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Progress in Natural science:Materials International 2014年第4期24卷 378-387页

作者： B.Uma Rajnikant K.sakthi Murugesan s.krishnan B.Milton Boaz Department of Physics R.M.K.Engineering College X-ray Crystallography Laboratory Post-Graduate Department of Physics & ElectronicsUniversity of Jammu PG and Research Department of Physics Presidency College Department of Physics B.S.Abdur Rehman University

Dichloro-diglycine zinc II(DCDGZ II),a semi-organic nonlinear optical material has been synthesized and single crystals were grown from the aqueous solution up to dimensions 20×10×3 *** title compound,DCDGZ II(C4H10Cl2N2O4Zn H2O) crystallizes into monoclinic structure with the space group of C2/*** unit-cell parameters were found to be a=14.4191(7),b=6.9180(2),c=12.9452(6) and Z=*** the crystal structure,DCDGZ II layer is building up alternatingly with layers of water in which the zinc ions lie on a twofold *** calculations for polarizability,which are useful for device fabrication were made using Clausius–Mosotti equation and Penn analysis and the results were *** transform infrared(FTIR) spectroscopic studies were performed for the identification of the different functional groups presented in the *** UV–vis–NIR absorption spectrum reveals that the lower UV cut-off wavelength is 240 *** optical band gap of the crystal was estimated as 2.2 *** surface morphology,thermal behaviour,dielectric properties have been studied using sEM,TG/DTA and LCR HITEsTER *** nonlinear optical property of the crystal was also confirmed using Kurtz powder technique.

关键词： Crystal structure Growth from solutions Characterization Non-linear optic materials

A review on transition metal oxides based photocatalysts for degradation of synthetic organic pollutants

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Journal of Environmental sciences 2024年第5期139卷 389-417页

作者： Athira krishnan Anna swarnalal Divine Das Midhina krishnan Viswanathan s.saji sMAshibli Department of Chemistry Amrita Vishwa VidyapeethamAmritapuriKerala690525India Interdisciplinary Research Center for Advanced Materials King Fahd University of Petroleum&MineralsDhahran31261Saudi Arabia Department of Chemistry University of KeralaKariavattom CampusThiruvananthapuramKerala695581India

This review provides insight into the current research trend in transition metal oxides(TMOs)-based photocatalysis in removing the organic colouring matters from *** easy understanding,the research progress has been presented in four generations according to the catalyst composition and mode of application,viz:single component TMOs(the firstgeneration),doped TMOs/binary TMOs/doped binary TMOs(the second-generation),inactive/active support-immobilized TMOs(the third-generation),and ternary/quaternary compositions(the fourth-generation).The first two generations represent suspended catalysts,the third generation is supported catalysts,and the fourth generation can be suspended or *** review provides an elaborated comparison between suspended and supported catalysts,their general/specific requirements,key factors controlling degradation,and the methodologies for performance *** the plausible fundamental and advanced dye degradation mechanisms involved in each generation of catalysts were *** existing challenges in TMOs-based photocatalysis and how the researchers approach the hitch to resolve it effectively are *** research trends are also presented.

关键词： Photocatalysis Dye degradation Transition metal oxides and composites supported catalysts suspended catalysts

Detection and defending the Xss attack using novel hybrid stacking ensemble learning-based DNN approach

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Digital Communications and Networks 2024年第3期10卷 716-727页

作者： Muralitharan krishnan Yongdo Lim seethalakshmi Perumal Gayathri Palanisamy IMs Sungkyunkwan UniversitySuwon16419South Korea Department of Mathematics Sungkyunkwan UniversitySuwon16419South Korea Department of Information Technology Madras Institute of TechnologyChennaiIndia Department of Mathematics PSG College of Arts and ScienceTamilnaduIndia

Existing web-based security applications have failed in many situations due to the great intelligence of *** web applications,Cross-site scripting(Xss)is one of the dangerous assaults experienced while modifying an organization's or user's *** avoid these security challenges,this article proposes a novel,all-encompassing combination of machine learning(NB,sVM,k-NN)and deep learning(RNN,CNN,LsTM)frameworks for detecting and defending against Xss attacks with high accuracy and *** on the representation,a novel idea for merging stacking ensemble with web applications,termed“hybrid stacking”,is *** order to implement the aforementioned methods,four distinct datasets,each of which contains both safe and unsafe content,are *** hybrid detection method can adaptively identify the attacks from the URL,and the defense mechanism inherits the advantages of URL encoding with dictionary-based mapping to improve prediction accuracy,accelerate the training process,and effectively remove the unsafe Jscript/Javascript keywords from the *** simulation results show that the proposed hybrid model is more efficient than the existing detection *** produces more than 99.5%accurate Xss attack classification results(accuracy,precision,recall,f1_score,and Receiver Operating Characteristic(ROC))and is highly resistant to Xss *** order to ensure the security of the server's information,the proposed hybrid approach is demonstrated in a real-time environment.

