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Optimized Electronic Modification of S-Doped CuO Induced by Oxidative Reconstruction for Coupling Glycerol Electrooxidation with Hydrogen Evolution

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Nano-Micro Letters 2023年第10期15卷 622-637页

作者： ruo‑yao fan Xue‑Jun Zhai Wei‑Zhen Qiao Yu‑Sheng Zhang Ning Yu Na Xu Qian‑Xi Lv Yong‑Ming Chai Bin Dong China State Key Laboratory of Heavy Oil Processing College of Chemistry and Chemical EngineeringChina University of Petroleum(East China)Qingdao 266580People’s Republic of China

Glycerol(electrochemical) oxidation reaction(GOR) producing organic small molecule acid and coupling with hydrogen evolution reaction is a critical aspect of ensuring balanced glycerol capacity and promoting hydrogen generation on a large scale. However, the development of highly efficient and selective non-noble metal-based GOR electrocatalysts is still a key problem. Here, an S-doped CuO nanorod array catalyst(S-CuO/CF) constructed by sulfur leaching and oxidative remodeling is used to drive GOR at low potentials: It requires potentials of only 1.23 and 1.33 V versus RHE to provide currents of 100 and 500 mA cm^(-2), respectively. Moreover, it shows satisfactory comprehensive performance(at 100 mA cm^(-2), V_(cell) = 1.37 V) when assembled as the anode in asymmetric coupled electrolytic cell. Furthermore, we propose a detailed cycle reaction pathway(in alkaline environment) of S-doped CuO surface promoting GOR to produce formic acid and glycolic acid. Among them, the C–C bond breaking and lattice oxygen deintercalation steps frequently involved in the reaction pathway are the key factors to determine the catalytic performance and product selectivity. This research provides valuable guidance for the development of transition metal-based electrocatalysts for GOR and valuable insights into the glycerol oxidation cycle reaction pathway.

关键词： Glycerol oxidation reaction(GOR) Hydrogen evolution reaction(HER) CuO Oxidative reconstruction Electronic modification

Effective regulation mechanisms of Fe-Ni(oxy)hydroxide:Ni-rich heteroatomic bonding(Ni–O–Fe–O–Ni)is essential

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Nano Research 2023年第10期16卷 12026-12034页

作者： ruo-yao fan Hui-Ying Zhao Zi-Yi Zhao Wen-Hui Hu Xin Liu Jian-Feng Yu Han Hu Yong-Ming Chai Bin Dong State Key Laboratory of Heavy Oil Processing College of Chemistry and Chemical EngineeringChina University of Petroleum(East China)Qingdao 266580China Stanford PULSE Institute SLAC National Accelerator LaboratoryMenlo ParkCA 95025USA

Although Fe-Ni combination performs well in transition metal-based oxygen evolution reaction(OER)electrocatalysts,there are lack of clear and general regulations mechanism to fully play the synergistic catalytic ***,we made the utmost of the interaction of Fe–Ni heteroatomic pair to obtain a highly active Fe-Ni(oxy)hydroxide catalytic layer on iron foam(IF)and nickel foam(NF)by in-situ electrochemical deposition and rapid surface reconstruction,which only required 327 and 351 mV overpotential to provide a large current of 1,000 mA·cm^(−2),*** results confirm that the moderate Ni-rich heteroatomic bonding(Ni–O–Fe–O–Ni)formed by adjusting the Ni/Fe ratio on the catalyst surface is important to offer predominant OER *** is a key component that enhances OER activity of Ni(O)OH,but Fe-rich structural surface formed by Fe–O–Ni–O–Fe bonding is not ***,the remarkable oxygen evolution performance of the prepared Ni2Fe(O)OH/IF and FeNi2(O)OH/NF can be chalked up to the optimized electronic structure of Fe–Ni heteroatomic bonding,the efficient gas spillover,the fast electron transport,and nanosheet clusters *** summary,our work suggests a comprehensive regulation mechanism for the construction of efficient Fe-Ni(oxy)hydroxide catalytic layer on inexpensive,stable,and self-supporting metallic material surface.

