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Selectively nucleotide-derived RuP on N,P-codoped carbon with engineered mesopores for energy-efficient hydrogen production assisted by hydrazine oxidation

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SusMat 2024年第1期4卷 166-177页

作者： Xiya Guan Yu Sun Simeng Zhao Haibo Li Suyuan Zeng Qingxia Yao rui Li Hongyan Chen Konggang qu School of Chemistry and Chemical Engineering Shandong Provincial Key Laboratory/Collaborative Innovation Center of Chemical Energy Storage&Novel Cell TechnologyLiaocheng UniversityLiaochengChina

Integrating hydrogen evolution reaction(HER)with hydrazine oxidation reaction(HzOR)has an encouraging prospect for the energy-saving hydrogen production,demanding the high-performance bifunctional HER/HzOR *** phosphide/doped carbon composites have exhibited superior activity towardmultiple electrocatalytic *** explore the decent water-soluble precursors containing bothNand P elements is highly attractive to facilely prepare metal phosphide/doped carbon ***,as one kind ecofriendly biomolecules,adenine nucleotide was first employed to selectively fabricate the highly pure RuP nanoparticles embedded into porous N,P-codoped carbons(RuP/PNPC)with a straightforward“mix-and-pyrolyze”*** newly prepared RuP/PNPC only requires 4.0 and−83.0 mV at 10 mA/cm^(2) separately in alkaline HER and HzOR,outperforming most of reported electrocatalysts,together with the outstanding neutral bifunctional ***,the two-electrode alkaline and neutral overall hydrazine splitting both exhibit significant power-efficiency superiority to the corresponding overall water splitting with the voltage difference of larger than 2 V,which can be also easily driven by the fuel cells and solar cells with considerableH2 *** report innovates the N-and P-bearing adenine nucleotide to effortlessly synthesize the high-quality RuP/doped carbon composite catalysts,highly potential as a universal platform for metal phosphide-related functional materials.

关键词： bifunctional electrocatalyst hydrazine oxidation hydrogen energy hydrogen evolution RuP

A novel profile modification HPF-Co gel satisfied with fractured low permeability reservoirs in high temperature and high salinity

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Petroleum Science 2024年第1期21卷 683-693页

作者： Ya-Kai Li Ji-rui Hou Wei-Peng Wu Ming qu Tuo Liang Wei-Xin Zhong Yu-Chen Wen Hai-Tong Sun Yi-Nuo Pan China University of Petroleum Beijing Beijing102249China PetroChina Tarim Oilfield Company Korla 841000XinjiangChina Key Laboratory of Improving Oil and Gas Recovery of Ministry of Education Northeast Petroleum University Daqing 163318HeilongjiangChina Xi'an Shiyou University Xi'an 710065ShaanxiChina Northwest Oilfield Company SINOPECUrumqi 830011XinjiangChina

Conformance control and water plugging are a widely used EOR method in mature ***,majority of conformance control and water plugging agents are unavoidable dehydrated situation in high-temperature and high-salinity low permeability ***,a novel conformance control system HPF-Co gel,based on high-temperature stabilizer(CoCl_(2)·H_(2)O,CCH)is *** HPF-Co bulk gel has better performances with high temperature(120℃)and high salinity(1×10^(5)mg/L).According to Sydansk coding system,the gel strength of HPF-Co with CCH is increased to code *** dehydration rate of HPF-Co gel is 32.0%after aging for 150 d at 120℃,showing excellent thermal *** rheological properties of HPF gel and HPF-Co gel are also *** results show that the storage modulus(G′)of HPF-Co gel is always greater than that of HPF *** effect of CCH on the microstructure of the gel is *** results show that the HPF-Co gel with CCH has a denser gel network,and the diameter of the three-dimensional network skeleton is 1.5-3.5μ*** 90 d of aging,HPF-Co gel still has a good three-dimensional *** spectroscopy results show that CCH forms coordination bonds with N and O atoms in the gel amide group,which can suppress the vibration of cross-linked sites and improve the stability at high *** core plugging test determines the optimized polymer gel injection strategy and injection velocity with HPF-Co bulk gel system,plugging rate exceeding 98%.Moreover,the results of subsequent waterflooding recovery can be improved by 17%.