关键词： Machine learning Deep neural networks Classification stacking ensemble Xss attack URL encoding Jscript/Javascript Web security

金属富燃料推进剂火箭冲压发动机一次和二次系统的性能分析

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推进技术 1982年第1期 58-68页

作者： V.Ramanujachari ,s.krishnan ,陈达明

冲压发动机由于它的高比冲、高速度和持续的推力,极适用于大气层飞行的导弹。最近二十年冲压发动机技术发展的主要里程碑是导弹上应用的整体式火箭——冲压发动机(IRR)的设计和验证。本文详细地介绍了固体推进剂火箭——冲压发动机(一种... 详细信息

冲压发动机由于它的高比冲、高速度和持续的推力,极适用于大气层飞行的导弹。最近二十年冲压发动机技术发展的主要里程碑是导弹上应用的整体式火箭——冲压发动机(IRR)的设计和验证。本文详细地介绍了固体推进剂火箭——冲压发动机(一种IRR)在平衡工况下的一种相对地简单的一元流分析法。分析中考虑了下列方面:1)轴对称进气道性能,2)金属富燃料固体推进剂主发动机的复杂的化学平衡组分,3)随着发生的多相流动,4)在二次燃烧室中空气和富燃料燃烧产物的混合和扩散以及随后的反应。应用该分析法介绍了一种典型的实例研究。

关键词：冲压发动机 IRR 喷管马赫数混气 M 数固体推进剂火箭轴对称进气道二次燃烧室推进剂药柱富燃料推进剂金属材料金属

Portable dielectrophoresis for biology:ADEPT facilitates cell trapping,separation,and interactions

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Microsystems & Nanoengineering 2024年第2期10卷 193-205页

作者： Lourdes Albina Nirupa Julius Dora Akgül Gowri krishnan Fabian Falk Jan Korvink Vlad Badilita Department Institute of Microstructure TechnologyKarlsruhe Institute of TechnologyHermann-von-Helmholtz-Platz 1Eggenstein-Leopoldshafen76344Baden-WürttembergGermany

Dielectrophoresis is a powerful and well-established technique that allows label-free,non-invasive manipulation of cells and particles by leveraging their electrical *** practical implementation of the associated electronics and user interface in a biology laboratory,however,requires an engineering background,thus hindering the broader adoption of the *** order to address these challenges and to bridge the gap between biologists and the engineering skills required for the implementation of DEP platforms,we report here a custom-built,compact,universal electronic platform termed ADEPT(adaptable dielectrophoresis embedded platform tool)for use with a simple microfluidic chip containing six *** versatility of the open-source platform is ensured by a custom-developed graphical user interface that permits simple reconfiguration of the control signals to address a wide-range of specific applications:(i)precision positioning of the single bacterium/cell/particle in the micrometer range;(ii)viability-based separation by achieving a 94%efficiency in separating live and dead yeast;(iii)phenotype-based separation by achieving a 96%efficiency in separating yeast and Bacillus subtilis;(iv)cell–cell interactions by steering a phagocytosis process where a granulocyte engulfs *** RGB-s ***,the set of experiments and the platform form a complete basis for a wide range of possible applications addressing various biological questions exploiting the plug-and-play design and the intuitive GUI of ADEPT.

关键词： Together separation separating

Does progress in microfracture techniques necessarily translate into clinical effectiveness?

