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The role of land use on the local climate and air quality during calm inter-monsoon in a tropical city

Geoscience Frontiers 2019年第2期10卷 405-415页

作者： M.C.G.Ooi A.Chan M.J.Ashfold M.Y.Oozeer k.I.Morris s.s.k.kong Department of Atmospheric science "Central University" Department of Civil Engineering University of Nottingham Malaysia Campus school of Environmental and Geographical sciences University of Nottingham Malaysia Campus Department of Geography and Environmental Management University of Waterloo Center of Excellence for sustainable Innovation and Research Initiative (CEsIRI) Department of Mechanical Engineering Ashesi University College

The modification of land use is known to be a major climate change driver to the local warming and air quality in cities. Despite the reduction of NOx over the years, the selangor state has captured a higher level of O_3 in year 2011. The measurement result has shown that the surge in O_3 level was attributed to the reduction of NO_x/NMHC ratio. This paper hence attempted to identify the role of land use change from 1999 to 2011 on the ground ozone air quality in the tropical urban conurbation, Greater kuala Lumpur(GkL), selangor, Malaysia. With the state-of-the-art chemical weather prediction tool, WRFChem, the external synoptic factors and emission inventory were controlled when comparing the chronological land use changes. The results showed that the urban-induced temperature and wind bias in the tropical region has induced stronger wind to disperse the NO_x and carries the TVOC from the suburban to the downwind urban region. The reduction of NO_x/TVOC has gradually shifted towards the optimum O_3 formation regime in 2011. The formation of highly concentrated ozone becomes more sensitive to the increment of TVOC as the NO_x level reduces in the urban. This highlights the essential involvement of TVOC in the ozone formation in lieu of the NOx reduction in the tropical city, a region with growing emitter of reactive biogenic ozone precursors.

关键词： Land use change Urban Ground ozone TVOC WRF-Chem Tropics

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Understanding the corrosion and bio-corrosion behaviour of Magnesium composites – a critical review

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Journal of Magnesium and Alloys 2024年第3期12卷 890-939页

作者： Prithivirajan sekar s.k.Panigrahi Department of Mechanical Engineering Indian Institute of Technology MadrasChennai600036India Applied Magnesium Research Center Center of Excellence in Materials and Manufacturing for Futuristic MobilityIndian Institute of Technology MadrasChennai600036India

Realising the potential of Magnesium(Mg),several globally leading ventures have invested in the Mg industry,but their relatively poor corrosion resistance is a never ending saga till *** corrosion and bio-corrosion behaviour of Mg has gained research attention and still remains a hot topic in the application of automobile,aerospace and biomedical *** intrinsic high electrochemical nature of Mg limits their utilization in diverse *** scenario has prompted the development of Mg composites with an aim to achieve superior corrosion and bio-corrosion *** present review enlightens the influence of grain size(Gs),secondary phase,texture,type of matrix and reinforcement on the corrosion and bio-corrosion behaviour of Mg ***,the corrosion and bio-corrosion behaviour of Mg composites manufactured by primary and secondary processing routes are ***,the comprehensive corrosion and bio-corrosion mechanisms of these Mg composites are ***,the individual role of Gs,texture and corrosive medium on corrosion and bio-corrosion behaviour of Mg composites are clarified and *** challenges encountered,unanswered issues in this field are explained in detail and accordingly the scope for future research is *** review is presented from basic concrete background to advanced corrosion mechanisms with an aim of creating interest among the readers like students,researchers and industry experts from various research ***,the corrosion and bio-corrosion behaviour of Mg composites are critically reviewed for the first time to:(i)contribute to the body of knowledge,(ii)foster research and development,(iii)make breakthrough,and(iv)create life changing innovations in the field of Mg composite corrosion.

关键词： Corrosion Bio corrosion Magnesium alloys Magnesium composites Magnesium implants.

