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波长可调谐氮化硅外腔半导体激光器

中国激光 2024年第13期51卷 58-65页

作者：陈怡茗丛庆宇贾连希邱阳赵兴岩郑少南董渊钟其泽胡挺上海大学微电子学院上海201800摘要波长可调谐外腔半导体激光器在片上全光通信和片上光子器件互连集成

波长可调谐外腔半导体激光器在片上全光通信和片上光子器件互连集成中发挥着至关重要的作用。采用两个半径不同的微环谐振器和两种不同结构的马赫-曾德尔干涉仪,设计了一种基于厚度为700 nm的氮化硅波导的外腔反射镜,并采用大马士革工... 详细信息

波长可调谐外腔半导体激光器在片上全光通信和片上光子器件互连集成中发挥着至关重要的作用。采用两个半径不同的微环谐振器和两种不同结构的马赫-曾德尔干涉仪,设计了一种基于厚度为700 nm的氮化硅波导的外腔反射镜,并采用大马士革工艺制作了外腔反射镜。结合Ⅲ-Ⅴ族反射型半导体光放大器和可调谐氮化硅外腔反射镜,通过对移相器热电极电压、可调耦合器热电极电压和微环谐振器热电极电压等参数进行调节,获得了最大调谐范围为55 nm、边模抑制比超过40 dB的外腔半导体激光器。

关键词：激光器外腔半导体激光器微环谐振器马赫-曾德尔干涉仪大马士革工艺

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近红外单层大视场角超透镜研究

半导体光电 2024年第4期45卷 530-535页

作者：陈若卉鲁依林赵兴岩邱阳郑少南钟其泽董渊胡挺上海大学微电子学院上海大学上海市智能感知芯片技术协同创新中心上海201800

大视场角透镜是成像系统的重要组成部分。为实现大视场成像效果,传统光学中需要由多个镜片组成的透镜组来纠正不同入射光角度带来的像差,从而在整个视场范围内获得无畸变的清晰图像。文章设计并制造了一种近红外超透镜,由分布在衬底两... 详细信息

大视场角透镜是成像系统的重要组成部分。为实现大视场成像效果,传统光学中需要由多个镜片组成的透镜组来纠正不同入射光角度带来的像差,从而在整个视场范围内获得无畸变的清晰图像。文章设计并制造了一种近红外超透镜,由分布在衬底两侧的单层超表面和金属光阑组成。该器件能够有效抑制像差,在940 nm波长下实现120°的广角成像。实验结果证明所制造的器件在设计的视场角范围内具有良好的聚焦性能,平均实验聚焦效率为45%。

关键词：超表面超透镜大视场角近红外光学设计

Study on the tribological properties of metal rolling bearing under lubrication with diketone lubricants

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Science China(Technological Sciences) 2024年第7期67卷 2003-2017页

作者： DU shaonan ZHANG ChenHui LUO Zhi State Key Laboratory of Tribology in Advanced Equipment Tsinghua UniversityBeijing 100084China Beijing National Laboratory of Molecular Sciences CAS Key Laboratory of Engineering PlasticsInstitute of ChemistryChinese Academy of SciencesBeijing 100190China

In this article, 1-(4-ethylphenyl)-nonane-1,3-dione(0206) was prepared by Claisen condensation. By mixing 0206, chelate, and base oil in a ratio of 3.2:4.8:2, a diketone lubricant(PAO=14(20%)) that can achieve superlubricity was prepared and applied to bearing lubrication experiments. The experimental results show that when the bearing was lubricated by base oil, the friction coefficient(COF) and temperature rise decreased with the decrease of the viscosity of PAO. When PAO=14(20%) was used as the lubricant, the COF of the bearing was the lowest(0.001), and the wear morphology was comparable to that of the bearing lubricated with commercial lubricant. Compared with the base oil with the same viscosity, it is found that the COF and temperature rise of the bearing lubricated by PAO=14(20%) were lower under any experimental conditions. And when the amount of lubricant added was 10 μL, the COF of the bearing lubricated by PAO=14(20%) reached a very low value(0.0004).Bearing ball surface analysis identified the formation of diketone adsorption films. Combined with the previous PAO=14(20%)superlubricity mechanism, it was considered that the occurrence of tribochemical reaction and the bearing effect of chelates were the main reasons for the existence of ultra-low friction coefficient and low wear. In addition, when there were polar molecules in the lubricant, they were adsorbed on the metal surface through tribochemical reactions, resulting in many irregular pits on the surface.