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World Journal of Orthopedics 2024年第3期15卷 266-284页

作者： sathish Muthu Vibhu krishnan Viswanathan Manoharan sakthivel Mohammed Thabrez Department of Orthopaedics Orthopaedic Research GroupCoimbatore 641045Tamil NaduIndia Department of Biotechnology Karpagam Academy of Higher EducationCoimbatore 641021Tamil NaduIndia Manoharan sakthivel Department of OrthopaedicsGovernment Medical CollegeKarur 639004Tamil NaduIndia Department of Orthopaedics Devadoss Multispecialty HospitalMadurai 625007Tamil NaduIndia Department of Medical Oncology Aster Medcity HospitalKochi 682034India

BACKGROUND Multitudinous advancements have been made to the traditional microfracture(MFx)technique,which have involved delivery of various acellular 2nd generation MFx and cellular MFx-III components to the area of cartilage *** relative benefits and pitfalls of these diverse modifications of MFx technique are still not widely *** To comparatively analyze the functional,radiological,and histological outcomes,and complications of various generations of MFx available for the treatment of cartilage *** A systematic review was performed using PubMed,EMBAsE,Web of science,Cochrane,and *** of any age and sex with cartilage defects undergoing any form of MFx were considered for *** included only randomized controlled trials(RCTs)reporting functional,radiological,histological outcomes or complications of various generations of MFx for the management of cartilage *** meta-analysis(NMA)was conducted in stata and Cochrane’s Confidence in NMA approach was utilized for appraisal of *** Forty-four RCTs were included in the analysis with patients of mean age of 39.40(±9.46)*** comparing the results of the other generations with MFX-I as a constant comparator,we noted a trend towards better pain control and functional outcome(KOOs,IKDC,and Cincinnati scores)at the end of 1-,2-,and 5-year time points with MFx-III,although the differences were not statistically significant(P>0.05).We also noted statistically significant Magnetic resonance observation of cartilage repair tissue score in the higher generations of microfracture(weighted mean difference:17.44,95%confidence interval:0.72,34.16,P=0.025;without significant heterogeneity)at 1 ***,the difference was not maintained at 2 *** was a trend towards better defect filling on MRI with the second and third generation MFx,although the difference was not statistically significant(P>0.05).CONCLUsION The higher generations of traditional MFx

关键词： Cartilage injury Microfracture Mesenchymal stem cells Platelet-rich plasma Bone marrow aspiration concentrates Clinical outcome Radiological outcome Meta-analysis Network meta-analysis

Defect mediated losses and degradation of perovskite solar cells:Origin impacts and reliable characterization techniques

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Journal of Energy Chemistry 2024年第7期94卷 217-253页

作者： Himangshu Baishy Ramkrishna Das Adhikari Mayur Jagdishbhai Patel Deepak Yadav Tapashi sarmah Mizanur Alam Manab Kalita Parameswar krishnan lyer Centre for Nanotechnology Indian Institute of Technology GuwahatiGuwahati 781039AssamIndia Department of Chemistry Indian Institute ofTechnology GuwahatGuwahati739AssamIndi

The rapid advancement of halide-based hybrid perovskite materials has garnered significant research attention,particularly in the domain of photovoltaic *** to their exceptional optoelec-tronic properties,they demonstrated power conversion efficiency(PcE)of over 25%in single junction solar *** the notable progress in PCE over the past decade,the inherent high defect density pre-senting in perovskite materials gives rise to several loss mechanisms and associated ion migration in per-ovskite solar cells(PsCs)during operational *** factors collectively contribute to a significant stability challenge in PsCs,placing their longevity far behind for *** numerous reports have explored defects,ion migration,and their impacts on device performance,a com-prehensive correlation between the types of defects and the degradation kinetics of perovskite materials and PsCs has been *** this context,this review aims to provide a comprehensive overview of the origins of defects and ion migration,emphasizing their correlation with the degradation kinetics of per-ovskite materials and PsCs,leveraging reliable characterization ***,these charac-terization techniques are intended to comprehend loss mechanisms by different passivation approaches to enhance the durability and PCE of PsCs.

关键词： Perovskite solar cells Defects lon migration Degradation stability

Detection and clearance in Alzheimer’s disease: leading with illusive chemical, structural and morphological features of the targets

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Neural Regeneration Research 2024年第3期19卷 497-498页

作者： Luís Gales i3s−Instituto de Investigação e Inovação em saúde Rua Alfredo AllenPortoPortugal(Gales L)IBMC−Instituto de Biologia Molecular e CelularUniversidade do PortoRua Alfredo AllenPortoPortugal ICBAs−Instituto de Ciências Biomédicas Abel salazar Rua de Jorge Viterbo FerreiraPortoPortugal

Highly specific interactions between biomolecules,such as antigen-antibody,protein-ligand,or nucleic acid base pair complementary are on the basis of the organization of complex *** same principles may be tentatively used in molecular medicine for diagnosis and therapeutics.A molecule can be designed to selectively bind a protease and thereby inhibit the production of a peptide that forms toxic aggregates in the brain or an antibody may be produced to bind specifically to that peptide for detection or clearance ***,interference in biological systems is not that *** a start there is the inhibition of the physiological role of the protease;moreover,several cleavage fragments may be produced,which may continue to diverge due to putative post-translational modification and self-assembly processes,hiding the toxic target in a“soup”of peptide species varying in size,structure and chemical composition.A perspective of the current status and challenges in targeting peptide species for diagnosis and treatment in the context of Alzheimer’s disease is given.

