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Science China Chemistry 2024年第9期67卷 2989-2997页

作者： Pengxin wang Xiaoyong Zhang Lingqing wang rui wang Dongxu Yang Key Laboratory of Preclinical Study for New Drugs of Gansu Province School of Basic Medical Sciences & Research Unit of Peptide ScienceChinese Academy of Medical Sciences Lanzhou University State Key Laboratory of Bioactive Substance and Function of Natural Medicines Institute of Materia Medica Chinese Academy of Medical Sciences and Peking Union Medical College School of Sciences Great Bay University Institute of Systems and Physical Biology Shenzhen Bay Laboratory

Chirality transformation is a basic, attractive, and important strategy for obtaining enantioenriched products with desired chiral elements. The reported chirality conversion reaction often involves the process from one type of chirality to another one. To better utilize the chirality transformation strategy for obtaining two or more products with different chiral elements in a single reaction, a new method of kinetic resolution accompanied by a chirality transformation protocol is proposed and successfully realized in this study. This process is used for the asymmetric oxidation of phenol compounds along with the kinetic resolution of oxaziridines. A wide scope of products, including axially chiral phenols, oxaziridines, and α-hydroxyl cyclic ketones were smoothly obtained in high levels of yields and enantioselectivities in the developed method. These products can be readily used for the synthesis of various types of chiral ligands, which are potential choices for other catalytic asymmetric reactions.

关键词： chirality transformation kinetic resolution accompanied axially chiral phenols chiral oxaziridines

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Neurotoxicity of tetramethylammonium ion on larval and juvenile zebrafish:Effects on neurobehaviors and multiple biomarkers

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Journal of Environmental Sciences 2024年第9期143卷 138-147页

作者： ruixin Zhang rui wang Jiajun Chang GDaniel Sheng Daqiang Yin Key Laboratory of Yangtze River Water Environment Ministry of EducationCollege of Environmental Science and EngineeringTongji UniversityShanghai 200092China Shanghai Institute of Pollution Control and Ecological Security Shanghai 200092China

Tetramethylammonium hydroxide(TMAH)is an important compound that utilized and released by the rapidly expanding semiconductor industry,which could hardly be removed by the conventional wastewater treatment *** a cholinergic agonist,the tetramethylammonium ion(TMA^(+))has been reported to induce toxicity to muscular and respiratory systems of mammals and human,however the toxicity on aquatic biota remains poorly *** investigated the neurotoxic effects of TMA^(+)exposure on zebrafish,based on neurobehavior tests and a series of *** inhibitions on the swimming distance of zebrafish larvae were observed when the exposure level exceeded 50 mg/L,and significant alterations on swimming path angles(straight and deflective movements)occurred even at 10 mg/*** tested neurobehavioral endpoints of zebrafish larvae were significantly positively correlated with reactive oxygen species(ROS)and malondialdehyde(MDA),significantly negatively related with the activities of antioxidant enzymes,but not significantly correlated with the level of acetylcholinesterase(AChE).Such relationship indicates that the observed neurotoxic effects on swimming behavior of zebrafish larvae is mainly driven by oxidative stress,rather than the alterations of *** the highest exposure concentration(200 mg/L),TMA^(+)evoked more severe toxicity on zebrafish juveniles,showing significantly stronger elevation on the MDA activity,and greater inhibitions on the activities of antioxidant enzymes and ACh E,suggesting juveniles were more susceptible to TMA^(+)exposure than larval zebrafish.

关键词： Tetramethylammonium Zebrafish Oxidative stress Acetylcholinesterase Neurobehavior

Evolutionary Multi-Tasking Optimization for High-Efficiency Time Series Data Clustering

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Tsinghua Science and Technology 2024年第2期29卷 343-355页

作者： rui wang Wenhua Li Kaili Shen Tao Zhang Xiangke Liao Xiangjiang Laboratory Changsha 410205China College of Systems Engineering National University of Defense TechnologyChangsha 410073China Ant Group Co. Ltd.Hangzhou 310000China College of Computer Science and Technology NUDTChangsha 410073China