关键词： superlubricity diketone chelate tribochemical recations bearing lubrication

Combination of diketone and PAO to achieve macroscale oil-based superlubricity at relative high contact pressures

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Friction 2024年第5期12卷 869-883页

作者： shaonan DU Chenhui ZHANG Zhi LUO State Key Laboratory of Tribology in Advanced Equipment Tsinghua UniversityBeijing100084China Beijing National Laboratory of Molecular Sciences CAS Key Laboratory of Engineering PlasticsInstitute of ChemistryChinese Academy of SciencesBeijing100190China

1-(4-ethylphenyl)-nonane-1,3-dione(0206)is an oil-soluble liquid molecule with rod-like *** this study,the chelate(0206-Fe)with octahedral structure was prepared by the reaction of ferric chloride and 1,*** experimental results show that when using 0206 and a mixed solution containing 60%0206-Fe and 40%0206(0206-Fe(60%))as lubricants of the steel friction pairs,superlubricity can be achieved(0.007,0.006).But their wear scar diameters(WSD)were very large(532µm,370µm),which resulted in the pressure of only 44.3 and 61.8 MPa in the contact areas of the friction *** 0206-Fe(60%)was mixed with PAO6,it was found that the friction coefficient(COF)decreased with increase of 0206-Fe(60%)in the *** the ratio of 0206-Fe(60%)to PAO6 was 8:2(PAO6(20%)),it exhibited better comprehensive tribological properties(232.3 MPa).Subsequent studies have shown that reducing the viscosity of the base oil in the mixed solution helped to reduce COF and increased *** the COF,contact pressure,and running-in time,it was found that the mixed lubricant(Oil3(20%))prepared by the base oil with a viscosity of 19.7 mPa·s(Oil3)and 0206-Fe(60%)exhibited the best tribological properties(0.007,161.4 MPa,3,100 s).

关键词： diketone oil-based lubricants chelate superlubricity

The impact of ester groups on 1,8-naphthalimide electron transport material in organic solar cells

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Chinese Journal of Structural Chemistry 2024年第6期43卷 18-21页

作者： shaonan Liu Shuixing Dai Minghua Huang School of Materials Science and Engineering Ocean University of ChinaQingdao266100China

Organic solar cells(OSCs)offer significant advantages,including light weight,mechanical flexibility,solution processability and translucency[1,2].In recent years,significant developments have been taken in the realm of research involving polymer donors[3,4],non-fullerene acceptors[5,6],and interlayer materials[7].The progress in these areas has propelled the field of OSCs towards increased power conversion efficiency(PCE)and improved device *** interface engineering of OSCs involves the optimization of hole transport materials and electron transport materials(ETMs)[8].Typically,ETMs play a crucial role in promoting charge extraction and transfer,contributing to the enhancement of Ohmic contact between the metal electrode and the active layer,thereby reducing the cathode work function(WF)[9].

关键词： transport thereby electron

Progresses and Prospects of Asymmetrically Coordinated Single Atom Catalysts for Lithium-Sulfur Batteries

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Energy & Environmental Materials 2024年第4期7卷 48-63页

作者： Rong Zhou shaonan Gu Meng Guo Shuzheng Xu Guowei Zhou Key Laboratory of Fine Chemicals in Universities of Shandong Jinan Engineering Laboratory for Multi-scale Functional Materials School of Chemistry and Chemical Engineering Qilu University of Technology(Shandong Academy of Sciences)

Lithium-sulfur batteries (LSBs) are widely regarded as promising next-generation batteries due to their high theoretical specific capacity and low material ***,the practical applications of LSBs are limited by the shuttle effect of lithium polysulfides (LiPSs),electronic insulation of charge and discharge products,and slow LiPSs conversion reaction kinetics.