关键词： Fe-Ni(oxy)hydroxide oxygen evolution reaction(OER) heteroatomic bonding Ni-rich structure regulation mechanisms

Tailoring electron transfer with Ce integration in ultrathin Co(OH)_(2) nanosheets by fast microwave for oxygen evolution reaction

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Journal of Energy Chemistry 2021年第8期30卷 299-305,I0007页

作者： Ya-Nan Zhou ruo-yao fan Shu-Yue Dou Bin Dong Yu Ma Wen-Li Yu Meng-Xuan Li Yu-Lu Zhou Chen-Guang Liu Yong-Ming Chai State Key Laboratory of Heavy Oil Processing China University of Petroleum(East China)Qingdao 266580China College of Science China University of Petroleum(East China)Qingdao 266580China

The intrinsic activity of Co(OH)_(2) for oxygen evolution reaction(OER)may be elaborately improved through the suitable valence *** modification at electronic level is proved to be an efficient strategy owing to the flexible transformation of Ce^(3+)/Ce4+.Herein,Ce0.21@Co(OH)_(2) with the optimized Ce doping have been fabricated to tailor the fast electron transfer for the enhanced activity and stability for ***,the obtained core-shell structure composed of vertical loose Co(OH)_(2) sheets not only exposes a large number of active sites,but also provides channels for Ce ***,the high pressure microwave with instantaneous heating can fast introduce Ce into Co(OH)_(2),obtaining Cex@Co(OH)_(2) with well dispersion and close *** intimated interaction between Ce and Co species may provide the"d-f electronic ladders"for accelerating electron transfer of the catalytic ***,Ce promotes the formation of Co-superoxide intermediate and/or the release of oxygen,which is considered to be the rate-determining step for *** electrochemical measurements confirmed the low overpotential of 300 m V at 10 m A cm^(-2) and great stability of Ce0.21@Co(OH)_(2) for *** work demonstrates a meaningful approach to realize the tuned electronic structure through metal doping.

关键词： Ultrathin Co(OH)_(2) Ce doping Electron regulation High pressure microwave Oxygen evolution reaction

Electrochemical deposition of Li_(2)S_(2)/Li_(2)S in aprotic Li–S batteries

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Particuology 2024年第7期90卷 516-521页

作者： Zhifeng yao Xiaozhong fan Long Kong School of Civil Engineering Xi'an University of Architecture&TechnologyXi'an 710055China Institute of Flexible Electronics(IFE) Northwestern Polytechnical UniversityXi'an 710129China

Lithium–sulfur(Li–S)batteries stand out the energy storage systems because of extremely high energy density(2600 W h Kg−1)and low-cost sulfur ***,the sluggish deposition from liquid Li polysulfides(LiPSs)to solid Li2S leads to mild power density and short cycle *** and regulating Li_(2)S_(2)/Li2S deposition are conceived to be importance to deliver second-plateau capacity in acceptable kinetics,which has the potential to operation Li–S batteries under electrolyte-lean *** perspective aims to summarize the proposed models that can describe the nucleation and propagation of three-dimensional Li_(2)S_(2)/Li2S,as well as affords critical views how electrolyte dictates LiPS conversion from liquid to *** hopes to encourage necessary scaffold strategies and electrolyte formulations to further improve energy density and life span of Li–S batteries.

关键词： Lithium–sulfur batteries Electrolyte Li_(2)S precipitation Characterization

Estimation of the anisotropy of hydraulic conductivity through 3D fracture networks using the directional geological entropy

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International Journal of Mining Science and Technology 2024年第2期34卷 137-148页

作者： Chuangbing Zhou Zuyang Ye Chi yao Xincheng fan Feng Xiong School of Infrastructure Engineering Nanchang UniversityNanchang 330031China b School of Resource and Environmental Engineering Wuhan University of Science and TechnologyWuhan 430081China School of Engineering China University of GeosciencesWuhan 430074China

With an extension of the geological entropy concept in porous media,the approach called directional entrogram is applied to link hydraulic behavior to the anisotropy of the 3D fracture networks.A metric called directional entropic scale is used to measure the anisotropy of spatial order in different *** with the traditional connectivity indexes based on the statistics of fracture geometry,the directional entropic scale is capable to quantify the anisotropy of connectivity and hydraulic conductivity in heterogeneous 3D fracture *** to the numerical analysis of directional entrogram and fluid flow in a number of the 3D fracture networks,the hydraulic conductivities and entropic scales in different directions both increase with spatial order(i.e.,trace length decreasing and spacing increasing)and are independent of the dip *** a result,the nonlinear correlation between the hydraulic conductivities and entropic scales from different directions can be unified as quadratic polynomial function,which can shed light on the anisotropic effect of spatial order and global entropy on the heterogeneous hydraulic behaviors.