关键词： Alzheimer diagnosis thereby

巴赫曼束(心耳间横肌束)及其动脉血供的多层螺旋CT成像对心房间传导异常和心律失常的提示

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国际医学放射学杂志 2008年第5期31卷 400-401页

作者： F.saremi s.Channual s.krishnan s.V.Gurudevan J.Narula A.Abolhoda 邱建星 Department of Radiological sciences University of California Irvine Medical Center 101 The City Drive Rte 140 Orange CA 92868-3298 USA.

目的利用64层CT成像回顾性研究健康人和病人的巴赫曼束（BB）的解剖及其血供。方法本研究依从HIPAA法案并得到了机构审查委员会的批准可免除知情同意书。回顾317例病人（对照组164例，病人组153例）的临床病史、心电图（ECG）和64层CT... 详细信息

目的利用64层CT成像回顾性研究健康人和病人的巴赫曼束（BB）的解剖及其血供。方法本研究依从HIPAA法案并得到了机构审查委员会的批准可免除知情同意书。回顾317例病人（对照组164例，病人组153例）的临床病史、心电图（ECG）和64层CT冠状动脉成像影像。病人组中，房颤（AF）或房间传导阻滞（IAB）68例（P波持续时间≥120ms），严重冠状动脉疾病（CAD）46例[发出窦房结（sAN）动脉的冠状动脉狭窄程度≥70％]，严重CAD同时有心电图异常39例（AF或IAB）。对BB的长度、

关键词：多层螺旋CT成像房间传导阻滞动脉血供心律失常传导异常冠状动脉狭窄程度心电图异常肌束

Astrophysical s-factor and reaction rate for 15N(p,γ)16O within the modified potential cluster model

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Chinese Physics C 2024年第4期48卷 130-145页

作者： s.B.Dubovichenko A.s.Tkachenko R.Ya.Kezerashvili N.A.Burkova B.M.Yeleusheva Fesenkov Astrophysical Institute 050020 AlmatyKazakhstan New York City College of Technology City University of New YorkBrooklyn11201 New YorkUSA Graduate school and University Center City University of New York10016 New YorkUSA al-Farabi Kazakh National University 050040 AlmatyKazakhstan

We study radiative p^(15)N capture on the ground state of ^(16)O at stellar energies within the framework of a modified potential cluster model(MPCM)with forbidden states,including low-lying *** investigation of the ^(15)N(p,γ0)^(16)O reaction includes the consideration of ^(3)s_(1) resonances due to E1 transitions and the contribution of the ^(3)P_(1) scattering wave in the p+^(15)N channel due to the ^(3)P_(1)→^(3)P_(0)M1 *** calculated the astrophysical low-energy s-factor,and the extrapolated s(0)turned out to be within 34.7−40.4 keV·*** important role of the asymptotic constant(AC)for the ^(15)N(p,γ0)16O process with interfering ^(3)s_(1)(312)and ^(3)s_(1)(962)resonances is elucidated.A comparison of our calculation for the s-factor with existing experimental and theoretical data is addressed,and a reasonable agreement is *** reaction rate is calculated and compared with the existing *** has negligible dependence on the variation of AC but shows a strong impact of the interference of ^(3)s_(1)(312)and ^(3)s_(1)(962)resonances in reference to the CNO Gamow windows,especially at low *** estimate the contribution of cascade transitions to the reaction rate based on the exclusive experimental data from ***.C.85,065810(2012).The reaction rate enhancement due to the cascade transitions is observed from T_(9)>0.3 and reaches the maximum factor~1.3 at T_(9)=*** present the Gamow energy window and a comparison of rates for radiative proton capture reactions ^(12)N(p,γ)^(13)O,^(13)N(p,γ)^(14)O,^(14)N(p,γ)^(15)O,and ^(15)N(p,γ)^(16)O obtained in the framework of the MPCM and provide the temperature windows,prevalence,and significance of each process.

关键词： low and astrophysical energies p^(15)N system thermonuclear reaction rate potential cluster model CNO-cycle