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H-bonding template-directed synthesis of a complete m-PDA-bridged ladder polyhydrosiloxane (OLPHS)

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Chinese Chemical Letters 2007年第7期18卷 779-782页

作者： Kui Lin Deng Tao Yi zhang Xiao Jing zhang Ping Xie rong ben zhang State Key Laboratory on Polymer Physics ＆ Chemistry Joint Laboratory of Polymer Science ＆ MaterialsInstitute of Chemistry Chinese Academy of Sciences Beijing 100080 China Graduate School of the Chinese Academy of Sciences Beijing 100039 China College of Chemistry ＆ Environmental Science Hebei University Baoding 071002 China

A highly ordered m-phenylenediimino-bridged ladder polyhydrosiloxane （abbr. OLPHS） with Mn = 1.24 × 10^4 was synthesized stoichiometric hydrolysis and dehydrochlorination condensation reaction between Si-Cl and Si-OH bonds. The complete ladder structure of OLPHS has been confirmed by the following three data. Two characteristic Bragg＇s peaks representing the ladder width （w = 0.94 nm） and ladder thickness （t = 0.42 nm） were observed in XRD analysis, which are consistent with those calculated by molecular simulation. The very sharp absorption with a small half-peak width （w1/2 = 0.5 ppm） for [（-HN）HSiO2/2]n moiety of OLPHS in ^29Si NMR spectrum indicated presence of the complete ladder structure. As collateral evidence, a higher glass transition temperature （Tg = 105 ℃） is also recorded in the DSC measurement, implying the high stiffness of ladder chain of OLPHS.

关键词： H-bonding template Ladder polysiloxane Self-assembly Stepwise coupling/polymerization

H-Bonding Self-assembled Template-directed Synthesis of a Reactive Amide-bridged Ladder Polyvinylsiloxane

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Chinese Chemical Letters 2006年第10期17卷 1361-1364页

作者： You Zhi WAN Ying Hua LIU Ping XIE rong ben zhang Department of Applied Chemistry School of Science Beijing University of Chemical Technology Beijing 100029 State Key Laboratory of Polymer Physics and Chemistry Joint Laboratory of Polymer Science and Materials Institute of Chemistry Chinese Academy of Sciences Beijing 100080

A novel, reactive amide-bridged ladder polyvinylsiloxane （abbr. LP） with Mn= 2.4×10^4 was synthesized for the first time by means of aryl amide H-bonding self-assembled template. The regularity of LP was characterized by the XRD, ^29Si NMR and DSC methods. XRD analysis demonstrated the ladder width w = 9.09A and the ladder thickness t = 3.89A, respectively, which are approximately consistent with the molecular simulation-calculated ones： w＇= 10.60A and t＇= 3.06A. ^29Si NMR displayed a resonance peak with small half peak width, △1/2 - 4 ppm, for the moiety [=Si（Vi）O2/2-]n of LP. Besides, as a collateral evidence, DSC measurement revealed a high glass transition temperature Tg = 225℃, suggesting high stiffness of the ladder main chain of LP.

关键词： Ladder polyvinylsiloxane stepwise coupling polymerization amido H-bonding interaction.

H-BONDING SELF-ASSEMBLED TEMPLATE-CONTROLLED SYNTHESIS OF A NOVEL SOLUBLE AND REACTIVE AMIDE-BRIDGED LADDERLIKE POLYHYDROSILOXANE

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Chinese Journal of Polymer Science 2006年第1期24卷 67-72页

作者： Guan-qun Zhong Qing-hua Duan Kui-lin Deng Ai-qin zhang Ping Xie Hai-liang zhang rong-ben zhang Institute of Polymer Science Xiangtan University Xiangtan 411105 China State Key Laboratory on Polymer Physics ＆ Chemistry Joint Laboratory of Polymer Science ＆ Materials Institute of Chemistry Chinese Academy of Sciences Beijing 100080 China College of Chemistry＆ Environmental Science Hebei University Baoding 071002 China

A novel soluble and reactive amide-bridged ladderlike polyhydrosiloxane （ALPHS） was first synthesized by an amido H-bonding self-assembled template. ALPHS with molecular weight M^-a = 18300 has very highly ordered ladderlike structure, which was confirmed by a sharp resonance absorption peak of [-Si（H）O2/2 ] moiety with the half peak width △1/2 〈 0.5 in^29Si-NMR spectrum. Presence of the reactive Si-H groups gives ALPHS an opportunity to further derive a variety of functional polymers by versatile Si-H reactions such as hydrosilylation, condensation, and so on.

