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Expanded porphyrin Exhibiting Off-Centered Out-of-plane Coordination to Dysprosium

CCs Chemistry 2024年第7期6卷 1731-1738页

作者： Dmitry I.Nazarov Jorge Labella Alexey v.Kuzmin Maxim A.Faraonov Evgenii N.Ivanov salavat s.Khasanov Tomas Torres Mikhail K.Islyaikin Dmitri v.Konarev Federal Research Center of problems of Chemical physics and Medicinal Chemistry RAs 142432 Chernogolovka Department of Organic Chemistry Universidad Autonoma de Madrid28049 Madrid Institute of solid-state physics RAs 142432 Chernogolovka Research Institute of Macroheterocycles Ivanovo State University of Chemistry and Technology15300 Ivanovo G.A.Krestov Institute of solution Chemistry of the Russian Academy of sciences 153045 Ivanovo Institute for Advanced Research in Chemical sciences Universidad Autonoma de Madrid28049 Madrid IMDEA-Nanociencia 28049 Madrid

The complexation of high-spin lanthanides to porphyrinoids is a powerful strategy for the development of advanced molecular *** this context,the use of expanded porphyrinoids remains elusive since their coordination chemistry is challenging to ***,taking inspiration from on-surface chemistry,we explored the coordination of Dy^(3+)to a six-membered porphyrinoid,namely,the hemihexaphyrazine ***,we observed the selective formation of a mono-nuclear off-centered,out-of-plane H_(2)Hhp-Dy^(3+)complex when performing the complexation under reductive *** this reaction,the oxidation state of the macrocycle did not *** X-ray diffraction analysis,we found that the coordination number of Dy in this complex was *** macrocycle cocrystallized with decamethylcobaltocene(Cp_(2)^(*)Co)molecules,giving rise to a wellordered solid-state packing,governed byπ-π*** a result of this organization,a small magnetic coupling between the neighboring molecules was *** in all,this work provides key insights into the coordination of magnetically active metals with expanded porphyrinoids,thus motivating the development of advanced spintronic devices.

关键词： porphyrins dysprosium macrocycle coordination chemistry magnetism

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A hybrid machine-learning model for solar irradiance forecasting

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Clean Energy 2024年第1期8卷 100-110页

作者： Ameera M.Almarzooqi Maher Maalouf Tarek H.M.El-Fouly vasileios E.Katzourakis Mohamed s.El Moursi Constantinos v.Chrysikopoulos Department of Industrial and systems Engineering Khalifa UniversityAbu DhabiPO Box 127788UAE Electrical Engineering and Computer science Department Khalifa University Abu DhabiUAE Department of Civil Infrastructure and Environmental Engineering Khalifa UniversityAbu DhabiPO Box 127788UAE school of Chemical and Environmental Engineering Technical University of CreteChaniaGreece

Nowcasting and forecasting solar irradiance are vital for the optimal prediction of grid-connected solar photovoltaic(pv)power *** plants face operational challenges and scheduling dispatch difficulties due to the fluctuating nature of their power *** the generation capacity within the electric grid increases,accurately predicting this output becomes increasingly essential,especially given the random and non-linear characteristics of solar irradiance under variable weather *** study presents a novel prediction method for solar irradiance,which is directly in correlation with pv power output,targeting both short-term and medium-term forecast *** proposed hybrid framework employs a fast trainable statistical learning technique based on the truncated-regularized kernel ridge regression *** proposed method excels in forecasting solar irradiance,especially during highly intermittent weather periods.A key strength of our model is the incorporation of multiple historical weather parameters as inputs to generate accurate predictions of future solar irradiance values in its scalable *** evaluated the performance of our model using data sets from both cloudy and sunny days in seattle and Medford,UsA and compared it against three forecasting models:persistence,modified 24-hour persistence and least *** on three widely accepted statistical performance metrics(root mean squared error,mean absolute error and coefficient of determination),our hybrid model demonstrated superior predictive accuracy in varying weather conditions and forecast horizons.