关键词： 3D fracture network Geological entropy Directional entropic scale Anisotropy Hydraulic conductivity

Image Inpainting Technique Incorporating Edge Prior and Attention Mechanism

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Computers, Materials & Continua 2024年第1期78卷 999-1025页

作者： Jinxian Bai yao fan Zhiwei Zhao Lizhi Zheng College of Information Engineering Xizang Minzu UniversityXianyang712000China

Recently,deep learning-based image inpainting methods have made great strides in reconstructing damaged ***,these methods often struggle to produce satisfactory results when dealing with missing images with large holes,leading to distortions in the structure and blurring of *** address these problems,we combine the advantages of transformers and convolutions to propose an image inpainting method that incorporates edge priors and attention *** proposed method aims to improve the results of inpainting large holes in images by enhancing the accuracy of structure restoration and the ability to recover texture *** method divides the inpainting task into two phases:edge prediction and image ***,in the edge prediction phase,a transformer architecture is designed to combine axial attention with standard *** design enhances the extraction capability of global structural features and location *** also balances the complexity of self-attention operations,resulting in accurate prediction of the edge structure in the defective *** the image inpainting phase,a multi-scale fusion attention module is *** module makes full use of multi-level distant features and enhances local pixel continuity,thereby significantly improving the quality of image *** evaluate the performance of our *** experiments are conducted on several datasets,including CelebA,Places2,and *** experiments show that our method outperforms the other mainstream ***,it improves Peak Signal-to-Noise Ratio(PSNR)and Structure Similarity Index Measure(SSIM)by 1.141~3.234 db and 0.083~0.235,***,it reduces Learning Perceptual Image Patch Similarity(LPIPS)and Mean Absolute Error(MAE)by 0.0347~0.1753 and 0.0104~0.0402,*** experiments reveal that our method excels at reconstructing images with complete structural information and c

关键词： Image inpainting transformer edge prior axial attention multi-scale fusion attention

Multi-functional and multi-scenario applications for MXene aerogels with synergistically enhanced asymmetric modules

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Nano Research 2024年第4期17卷 3359-3368页

作者： Junru yao Jintang Zhou Feng Yang Guiyu Peng Yijie Liu Zhengjun yao fan Wu Haibo Zeng College of Materials Science and Technology Nanjing University of Aeronautics and AstronauticsNanjing 211100China Key Laboratory of Material Preparation and Protection for Harsh Environment(Nanjing University of Aeronautics and Astronautics) Ministry of Industry and Information TechnologyNanjing 211100China School of Mechanical Engineering Nanjing University of Science and TechnologyNanjing 210094China

The development of multifunctional materials and synergistic applications of various functions are important conditions for integrated and miniaturized ***,we developed asymmetric MXene/aramid nanofibers/polyimides(AMAP)aerogels with different modules using an integrated molding *** asymmetric modules(layered MXene/aramid nanofibers section and porous MXene/aramid nanofibers/polyimides section)interactions are beneficial for enhanced performances,resulting in low reflection electromagnetic interference(EMI)shielding(specific shielding effectiveness of 2483(dB·cm^(3))/g and a low R-value of 0.0138),high-efficiency infrared radiation(IR)stealth(ultra-low thermal conductivity of 0.045 W/(m·K)and IR emissivity of 0.32 at 3–5μm and 0.28 at 8–14μm),and excellent thermal management performances of insulated Joule ***,these multifunctional AMAP aerogels are suitable for various application scenarios such as personal and building protection against electromagnetic pollution and cold,as well as military equipment protection against infrared detection and EMI.

