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Toward long-life Zn anode using highly polar electrolyte additives

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Journal of Energy Chemistry 2025年第2期101卷 651-660页

作者： Nengbin Cai Hongming Chen Busheng Zhang Zijing Liu Xinbo he Dan Zhou Beijing Advanced Innovation Center for Materials Genome Engineering University of Science and Technology Beijing Shunde Innovation School University of Science and Technology Beijing School of Textile Science and Engineering Wuyi University

Unstable Zn interface caused by rampant dendrite growth and parasitic side reactions always hinders the practical application of aqueous zinc metal batteries（AZMBs）,herein,tyrosine（Tyr） with high molecular polarity was introduced into aqueous electrolyte to modulate the interfacial electrochemistry of Zn *** AZMBs,the positively charged side of Tyr can be well adsorbed on the surface of Zn anode to form a water-poor layer,and the exposed carboxylate side can be easily coordinated with Zn2+,favoring inducing uniform plating of Zn2+and inhibiting the occurrence of water-induced side *** in turn enable the achievement of highly stable Zn ***,the Zn anodes achieve outstanding cyclic stability(3000 h at 2 mA cm-2,2 mA h cm-2and 1300 h at 5 mA cm-2,5 mA h cm-2),high average Coulombic efficiency（99.4% over 3200 cycles）,and high depth of discharge（80% for 500 h）.Besides,the assembled Zn‖NaV3O8·1.5H2O full cells deliver remarkable capacity retention and ultra-long lifetime(61.8% over 6650 cycles at 5 A g-1) and enhanced rate capability(169 mA h g-1at 5 A g-1).The work may promote the design and deep understanding of electrolyte additives with high molecular polarity for high-performance AZMBs.

关键词： AZMBs Electrolyte additives Highly stable Zn anode Interfacial electrochemistry Tyr

The detection,extraction and parameter estimation of extreme-mass-ratio inspirals with deep learning

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Science China(Physics,Mechanics & Astronomy) 2025年第1期68卷 82-92页

作者： Qianyun Yun Wen-Biao Han Yi-Yang Guo he Wang Minghui Du Hangzhou Institute for Advanced Study University of Chinese Academy of SciencesHangzhou 310124China Shanghai Astronomical Observatory Chinese Academy of SciencesShanghai 200030China School of Physics and Astronomy Shanghai Jiao Tong UniversityShanghai 200240China School of Astronomy and Space Science University of Chinese Academy of SciencesBeijing 100049China Taiji Laboratory for Gravitational Wave Universe(Beijing/Hangzhou) University of Chinese Academy of SciencesBeijing 100049China Lanzhou Center for Theoretical Physics Key Laboratory of Theoretical Physics of Gansu ProvinceKey Laboratory of Quantum Theory and Applications of MoELanzhou UniversityLanzhou 730000China Institute of Theoretical Physics&Research Center of Gravitation Lanzhou UniversityLanzhou 730000China International Centre for Theoretical Physics Asia-Pacific(ICTP-AP) University of Chinese Academy of Sciences(UCAS)Beijing 100049China Center for Gravitational Wave Experiment National Microgravity LaboratoryInstitute of MechanicsChinese Academy of SciencesBeijing 100190China

One of the primary goals of space-borne gravitational wave detectors is to detect and analyze extreme-mass-ratio inspirals(EM-RIs).This task is particularly challenging because EMRI signals are complex,lengthy,and *** this work,we introduce a 2-layer convolutional neural network(CNN)approach to detect EMRI signals for space-borne detectors,achieving a true positive rate(TPR)of 96.9%at a 1%false positive rate(FPR)for signal-to-noise ratio(SNR)from 50 to ***,the key intrinsic parameters of EMRIs such as the mass,spin of the supermassive black hole(SMBH)and the initial eccentricity of the orbit can also be inferred directly by employing a neural *** mass and spin of the SMBH can be determined at 99%and 92%*** will greatly reduce the parameter spaces and computing cost for the following Bayesian parameter *** model also has a low dependency on the accuracy of the waveform *** study underscores the potential of deep learning methods in EMRI data analysis,enabling the rapid detection of EMRI signals and efficient parameter estimation.

关键词： gravitational wave EMRIs deep-learing

EDA-complexes-enabled photochemical synthesis of α-amino acids with imines and tetrabutylammonium oxalate

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Chinese Chemical Letters 2025年第1期36卷 1-2页

作者： Min-Hang Zhou Jun Jiang Wei-Min he School of Chemistry and Chemical Engineering University of South ChinaHengyang 421001China

The synthesis ofα-amino acid from imines with different carbonyl sources is attractive for both synthetic organic and medicinal chemistry ***,which were easily available from the corresponding ketones and amines,were employed as one of the most ideal ***,cyanation and subsequent hydrolysis were required to install the carboxyl group^([1]).In these cases,the toxicity of the cyanation reagents limited its further synthetic applications in organic ***,metal activation of imine substrates to make the organometallic intermediate and trap CO_(2) to give the desiredα-amino acid were also developed by many groups(Scheme 1A).The utilization of stoiochiometric amounts of metal reagents was required to realize the ***,Yu reported a novel photocatalytic reductive carboxylation protocol for synthesis ofα-amino acid from imines with CO_(2)as the carbonyl source^([2]).

