction performances of idealized porous structures are directly compared with real foams across a wide range of *** foam structures are reconstructed using X-ray computed tomography and image processing techniques,while Kelvin and Weaire-Phelan structures are generated through periodic unit cell *** detailed temperature fields inside the porous structures are determined by solving the heat conduction equation at the pore *** results present that the equivalent thermal conductivity of Kelvin and Weaire-Phelan structures is similar to and greater than that of the real foam structure with the same strut *** thermal tortuosity of real foam structure is relatively larger and the heat conduction path becomes straighter by adopting the anisotropic *** thermal tortuosity of the fluid channels for Kelvin,Weaire-Phelan,and real foam structures is close to *** thermal conductivity of porous structures with heat transfer fluid increases as the thermal conductivity ratio of fluid to solid becomes larger.A small porosity of porous media leads to a larger equivalent thermal conductivity due to the dominant contribution of porous skeleton in the heat conduction *** derived from parallel and series models,as well as the Maxwell-Eucken models,provide decent predictions of effective thermal conductivity,with an average error of less than 8%in the entire range of thermal conductivity ratio.

关键词： volumetric solar receiver porous morphology direct pore-scale simulation equivalent thermal conductivity thermal tortuosity empirical correlation

安注箱对小型模块化压水堆LOCA的影响研究

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核动力工程 2015年第3期36卷 45-49页

作者：高颖贤申亚欧曾未中国核动力研究设计院核反应堆系统设计技术重点实验室成都610041

基于小型模块化压水堆失水事故(LOCA)的现象和特征,分析燃料包壳峰值温度(PCT)出现的机理,并研究安注箱(ACC)设置对PCT和事故长期降压的影响。结果表明:在一定范围中等破口尺寸LOCA下,ACC注水可能导致堆芯更不利的后果,小型堆可合理考虑... 详细信息

基于小型模块化压水堆失水事故(LOCA)的现象和特征,分析燃料包壳峰值温度(PCT)出现的机理,并研究安注箱(ACC)设置对PCT和事故长期降压的影响。结果表明:在一定范围中等破口尺寸LOCA下,ACC注水可能导致堆芯更不利的后果,小型堆可合理考虑ACC的作用进行系统设计。

关键词：小型模块化压水堆安注箱(ACC) 失水事故

Understanding the failure mechanism towards developing high-voltage single-crystal Ni-rich Co-free cathodes

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Green Energy & Environment 2024年第6期9卷 1045-1057页

作者： Jixue shen Bao Zhang Changwang Hao Xiao Li Zhiming Xiao Xinyou He Xing ou Engineering Research Center of the Ministry of Education for Advanced Battery Materials School of Metallurgy and EnvironmentCentral South UniversityChangsha410083China Zhejiang Power New Energy Co. Ltd.Zhuji311899China Material Science and Chemistry Engineering College China University of GeosciencesWuhan430074China

Benefited from its high process feasibility and controllable costs,binary-metal layered structured LiNi_(0.8)Mn_(0.2)O_(2)(NM)can effectively alleviate the cobalt supply crisis under the surge of global electric vehicles(EVs)sales,which is considered as the most promising nextgeneration cathode material for lithium-ion batteries(LIBs).However,the lack of deep understanding on the failure mechanism of NM has seriously hindered its application,especially under the harsh condition of high-voltage without sacrifices of reversible ***,singlecrystal LiNi_(0.8)Mn_(0.2)O_(2) is selected and compared with traditional LiNi_(0.8)Co_(0.1)Mn_(0.1)O_(2)(NCM),mainly focusing on the failure mechanism of Cofree cathode and illuminating the significant effect of Co element on the Li/Ni antisite defect and dynamic ***,the presence of high Li/Ni antisite defect in NM cathode easily results in the extremely dramatic H2/H3 phase transition,which exacerbates the distortion of the lattice,mechanical strain changes and exhibits poor electrochemical performance,especially under the high cutoff ***,the reaction kinetic of NM is impaired due to the absence of Co element,especially at the single-crystal ***,the negative influence of Li/Ni antisite defect is controllable at low current densities,owing to the attenuated ***,Co-free NM can exhibit better safety performance than that of NCM *** findings are beneficial for understanding the fundamental reaction mechanism of single-crystal Ni-rich Co-free cathode materials,providing new insights and great encouragements to design and develop the next generation of LIBs with low-cost and high-safety performances.