关键词： multifunctional material electromagnetic interference shielding low reflection infrared radiation stealth thermal insulation Joule heating

A symmetric substructuring method for analyzing the natural frequencies of conical origami structures

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Theoretical & Applied Mechanics Letters 2024年第3期14卷 203-210页

作者： Chenhao Lu yao Chen Weiying fan Jian Feng Pooya Sareh Key Laboratory of Concrete and Prestressed Concrete Structures of Ministry of Education and National Prestress Engineering Research CenterSoutheast UniversityNanjing 211189China School of Engineering University of LiverpoolLiverpool L693BXUnited Kingdom Creative Design Engineering Lab(Cdel) School of EngineeringNewcastle UniversityNewcastle upon Tyne NE17RUUnited Kingdom Escuela Técnica Superior de Ingeniería y Diseño Industrial Universidad Politécnica de Madrid(UPM)Madrid 28012Spain

Conical origami structures are characterized by their substantial out-of-plane stiffness and *** investigations have commonly focused on the static characteristics of these lightweight ***,the efficient analysis of the natural vibrations of these structures is pivotal for designing conicalorigami structures with programmable stiffness and *** this paper,we propose a novel method to analyzethe natural vibrations of such structures by combining a symmetric substructuring method(SSM)and a gener-alized eigenvalue *** exploits the inherent symmetry of the structure to decompose it into a finiteset of repetitive *** doing so,we reduce the dimensions of matrices and improve computationalefficiency by adopting the stiffness and mass matrices of the substructures in the generalized eigenvalue *** element simulations of pin-jointed models are used to validate the computational results of the ***,the parametric analysis of the structures demonstrates the influences of the number of seg-ments along the circumference and the radius of the cone on the structural mass and natural frequencies of ***,we present a comparison between six-fold and four-fold conical origami structures anddiscuss the influence of various geometric parameters on their natural *** study provides a strategyfor efficiently analyzing the natural vibration of symmetric origami structures and has the potential to contributeto the efficient design and customization of origami metastructures with programmable stiffness.

关键词： Natural structural vibration Origami design Group theory Symmetric substructuring method(SSM) Generalized eigenvalue analysis

Origin of the Yueguang gold deposit in Xinhua, Hunan Province, South China: insights from fl uid inclusion and hydrogen–oxygen stable isotope analysis

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Acta Geochimica 2024年第2期43卷 235-254页

作者： Hongxin fan Qiang Wang Yulong Yang yao Tang Hao Zou College of Earth Sciences Chengdu University of TechnologyChengdu 610059China College of Earth Sciences Jilin UniversityJilin 130061China

The Yueguang gold deposit is located in Fengjia,Xinhua County,Hunan Province,South *** represents a recently discovered small-scale gold deposit situated in the southwestern region of the Jiangnan Orogenic Belt,west of the Baimashan granitic *** order to discern the characteristics of the ore-formingﬂuids,the underlying mineralization processes,and establish a foundation for the origin of the Yueguang gold depositﬂuid inclusion micro-thermometry,as well as quartz hydrogen and oxygen isotope analysis,have been carried out on samples obtained from various stages of *** hydrothermal miner-alization stages within the Yueguang gold deposit can be categorized into three stages:(i)the barren,pre-ore quartz-pyrite stage(Stage Ⅰ),the quartz-pyrite-gold stage(Stage Ⅱ),and the post-ore quartz-carbonate stage(Stage Ⅲ),with the second stage being the main mineralization ***ﬂuid inclusions identiﬁed in samples from the main min-eralization stage can predominantly be described with the NaCl–H_(2)O and CO_(2)–NaCl–H_(2)O *** inclusions display homogenization temperatures ranging from 158.8 to 334.9℃,and theﬂuid salinity ranges from 0.3%to 4.0%(wt.%NaCl equiv.).Laser Raman spectroscopy analysis of individual inclusions further reveals the presence of gas-phases such as CO_(2),CH_(4),and N_(2).Isotopic analysis indicatesδ^(18)Oﬂuid values ranging from 3.95 to 6.7‰ and δDH_(2)O values ranging from-71.9 to-55.7‰.These results indi-cate that the ore-formingﬂuid of the Yueguang gold deposit belongs to metamorphic hydrothermalﬂuids of middle-low temperature and low *** the process of ore formation,gold is transported in the form of Au(HS)2-complexes,with gold deposition being driven byﬂuid ***,the Yueguang gold deposit is categorized as an orogenic gold deposit dominated by metamorphic hydrother-malﬂ*** may become a new target for gold exploration in the Baimashan region,central Hunan Province.

关键词： Hunan province Yueguang gold deposit Fluid inclusions Hydrogen–oxygen isotopes Laser Raman Fluid immiscibility Orogenic gold deposit