关键词： Low permeability reservoir High-temperature resistant gel Complexation reaction Polymer gel injection strategy Plugging rate Enhanced oil recovery

Zwitterionic ring-opening polymerization of macrocyclic ethyleneoxy-substituted carbonate:Access to cyclic PEG-like polycarbonate

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Chinese Chemical Letters 2024年第3期35卷 282-286页

作者： Jin Huang Jinwen Li rui Yan Yuanyuan qu Fengzhen Guo Lei Shen Can-liang Ma Jie Sun Zhenjiang Li Kai Guo State Key Laboratory of Materials-Oriented Chemical Engineering College of Biotechnology and Pharmaceutical EngineeringNanjing Tech UniversityNanjing 211816China Institute of Nanjing Advanced Biomaterials&Processing Equipment Lishui Economic Development ZoneNanjing 211299China

The innovation in polymer design to rival conventional polyethylene glycol(PEG)is an important approach to achieving a more sustainable ***,cyclic PEG-like polycarbonates having high molecular weight(4.4–49.5 kg/mol)were enabled through zwitterionic ring-opening polymerization(ZROP)of macrocyclic carbonates(MCs)mediated by N-heterocyclic carbene(NHC).The thermodynamic behavior of polymerization depends on the ring size of *** this process,the ZROP of 11-membered MC was driven by the change of enthalpy(ΔH_(p))which differed from the ZROP of 14-membered MC driven by the entropic change(ΔS_(p)).Cyclic polycarbonates depicted improved thermostability(T_(d5%)≥204℃)and higher glass transition temperatures(T_(g)>–40℃)in comparison to their linear analogues(T_(d5%)≤185℃,T_(g)~–50℃).In addition,the mechanism of ZROP of MC was addressed through computational study.A distinct mechanism of polymerization distinguishable from the well-known NHC-mediated ZROP of cyclic esters was revealed,where the zwitterion from nucleophilic addition to MC,*** intermediate,cannot be ring-opened probably due to the delocalization of negative charge on the carbonate group,but serves as an active center for the *** comparison to PEG,the attained polymer demonstrated comparable hydrophilic and biocompatible properties,as revealed by the results of contact angle and in vitro cytotoxicity studies,suggesting that cyclic polycarbonate hold the promise as the alternative of PEG.

关键词： Zwitterionic ring-opening polymerization Cyclic polycarbonate Macrocycles Tetrahedral intermediate NHC carbene

多波段共孔径光学成像系统的几种实现途径(特约)

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红外与激光工程 2020年第6期49卷 270-281页

作者：邓键曲锐黄建兵苏州领锐源奕光电科技有限公司江苏苏州215216 中国科学院西安光学精密机械研究所陕西西安710119

借助微分方法,提出光学系统内的消波段间色差和波段内色差条件,建立了扩展的复消色差理论,通过对比各自波段和全波段的折射率-色差系数,进行材料配对,并迭代优化校正各类像差。由此介绍了几种多波段共孔径光学系统的实现途径和具体设计... 详细信息

借助微分方法,提出光学系统内的消波段间色差和波段内色差条件,建立了扩展的复消色差理论,通过对比各自波段和全波段的折射率-色差系数,进行材料配对,并迭代优化校正各类像差。由此介绍了几种多波段共孔径光学系统的实现途径和具体设计实例,包括:透射式结构的宽波段及多波段成像物镜光学系统;透射式结构的中波/近红外二次成像变焦系统;透射式结构的中/长波红外二次成像变焦系统;通过反求工程(Reverse Engineering)设计了AN/AAQ-33"狙击手XR"吊舱采用的中波/近红外共孔径透射式前置望远系统主光路;AN/ASQ-228 ATFLIR吊舱采用的共孔径离轴三反射式消像散前置望远系统主光路;AN/AAS-52 MTS-B吊舱采用的同轴偏视场三反前置望远系统主光路;EKV采用的同轴四反二次成像系统;拓展介绍了采用同轴折反式前置望远+后置成像结构的光路结构,包括同轴折反式中波/短波/近红外和长/中/短波红外望远系统+后置分光成像系统的设计;以及一些典型弹载光学系统共孔径或共光路的设计。

关键词：光学设计多波段共孔径折反式光学系统前置望远系统

Different Types of Bone Fractures Observed by Terahertz Time-Domain Spectroscopy

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Acta Mechanica Solida Sinica 2024年第3期37卷 468-477页

作者： Minghao Zhang Xianjia Meng Zhiyong Wang Chuanyong qu Chuan qu Donghui Fu Department of Mechanics Tianjin UniversityTianjin300072China Tianjin Key Laboratory of Modern Engineering Mechanics Tianjin300072China

