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Multispectral sensing of biological liquids with hollow-core microstructured optical fibres

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Light(Science & Applications) 2020年第1期9卷 346-357页

作者： Timur ermatov roman e.noskov Andrey AMachnev Ivan Gnusov Vsevolod Atkin ekaterina N.Lazareva Sergei V.German Sergey S.Kosolobov Timofei S.Zatsepin Olga V.Sergeeva Julia S.Skibina Pavel Ginzburg Valery V.Tuchin Pavlos G.Lagoudakis Dmitry A.Gorin Skolkovo Institute of Science and Technology 3 Nobelya str.Moscow 121205Russia Department of electrical engineering Tel Aviv UniversityRamat AvivTel Aviv 69978Israel Light-Matter Interaction Centre Tel Aviv UniversityRamat AvivTel Aviv 69978Israel Saratov State University 83 Astrakhanskaya str.Saratov 410012Russia Tomsk State University 36 Lenin’s av.Tomsk 634050Russia M.V.Lomonosov Moscow State University Leninskie Gory1-3Moscow 119992Russia SPe LLC Nanostructured Glass Technology 10150 Let OktjabrjaSaratov 410033Russia Center for Photonics and 2D Materials Moscow Institute of Physics and TechnologyDolgoprudny 141700Russia Institute of Precision Mechanics and Control of the Russian Academy of Sciences 24 Rabochaya str.Saratov 410028Russia

The state of the art in optical biosensing is focused on reaching high sensitivity at a single wavelength by using any type of optical *** common strategy,however,disregards the promising possibility of simultaneous measurements of a bioanalyte’s refractive index over a broadband spectral ***,we address this issue by introducing the approach of in-fibre multispectral optical sensing(IMOS).The operating principle relies on detecting changes in the transmission of a hollow-core microstructured optical fibre when a bioanalyte is streamed through it via liquid *** offers a unique opportunity to measure the refractive index at 42 wavelengths,with a sensitivity up to ~3000 nm per refractive index unit(RIU)and a figure of merit reaching 99 RIU^(−1) in the visible and near-infra-red spectral *** apply this technique to determine the concentration and refractive index dispersion for bovine serum albumin and show that the accuracy meets clinical needs.

关键词： refractive spectral microstructure

Modifying light–matter interactions with perovskite nanocrystals inside antiresonant photonic crystal fiber

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Photonics Research 2021年第8期9卷 1462-1469页

作者： ANDReY A.MACHNeV ANATOLY P.PUSHKAReV PAVeL TONKAeV roman e.noskov KRISTINA R.RUSIMOVA PeTeR J.MOSLeY SeRGeY V.MAKAROV PAVeL B.GINZBURG IVAN I.SHISHKIN School of electrical engineering Tel Aviv UniversityTel Aviv 69978Israel Department of Physics and engineering ITMO UniversitySaint Petersburg 197101Russia Centre for Photonics and Photonic Materials Department of PhysicsUniversity of BathBath BA27AYUK Photonics and 2D Materials Moscow Institute of Physics and TechnologyDolgoprudny 141700Russia

Structured environments are employed in a plethora of applications to tailor dynamics of light–matter interaction processes by modifying the structure of electromagnetic *** promising example of such a system is antiresonant photonic crystal fibers(AR-PCFs),which allow light–analyte interactions in a very long *** we probe contribution of microstructuring and nontrivial mode hierarchy on light–matter interactions in AR-PCFs by investigating lifetime shortening of perovskite(CsPbBr3)nanocrystals grown to fiber *** crystals have been deposited using a wet chemistry approach and then excited by a supercontinuum source in the 450–500 nm *** spectra have been measured and analyzed via the time-correlated single photon counting(TCSPC)technique,unravelling contributions of core and cladding *** lifetime imaging inside an AR-PCF enables mapping input of various electromagnetic channels into light–matter interaction *** results pave the way for tailoring the dynamics of high-order quantum processes,promoting the concept of AR-PCF as a light-driven reactor.

关键词： fiber light resonant

Supercurrent decay in ballistic magnetic Josephson junctions

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npj Computational Materials 2022年第1期8卷 186-196页

作者： HervéNess Ivan A.Sadovskyy Andrey e.Antipov Mark van Schilfgaarde roman M.Lutchyn Department of Physics King’s College LondonStrand CampusLondonWC2R 2LSUK Microsoft Quantum Microsoft Station QUniversity of CaliforniaSanta BarbaraCA93106USA National Renewable energy Laboratory GoldenCO80401USA

We investigate transport properties of ballistic magnetic Josephson junctions and establish that suppression of supercurrent is an intrinsic property of the junctions,even in absence of *** studying the role of ferromagnet thickness,magnetization,and crystal orientation we show how the supercurrent decays exponentially with thickness and identify two mechanisms responsible for the effect:(i)large exchange splitting may gap out minority or majority carriers leading to the suppression of Andreev reflection in the junction,(ii)loss of synchronization between different modes due to the significant dispersion of the quasiparticle velocity with the transverse *** results for Nb/Ni/Nb junctions are in good agreement with recent experimental *** approach combines density functional theory and the Bogoliubov-de Gennes model and opens a path for material composition optimization in magnetic Josephson junctions and superconducting magnetic spin valves.