关键词： synthesis carbonyl photochemical

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面向机动目标的设定时间多约束协同制导律

自动化学报 2025年第1期51卷 104-116页

作者：李鹤宇王建斌张锐宋峰北京电子工程总体研究所北京100854

针对三维空间中多航天器协同捕获机动目标问题,提出一种具有终端角度约束和时间一致性约束的设定时间协同制导律,将视线(Line-of-sight,LOS)角误差和齐射攻击的收敛时间作为一个可提前设定的参数,实现对收敛时间进行设置.构建三维场景... 详细信息

针对三维空间中多航天器协同捕获机动目标问题,提出一种具有终端角度约束和时间一致性约束的设定时间协同制导律,将视线(Line-of-sight,LOS)角误差和齐射攻击的收敛时间作为一个可提前设定的参数,实现对收敛时间进行设置.构建三维场景航天器−目标运动学模型,在沿视线方向将同时攻击问题转化为一致性问题,提出一种分布式协同制导律,设定时间内使得多个航天器剩余飞行时间相等;在垂直视线方向利用滑模控制方法对制导律进行设计,使得每个航天器的视线角在设定时间内达到期望值.上述制导律中,设计了一种设定时间扩展状态观测器(Predefined-time extended state observer,PTESO)对未知的目标加速度进行估计.数值仿真结果验证了方法的有效性.

关键词：航天器协同制导律设定时间收敛状态估计时间一致性

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High-temperature calcination dramatically promotes the activity of Cs/Co/Ce-Sn catalyst for soot oxidation

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Chinese Chemical Letters 2025年第1期36卷 534-538页

作者： Meng Wang Yan Zhang Yunbo Yu Wenpo Shan Hong he Center for Excellence in Regional Atmospheric Environment Institute of Urban EnvironmentChinese Academy of SciencesXiamen 361021China Zhejiang Key Laboratory of Urban Environmental Processes and Pollution Control Ningbo Urban Environment Observation and Research StationInstitute of Urban EnvironmentChinese Academy of SciencesNingbo 315800China State Key Joint Laboratory of Environment Simulation and Pollution Control Research Center for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China University of Chinese Academy of Sciences Beijing 100049China

Catalytic oxidation of soot is of great importance for emission control on diesel *** this work,a highly active Cs/Co/Ce-Sn catalyst was investigated for soot oxidation,and it was unexpectedly found that high-temperature calcination greatly improved the activity of the *** the calcination temperature was increased from 500℃ to 750℃,T_(50) decreased from 456.9℃ to 389.8℃ in a NO/O_(2)/H_(2)O/N_(2) *** results revealed that high-temperature calcination can promote the ability to transfer negative charge density from Cs to other metal cations in Cs/Co/Ce-Sn,which will facilitate the production of more oxygen defects and the generation of more surface-active oxygen *** oxygen species are beneficial to the oxidation of NO to NO_(2),leading to the high yield of NO_(2) ***,the Cs/Co/Ce-Sn catalyst calcined at 750℃ demonstrated higher activity than that calcined at 500℃.This work provides a pathway to prepare high efficiency catalysts for the removal of soot and significant insight into the effects of calcination on soot oxidation catalysts.

关键词： Soot oxidation Calcination Surface defects Surface-active oxygen species NO_(2)

Impact of ocean data assimilation on the seasonal forecast of the 2014/15 marine heatwave in the Northeast Pacific Ocean

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Atmospheric and Oceanic Science Letters 2025年第1期18卷 24-31页

作者： Tiantian Tang Jiaying he Huihang Sun Jingjia Luo Institute for Climate and Application Research(ICAR)/Key Laboratory of Meteorological Disaster Nanjing University of Information Science and TechnologyNanjingChina

A remarkable marine heatwave,known as the“Blob”,occurred in the Northeast Pacific Ocean from late 2013 to early 2016,which displayed strong warm anomalies extending from the surface to a depth of 300 *** study employed two assimilation schemes based on the global Climate Forecast System of Nanjing University of Information Science(NUIST-CFS 1.0)to investigate the impact of ocean data assimilation on the seasonal prediction of this extreme marine *** sea surface temperature(SST)nudging scheme assimilates SST only,while the deterministic ensemble Kalman filter(EnKF)scheme assimilates observations from the surface to the deep *** latter notably improves the forecasting skill for subsurface temperature anomalies,especially at the depth of 100-300 m(the lower layer),outperforming the SST nudging *** excels in predicting both horizontal and vertical heat transport in the lower layer,contributing to improved forecasts of the lower-layer warming during the *** improvements stem from the assimilation of subsurface observational data,which are important in predicting the upper-ocean *** results suggest that assimilating ocean data with the EnKF scheme significantly enhances the accuracy in predicting subsurface temperature anomalies during the Blob and offers better understanding of its underlying mechanisms.