关键词： Ladderlike Polyhydrosiloxane Amido H-bonding template.

SYNTHESIS AND CHARACTERIZATION OF A NOVEL ALCOHOL-SOLUBLE POLYORGANOSILOXANE CONTAINING AMINO SIDE GROUPS

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Chinese Journal of Polymer Science 2001年第1期19卷 97-102页

作者： Chun-qing Liu Yang Liu Zhong-rong Shen Ping Xie rong-ben zhang Chao-bin He Tai-shung Chung PCLCC Center for Molecular Science Institute of Chemistry Chinese Academy of Sciences Beijing 100080 China PCLCCCenter for Molecular Science Institute of Chemistry Chinese Academy of Sciences Beijing 100080 China PCLCCCenter for Molecular Science Institute of Chemistry Chinese Academy of Sciences Beijing 100080 China PCLCCCenter for Molecular Science Institute of Chemistry Chinese Academy of Sciences Beijing 100080 China PCLCCCenter for Molecular Science Institute of Chemistry Chinese Academy of Sciences Beijing 100080 China Institute of Materials Research and Engineering National University of Singapore Singapore 119260 Institute of Materials Research and Engineering National University of Singapore Singapore 119260

A novel alcohol-soluble polyorganosiroxane containing amino side groups, poly[3-(4-aminophenoxy)-aminophenoxy) propylmethylsiloxane] (2), was first prepared by the reduction of nitro groups on 4-nitrophenoxypropyl side chains of poly[3-(4-nitrophenoxy)propylmethylsiloxane] (1). The reaction proceeded easily with nearly 100% conversion. The synthesized alcohol-soluble polymer 2, which has potential application as a precursor for preparing advanced functional polymers, was characterized by FTIR, H-1-NMR, C-13-NMR, Si-29-NMR, VPO and GPC, respectively.

关键词： alcohol-soluble polyorganosiloxane reduction characterization

ARCHITECTURE OF LADDER,TUBULAR AND SIEVE-PLATE POLYMERS PREPARED BY STEPWISE COUPLING POLYMERIZATION

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Chinese Journal of Polymer Science 2000年第3期18卷 195-206页

作者： rong-ben zhang Ping Xie Dao-rong Dai Chun-qing Liu Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, China 中科院化学所北京

'Stepwise-coupling polymerization' (SCP) is a very useful approach for preparing microstructure-controllable ordered network polymers, including soluble one-dimensional ladderlike polymers (LP) and tubular polymers (TP), and two-dimensional sieve-plate polymers. The novel reactive LPs are important precursors of micro-structure controllable polymers such as 'fishbone-' or 'rowboat-' like mesomorphic polymers and their metal complexes as well as tubular polymers (TPs). They are full of great potential for use as advanced materials.

关键词： stepwise coupling polymerization ladder polysiloxane tubular polymers

THE FLOW IN ROTATING CURVED CIRCULAR PIPE

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Journal of Hydrodynamics 2000年第1期12卷 108-116页

作者： zhang Jin suo, Shen Xin rong, zhang ben zhao Department of Mechanics, Zhejiang University, Hangzhou 310027, P.R.China Zhejiang Univ Hangzhou China

The combined effects of the system rotation (Coriolis force) and curvature (centrifugal force) on the flow in rotating curved circular pipe with small curvature are examined by perturbation method. A second order perturbation solution is presented. The secondary flow structure and the primary axial velocity distributions are studied in detail. The loops of the secondary flow are more complex than those in a curved pipe without rotation or a rotating straight pipe. Its numbers depend on the body force ratio F which represents the ratio of the Coriolis to the centrifugal force. The maximum of the axial velocity is pushed to either outer bend or inner bend, which is also determined by F. The results are confirmed by the results of other authors who studied the same problem by different methods.