Time series clustering is a challenging problem due to the large-volume,high-dimensional,and warping characteristics of time series *** clustering methods often use a single criterion or distance measure,which may not capture all the features of the *** paper proposes a novel method for time series clustering based on evolutionary multi-tasking optimization,termed i-MFEA,which uses an improved multifactorial evolutionary algorithm to optimize multiple clustering tasks simultaneously,each with a different validity index or distance ***,i-MFEA can produce diverse and robust clustering solutions that satisfy various preferences of *** on two artificial datasets show that i-MFEA outperforms single-objective evolutionary algorithms and traditional clustering methods in terms of convergence speed and clustering *** paper also discusses how i-MFEA can address two long-standing issues in time series clustering:the choice of appropriate similarity measure and the number of clusters.

关键词： time series clustering evolutionary multi-tasking multifactorial optimization clustering validity index distance measure

A study of novel real-time power balance strategy with virtual asynchronous machine control for regional integrated electric-thermal energy systems

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Science China(Technological Sciences) 2024年第7期67卷 2074-2086页

作者： wang rui LI Ming-Jia wang YiBo SUN QiuYe ZHANG PinJia College of Information Science and Engineering Northeastern UniversityShenyang 110819China School of Mechanical Engineering Beijing Institute of TechnologyBeijing 100081China Department of Electrical Engineering Tsinghua UniversityBeijing 100084China

The development of regional integrated electric-thermal energy systems(RIETES) is considered a promising direction for modern energy supply systems. These systems provide a significant potential to enhance the comprehensive utilization and efficient management of energy resources. Therein, the real-time power balance between supply and demand has emerged as one pressing concern for system stability operation. However, current methods focus more on minute-level and hour-level power optimal scheduling methods applied in RIETES. To achieve real-time power balance, this paper proposes one virtual asynchronous machine(VAM) control using heat with large inertia and electricity with fast response speed. First, the coupling timescale model is developed that considers the dynamic response time scales of both electric and thermal energy systems. Second, a real-time power balance strategy based on VAM control can be adopted to the load power variation and enhance the dynamic frequency response. Then, an adaptive inertia control method based on temperature variation is proposed, and the unified expression is further established. In addition, the small-signal stability of the proposed control strategy is validated. Finally, the effectiveness of this control strategy is confirmed through MATLAB/Simulink and HIL(Hardware-in-the-Loop) experiments.

关键词： regional integrated electric-thermal energy systems real-time power balance virtual asynchronous machine adaptive inertia small-signal stability

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Light/pH dual-responsive magnetic metal-organic frameworks composites for phosphorylated peptide enrichment

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Chinese Chemical Letters 2024年第7期35卷 222-226页

作者： rui wang He Qi Haijiao Zheng Qiong Jia College of Chemistry Jilin UniversityChangchun 130012China Key Laboratory for Molecular Enzymology and Engineering of Ministry of Education School of Life SciencesJilin UniversityChangchun 130012China

Metal-organic frameworks(MOFs)combined with specific ligands are highly adaptable smart materials that can respond to external and physiological *** this study,we introduced a pyridinyl zwitterionic ligand with light/pH dual response into magnetic MOF composite(Fe_(3)O_(4)@ZW-MOF)for enrichment of phosphorylated peptides for the first *** introduction of the developed ligand gives MOF material dual response *** stimulation affects the generation/disappearance of free radicals of the pyridine derivative,resulting in a change in the charge gradient of the zwitterion,and zwitterion can also regulate the p H of the solution by adding acid or ***,the reversible capture and release of phosphorylated peptides can be easily achieved by adjusting light and *** established phosphorylated peptide enrichment platform exhibits high sensitivity(detection limit of 1 fmol),high selectivity(β-casein:BSA,1:1000),and good reusability(7 cycles).In addition,the method was applied to the enrichment of phosphorylated peptides in complex systems(non-fat milk and human serum),demonstrating the feasibility of this method for phosphoproteom *** conclusion,the synthesized Fe_(3)O_(4)@ZW-MOF is a promising MOF material,which provides the possibility to advance the application of responsive MOFs materials in proteomics.