Microcracks are common in compact bone,but their continued propagation can lead to macroscopic *** microcracks cannot be visualized radiographically,necessitating alternative noninvasive methods to identify excessive microcracking and prevent *** this study,terahertz time-domain spectroscopy(THz-TDS)was used to examine bone interiors near cracks resulting from loading in bovine tibia *** loading configurations,such as impact,quasi-static loading,and fatigue loading,known to induce different types of micro-scale damage,were *** values of refractive index and absorption coefficient of the bone samples were then determined from the THz-TDS spectra acquired before loading and after *** study revealed that different loading configurations led to varying terahertz optical coefficients associated with various types of bone ***,the refractive index notably increased under fatigue loading but remained relatively stable during quasi-static *** absorption coefficient of bone decreased only under fatigue ***,samples were subjected to axial and radial impacts without sustaining *** indicated that in the undamaged state,the change in refractive index was smaller compared to after impact failure,while the change in absorption coefficient remained consistent after *** radial impact loading,changes in refractive index and absorption coefficient were significantly more pronounced than under axial *** to loading,the measured value of refractive index was 2.72±0.11,and the absorption coefficient was 6.33±0.09 mm^(−1)at 0.5 THz.

关键词： Terahertz time-domain spectroscopy Bone Microdamage Noninvasive method

Impacts of Comorbidity and Mental Shock on Organic Micropollutants in Surface Water During and After the First Wave of COVID-19 Pandemic in Wuhan (2019–2021), China

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Engineering 2024年第6期37卷 40-48页

作者： Jian Zhao Jin Kang Xiaofeng Cao rui Bian Gang Liu Shengchao Hu Xinghua Wu Chong Li Dianchang Wang Weixiao Qi Cunrui Huang Huijuan Liu Jiuhui qu Center for Water and Ecology State Key Joint Laboratory of Environment Simulation and Pollution ControlSchool of EnvironmentTsinghua UniversityBeijing 100084China Hubei Provincial Research Institute of Environmental Science Wuhan 430072China Key Laboratory of Drinking Water Science and Technology Research Centre for Eco-Environmental SciencesChinese Academy of SciencesBeijing 100085China Sanitary Engineering Department of Water ManagementFaculty of Civil Engineering and GeosciencesDelft University of TechnologyDelft 2600 GAThe Netherlands China Three Gorges Corporation Wuhan 430010China Vanke School of Public Health Tsinghua UniversityBeijing 100084China

The first pandemic wave of coronavirus disease 2019(COVID-19)induced a considerable increase in several antivirals and antibiotics in surface *** common symptoms of COVID-19 are viral and bacterial infections,while comorbidities(e.g.,hypertension and diabetes)and mental shock(e.g.,insomnia and anxiety)are ***,little is known about the long-term impacts of comorbidities and mental shock on organic micropollutants(OMPs)in surface ***,we monitored 114 OMPs in surface water and wastewater treatment plants(WWTPs)in Wuhan,China,between 2019 and *** pandemic-induced OMP pollution in surface water was confirmed by significant increases in 26 OMP *** increases in four antihypertensives and one diabetic drug suggest that the treatment of comorbidities may induce OMP ***,cotinine(a metabolite of nicotine)increased 155 times to 187 ngL1,which might be associated with increased ***,the increases in zolpidem and sulpiride might be the result of worsened insomnia and ***,it is reasonable to note that mental-health protecting drugs/behavior also contributed to OMP *** the observed OMPs,telmisartan,lopinavir,and ritonavir were associated with significantly higher ecological risks because of their limited WWTP-removal rate and high *** study provides new insights into the effects of comorbidities and mental shock on OMPs in surface water during a pandemic and highlights the need to monitor the fate of related pharmaceuticals in the aquatic environment and to improve their removal efficiencies in WWTPs。

关键词： Coronavirus disease 2019 Comorbidities Mental shock Micropollutant Surface water

Features of gastric cancer by anatomic subsite in northern China: A multi-center Health Science Report database study

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World Journal of Gastrointestinal Oncology 2022年第11期14卷 2238-2252页

作者： rui-Ze qu Yan-Peng Ma Xiao-Yuan Bao Li-Yuan Tao Xin Zhou Si-Yi Lu Yi Zhang Bing-Yan Wang Fei Li Lin Tuo Zhi-Peng Zhang Wei Fu Department of General Surgery Cancer CenterPeking University Third HospitalBeijing 100191China Medical Informatics Center Peking University Health Science CenterBeijing 100191China Research Center of Clinical Epidemiology Peking University Third HospitalBeijing 100191China Department of Hospital Management Peking University Health Science CenterBeijing 100191China