关键词： solar power generation kernel ridge regression hybrid model forecasting

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prognostic role of selection criteria for liver transplantation in patients with hepatocellular carcinoma:Review and bibliometric

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iLIvER 2024年第1期3卷 52-61页

作者： pamela scarlett Espinoza Loyola Diana Laura Muratalla Bautista Karen Adela Hernández Bautista Elizabeth Gil White JoséAntonio González Moreno Daniel Angel Torres del Real víctor Manuel páez Zayas Carla Escorza-Molina Fernando Mondragón Rodríguez Omar vásquez Gómez Luis Jorge Fernández López paul santiago Mogrovejo vázquez Isidoro Aczel sánchez-Cedillo víctor Jose visag Castillo social service Internship Universidad Nacional Autónoma de MéxicoMexico City 04510Mexico social service Internship Universidad AnahuacMexico City 04510Mexico Department of surgery Division of Transplantation surgery Hospital General de MéxicoMexico City 06720Mexico Departament of Gastroenterology Division of HepatologyHospital General de MéxicoMexico City 06720Mexico Departmanet of Anesthesiology Hospital General de MéxicoMexico City 06720Mexico

Hepatocellular carcinoma(HCC)is one of the most common cancers in the world and is one of the leading indications for liver transplantation,liver transplantation is the gold standard treatment for end stage liver *** is based up on radiological characteristics and rarely biopsy *** treatment must be individualized to each patient to improve recurrences and *** this article,we focus on the different selection criteria for liver *** study aimed to investigate the distribution laws and research frontiers of international literature,so as to present holistic bibliometric evaluation of the studies on 5-year survival and disease-free recurrence in 5 years,according to hepatocarcinoma criteria for liver *** paper aims to review and analyze 5-year survival and disease-free recurrence based on hepatocarcinoma criteria for liver *** systematically examines and summarizes distribution characteristics and research frontiers through bibliometric analysis.A bibliographic search was implemented in pubMed/Medline,Clinical Key,science Direct and Index Medicus with MEsH terms,from the year 1996–*** selected for transplantation using the Metroticket 2.0(MT2)criteria had the highest overall survival along with patients selected for transplantation using the Milan Criteria had the best 5-year disease-free *** Metroticket 2.0 criteria(MT2)and Milan Criteria(MC)have shown the most favorable post-transplant outcomes for patients with hepatocellular carcinoma(HCC).However,MC demonstrated the best 5-year disease-free recurrence rate,underscoring the significance of taking into account tumor morphology and biology when determining the eligibility of HCC patients for liver *** distribution characteristics and research frontiers by bibliometrics concerning prognostic role of selection criteria for liver transplantation in patients with hepatocellular carcinoma the collaboration

关键词： Hepatocellular carcinoma Liver transplantation survival Criteria Recurrence Bibliometrics

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BaTiO3 solid solutions co-doped with Gd3+ and Eu3+:synthesis,structural evolution and dielectric properties

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Journal of Rare Earths 2024年第10期42卷 1920-1926页

作者： R.Martínez-López M.pérez-Labra J.A.Romero-serrano F.R.Barrientos-Hernández M.Reyes-pérez M.I.valenzuela-Carrillo G.Urbano-Reyes v.E.Reyes-Cruz G.I.Dávila-pulido Academic Area of Earth sciences and Materials Autonomous University of Hidalgo State Metallurgy and Materials Department ESIQIE-IPNUPALM Autonomous University of Coahuila Boulevard Adolfo López Mateos S/n