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A new route to weak force sensing beyond sQL:squeezed magnons in cavity magnomechanics

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science China(Physics,Mechanics & Astronomy) 2024年第10期67卷 166-167页

作者： s.k.Özdemir Department of Engineering science and Mechanics and Materials Research Institute(MRI)The Pennsylvania State UniversityUniversity ParkPA 16802USA

Quantum mechanics imposes limits on measurement accuracy through quantum noise which typically has two components:First is the shot noise originating from vacuum fluctuations and referred to as the imprecision *** is ... 详细信息

关键词： quantum typically vacuum

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Dispersion effect of nano-structure pyrolytic carbon on mechanical,electrical,and microstructural characteristics of cement mortar composite

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International Journal of smart and Nano Materials 2024年第3期15卷 534-578页

作者： N.k.karthikeyan s.Elavenil school of Civil Engineering Vellore Institute of TechnologyChennaiIndia

In material science,converting waste into nanomaterials by green technologies highlights the interest in producing sus-tainable carbon nanomaterial(sCN).This study first-ever uti-lized tyre-char as a Nano-structure Pyrolytic Carbon(NsPC)to develop electrically conductive *** other car-bon nanomaterials,the efficiency of NsPC particle as an sCN in developing electrically conductive composites was investi-gated in terms of dispersion,mechanical,water absorption,electrical resistivity,and *** results of sedi-mentation and zeta potential(-19 mV)showed the excellent dispersion of NsPC particle in water with the combined effect of superplasticizer and *** compressive(40.37%)and flexural strength(10.76%)than that of plain cement mortar composite(CMC)is achieved with 2 wt.%and 1.5 wt.%of NsPC particle,*** water absorption rate and volume of permeable voids were reduced,exhibiting less *** percolation zone of AC and DC resis-tivity of NsPC composite ranges between 1 and 2 wt.%,and the established percolation threshold is at 2 wt.%.XRD analysis showed C-s-H formation consistently increased with curing age,and HR-sEM with EDAX analysis exhibits the dense micro-structure and well-distributed NsPC particle at the *** experimental outcomes significantly enhanced the relia-bility and provided a framework for tailoring NsPC particle as sCN for developing electrically conductive composite.

关键词： sustainable nanomaterial dispersion mechanical properties electrical resistivity microstructure analysis

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High-precision inverse potentials for neutron-proton scattering using piece-wise smooth Morse functions

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Chinese Physics C 2024年第10期48卷 201-213页

作者： Ayushi Awasthi Arushi sharma Ishwar kant O.s.k.s.sastri Department of Physics and Astronomical science Central University of Himachal PradeshDharmshala176215India

The aim of this study is to construct inverse potentials for various ℓ-channels of neutron-proton scattering using a piece-wise smooth Morse function as a *** phase equations for single-channel states and the coupled equations of multi-channel scattering are solved numerically using the 5^(th) order Runge-kutta *** employ a piece-wise smooth reference potential comprising three Morse functions as the initial *** a machine learning-based genetic algorithm,we optimize the model parameters to minimize the mean-squared error between simulated and anticipated phase *** approach yields inverse potentials for both single and multichannel scattering,achieving convergence to a mean-squared error≤10^(-3).The resulting scattering lengths"a_(0)"and effective ranges"r"for ^(3)s_(1) and ^(1)s_(0) states,expressed as[a_(0),r],are found to be[5.445(5.424),1.770(1.760)]and[–23.741(–23.749),2.63(2.81)],respectively;these values are in excellent agreement with experimental ***,the calculated total scattering cross-sections are highly consistent with their experimental counterparts,having a percentage error of less than 1%.This computational approach can be easily extended to obtain interaction potentials for charged particle scattering.

