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Hydrothermal decomposition of potassium feldspar under alkaline conditions

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Hydrothermal decomposition of potassium feldspar under alkal...

Understanding the corrosion and bio-corrosion behaviour of Magnesium composites – a critical review

中国科学院地质与地球物理研究所2015年度（第15届）学术年会

作者： s.k.liu C.Han J.M.liu H.Li key Laboratory of Mineral Resources Institute of Geology and GeophysicsChinese Academy of Sciences state key Laboratory of Lithospheric Evolution Institute of Geology and GeophysicsChinese Academy of Sciences

Potassium feldspar(k-feldspar)is important for keeping ecological balance on *** example,the weathering of k-feldspar generates dissolved elemental k,a necessary nutrient in ***,important developments on k-rich feldspar as an alternative potash have been reported in a broad spectrum of geographical contexts and ***,it is a key point to understand the mechanism of extracting potassium from k-rich rocks such as ***"cook-and-look"experiment cannot completely elucidate the dissolution mechanism of feldspar but can provide a clear idea on physicochemical properties of k-feldspar under some extreme *** this study,the reaction between feldspar and different alkalis under hydrothermal conditions was systematically investigated by combining various techniques,such as scanning electron microscopy(sEM),energy-dispersive X-ray spectroscopy,inductively coupled plasma-optical emission spectrometry.X-ray powder diffraction,and the Rietveld *** deposition of second phases on the surface of k-feldspar was observed by *** reaction process of k-feldspar and Ca(OH) was discussed by comparing the reaction between k-feldspar bulk and Ca(OH) solution with the reaction between k-feldspar and lime(CaO)powders.A transitional compound[Ca≡2AlsiO≡xOH]for kAlsiO-CaO-HO system was observed for the first *** phases appeared at different ***,a model of k-feldspar decomposition under hydrothermal condition was *** of k-feldspar hydrothermal reaction provide important and meaningful hints on the utilization of k-feldspar as an alternative to potash,and are helpful for understanding the role of k-feldspar in keeping the ecological balance of the Earth during weathering.

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Journal of Magnesium and Alloys 2024年第3期12卷 890-939页

作者： Prithivirajan sekar s.k.Panigrahi Department of Mechanical Engineering Indian Institute of Technology MadrasChennai600036India Applied Magnesium Research Center Center of Excellence in Materials and Manufacturing for Futuristic MobilityIndian Institute of Technology MadrasChennai600036India

Realising the potential of Magnesium(Mg),several globally leading ventures have invested in the Mg industry,but their relatively poor corrosion resistance is a never ending saga till *** corrosion and bio-corrosion behaviour of Mg has gained research attention and still remains a hot topic in the application of automobile,aerospace and biomedical *** intrinsic high electrochemical nature of Mg limits their utilization in diverse *** scenario has prompted the development of Mg composites with an aim to achieve superior corrosion and bio-corrosion *** present review enlightens the influence of grain size(Gs),secondary phase,texture,type of matrix and reinforcement on the corrosion and bio-corrosion behaviour of Mg ***,the corrosion and bio-corrosion behaviour of Mg composites manufactured by primary and secondary processing routes are ***,the comprehensive corrosion and bio-corrosion mechanisms of these Mg composites are ***,the individual role of Gs,texture and corrosive medium on corrosion and bio-corrosion behaviour of Mg composites are clarified and *** challenges encountered,unanswered issues in this field are explained in detail and accordingly the scope for future research is *** review is presented from basic concrete background to advanced corrosion mechanisms with an aim of creating interest among the readers like students,researchers and industry experts from various research ***,the corrosion and bio-corrosion behaviour of Mg composites are critically reviewed for the first time to:(i)contribute to the body of knowledge,(ii)foster research and development,(iii)make breakthrough,and(iv)create life changing innovations in the field of Mg composite corrosion.

关键词： Corrosion Bio corrosion Magnesium alloys Magnesium composites Magnesium implants.

PERIODIC sYsTEMs WITH TIME DEPENDENT MAXIMAL MONOTONE OPERATORs

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Acta Mathematica scientia 2024年第4期44卷 1280-1300页

作者： Zhenhai liu Nikolaos s.PAPAGEORGIOU Center for Applied Mathematics of Guangri Yulin Normal UniversityYulin 537000China Guangri key Laboratory of Universities Optimization Control and Engineering Calculation College of Mathematics and PhysicsGuangri Minzu UniversityNanning 530006China Department of Mathematics National Technical UniversityZografou Campus15780 AthensGreece

We consider a first order periodic system in R^(N),involving a time dependent maximal monotone operator which need not have a full domain and a multivalued *** prove the existence theorems for both the convex and nonconvex *** also show the existence of extremal periodic solutions and provide a strong relaxation ***,we provide an application to nonlinear periodic control systems.