BACKGROUND The features of gastric cancer based on the anatomic site remain unknown in northern China *** To analyze gastric cancer features and associated trends based on the anatomical site in northern China *** This cross-sectional study used incident gastric cancer case data from 10 Peking University-affiliated hospitals(2014 to 2018).The clinical and prevailing local features were *** A total of 10709 patients were enrolled,including antral(42.97%),cardia(34.30%),and stomach body(18.41%)gastric cancer *** in the cardia had the highest male:female ratio,proportion of elderly patients,and patients with complications,including hypertension,diabetes,cerebrovascular,and coronary diseases(P<0.001).gastric cancer involving the antrum showed the lowest proportion of patients from rural areas and accounted for the highest hospitalization rate and cost(each P<0.001).The proportion of patients with cancer involving the cardia increased with an increase in the number of gastroesophageal reflux disease cases during the same period(P<0.001).Multivariate analysis revealed that tumor location in the cardia increased the risk of inhospital mortality(P=0.046).Anatomical subsite was not linked to postoperative *** The features of gastric cancer based on the anatomical site differ between northern China and other regions,both globally and within the *** factors may account for these differences and should affect policy-making and clinical practice.

关键词： Feature Gastric cancer Anatomical site Northern China

Timing and Spectral Analysis of the Black Hole X-Ray Binary MAXI J1803-298 with Insight-HXMT Data

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Research in Astronomy and Astrophysics 2024年第6期24卷 209-224页

作者： Ying-Chen Xu Jin-Lu qu MMéndez rui-Can Ma Long Ji Liang Zhang Yue Huang Qing-Cui Bu Li-Ming Song Key Laboratory of Particle Astrophysics Institute of High Energy PhysicsChinese Academy of SciencesBeijing 100049China University of Chinese Academy of Sciences Chinese Academy of SciencesBeijing 100049China Kapteyn Astronomical Institute University of GroningenP.O.BOX 8009700 AV GroningenThe Netherlands Dongguan Neutron Science Center Dongguan 523808China School of Physics and Astronomy Sun Yat-Sen UniversityZhuhai 519082China Institut für Astronomie und Astrophysik Kepler Center for Astro and Particle PhysicsEberhard Karls UniversitätSand 1D-72076 TübingenGermany

We present a comprehensive analysis of the 2021 outburst of MAXI J1803–298 utilizing observations of the Insight-Hard X-ray Modulation Telescope(Insight-HXMT)spanning from the low hard state to the high soft *** the Insight-HXMT data set,compared to the previous work,we identify a more prolonged presence of typeC quasi-periodic oscillations(QPOs)with centroid frequencies ranging from~0.16 to 6.3 Hz,which present correlations with the hardness ratio and the photon index of the Comptonized *** QPO frequencies less than~2 Hz,the QPO phase lags are hard(photons of 10–19 keV arrive later than those of 1–4 keV),while at higher frequencies,the lags become soft at and above~4 ***,the spectra in all Insight-HXMT observations consist of a multi-color blackbody component and a Comptonized component,as commonly observed in classical black hole X-ray *** analyze state transitions and the evolution of accretion geometry in this *** fitted inner disk radius increases abnormally during the low hard state,hypothesized to result from the corona condensing onto the inner ***,two significant drops in flux are observed during the soft intermediate state,maybe implying changes in the corona/jet and the disk,respectively.

关键词： X-rays:binaries accretion accretion disks stars:black holes

A Study on the End-Effector Exchange Mechanism of a Space Robot

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Journal of Mechanics Engineering and Automation 2017年第5期7卷 278-284页

作者： rui qu Yuto Takei Mitsushige Oda Hiroki Nakanishi Armin Wedler Kent Yoshikawa Department of Mechanical and Aerospace Engineering Tokyo Institute of Technology Tokyo 1528550 Japan RMC (Robotics and Mechatronics CenteO DLR (German Aerospace Center) Oberpfaffenhofen 82234 Germany

This study investigates the necessity for space robots to independently exchange their end-effectors due to the contradiction that exists between the requirements of various robots in space missions and the payload capacity limits of rockets. The results of this study summarize the system requirements for a new end-effector exchange mechanism, including compact size, misalignment tolerance, and regolith tolerance. This is followed by the development of a prototype model with a set of test apparatus. Then the function of the prototype is verified, the prototype is optimized, and the relation between docking force and misalignment is examined through operation tests.

关键词： Space robot end-effector exchange mechanism operation test.