In this paper,the synthesis,structural evolution,and dielectric properties of BaTiO3solid solutions codoped with rare earth elements(Gd3+and Eu3+) prepared using the solid-state reaction method are *** pure precursor powders of BaCl3,TiO2,Gd2O3,and Eu2O3were mixed in stoichiometric proportions,ground in an agate mortar before being uniaxially pressed at 250 Mpa and sintered at 1300℃ in air atmosphere for 6 h to obtain Ba1-3xGd2xTi1-3xEu4xO3（x=0,0.0015,0.01 and0.1）.X-ray diffraction（XRD） and Rietveld's refinement results reveal the crystal phase ferroelectric tetragonal BaTiO3for the samples with x=0,0.0015 and 0.01, as well as a consistent increment in the lattice parameters caused by the *** solubility limit of Gd3+and Eu3+in the BaTiO3structure is reached for the sample with x>0.01,and the orthorhombic Eu2TiO5and monoclinic BaTi2O5secondary phases were *** Raman results show the characteristic peaks of ferroelectric tetragonal BaTiO3around 716 cm-1（LO of A1 symmetry）,515 cm-1（TO of A1 symmetry）,and 305 cm-1（B1）.The maximum relative permittivity measured at 1 kHz was recorded to be 6151.8 for the sample with x=0.0015,and a decrease in the Curie temperature to 105℃ with respect to the undoped sample was *** punctual microanalysis for the samples with x=0.0015,0.01,and 0.1 reveals grains composed of Ba,Ti,O,Gd,and Eu homogeneously distributed in the *** Ba/Ti ratios for samples with x=0.0015,0.01 and 0.1 are 2.86,2.91,and 0.68,respectively,indicating substitution at the Ti site for samples with x=0.0015 and 0.01 and a substitution at the Ba site for the sample with x=0.1.

关键词： BaTiO3 Doping Europium Gadolinium Rare earths synthesis

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Fluoride contamination in groundwater:A global review of the status,processes,challenges,and remedial measures

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Geoscience Frontiers 2024年第2期15卷 1-29页

作者： E.shaji K.v.sarath M.santosh p.K.Krishnaprasad B.K.Arya Manisha s.Babu Department of Geology University of KeralaKariavattom CampusThiruvananthapuramKerala 695581India school of Earth sciences and Resources China University of Geosciences(Beijing)29 Xueyuan RoadBeijing 100083China Department of Earth science University of AdelaideAdelaideSA 5005Australia Department of Geology Central University of KeralaTejaswini HillsPeriyeKasaragodKerala 671316India

Groundwater pollution by fluoride is one of the prime concerns of the world population due to its toxicity,which results in adverse health *** this paper,we review the current scenario of the fluoride contamination of groundwater in various countries across the globe and its impact on human *** the last decade,several newly affected regions have been reported all over the world,with more than 100 countries affected by fluoride contamination in groundwater(concentration exceeding the acceptable limit of 1.5 mg/L defined by the World Health Organization).Fluoride poisoning is mainly due to the unsupervised ingestion of products for dental and oral hygiene and over-fluoridated drinking *** is estimated that more than 200 million people from different countries are affected by fluoriderelated groundwater issues and health *** highest among these are from the countries in Africa(38),Asia(28),and Europe(24),followed by countries like south America(5),North America(3),and Australia(2).The source of fluoride in drinking water is primarily geogenic,together with forage,grasses and grains,tea,and anthropogenic *** countries affected were correlated with climatic zones and geological factors to gain insights into geospatial *** analyses show that most of the fluoride pollution-prone zones are located in high-grade metamorphic terranes with granitoid or alkaline intrusions,geothermal hot springs,and volcanic regions with arid or semi-arid climatic *** study also finds that children across the globe are more vulnerable than adults to fluoride *** review finds that,although there are efficient fluoride removal techniques,including filters with next-generation nanomaterials,to date,there has not been a single technique developed that can claim to be a practically robust solution for fluoride removal from drinking ***,we suggest developing next-generation filters that can retain essential miner

关键词： Fluoride Groundwater Water contamination WHO standards Climate zones Remediation sustainable Development Goals

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CCD/EMCCD光电参数测试系统的设计与应用

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中国光学（中英文） 2024年第3期17卷 693-703页

作者：沈吉 vIACHEsLAv v.Zabudsky 常维静那启跃简云飞 OLEG v.Rikhalsky OLEKsANDR G.Golenkov vOLODYMYR p.Reva 华东光电集成器件研究所江苏苏州215263 乌克兰科学院v.E.Lashkaryov半导体物理研究所乌克兰基辅01001 乌克兰科学院Bogomoletz生理学研究所乌克兰基辅01001

本文开发了一种用于测量CCD和EMCCD(电子倍增CCD)芯片光电参数的测试系统。该测试系统通过自动模式或手动模式间的切换,测量器件的暗电流、读出放大器的响应度、电荷转移效率、电荷容量和其他参数。该测试系统可以针对不同规格和结构的C... 详细信息