关键词： Li/Ni antisite defect Dynamic characteristic High-voltage Single-crystal Ni-rich Co-free cathodes Lithium-ion batteries

Genome-Wide Expression Profile of Maize Root Response to Phosphorus Deficiency Revealed by Deep Sequencing

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Journal of Integrative Agriculture 2014年第6期13卷 1216-1229页

作者： SU Shun-zhong WU Ling LIU Dan LU yan-li LIN Hai-jian ZHANG Shu-zhi shen ya-ou LIU Hai-lan ZHANG Zhi-ming RONG Ting-zhao ZHANG Xiao TIAN Yue-hui NIE Zhi GAO Shi-bin Key Laboratory of Biology and Genetic Improvement of Maize in Southwest Region Ministry of Agriculture/Maize Research InstituteSichuan Agricultural University

Phosphorus （P） is one of the three primary macronutrients that are required in large amounts for plant growth and development. To better understand molecular mechanism of maize and identify relevant genes in response to phosphorus deficiency, we used Solexa/Illumina＇s digital gene expression （DGE） technology to investigate six genome-wide expression profiles of seedling roots of the low-P tolerant maize inbred line 178. DGE studies were conducted at 6, 24 and 72 h under both phosphorus deficient and sufficient conditions. Approximately 3.93 million raw reads for each sample were sequenced and 6 816 genes exhibited significant levels of differential expressions in at least one of three time points in response to P starvation. The number of genes with increased expression increased over time from 6 to 24 h, whereas genes with decreased expression were more abundant at 72 h, suggesting a gradual response process for P deficiency at different stages. Gene annotations illustrated that most of differentially expressed genes （DEGs） are involved in different cellular and molecular processes such as environmental adaptation and carbohydrate metabolism. The expression of some known genes identified in other plants, such as those involved in root architecture, P metabolism and transport were found to be altered at least two folds, indicating that the mechanisms of molecular and morphological adaptation to P starvation are conserved in plants. This study provides insight into the general molecular mechanisms underlying plant adaptation to low-P stress and thus may facilitate molecular breeding for improving P utilization in maize.

关键词： maize phosphorus efficiency root digital gene expression

Enhanced vision-transformer integrating with semi-supervised transfer learning for state of health and remaining useful life estimation of lithium-ion batteries

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Energy and AI 2024年第3期17卷 380-396页

作者： ya-Xiong Wang Shangyu Zhao Shiquan Wang Kai ou Jiujun Zhang School of Mechanical Engineering and Automation Fuzhou UniversityFuzhou 350108China College of Materials Science and Engineering Fuzhou UniversityFuzhou 350108China

The state of health(SOH)and remaining useful life(RUL)of lithium-ion batteries are crucial for health management and ***,most data-driven estimation methods heavily rely on scarce labeled data,while traditional transfer learning faces challenges in handling domain shifts across various battery *** paper proposes an enhanced vision-transformer integrating with semi-supervised transfer learning for SOH and RUL estimation of lithium-ion batteries.A depth-wise separable convolutional vision-transformer is developed to extract local aging details with depth-wise convolutions and establishes global dependencies between aging information using multi-head *** mean discrepancy is employed to initially reduce the distribution difference between the source and target domains,providing a superior starting point for fine-tuning the target domain ***,the abundant aging data of the same type as the target battery are labeled through semi-supervised learning,compensating for the source model's limitations in capturing target battery aging *** regularization incorporates the cross-entropy between predictions with and without adversarial perturbations into the gradient backpropagation of the overall *** particular,across the experimental groups 13–15 for different types of batteries,the root mean square error of SOH estimation was less than 0.66%,and the mean relative error of RUL estimation was 3.86%.Leveraging extensive unlabeled aging data,the proposed method could achieve accurate estimation of SOH and RUL.