关键词： Josephson decay magnetic

Microalgae contribution in enhancing the circular economy drive of biochemical conversion systems-A review

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Carbon Resources Conversion 2024年第2期7卷 95-109页

作者： Kelechi e.Anyaoha Felix Krujatz Isla Hodgkinson roman Maletz Christina Dornack Technische Universität Dresden Chair of Waste Management and Circular EconomyPratzschwitzer Str.1501796 PirnaGermany Institute of Natural Materials Technology RadebergGermany Biotopa gGmbH Center for Applied Aquaculture and Bioeconomy RadebergGermany Department of Agricultural engineering Imo State Polytechnic OmumaNigeria

The global impact of greenhouse gas emissions requires concerted efforts to reduce emissions and energy use,and to increase carbon capture and *** the circular economy in CO_(2)sequestration systems optimises resource use and reduces the emissions burden throughout the supply *** capture from anaerobic digestion,composting and fermentation(particularly ethanol)processes offers great opportunities for climate change *** waste/by-products generated from these processes can limit the need to source nutrients from outside the system and increase the potential for circular *** integration of microalgae cultivation with each of anaerobic digestion,composting and ethanol fermentation processes provides a new model for climate change mitigation of biogenic CO_(2)and circular *** this model is limited by high energy consumption and nutrient demand,seasonal variability,operational efficiency and end-user requirements,further research and policy support will go a long way in realising the associated benefits,including in CO_(2)fixation,nutrient recovery,waste remediation and as an alternative source of animal feed.

关键词： Circular economy Anaerobic digestion Composting Microalgae

effect of cation(Li^+, Na^+, K^+, Rb^+, Cs^+) in aqueous electrolyte on the electrochemical redox of Prussian blue analogue(PBA) cathodes

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Journal of energy Chemistry 2020年第1期29卷 31-38,I0002页

作者： Satyajit Phadke roman Mysyk Meriem Anouti Laboratoire PCM2e Universite de ToursBatiment JParc de Grandmont37200 ToursFrance Parque Tecnologico C/Albert Einstein 48 CP01510 MilanoAlavaSpain

Prussian blue analogue(PBA)material is a promising cathode for applications in Na-ion and K-ion batteries which can support high c-rates for charge and *** this study,the material of composition[K2 CuIIFeII(CN)6]was synthesized and its structural and electrochemical redox behavior was investigated with 5 different alkali insertion cations(Li^+,Na^+,K^+,Rb^+,Cs^+).Galvanostatic measurements indicate that the redox potential strongly depends on the ionic radius of the inserted *** redox potential varies by 400 m V between using Li^+(0.79A)or Cs^+(1.73A)in the *** underlying modification of the Fe2^+/Fe3^+redox potential in PBA is proposed to be due to the weakening of the Fe–C bond in the *** hypothesis is supported by XRD measurements which reveal that the lattice parameter of the de-intercalated host structure follows the same trend of monotonic increase with the cation *** relatively minor volume changes accompanying the redox(1.2%–2.4%)allow the PBA to accommodate differently sized cations,although the structural hindrances are quite pronounced at high c-rates for the larger ones(Rb^+and Cs^+).Cycle aging studies indicate that the minimum capacity fade rate is observed in case of K^+ and Rb^+ containing *** peak intensity corresponding to the[220]crystallographic plane varies depending on the state of charge of PBA,since this plane contains the insertion *** to the sensitivity of the redox potential to the insertion cation coupled with the observed fast ion-exchange ability,the PBA material may find additional analytical applications such as ion sensing or filtration devices.

关键词： Prussian blue Cathode Alkali cations XRD Batteries

Titanium oxide artificial synaptic device:Nanostructure modeling and synthesis,memristive cross-bar fabrication,and resistive switching investigation

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Nano Research 2023年第7期16卷 10222-10233页

作者： Vadim I.Avilov roman V.Tominov Zakhar e.Vakulov Lev G.Zhavoronkov Vladimir A.Smirnov Research Laboratory Neuroelectronics and Memristive Nanomaterials(NeUROMeNA Lab) Southern Federal UniversityTaganrog 347922Russia Institute of Nanotechnologies Electronics and Electronic Equipment EngineeringSouthern Federal UniversityTaganrog 347922Russia

The paper shows the results of the mathematical model development and the numerical simulation of the oxygen vacancies,and the distribution of TiO,Ti_(2)O_(3),and TiO_(2)oxides in the titanium oxide nanostructure obtained by local anodic oxidation(anodization).The effect of the anodization voltage pulse duration and amplitude on the titanium oxide composition distribution and the conduction channel formation was *** device prototypes based on electrochemical titanium oxide are fabricated and *** was shown that forming free resistive switching between the low resistances state(LRS)1.43±0.54 kΩand the high resistance state(HRS)28.75±9.75 kΩwere observed during 100,000 switching cycles and LRS 1.49±0.23 kΩwas maintained for 10,000 *** resistive switching of the synaptic device prototype was *** was shown that increasing Uset from 0.5 to 1.5 V leads to different LRS from 3.96±0.19 to 0.71±0.10 kΩ.The results obtained can be used in the development of technological foundations for the formation of high-performance multilevel artificial synapses for elements of neuroelectronics and hardware neural networks.