本文开发了一种用于测量CCD和EMCCD(电子倍增CCD)芯片光电参数的测试系统。该测试系统通过自动模式或手动模式间的切换,测量器件的暗电流、读出放大器的响应度、电荷转移效率、电荷容量和其他参数。该测试系统可以针对不同规格和结构的CCD/EMCCD器件,实现CCD晶圆或封装好的成品的参数测试,实现576×288、640×512、768×576、1024×1024、1280×1024 CCD/EMCCD的测试和筛选。

关键词： CCD EMCCD 测试系统光电参数

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Collisionless shock acceleration of protons in a plasma slab produced in a gas jet by the collision of two laser-driven hydrodynamic shockwaves

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Matter and Radiation at Extremes 2024年第2期9卷 12-25页

作者： J.-R.Marquès L.Lancia p.Loiseau p.Forestier-Colleoni M.Tarisien E.Atukpor v.Bagnoud C.Brabetz F.Consoli J.Domange F.Hannachi p.Nicolaï M.salvadori B.Zielbauer LULI CNRSÉcole PolytechniqueCEASorbonne UniversitéInstitut Polytechnique de Paris91128 Palaiseau CedexFrance CEA DAMDIF91297 Arpajon CedexFrance Universitéparis-saclay CEALMCE91680 Bruyères-le-ChatelFrance CENBG CNRS-IN2P3Universitéde Bordeaux33175 Gradignan CedexFrance GsI Helmholtzzentrum für schwerionenforschung GmbH Planckstraße 164291 DarmstadtGermany University of Darmstadt Schloßgartenstr.764289 DarmstadtGermany ENEA Fusion and Technologies for Nuclear safety Department C.R.FrascatiVia Enrico Fermi 45FrascatiRomeItaly CELIA Universitéde Bordeaux–CNRS–CEA33405 TalenceFrance Universitéparis-saclay CEALIDYL91191 Gif-sur-YvetteFrance

We have recently proposed a new technique of plasma tailoring by laser-driven hydrodynamic shockwaves generated on both sides of a gas jet[Marquès et al.,*** 28,023103(2021)].In a continuation of this numerical work,we study experimentally the influence of the tailoring on proton acceleration driven by a high-intensity picosecond laser in three cases:without tailoring,by tailoring only the entrance side of the picosecond laser,and by tailoring both sides of the gas *** tailoring,the acceleration is transverse to the laser axis,with a low-energy exponential spectrum,produced by Coulomb *** the front side of the gas jet is tailored,a forward acceleration appears,which is significantly enhanced when both the front and back sides of the plasma are *** forward acceleration produces higher-energy protons,with a peaked spectrum,and is in good agreement with the mechanism of collisionless shock acceleration(CsA).The spatiotemporal evolution of the plasma profile is characterized by optical shadowgraphy of a probe *** refraction and absorption of this beam are simulated by post-processing 3D hydrodynamic simulations of the plasma *** with the experimental results allows estimation of the thickness and near-critical density of the plasma slab produced by tailoring both sides of the gas *** parameters are in good agreement with those required for CsA.

关键词： acceleration hydrodynamic collision

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LeafspotNet:A deep learning framework for detecting leaf spot disease in jasmine plants

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Artificial Intelligence in Agriculture 2024年第2期12卷 1-18页

作者： shwetha v Arnav Bhagwat vijaya Laxmi Department of Electrical and Electronics Engineering Manipal Institute of TechnologyManipalManipal Academy of Higher EducationManipal 576104KarnatakaIndia

Leaf blight spot disease,caused by bacteria and fungi,poses a threat to plant health,leading to leaf discoloration and diminished agricultural *** response,we present a MobileNetv3 based classifier designed for the Jasmine plant,leveraging lightweight Convolutional Neural Networks(CNNs)to accurately identify disease *** model integrates depth wise convolution layers and max pool layers for enhanced feature extraction,focusing on crucial low level features indicative of the *** preprocessing techniques,including data augmentation with Conditional GAN and particle swarm Optimization for feature selection,the classifier achieves robust *** on curated datasets demonstrates an outstanding 97%training accuracy,highlighting its *** world testing with diverse conditions,such as extreme camera angles and varied lighting,attests to the model's resilience,yielding test accuracies between 94%and 96%.The dataset's tailored design for CNN based classification ensures result ***,the model's lightweight classification,marked by fast computation time and reduced size,positions it as an efficient solution for real time *** comprehensive approach underscores the proposed classifier's significance in addressing leaf blight spot dis-ease challenges in commercial crops.