关键词： State of health(S0H) Remaining useful life(RUL) Depth-wise separable convolutional vision-transformer Transfer learning Maximum mean discrepancy Semi supervised learning

Research on feed-pulse collaborative control method in micro-electrical discharge machining

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Advances in Manufacturing 2024年第2期12卷 270-287页

作者： Qiang Gao ya-ou Zhang Xue-Cheng Xi Yuan-Ding Wang Xiao-Fei Chen Wan-sheng Zhao School of Mechanical Engineering Shanghai Jiao Tong UniversityShanghai200240People’s Republic of China State Key Laboratory of Mechanical System and Vibration Shanghai200240People’s Republic of China Shanghai Institute of Space Propulsion Shanghai201112People’s Republic of China

Reducing the short-circuit rate and increasing the effective discharge rate are important targets for improving the servo control effect of micro-electrical discharge machining(micro-EDM),as these two indicators are closely related to the machining efficiency and *** this study,a feed-pulse collaborative control(FPCC)method is proposed for micro-EDM based on two dimensions(space and time).In the spatial dimension,a feed control strategy with a discharge holding process is ***,in the time dimension,a forward-looking pulse control strategy is adopted,in which the pulse interval is adjusted based on a sequence analysis of feed commands and discharge *** experiments are carried out to determine the key parameters used in this method,including the discharge holding threshold and pulse interval adjustment value(T_(off_(adj))).The feed smoothness and discharge sufficiency analyses of the experimental results show that compared to the traditional double threshold average voltage method,the FPCC method reduces the number of long-distance retreats by 64%and improves the effective discharge time by 40%.

关键词： Micro-electrical discharge machining(micro-EDM) Electrode feed control Discharge pulse control Machining surface quality

基于Galerkin Nodal方法的升潜条件对并联通道流动不稳定性影响分析研究

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核动力工程 2015年第S2期36卷 102-107页

作者：申亚欧陈伟丁书华钱立波中国核动力研究设计院核反应堆系统设计技术重点实验室成都610041

针对矩形并联通道,基于Galerkin Nodal法建立了升潜条件下并联通道流动不稳定性分析集总参数模型,包括静止条件下并联通道流动不稳定性模型和升潜条件附加力模型,并基于此模型分析了升潜条件下并联通道流动不稳定性的影响。分析结果表明... 详细信息

针对矩形并联通道,基于Galerkin Nodal法建立了升潜条件下并联通道流动不稳定性分析集总参数模型,包括静止条件下并联通道流动不稳定性模型和升潜条件附加力模型,并基于此模型分析了升潜条件下并联通道流动不稳定性的影响。分析结果表明:升潜幅值对并联通道流动不稳定性影响不明显。当升潜加速度频率与系统脉动频率差别较大时,升潜加速度频率对界限功率影响不大;当升潜加速度频率与系统脉动频率相近时,会显著降低系统界限功率;当系统处于非对称工况时,升潜条件的影响将显著增强。

关键词：并联通道流动不稳定性升潜条件

Recovery and in-situ reduction of precious metals by graphdiyne and graphdiyne oxide for antibacterial use

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Rare Metals 2024年第4期43卷 1747-1757页

作者： Ming-Ji Jiang ya-Na Zhang Ling-shen Meng Jing Kang Yong-Jun Li Alideertu Dong College of Chemistry and Chemical Engineering Inner Mongolia UniversityHohhot010021China Engineering Research Center of Dairy Quality and Safety Control Technology Ministry of EducationInner Mongolia UniversityHohhot010021China Department of Chemistry University of ZurichCH-8057ZurichSwitzerland Laboratory of Organic Solids and Beijing National Laboratory for Molecular Sciences Institute of ChemistryChinese Academy of SciencesBeijing100190China

Based on the in-situ self-reduction and chemical stability,graphdiyne(GDY)and graphdiyne oxide(GDYO)are used as trapping agents to investigate the ability for recovering Au^(3+),Ag^+,and Pd^(2+)under different pH values and interfering *** strong acidity at pH=1,these two agents demonstrate high select recovery towards the three precious metal ions,which could be insitu reduced to nanoparticles(NPs).In addition,superparamagnetic Fe_(3)O_(4)NPs are deposited on the surfaces of GDY and *** magnetic responses enable GDYFe_(3)O_(4)to recover precious metals conveniently and efficiently by the aid of an external magnetic *** study also confirms the antibacterial activity of the as-recovered NPs deposited on GDY and GDYO against Escherichia coli and Staphylococcus aureus(1×10^(5)colony-forming unit(CFU)·mL^(-1)),and the antibacterial rates are 100%.This strategy of recovering precious metals and subsequently reusing to combat pathogens will be of great significance for environmental remediation and biomedical applications.

关键词： Graphdiyne In-situ reduction Recovery Precious metals Antibacterial