关键词： inverse potentials neutron-proton scattering piece-wise smooth Morse function phase function method reference potential approach genetic algorithm

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Enhancing Multicriteria-Based Recommendations by Alleviating scalability and sparsity Issues Using Collaborative Denoising Autoencoder

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Computers, Materials & Continua 2024年第2期78卷 2269-2286页

作者： s.Abinaya k.Uttej kumar school of Computer science&Engineering Vellore Institute of TechnologyChennaiTamilnadu600127India

A Recommender system(Rs)is a crucial part of several firms,particularly those involved in *** conventional Rs,a user may only offer a single rating for an item-that is insufficient to perceive consumer ***,businesses in industries like e-learning and tourism enable customers to rate a product using a variety of factors to comprehend customers’*** the other hand,the collaborative filtering(CF)algorithm utilizing AutoEncoder(AE)is seen to be effective in identifying user-interested ***,the cost of these computations increases nonlinearly as the number of items and users *** triumph over the issues,a novel expanded stacked autoencoder(EsAE)with kernel Fuzzy C-Means Clustering(kFCM)technique is proposed with two *** the first phase of offline,the sparse multicriteria rating matrix is smoothened to a complete matrix by predicting the users’intact rating by the EsAE approach and users are clustered using the kFCM *** the next phase of online,the top-N recommendation prediction is made by the EsAE approach involving only the most similar user from multiple *** the EsAE_kFCM model upgrades the prediction accuracy of 98.2%in Top-N recommendation with a minimized recommendation generation *** experimental check on the Yahoo!Movies(YM)movie dataset and TripAdvisor(TA)travel dataset confirmed that the EsAE_kFCM model constantly outperforms conventional Rs algorithms on a variety of assessment measures.

关键词： Recommender systems multicriteria rating collaborative filtering sparsity issue scalability issue stacked-autoencoder kernel Fuzzy C-Means Clustering

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Conformation and Counterion Distribution of Polyelectrolyte in solution as Viewed from Dielectric Approach

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Chinese Journal of Polymer science 2024年第9期42卷 1278-1301,I0005页

作者： kong-shuang Zhao College of Chemistry Beijing Normal UniversityBeijing 100875China

Polyelectrolyte solutions are more variable than uncharged macromolecule due to electrical interaction between charged molecules and surrounding ***,the subject of polyelectrolyte solutions has attracted a wide range of interests in both basic and applied research,and has also been extensively ***,the understanding of the molecular dynamics and conformation of polyelectrolytes in solution remains to be deepened,and universal consensus on some key issues have not been *** methods have contributed to solving the above problems in different ways,including dielectric relaxation spectroscopy(DRs).In this perspective,we briefly reviewed the history of dielectric spectroscopic research on polyelectrolyte solution,with emphasis on summarizing our *** particular,we expound the characteristics of DRs and its ability to obtain the internal information of the system of ***,we evaluate the advantages and limitations of the dielectric method and discussed future prospects of this field.

关键词： Polyelectrolyte Dielectric relaxation spectroscopy Chain conformation Thermosensitive microgel PNIPAM microgel spherical polyelectrolyte brushes

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Emission colour tuning in kLnF_(4):Yb^(3+),Er^(3+)/Ho^(3+)phosphor

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Journal of Rare Earths 2024年第1期42卷 57-65,I0002页

作者： Janani k Gayathri E Vijayatha V Ramasubramanian s Thiyagarajan P Department of science and Humanities Nehru Institute of TechnologyKaliapuramThirumalayampalayamCoimbatoreIndia Department of sciences Amrita School of Physical SciencesAmrita Vishwa VidyapeethamCoimbatoreIndia Department of Physics Anna UniversityChennaiIndia

kLnF_(4):Yb^(3+),Er^(3+)/Ho^(3+)(Ln=Y,Yb,Gd)phosphors were prepared by solid-state reaction *** each of the Yb^(3+)/Er^(3+)and Yb^(3+)/Ho^(3+)co-doped phosphors independently,phase confirmation and morphological examination were accomplished using the X-ray diffraction technique and scanning electron microscope analysis.X-ray photoelectron spectroscopy analysis shows the charge state and existence of lanthanides and *** luminescence emissions of green and red colour were detected for the synthesized *** changes in the upconverted emission intensities and colour output pertaining to the change of the lanthanide host matrix along with dopants were investigated for the prepared *** the upconversion luminescence,erbium-doped samples exhibit a predominance of red emission while holmium-doped samples display a prevalence of green *** rare-earth Er/Ho doped kYbF4shows strong red emission compared to other ***_(4):Yb,Er/Ho exhibits relatively significant green upconve rsion emissions,while Yb,Er-doped kGdF_(4)host displays a 10-fold increase in green/red emission ratio with an increase in the input power of 20-780 *** photoluminescence studies and decay curve analysis were carried out using UV light excitation for the developed phosphors.A higher lifetime of 2.2 ms was measured for the downshifting red emission in the Ho doped kYbF_(4)*** study suggests a potential for colour tunability in the upconversion and downshifting emissions through host modifications to the fluoride phosphor.