关键词： CNN Detection Leaf CGAN Augmentation Classification swarm optimization Disease detection Tomato leaf Casava leaf

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CoopAI-Route: DRL Empowered Multi-Agent Cooperative system for Efficient Qos-Aware Routing for Network slicing in Multi-Domain sDN

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Computer Modeling in Engineering & sciences 2024年第9期140卷 2449-2486页

作者： Meignanamoorthi Dhandapani v.vetriselvi R.Aishwarya College of Engineering Guindy Anna UniversityChennai600025India

The emergence of beyond 5G networks has the potential for seamless and intelligent connectivity on a global *** slicing is crucial in delivering services for different,demanding vertical applications in this ***-generation applications have time-sensitive requirements and depend on the most efficient routing path to ensure packets reach their intended ***,the existing Ip(Internet protocol)over a multi-domain network faces challenges in enforcing network slicing due to minimal collaboration and information sharing among network *** inter-domain routing methods,like Border Gateway protocol(BGp),cannot make routing decisions based on performance,which frequently results in traffic flowing across congested paths that are never *** address these issues,we propose CoopAI-Route,a multi-agent cooperative deep reinforcement learning(DRL)system utilizing hierarchical software-defined networks(sDN).This framework enforces network slicing in multi-domain networks and cooperative communication with various administrators to find performance-based routes in intra-and ***-Route employs the Distributed Global Topology(DGT)algorithm to define inter-domain Quality of service(Qos)***-Route uses a DRL agent with a message-passing multi-agent Twin-Delayed Deep Deterministic policy Gradient method to ensure optimal end-to-end routes adapted to the specific requirements of network slicing *** evaluation demonstrates CoopAI-Route’s commendable performance in scalability,link failure handling,and adaptability to evolving topologies compared to state-of-the-art methods.

关键词： 6G multi-domain multi-agent routing DRL sDN

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A new perspective on intervertebral disc calcification—from bench to bedside

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Bone Research 2024年第1期12卷 50-61页

作者： Emanuel J.Novais Rajkishen Narayanan Jose A.Canseco Koen van de Wetering Christopher K.Kepler Alan s.Hilibrand Alexander R.vaccaro Makarand v.Risbud Department of Orthopaedic surgery Sidney Kimmel Medical CollegeThomas Jefferson UniversityPhiladelphiaPAUSA Unidade Local de saúde do Litoral Alentejano Orthopedic DepartmentSantiago do CacémPortugal Rothman Orthopedic Institute at Thomas Jefferson University PhiladelphiaPAUSA

Disc degeneration primarily contributes to chronic low back and neck ***,there is an urgent need to understand the spectrum of disc degeneration phenotypes such as fibrosis,ectopic calcification,herniation,or mixed *** these phenotypes,disc calcification is the least *** calcification,by definition,is the pathological mineralization of soft tissues,widely studied in the context of conditions that afflict vasculature,skin,and ***,disc calcification is associated with poor surgical outcomes and back pain refractory to conservative *** is frequently seen as a consequence of disc aging and progressive degeneration but exhibits unique molecular and morphological characteristics:hypertrophic chondrocyte-like cell differentiation;TNAp,ENpp1,and ANK upregulation;cell death;altered pi and ppi homeostasis;and local *** studies in mouse models have provided a better understanding of the mechanisms underlying this *** is essential to recognize that the presentation and nature of mineralization differ between AF,Np,and Ep ***,the combination of anatomic location,genetics,and environmental stressors,such as aging or trauma,govern the predisposition to ***,the systemic regulation of calcium and pi metabolism is less important than the local activity of ppi modulated by the ANK-ENpp1 axis,along with disc cell death and differentiation *** there is limited understanding of this phenotype,understanding the molecular pathways governing local intervertebral disc calcification may lead to developing disease-modifying drugs and better clinical management of degeneration-related pathologies.

关键词： degeneration metabolism intervertebral

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