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Hydroxyapatite-containing PEO-coating design for biodegradable Mg-0.8Ca alloy: Formation and corrosion behaviour

Journal of Magnesium and Alloys 2023年第12期11卷 4468-4484页

作者： A.s.Gnedenkov s.L.sinebryukhov v.s.Filonina s.v.Gnedenkov Institute of Chemistry of FEB RAs 159 Pr.100-letiya VladivostokaVladivostok690022Russian Federation

In this study, the biocompatible protective coating was formed using plasma electrolytic oxidation(PEO) on bioresorbable Mg-0.8Ca alloy. The composition of the formed coating was studied using XRD, sEM-EDX analysis, and micro-Raman spectroscopy. The uniform distribution of hydroxyapatite over the thickness of protective PEO-layer was established. Using traditional(EIs, PDP, OCP) and local scanning electrochemical methods(svET, sIET with H^(+)-selective microelectrode), the level of protective properties of PEO-layer in a biological environment(mammalian cell culture medium, MEM) was determined. It was established that modification of Mg-0.8Ca alloy surface by PEO contributes to a significant increase in the corrosion resistance of the surface layer, making it possible to control the process of material‘s biodegradation. The maximum local electrochemical activity was recorded after 72 h of testing, while for the uncoated sample,intense corrosion degradation was recorded in the first 12 min of exposure to the cell culture medium. Formation of the PEO-coating results in a twofold decrease in the corrosion current density(2.8·10^(-6)A cm^(-2)) and an increase in the impedance modulus measured at a low frequency(1.7·10^(4)Ω cm^(2)) in comparison with the uncoated material(9.5·10^(-6)A cm^(-2);8.1·10^(3)Ω cm^(2)). The mechanism of material bioresorption was established and a model for biodegradation process of Mg-0.8Ca alloy with hydroxyapatite-containing PEO-coating in MEM was proposed. Analysis of these results and comparing with others obtained by various scientific groups indicate the prospects for application of biocompatible PEO-coating on Mg-Ca alloy in implant surgery.

关键词： Magnesium-calcium alloy Biodegradation Implant surgery Plasma electrolytic oxidation Electrochemistry Minimum essential medium Hydroxyapatite

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Modelling Magnetoresistance Effect in Limited Anisotropic semiconductors

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Chinese Physics Letters 2017年第7期34卷 212-214页

作者： Filippov v.v. Mitsuk s.v. Lipetsk state Pedagogical University of P. P. semenov-Tyan-shansky Lipetsk 398020 the Russian Federation Lipetsk state Technical University Lipetsk 398600 the Russian Federation

A macroscopic model of the magnetoresistance effect in fimited anisotropic semiconductors is built. This model allows us to solve the problem of measurement of physical magnetoresistance components of crystals and films. Based on a unified mathematical model the method is worked out enabling us to measure tensor components of the specific electrical resistance and the relative magnetoresistance of anisotropic semiconductors simultaneously.

关键词： Modelling Magnetoresistance Effect in Limited Anisotropic semiconductors

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Generalised tanh-shaped hyperbolic potential: Klein–Gordon equation's bound state solution

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Communications in Theoretical Physics 2023年第7期75卷 22-32页

作者： v H Badalov s v Badalov Institute for Physical Problems Baku State University1148 BakuAzerbaijan Theoretical Materials Physics Paderborn UniversityD-33098 PaderbornGermany Theoretical PhysicsⅦ University of BayreuthD-95440 BayreuthGermany

The development of potential theory heightens the understanding of fundamental interactions in quantum *** this paper,the bound state solution of the modified radial Klein–Gordon equation is presented for generalised tanh-shaped hyperbolic potential from the Nikiforov–Uvarov *** resulting energy eigenvalues and corresponding radial wave functions are expressed in terms of the Jacobi polynomials for arbitrary l *** is also demonstrated that energy eigenvalues strongly correlate with potential parameters for quantum *** particular cases,the generalised tanh-shaped hyperbolic potential and its derived energy eigenvalues exhibit good agreement with the reported ***,the rovibrational energies are calculated for three representative diatomic molecules,namely H2,HCl and *** lowest excitation energies are in perfect agreement with experimental ***,the potential model is displayed to be a viable candidate for concurrently prescribing numerous quantum systems.

关键词： Klein-Gordon equation hyperbolic potential Nikiforov-Uvarov method diatomic molecules

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Olfactory receptors in neural regeneration in the central nervous system

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Neural Regeneration Research 2025年第9期20卷 2480-2494页

作者： Rafael Franco Claudia Garrigós Toni Capó Joan serrano-Marín Rafael Rivas-santisteban Jaume Lillo Molecular Neurobiology Laboratory Department of Biochemistry and Molecular BiomedicineFacultat de BiologiaUniversitat de BarcelonaBarcelonaSpain CiberNed Network Center for Biomedical Research in Neurodegenerative Diseases Spanish National Health Institute Carlos ⅢMadridSpain school of Chemistry Universitat de BarcelonaBarcelonaSpain Department of Biochemistry and Physiology School of Pharmacy and Food SciencesUniversitat de BarcelonaBarcelonaSpain Laboratory of Computational Medicine Biostatistics UnitFaculty of MedicineAutonomous University of BarcelonaCampus BellaterraBarcelonaSpain