关键词： Rare earths Energy transfer upconversion Downshifting Colour coordinates

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Flat jet electrochemical milling of TC4 alloy with tailoring backward parallel flow

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Chinese Journal of Aeronautics 2024年第4期37卷 574-592页

作者： Huanghai kong Ningsong QU College of Mechanical and Electrical Engineering Nanjing University of Aeronautics and AstronauticsNanjing 210016China

In flat jet electrochemical milling, the electrolyte forms a backward parallel flow after impacting the workpiece, resulting in a weak current density distribution on the workpiece. Poor surface quality usually occurs on the machined titanium alloy surface because it inevitably suffers from the weak current density. In this study, a method of flat jet electrochemical milling with tailoring the backward parallel flow was proposed to eliminate the negative effects caused by the weak current density. Multiphysics simulations are carried out to comprehend the mechanism of flat jetEC milling with tailoring backward parallel flow and better construct the novel tool *** on flat jet electrochemical milling of TC4 alloy with and without tailoring backward parallel flow are conducted. The results reveal that, compared with flat jet electrochemical milling without tailoring backward parallel flow, the recommended tool reduces the surface roughness by86% to 93%, and improves the material removal rate by 93% to 163% with different feed ***, the recommended tool is more conducive to maintaining the inherent hardness of the material. Finally, a surface with low sa of 0.37 μm is obtained.

关键词： Flat jet electrochemical milling TC4 alloy surface roughness Micro-hardness Material removal rate

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soil inorganic amendments produce safe rice by reducing the transfer of Cd and increasing key amino acids in brown rice

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Journal of Environmental sciences 2024年第2期136卷 121-132页

作者： Fanyi kong shenggao Lu Zhejiang Provincial key Laboratory of Agricultural Resources and Environment Key Laboratory of Environmental Remediation and Ecosystem HealthMinistry of EducationCollege of Environmental and Resource SciencesZhejiang UniversityHangzhou 310058China

The digestibility of cadmium(Cd)in brown rice is directly related to amino acid metabolism in rice and human *** our field study,three kinds of alkaline calcium-rich soil inorganic amendments(sIAs)at three dosages were applied to produce safe rice and improve the quality of rice in Cd-contaminated *** the increased application of sIA,Cd content in iron plaque on rice root significantly increased,the transfer of Cd from rice root to grain significantly decreased,and then Cd content in brown rice decreased *** vitro digestibility of Cd in brown rice was estimated by a physiologically based extraction *** showed that more than 70%of Cd in brown rice could be digested by simulated gastrointestinal *** on the total and digestible Cd contents in brown rice to evaluate the health risk,the application of 2.25 ton sIA/ha could produce safe rice in acidic slightly Cd-contaminated paddy *** amino acids(AAs)in brown rice were determined by high-performance liquid *** contents of 5 key AAs(kAAs)that actively respond to environmental changes increased significantly with the increased application of *** structural equation model indicated that kAAs could be affected by the Cd translocation capacity from rice root to grain,and consequently altered the ratio of indigestible Cd in brown *** formation of indigestible kAAs-Cd complexes by combining kAAs(phenylalanine,leucine,histidine,glutamine,and asparagine)with Cd in brown rice could be considered a potential mechanism for reducing the digestibility of Cd.

关键词： Cadmium digestibility soil inorganic amendments safe rice Amino acid Priming effect Health risk

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