关键词： Seasonal forecast Ocean data assimilation Marine heatwave Subsurface temperature

Experimental and numerical simulation of the attenuation effect of blast shock waves in tunnels at different altitudes

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Defence Technology(防务技术) 2025年第1期43卷 120-141页

作者： Changjiang Liu Hujun Li Zhen Wang Yong he Guokai Zhang Mingyang Wang School of Mechanical Engineering Nanjing University of Science and TechnologyNanjing 210094China State Key Laboratory of Disaster Prevention and Mitigation of Explosion and Impact People's Liberation Army Engineering UniversityNanjing 210014China

Traffic engineering such as tunnels in various altitudinal gradient zone are at risk of accidental explosion,which can damage personnel and *** prediction of the distribution pattern of explosive loads and shock wave propagation process in semi-enclosed structures at various altitude environment is key research focus in the fields of explosion shock and fluid *** effect of altitude on the propagation of shock waves in tunnels was investigated by conducting explosion test and numerical *** on the experimental and numerical simulation results,a prediction model for the attenuation of the peak overpressure of tunnel shock waves at different altitudes was *** results showed that the peak overpressure decreased at the same measurement points in the tunnel entrance under the high altitude *** contrast,an increase in altitude accelerated the propagation speed of the shock wave in the *** average error between the peak shock wave overpressure obtained using the overpressure prediction formula and the measured test data was less than15%,the average error between the propagation velocity of shock waves predicted values and the test data is less than 10%.The method can effectively predict the overpressure attenuation of blast wave in tunnel at various altitudes.

关键词： Shock wave propagation Tunnel Altitude effect Peak overpressure Shock waves velocity Engineering safety

Recent Strategies and Advances in Hydrogel‑Based Delivery Platforms for Bone Regeneration

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Nano-Micro Letters 2025年第3期17卷 389-439页

作者： Xiao Wang Jia Zeng Donglin Gan Kun Ling Mingfang he Jianshu Li Yongping Lu Scientific and Technological Innovation Center for Biomedical Materials and Clinical Research Guangyuan Key Laboratory of Multifunctional Medical HydrogelGuangyuan Central HospitalGuangyuan 628000People’s Republic of China Jiangsu Collaborative Innovation Center of Biomedical Functional Materials Jiangsu Key Laboratory of Bio‑Functional MaterialsSchool of Chemistry and Materials ScienceNanjing Normal UniversityNanjing 210023People’s Republic of China College of Polymer Science and Engineering State Key Laboratory of Polymer Materials EngineeringSichuan UniversityChengdu 610065People’s Republic of China

Bioactive molecules have shown great promise for effectively regulating various bone formation processes,rendering them attractive therapeutics for bone ***,the widespread application of bioactive molecules is limited by their low accumulation and short half-lives in *** have emerged as ideal carriers to address these challenges,offering the potential to prolong retention times at lesion sites,extend half-lives in vivo and mitigate side effects,avoid burst release,and promote adsorption under physiological *** review systematically summarizes the recent advances in the development of bioactive molecule-loaded hydrogels for bone regeneration,encompassing applications in cranial defect repair,femoral defect repair,periodontal bone regeneration,and bone regeneration with underlying ***,this review discusses the current strategies aimed at improving the release profiles of bioactive molecules through stimuli-responsive delivery,carrier-assisted delivery,and sequential ***,this review elucidates the existing challenges and future directions of hydrogel encapsulated bioactive molecules in the field of bone regeneration.

关键词： Hydrogel Bone regeneration Bioactive molecules Drug delivery Nano-/microscale carriers

PrDA1-1 and its interacting proteins PrTCP1/PrTCP9 in flare tree peony affect yield by regulating seed weight and number

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Journal of Integrative Agriculture 2025年第2期24卷 610-622页

作者： Chunyan he Fangyun Cheng State Key Laboratory of Efficient Production of Forest Resources Beijing Forestry University National Engineering Research Center for Floriculture Beijing Forestry University Peony International Institute Beijing Forestry University School of Landscape Architecture Beijing Forestry University

Tree peony is an emerging woody oilseed crop that has the potential to help meet the growing demand for edible oil and biofuel, and breeding high-yield varieties is the key to increasing production. The DA1 gene regulates seed weight and number and effectively improves crop yield, although its function in tree peonies has not yet been reported. In this study, three PrDA1 genes were first identified in the whole genome of ‘Jing Hong' flare tree peony(Paeonia rockii). PrDA1-1 is homologous to AtDA1 and contains three types of conserved structural domains: UIM(ubiquitin-interacting motif), LIM(Lin11, Isl-1, and Mec-3), and DA-like. PrDA1-1 was strongly expressed during both the early and late stages of seed development, and its constitutive expression in Arabidopsis reduced seed number but increased seed weight, which ultimately led to a reduction in yield. PrDA1-1 was found to interact with PrTCP1/PrTCP9 in yeast and plants, and the constitutive expression of PrTCP1/PrTCP9 in Arabidopsis increased seed weight and number, which resulted in higher yield. Since this study showed that PrDA1-1 and PrTCP1/PrTCP9 regulate seed weight and number to affect yield, these new genetic resources will help to improve the seed yield of tree peonies.

关键词： DA1 gene family PrTCP1/PrTCP9 Paeonia rockii seed traits