Olfactory receptors are crucial for detecting odors and play a vital role in our sense of smell,influencing behaviors from food choices to emotional *** receptors also contribute to our perception of flavor and have potential applications in medical diagnostics and environmental *** ability of the olfactory system to regenerate its sensory neurons provides a unique model to study neural regeneration,a phenomenon largely absent in the central nervous *** gained from how olfactory neurons continuously replace themselves and reestablish functional connections can provide strategies to promote similar regenerative processes in the central nervous system,where damage often results in permanent *** the molecular and cellular mechanisms underpinning olfactory neuron regeneration could pave the way for developing therapeutic approaches to treat spinal co rd injuries and neurodegenerative diseases like Alzheimer's *** ctory receptors are found in almost any cell of eve ry orga n/tissue of the mammalian *** ectopic expression provides insights into the chemical structures that can activate olfactory *** addition to odors,olfactory receptors in ectopic expression may respond to endogenous compounds and molecules produced by mucosal colonizing *** analysis of the function of olfactory receptors in ectopic expression provides valuable information on the signaling pathway engaged upon receptor activation and the receptor's role in proliferation and cell differentiation *** review explo res the ectopic expression of olfa ctory receptors and the role they may play in neural regeneration within the central nervous system,with particular attention to compounds that can activate these receptors to initiate regenerative *** suggests that olfactory receptors could serve as potential therapeutic targets for enhancing neural repair and recovery following central nervous syste

关键词： adenosine receptors adrenergic receptors ectopic expression G proteincoupled receptors glia neurons

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synthesis of MoO_3 by glow discharge in contact with water

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Plasma science and Technology 2019年第2期21卷 97-104页

作者： A v KHLYUsTOvA N A sIROTKIN A s KRAYEv v A TITOv A v AGAFONOv Laboratory of Chemistry of Carbohydrate Coordination Compounds and supermolecular system G.A.Krestov Institute of Solution Chemistry of RAS

An atmospheric pressure glow discharge was ignited between a molybdenum anode and the water surface of a cathode for the synthesis of MoO_3 powders. The action of glow discharge leads to the non-equilibrium evaporation of water, sputtering of the metal anode and formation of molybdenum(vI) oxide, which deposited on the anode. The chemical composition and morphology of the obtained powder were performed by using x-ray diffraction spectroscopy,scanning electron microscopy and Fourier transform infrared spectroscopy. It was found that the synthesized powders are pure α-MoO_3. The possible mechanism of the formation of molybdenum trioxide during glow discharge treatment was described. The photocatalytic performance of MoO_3 was estimated through the degradation of Rhodamine B under dark and Uv irradiation conditions. Orthorhombic MoO_3 exhibited the best photocatalytic activity for the photodegradation of Rhodamine B of 100% under Uv irradiation for 15 min.

关键词： molybdenum oxide glow discharge photocatalytic activity

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Investigation of thermal evolution of nanodomain structures in nonlinear barium sodium niobate crystals

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Chinese Optics Letters 2008年第2期6卷 143-145页

作者： s.v.Ivanova P.N.Lebedev Physical Institute of RAs Leninsky pr.53 Moscow 119991Russia

By the 90° elastic light scattering investigation and far field observation in the range of 20 - 800 ℃, the relation between behavior of light scattering anomalies and evolution of nanodomain structures in lattice of barium sodium niobate （Ba2NaNb5O15, BsN） crystal was clarified. The correlation between anomalies on the temperature curves of the elastic light scattering intensity and temperature transformations of nanodomains was studied by X-ray and electron microscope methods. Phase transition near 500 ℃ and movement in field of scattering light could be explained by appearance of a new incommensurate phase.

关键词： Elastic scattering Light fields Light intensity Light scattering Transmission electron microscopy X ray microscopy

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solution‑Processed Thin Film Transparent Photovoltaics:Present Challenges and Future Development

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Nano-Micro Letters 2025年第2期17卷 566-600页

作者： Tianle Liu Munerah M.s.Almutairi Jie Ma Aisling stewart Zhaohui Xing Mengxia Liu Bo Hou Yuljae Cho UM-sJTU Joint Institute Shanghai Jiao Tong UniversityShanghai 200240People’s Republic of China school of Physics and Astronomy Cardiff UniversityCardiff CF243AAWalesUK Department of Electrical and Computer Engineering Yale UniversityNew HavenCT 06511USA Energy sciences Institute Yale UniversityWest HavenCT 06516USA Future Photovoltaics Research Center Global Institute of Future TechnologyShanghai Jiao Tong UniversityShanghai 200240People’s Republic of China