关键词： artificial intelligence neuromorphic systems memristive cross bar resistive switching scanning probe microscopy titanium oxide

employing Per-Component Time Step in DSMC Simulations of Disparate Mass and Cross-Section Gas Mixtures

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Communications in Computational Physics 2013年第8期14卷 703-721页

作者： roman V.Maltsev 8-22 KoltsovoNovosibirsk630559Russia

A new approach to simulation of stationary flows by Direct Simulation Monte Carlo method is *** idea is to specify an individual time step for each component of a gas *** approach consists of modifications mainly to collision phase simulation and recommendations on choosing time step *** allows lowering the demands on the computational resources for cases of disparate collision diameters of molecules and/or disparate molecular *** are cases important e.g.,in vacuum deposition *** tests of the new approach are ***,the usage of new approach is demonstrated on a problem of silver nanocluster diffusion in argon carrier gas under conditions of silver deposition experiments.

关键词： Direct Simulation Monte Carlo time step disparate masses gas mixture nanoclusters

Taxonomy,distribution,and contemporary exposure of terrestrial mammals to floods and human pressure across different areas for biodiversity conservation in China

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Integrative Zoology 2024年第3期19卷 458-467页

作者： roman SHARNUUD eric I.AMeCA MOe Key Laboratory for Biodiversity Science&ecological engineering College of Life SciencesBeijing Normal UniversityBeijingChina Climate Change Specialist Group Species Survival CommissionInternational Union for Conservation of NatureGlandSwitzerland

A significant research focus is placed on identifying animal species and areas at future risk to human-induced alterations of the environment and long-term changes in climatic ***,the extent to which exposure to extreme climatic events and intense human pressure can increase the risk of harmful impacts on species remains poorly *** on terrestrial mammals in China,one of the world’s megadiverse countries,we investigated patterns of contemporary exposure to floods and human pressures and determined their taxonomic representation and distribution across three major area-based conservation schemes,namely,national nature reserves(NNRs),priority areas for biodiversity conservation(PABCs),and key biodiversity areas(KBAs).Among the 440 species assessed with moderate or high exposure to floods,327(∼75%)also qualified as moderate or high in exposure to intense human *** species mainly belong to the orders Chiroptera,eulipotyphla,and ***,there were 305,311,and 311 species with moderate or high exposure to flood and intense human pressure represented across NNRs,PABCs,and KBAs,*** findings support the prioritization of KBAs for expansion of site-based protection efforts such as NNRs in China,considering threats to species from exposure to adverse effects from both extreme climate and human pressure.

关键词： conservation floods human pressure mammals taxonomy

Differentiation of recent local geodynamic and seismic processes of technogenic-loaded territories based on the example of Dnister Hydro Power Complex(Ukraine)

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Geodesy and Geodynamics 2020年第5期11卷 391-400页

作者： Ihor Savchyn roman Pronyshyn Lviv Polytechnic National University Institute of GeodesyUkraine Institute of Geophysics of NAS of Ukraine Ukraine

The purpose of the study is to analyse and interpret recent local geodynamic and seismic processes on the territory of Dnister Hydro Power Complex that appeared as a result of the additional technogenic loading due to the filling of the Dnister upper reservoir on October 26, 2012. The research was conducted based on the data from the Novodnistrovsk seismic station NDNU since 2005, the results of the 18 cycles of periodic static GNSS campaigns conducted during 2004 e2018, and also the analysis of archival and literary materials. It has been established that the dominant feature of the latest stage in the development of the geological structure of the Dnister Hydropower Complex is unbreakable tectonic *** 2012 to 2018 a significant increase in local seismic activity on the Dnister Hydropower Complex was recorded. Obviously, the growth of local seismic activity immediately after the Dnister upper reservoir was filled with water on October 26, 2012, is associated with the phenomenon of reservoir induced seismicity. The study determined the distribution velocity of dilatation of the territory of the Dnister PSPP(Pumped-Storage Power Plant) before and after filling the Dnister upper reservoir and their schemes were constructed. The analysis of the distribution of velocity dilatation testifies an increased geodynamic activity in the places where extreme values of compression and expansion are revealed.

关键词： reservoir seismic Hydropower