关键词： Light pH Dual-response Metal-organic frameworks Phosphorylated peptide

A combination of straw incorporation and polymer-coated urea offsets soil ammonia and nitrous oxide emissions in winter wheat fields

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Journal of Integrative Agriculture 2024年第5期23卷 1718-1736页

作者： Xiaoyun wang Yajie Tian Qianhui Zhang Zhengxin Zhao rui wang Huanjie Cai Key Laboratory of Agricultural Soil and Water Engineering in Arid and Semiarid Areas of Ministry of Education Northwest A&F UniversityYangling712100China College of Water Resources and Architectural Engineering Northwest A&F UniversityYangling 712100China

The combined effects of straw incorporation(SI)and polymer-coated urea(PCU)application on soil ammonia(NH_(3))and nitrous oxide(N_(2)O)emissions from agricultural fields have not been comprehensively evaluated in Northwest *** conducted a two-year field experiment to assess the effects of combining SI with either uncoated urea(U)or PCU on soil NH_(3)emissions,N_(2)O emissions,winter wheat yields,yield-scaled NH_(3)(/NH_(3)),and yield-scaled N_(2)O(/N_(2)O).Five treatments were investigated,no nitrogen(N)fertilizer(N_(0)),U application at 150 kg N ha-1 with and without SI(SI+U and S_(0)+U),and PCU application at 150 kg N ha^(-1) with and without SI(SI+PCU and S_(0)+PCU).The results showed that the NH_(3);emissions increased by 20.98-34.35%following Sl compared to straw removal,mainly due to increases in soil ammonium(NH_(4)^(+)-N)content and water-flled pore space(WFPS).SI resulted in higher N_(2)O emissions than under the So scenario by 13.31-49.23%due to increases in soil inorganic N(SIN)contents,WFPS,and soil microbial *** contrast,the PCU application reduced the SIN contents compared to the U application,reducing the NH_(3)and N_(2)O emissions by 45.99-58.07 and 18.08-53.04%,***,no significant positive effects of the SI or PCU applications on the winter wheat yield were *** lowest /NH_(3) and /N_(2)O values were observed under the S_(0)+PCU and SI+PCU *** results suggest that single PCU applications and their combination with straw are the optimal agricultural strategies for mitigating gaseous N emissions and maintaining optimal winter wheat yields in Northwest China.

关键词： straw incorporation polymer-coated urea NH_(3)and N_(2)O emissions winter wheat yields

Nonlocal coherence harvesting from quantum vacuum

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Communications in Theoretical Physics 2024年第7期76卷 46-53页

作者： rui-Di wang Shu-Min Wu Xiao-Li Huang Department of Physics Liaoning Normal University

It is well known that nonlocal coherence reflects nonclassical correlations better than quantum entanglement. Here, we analyze nonlocal coherence harvesting from the quantum vacuum to particle detectors adiabatically interacting with a quantum scalar field in Minkowski *** find that the harvesting-achievable separation range of nonlocal coherence is larger than that of quantum entanglement. As the energy gap grows sufficiently large, the detectors harvest less quantum coherence, while the detectors could extract more quantum entanglement from the vacuum state. Compared with the linear configuration and the scalene configuration, we should choose the model of equilateral triangle configuration to harvest tripartite coherence from the vacuum. Finally, we find a monogamous relationship, which means that tripartite l1-norm of coherence is essentially bipartite types.

关键词： monogamous relationship nonlocal coherence quantum vacuum

Stabilization and detection of labile reaction intermediates in supramolecular containers

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Chinese Chemical Letters 2024年第6期35卷 47-52页

作者： rui wang Yang Liang Julius Rebek Jr. Yang Yu Center for Supramolecular Chemistry&Catalysis and Department of Chemistry College of ScienceShanghai UniversityShanghai 200444China Skaggs Institute for Chemical Biology and Department of Chemistry The Scripps Research InstituteLa JollaCA 92037United States

Detection and observation of reactive intermediates is an essential step in investigation of reaction ***,most reactive intermediates are unstable and present at low concentrations;their short lifetimes make them difficult to detect and *** containers offer opportunities for the stabilization and characterization of those labile species,through isolation from the media and protection inside the cavity of the *** this review,we summarize the examples of labile reaction intermediates that are stabilized and characterized with the help of supramolecular *** container compounds include carcerands,deep cavitands and amide *** focus on unstable guest species-cyclobutadiene,benzocyclopropenone,o-benzyne,1,2,4,6-cycloheptatetraene,anti-Bredt's olefin,fluorophenoxycarbene,O-acylisoamide,and hemiaminalthat act as intermediates in certain organic reactions.