关键词： periodic boundary condition time-dependent maximal monotone operator convex and nonconvex problems extremal solutions strong relaxation

A new route to weak force sensing beyond sQL:squeezed magnons in cavity magnomechanics

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science China(Physics,Mechanics & Astronomy) 2024年第10期67卷 166-167页

作者： s.k.Özdemir Department of Engineering science and Mechanics and Materials Research Institute(MRI)The Pennsylvania State UniversityUniversity ParkPA 16802USA

Quantum mechanics imposes limits on measurement accuracy through quantum noise which typically has two components:First is the shot noise originating from vacuum fluctuations and referred to as the imprecision *** is ... 详细信息

关键词： quantum typically vacuum

Thermo-kinetic characteristics on stabilizing hetero-phase interface of metal matrix composites by crystal plasticity finite element method

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Journal of Materials science & Technology 2024年第2期169卷 53-67页

作者： Y.B.Zhang s.J.song F.liu state key Laboratory of solidification Processing Northwestern Polytechnical UniversityXi’an 710072China Analytical&Testing Center Northwestern Polytechnical UniversityXi’an 710072China

Using dislocation-based constitutive modeling in three-dimension crystal plasticity finite element(3D CPFE)simulations,co-deformation and instability of hetero-phase interface in different material systems were herein studied for polycrystalline metal matrix composites(MMCs).Local stress and strain fields in two types of 3layer MMCs such as fcc/fcc Cu-Ag and fcc/bcc Cu-Nb have been predicted under simple compressive ***,more severe strain-induced interface instability can be observed in the fcc/bcc systems than in the fcc/fcc systems upon refining to metallic nanolayered composites(MNCs).By detailed analysis of stress and strain localization,it has been demonstrated that the interface instability is always accompanied by high-stress concentration,i.e.,thermodynamic characteristics,or high strain prevention i.e.,kinetic characteristics,at the hetero-phase *** then follows that the thermodynamic driving forceG and the kinetic energy barrier Q during dislocation and shear banding can be adopted to classify the deformation modes,following the so-called thermo-kinetic *** by inserting a high density of high-energy interfaces into the Cu-Nb composites,such thermo-kinetic integration at the hetero-phase interface allows a successful establishment of MMCs with the high△G-high Q deformation mode,which ensures high hardening and uniform strain distri-bution,thus efficiently suppressing the shear band,stabilizing the hetero-phase interface,and obtaining an exceptional combination in strength and *** hetero-phase interface chosen by a couple of thermodynamics and kinetics can be defined as breaking the thermo-kinetic correlation and has been proposed for artificially designing MNCs.

关键词： Thermodynamics and kinetics Physics-based constitutive modeling Hetero-phase interface Crystal plasticity finite element

Compressive property and energy absorption characteristic of interconnected porous Mg-Zn-Y alloys with adjusting Y addition

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Journal of Magnesium and Alloys 2024年第1期12卷 171-185页

作者： J.A.liu s.J.liu B.Wang W.B.sun X.J.liu Z.W.Han College of Materials science and Engineering Key Laboratory of Automobile Materials(Ministry of Education)Jilin UniversityChangchun 130022PR China key Laboratory of Bionic Engineering(Ministry of Education) College of Biological and Agricultural EngineeringJilin UniversityChangchun130022PR China Weihai Institute for Bionics-Jilin University Weihai 264205PR China

In this study,interconnected porous Mg-2Zn-xY alloys with different phase compositions were prepared by various Y additions(x=0.4,3,and 6 wt.%)to adjust the compressive properties and energy absorption *** characterization methods were then applied to identify the microstructure of the porous Mg-Zn-Y and describe the details of the second *** tests were performed at room temperature(RT),200℃,and 300℃to study the impact of the Y addition and testing temperature on the compressive properties of the porous *** experimental results showed that a high Y content promotes a microstructure refinement and increases the volume fraction of the second *** the Y content increases,different Mg-Zn-Y ternary phases appear:I-phase(Mg_(3)Zn_(6)Y),W-phase(Mg_(3)Zn_(3)Y_(2)),and LPsO phase(Mg_(12)ZnY).When the Y content ranges between 0.4%and 6%,the compressive strength increases from 6.30MPa to 9.23 MPa,and the energy absorption capacity increases from 7.33 MJ/m^(3)to 10.97 MJ/m^(3)at RT,which is mainly attributed to the phase composition and volume fraction of the second ***,the average energy absorption efficiency is independent of the Y *** addition,the compressive deformation behaviors of the porous Mg-Zn-Y are altered by the testing *** compressive strength and energy absorption capacity of the porous Mg-Zn-Y decrease due to the softening effect of the high temperature on the *** deformation behaviors at different temperatures are finally observed to reflect the failure mechanisms of the struts.