关键词： secondary flow curved pipe perturbation method

SYNTHESIS AND CHARACTERIZATION OF NOVEL REACTIVE POLYORGANOSILOXANE CONTAINING NITRO GROUPS

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Chinese Journal of Polymer Science 2001年第1期19卷 1-6页

作者： Chun-qing Liu Yang Liu Ping Xie rong-ben zhang Chao-bin He Neal Tai-shung Chung PCLCC Center for Molecular Science Institute of Chemistry Chinese Academy of Sciences Beijing 100080 China PCLCCCenter for Molecular Science Institute of Chemistry Chinese Academy of Sciences Beijing 100080 China PCLCCCenter for Molecular Science Institute of Chemistry Chinese Academy of Sciences Beijing 100080 China PCLCCCenter for Molecular Science Institute of Chemistry Chinese Academy of Sciences Beijing 100080 China Institute of Materials Research and Engineering National University of Singapore Singapore 119260 Institute of Materials Research and Engineering National University of Singapore Singapore 119260

A novel reactive polyorganosiloxane containing nitro groups was first prepared by acid-catalyzed equilibration polymerization. The monomer, 3-(4-nitrophenoxy)propylmethyldichlorosilane (NPPMS), was synthesized by hydrosilylation reaction with dicyciopentadienylplatinum(II) chloride (Cp2PtCl2) catalyst in high yield. The synthesized polynitroorganosiloxane, which has potential application as a precursor for synthesizing advanced functional polymers, was characterized by FTIR, H-1-NMR, C-13-NMR, Si-29-NMR, vapor pressure osmometry (VPO) and gel permeation chromatography(GPC).

关键词： polyorganosiloxane equilibration polymerization hydrosilylation characterization

U-Net Models for Representing Wind Stress Anomalies over the Tropical Pacific and Their Integrations with an Intermediate Coupled Model for ENSO Studies

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Advances in Atmospheric Sciences 2024年第7期41卷 1403-1416页

作者： Shuangying Du rong-Hua zhang Key Laboratory of Ocean Circulation and Waves Institute of OceanologyChinese Academy of SciencesQingdao266071China School of Marine Sciences Nanjing University of Information Science and TechnologyNanjing210044China Laosan Laboratory Qingdao266237China University of Chinese Academy of Sciences Beijing100049China

El Niño-Southern Oscillation(ENSO)is the strongest interannual climate mode influencing the coupled ocean-atmosphere system in the tropical Pacific,and numerous dynamical and statistical models have been developed to simulate and predict *** some simplified coupled ocean-atmosphere models,the relationship between sea surface temperature(SST)anomalies and wind stress(τ)anomalies can be constructed by statistical methods,such as singular value decomposition(SVD).In recent years,the applications of artificial intelligence(AI)to climate modeling have shown promising prospects,and the integrations of AI-based models with dynamical models are active areas of *** study constructs U-Net models for representing the relationship between SSTAs andτanomalies in the tropical Pacific;the UNet-derivedτmodel,denoted asτUNet,is then used to replace the original SVD-basedτmodel of an intermediate coupled model(ICM),forming a newly AI-integrated ICM,referred to as *** simulation results obtained from ICM-UNet demonstrate their ability to represent the spatiotemporal variability of oceanic and atmospheric anomaly fields in the equatorial *** the ocean-only case study,theτUNet-derived wind stress anomaly fields are used to force the ocean component of the ICM,the results of which also indicate reasonable simulations of typical ENSO *** results demonstrate the feasibility of integrating an AI-derived model with a physics-based dynamical model for ENSO modeling ***,the successful integration of the dynamical ocean models with the AI-based atmospheric wind model provides a novel approach to ocean-atmosphere interaction modeling studies.

关键词： U-Net models wind stress anomalies ICM integration of AI and physical components

Self-Triggered Set Stabilization of Boolean Control Networks and Its Applications

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IEEE/CAA Journal of Automatica Sinica 2024年第7期11卷 1631-1642页

作者： rong Zhao Jun-e Feng Dawei zhang the School of Mathematics Shandong UniversityShandong UniversityJinan 250100China

Set stabilization is one of the essential problems in engineering systems, and self-triggered control(STC) can save the storage space for interactive information, and can be successfully applied in networked control systems with limited communication resources. In this study, the set stabilization problem and STC design of Boolean control networks are investigated via the semi-tensor product technique. On the one hand, the largest control invariant subset is calculated in terms of the strongly connected components of the state transition graph, by which a graph-theoretical condition for set stabilization is derived. On the other hand, a characteristic function is exploited to determine the triggering mechanism and feasible controls. Based on this, the minimum-time and minimum-triggering open-loop, state-feedback and output-feedback STCs for set stabilization are designed,respectively. As classic applications of self-triggered set stabilization, self-triggered synchronization, self-triggered output tracking and self-triggered output regulation are discussed as well. Additionally, several practical examples are given to illustrate the effectiveness of theoretical results.

关键词： Boolean control networks(BCNs) output regulation self-triggered control semi-tensor product of matrices set stabilization synchronization