关键词： Supramolecular containers Reaction intermediates Labile species stabilization Short-lived species detection Supramolecular chemistry

Characteristics of water alternating CO_(2)injection in low-permeability beach-bar sand reservoirs

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Energy Geoscience 2024年第1期5卷 224-229页

作者： Maolei Cui rui wang Zengmin Lun Chengyuan Lv State Key Laboratory of Shale Oil and Gas Enrichment Mechanisms and Effective Development Beijing100083China Key Laboratory of Marine Oil and Gas Reservoir Production SINOPECBeijing100083China Petroleum Exploration and Development Research Institute SINOPECBeijing100083China

Water flooding can be ineffective in highly heterogeneous low-permeability beach-bar sand *** introduction of CO_(2)flooding helps boost the oil production of the reservoirs but only in an early *** the late stage of flooding,gas channeling would *** alternating gas(CO_(2))(WAG)process can be used to delay gas channeling and improve the effect of CO_(2)injection,though its adaptability to beach-bar sand reservoirs remains *** order to clarify CO_(2)injection characteristics in these reservoirs,experiments were carried out in high-temperature high-pressure NMR on-line displacement experiment apparatus to simulate different flooding modes on synthetic cores that can reflect the vertical heterogeneity of beach-bar *** CO_(2)injection modes were implemented on these cores and the displacement characteristics and residual oil distribution features during both WAG injection and continuous CO_(2)injection were analyzed quantitatively and *** results show that the scheme of WAG injection after continuous CO_(2)injection can obtain better oil displacement efficiency than that of the scheme of continuous CO_(2)injection after WAG injection,but there is no significant difference in respect of oil displacement efficiency of WAG flooding between the mode of bar-injection e beach-production(injection into bar sand e production from beach sand)and the mode of beach-injection e beach-production(injection into and production from beach sand),with the former mode having a higher oil recovery *** wider pore-size distribution range of microscopic residual oil after WAG injection shows great potential of enhancing oil recovery from subsequent continuous gas *** WAG injection is implemented prior to continuous CO_(2)injection,the displacement effect of the latter is more *** research may provide a theoretical basis for CO_(2)EOR in this type of reservoirs.

关键词： Beach-bar sand Low permeability CO_(2)injection WAG NMR

Technological advancement and industrialization path of Sinopec in carbon capture,utilization and storage,China

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Energy Geoscience 2024年第1期5卷 204-211页

作者： Yang Li rui wang Qingmin Zhao Zhaojie Xue China Petroleum&Chemical Corporation Beijing100728China Sinopec Exploration&Production Research Institute Beijing100083China

Carbon capture,utilization and storage(CCUS)technology is an important means to effectively reduce carbon emissions from fossil energy combustion and industrial *** the crisis of climate change,CCUS has attracted increasing attention in the *** technology as developed rapidly in China is technically feasible for large-scale application in various *** R&D and demonstration of CCUS in China Petroleum&Chemical Corporation(Sinopec)are summarized,including carbon capture,carbon transport,CO_(2)enhanced energy recovery(including oil,gas,and water,etc.),and comprehensive utilization of CO_(2).Based on the source-sink matching characteristics in China,two CCUS industrialization scenarios are proposed,namely,CO_(2)-EOR,CO_(2)-driven enhanced oil recovery using centralized carbon sinks in East China and CO_(2)-EWR,CO_(2)-driven enhanced water recovery(EWR)using centralized carbon sources from the coal chemical industry in West ***,a CCUS industrialization path from Sinopec's perspective is suggested,using CO_(2)-EOR as the major means and CO_(2)-EWR,CO_(2)-driven enhanced gas recovery(CO_(2)-EGR)and other utilization methods as important supplementary means.

关键词： Carbon capture Transport Enhanced energy recovery Comprehensive utilization Industrialization path