关键词： Porous magnesium Rare earth elements Microstructure Compressive behavior Energy absorption characteristic

Full-spectrum Bi@srTiO_(3) for bi-directional promotion effects on photocatalytic redox reaction:Insight into intermediates and mechanism

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Journal of Rare Earths 2024年第5期42卷 917-929,I0004页

作者： Bin liu Nanhao Zhou Jun liu Xinglei Wang Peter k.J.Robertson Xiaoyuan Chen Chao Chen Jianmin Luo Chuanyi Wang school of Chemistry and Civil Engineering Shaoguan UniversityShaoguan512005China Chengdu Customs Technology Center Chengdu610041China key Laboratory of Pollutant Chemistry and Environmental Treatment College of Chemistry and Environmental ScienceYili Normal UniversityYining835000China school of Chemistry and Chemical Engineering Queen's University BelfastStranmillis RoadBelfastBT95AGUnited Kingdom Guangzhou Institute of Industrial Intelligence(GIII) Guangzhou511400China

The development of full-spectrum photocatalysts active in the near-infrared(NIR)region has gained increasing attention for deleterious pollutant *** integration of plasmonic metals with semico nductors is an effective way to widen the light re sponse range of photocatalysts due to the strong light absorption and fast plasmonic energy transfer of the localized surface plasmon resonance(LsPR).In this work,the full-spectrum responsive Bi@srTiO_(3) was prepared via facile solvothermal chemical *** optimal Bi@srTiO_(3) achieves exceptional photocatalytic Cr(VI)reduction efficiency and tetracycline degradation,realizing bi-directional promotion effects on redox *** to density functional theory(DFT)simulations,the extraordinary photocatalytic performance is attributed to the tunable builtin electric field(IEF)of the Ohmic *** favorable adaptability in real water and high stability of BsTO-25 were proved by experime ntal *** the po ssible photocatalytic mechanism was proposed based on theoretical calculation and experimental ***,the non-toxicity of the BsTO-25 was evaluated by *** cultivation,which further proves the feasibility of treating wastewater with *** work provides a new perspective on constructing full-spectrum-driven photocatalysts for applications dealing with environmental remediation.

关键词： Full-spectrum photocatalysts Localized surface plasmon resonance Ohmic contact Cr(Ⅵ)reduction Antibiotic degradation Rare earths

Dispersion effect of nano-structure pyrolytic carbon on mechanical,electrical,and microstructural characteristics of cement mortar composite

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International Journal of smart and Nano Materials 2024年第3期15卷 534-578页

作者： N.k.karthikeyan s.Elavenil school of Civil Engineering Vellore Institute of TechnologyChennaiIndia

In material science,converting waste into nanomaterials by green technologies highlights the interest in producing sus-tainable carbon nanomaterial(sCN).This study first-ever uti-lized tyre-char as a Nano-structure Pyrolytic Carbon(NsPC)to develop electrically conductive *** other car-bon nanomaterials,the efficiency of NsPC particle as an sCN in developing electrically conductive composites was investi-gated in terms of dispersion,mechanical,water absorption,electrical resistivity,and *** results of sedi-mentation and zeta potential(-19 mV)showed the excellent dispersion of NsPC particle in water with the combined effect of superplasticizer and *** compressive(40.37%)and flexural strength(10.76%)than that of plain cement mortar composite(CMC)is achieved with 2 wt.%and 1.5 wt.%of NsPC particle,*** water absorption rate and volume of permeable voids were reduced,exhibiting less *** percolation zone of AC and DC resis-tivity of NsPC composite ranges between 1 and 2 wt.%,and the established percolation threshold is at 2 wt.%.XRD analysis showed C-s-H formation consistently increased with curing age,and HR-sEM with EDAX analysis exhibits the dense micro-structure and well-distributed NsPC particle at the *** experimental outcomes significantly enhanced the relia-bility and provided a framework for tailoring NsPC particle as sCN for developing electrically conductive composite.

关键词： sustainable nanomaterial dispersion mechanical properties electrical resistivity microstructure analysis

Enhancing Multicriteria-Based Recommendations by Alleviating scalability and sparsity Issues Using Collaborative Denoising Autoencoder

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Computers, Materials & Continua 2024年第2期78卷 2269-2286页

作者： s.Abinaya k.Uttej kumar school of Computer science&Engineering Vellore Institute of TechnologyChennaiTamilnadu600127India

A Recommender system(Rs)is a crucial part of several firms,particularly those involved in *** conventional Rs,a user may only offer a single rating for an item-that is insufficient to perceive consumer ***,businesses in industries like e-learning and tourism enable customers to rate a product using a variety of factors to comprehend customers’*** the other hand,the collaborative filtering(CF)algorithm utilizing AutoEncoder(AE)is seen to be effective in identifying user-interested ***,the cost of these computations increases nonlinearly as the number of items and users *** triumph over the issues,a novel expanded stacked autoencoder(EsAE)with kernel Fuzzy C-Means Clustering(kFCM)technique is proposed with two *** the first phase of offline,the sparse multicriteria rating matrix is smoothened to a complete matrix by predicting the users’intact rating by the EsAE approach and users are clustered using the kFCM *** the next phase of online,the top-N recommendation prediction is made by the EsAE approach involving only the most similar user from multiple *** the EsAE_kFCM model upgrades the prediction accuracy of 98.2%in Top-N recommendation with a minimized recommendation generation *** experimental check on the Yahoo!Movies(YM)movie dataset and TripAdvisor(TA)travel dataset confirmed that the EsAE_kFCM model constantly outperforms conventional Rs algorithms on a variety of assessment measures.

关键词： Recommender systems multicriteria rating collaborative filtering sparsity issue scalability issue stacked-autoencoder kernel Fuzzy C-Means Clustering