Electrical energy is essential for modern society to sustain economic *** soaring demand for the electrical energy,together with an awareness of the environmental impact of fossil fuels,has been driving a shift towards the utilization of solar ***,traditional solar energy solutions often require extensive spaces for a panel installation,limiting their practicality in a dense urban *** overcome the spatial constraint,researchers have developed transparent photovoltaics(TPv),enabling windows and facades in vehicles and buildings to generate electric *** TPv advancements are focused on improving both transparency and power output to rival commercially available silicon solar *** this review,we first briefly introduce wavelength-and non-wavelengthselective strategies to achieve *** of merit and theoretical limits of TPvs are discussed to comprehensively understand the status of current TPv *** we highlight recent progress in different types of TPvs,with a particular focus on solution-processed thin-film photovoltaics(Pvs),including colloidal quantum dot Pvs,metal halide perovskite Pvs and organic *** applications of TPvs are also reviewed,with emphasis on agrivoltaics,smart windows and ***,current challenges and future opportunities in TPv research are pointed out.

关键词： Transparent semiconductors solution-processable transparent solar cell Emerging solar cell materials Buildingintegrated photovoltaics

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Esterification of levulinic acid to n-butyl levulinate over heteropolyacid supported on acid-treated clay

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Journal of Natural Gas Chemistry 2011年第1期20卷 18-24页

作者： s. Dharne v. v. Bokade Catalysis Division National Chemical Laboratory (CSIR)

Levulinic acid has been identified as a promising green, biomass-derived platform chemical. n-Butyl levulinate is used as an important intermediate having diverse applications. The present work focuses on the synthesis of n-butyl levulinate by esterification of levulinic acid with n-butanol using heteropolyacid （HPA） supported on acid-treated clay montmorillonite （K10）. 20% （w/w） dodecatungestophosphoric acid （DTPA） supported on K10 was found to be the most efficient catalyst with 97% levulinic acid conversion and 100% selectivity towards n-butyl levulinate. Effects of various process parameters were studied to examine the efficacy of 20% （w/w） DTPA/K10 for optimization of the activity.

关键词： levulinic acid n-butanol dodectungestophosphoric acid K10 n-butyl levulinate

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synthesis and photoluminescence studies of Ba(Gd,Ln)B_9O_(16):Eu^(3+)(Ln=La,Y) phosphors for n-Uv LED lighting and display devices

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Journal of Rare Earths 2015年第2期33卷 140-147页

作者： v.v.Rangari s.J.Dhoble Department of Physics RTM Nagpur University

BaGdB9O16：Eu^3＋ and Ba（Gd,Ln）B9O16：Eu^3＋（Ln=La, Y） phosphors were synthesized by solid state diffusion method. The X-ray diffraction, scanning electron microscopy（sEM） and photoluminescence properties were investigated. The as-synthesized BaGdB9O16：Eu^3＋ and Ba（Gd,Ln）B9O16：Eu^3＋（Ln=La, Y） phosphors showed strong red emission under ultraviolet light excitation. By partially substituting Gd^3＋ by La^3＋ and Y^3＋ ions in the host BaGdB9O16：Eu^3＋ materials, the maximum emission intensity was observed for the optimum composition of BaGd0.91La0.8B9O16Eu0.01 phosphor. The experimental results indicated that the Eu doped BaGdB9O16 and Ba（Gd,Ln）B9O16（Ln=La, Y） phosphors were promising red phosphors, which might find potential applications in near-Uv excited LED lighting as well as display devices. Comparison of as-synthesized phosphors with standard phosphor used in CFL（compact fluorescent lamp） was also done. Energy transfer mechanism of Gd^3＋ to Eu^3＋ was also discussed in this paper.

关键词： phosphor solid state diffusion display devices photoluminescence rare earths

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Processes underlying the laser photochromic effect in colloidal plasmonic nanoparticle aggregates

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Chinese Physics B 2020年第3期29卷 412-419页

作者： A E Ershov v s Gerasimov I L Isaev A P Gavrilyuk s v Karpov Institute of Computational Modeling sB RAs 660036KrasnoyarskRussia siberian Federal University Krasnoyarsk660041Russia Kirensky Institute of Physics Federal Research Center KSC SB RAS660036KrasnoyarskRussia siberian state University of science and Technology Krasnoyarsk 660014Russia

We have studied the dynamic and static processes occurring in disordered multiparticle colloidal Ag aggregates with natural structure and affecting their plasmonic absorption spectra under pico-and nanosecond pulsed laser radiations, as well as the physical origin responsible for these processes. We have shown that depending on the duration of the laser pulse,the mechanisms of laser modification of such aggregates can be associated both with changes in the resonant properties of the particles due to their heating and melting(picosecond irradiation mode) and with the particle shifts in the resonant domains of the aggregates(nanosecond pulses) which depend on the wavelength, intensity, and polarization of the *** mechanisms result in formation of a narrow dip in the plasmonic absorption spectrum of the aggregates near the laser radiation wavelength and affect the shape and position of the dip. The effect of polydispersity of nanoparticle aggregates on laser photochromic reaction has been studied.

关键词： nanoparticle surface plasmon resonance photochromic process pulsed laser radiation

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