关键词： asymmetrical coordination conversion catalysis Li-S batteries shuttle effect single atom catalysts

Silicon substrate-integrated hollow waveguide for miniaturized optical gas sensing

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Photonics Research 2022年第1期10卷 261-268页

作者： shaonan zheng HONG CAI LINFANG XU NANXI LI ZHONGHUA GU YAO ZHANG WEIGUO CHEN YANYAN ZHOU QINGXIN ZHANG LENNON YAO TING LEE Institute of Microelectronics A*STAR(Agency for ScienceTechnology and Research)Singapore 138634Singapore

Gas sensors have a wide variety of *** various existing gas sensing technologies,optical gas sensors have outstanding *** development of the Internet of Things and consumer electronics has put stringent requirements on miniaturized gas sensing ***,we demonstrate a chip-scale silicon substrate-integrated hollow waveguide(Si-iHWG) to serve as an optical channel and gas cell in an optical gas *** is fabricated through silicon wafer etching and wafer *** Si-i HWG chip is further assembled with an off-chip light source and detector to build a fully functional compact nondispersive infrared(NDIR) CO_(2) *** chip size is 10 mm × 9 mm,and the dimension of the sensor excluding the microcontroller board is 50 mm × 25 mm × 16 *** chip solution with compactness,versatility,robustness,and low cost provides a cost-effective platform for miniaturized optical sensing applications ranging from air quality monitoring to con-sumer electronics.

关键词： waveguide optical cost

Parameter selection for the hydroconversion of waste polyethylene plastic under mild conditions: A comprehensive evaluation

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Science China(Technological Sciences) 2024年第8期67卷 2413-2426页

作者： CHENG LeiLei CHEN RuiZhe ZHU WeiQiang TIAN shaonan GU Jing YUAN HaoRan CHEN Yong Guangzhou Institute of Energy Conversion Chinese Academy of SciencesGuangzhou 510640China School of Energy Science and Engineering University of Science and Technology of ChinaHefei 230026China Institute of Process Engineering Chinese Academy of SciencesBeijing 100190China

The hydrogenolysis/hydrocracking of waste polyethylene(PE) has recently been intensively studied, with the general pursuit of low-temperature reaction conditions, increased oil-phase yield, and narrower carbon chain distribution. Before this, we utilized a ball-milled ZSM-22 catalyst loaded with Ru nanoparticles(NPs), which exhibited excellent hydroconversion performance. It deconstructed PE into >80 wt.% oil products under low temperatures and short reaction times. Herein, we investigated the influence of varying temperature/pressure parameters on the degree of specific hydrocracking/internal hydrogenolysis/terminal hydrogenolysis reactions. From the comprehensive energy efficiency perspective, including stirring, reaction, and product separation, as well as taking into account the degree of product isomerization and catalyst lifespan, we analyzed the optimization of parameters. This research abandons the notion that lower temperatures are better and proposes a more comprehensive evaluation framework for low-consumption hydroconversion of PE to produce high-value products.

关键词： plastic upcycling polyethylene hydrocracking hydrogenolysis comprehensive energy efficiency

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Mitigation of Optical Multipath Interference Algorithms in IM-DD Transmission System

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China Communications 2024年第4期21卷 1-9页

作者： Huo Jiahao Zhu Jin Zhu Zuqing Zhang Xiaoying Liu shaonan Tao Jianlong Wei Huangfu School of Computer and Communication Engineering University of Science and Technology BeijingBeijing 100083China School of Information Science and Technology University of Science and Technology of ChinaHefei 230026China

This paper aimed to propose two algorithms,DA-M and RF-M,of reducing the impact of multipath interference(MPI)on intensity modulation direct detection(IM-DD)systems,particularly for four-level pulse amplitude modulation(PAM4)***-M reduced the fluctuation by averaging the signal in blocks,RF-M estimated MPI by subtracting the decision value of the corresponding block from the mean value of a signal block,and then generated interference-reduced samples by subtracting the interference signal from the product of the corresponding MPI estimate and then weighting *** paper firstly proposed to separate the signal before decision-making into multiple blocks,which significantly reduced the complexity of DA-M and *** results showed that the MPI noise of 28 GBaud IMDD system under the linewidths of 1e5 Hz,1e6 Hz and 10e6 Hz can be effectively alleviated.

关键词： IM-DD multipath interference PAM4