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Progress and review of the studies on the end-Triassic mass extinction event

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Science China Earth Sciences 2005年第12期48卷 2049-2060页

作者： DENG Shenghui1,2. LU Yuanzheng1,2.3.& XU Daoyi4 1. research Institute of {2. exploration and {3., beijing 100083. China 2. Key Laboratory of Oil and Gas Reservoir of PetroChina, beijing 100083. China 3. China University of Geosciences, beijing 100083. China 4. Institute of Geology, China Earthquake Administration, beijing 10002., China 1. research Institute of petroleum {2. and {3. 100083 Beijing China 2. Key Laboratory of Oil and Gas Reservoir of PetroChina 100083 Beijing China 3. China University of Geosciences 100083 Beijing China 4. Institute of Geology China Earthquake Administration 100029 Beijing China

The mass extinction at the end-Triassic is one of the five biggest in the Phanerozoic. However,it is the least well understood among these five events, and only till last decade it became a great academic interesting subject to geologists. The evidences for this event come obviously from bivalves, brachiopods, ammonites, corals, radiolaria, ostracods and foraminifera of marine habitats, and plants and tetrapods of terrestrial realm. By contrast, for some of other groups, such as marine gastropods and marine vertebrates, no mass extinction has been recog-nized yet. The extinction event is strongly marked at specific level but shown a complicated situa-tion at generic and family levels. Dramatic changing of the environment, such as the temperature raise due to the greenhouse effect, the marine anoxic habitats caused by a sudden transgression after the regression at the end of Triassic, has been claimed to be the main cause of the extinction. Many hypotheses have been suggested to demonstrate the mechanisms of the environment changing, among which two popular ones are the bolide impact and volcanic eruption. The Triassic-Jurassic (Tr-J) boundary mass extinction event is still poorly understood because no enough data have been obtained from the Tr-J boundary successional sections of both marine and terrestrial sediments, and most of these studies were regionally restricted. The basic aspects of the event and its associated environmental conditions remain poorly characterized and the causal mechanism or mechanisms are equivocal. Some authors even doubt its occurrence. China has many successionally developed terrestrial and marine Tr-J sections. Detailed studies of these sections may be important and significant for well understanding of the event.

关键词： progress, review, end-Triassic, mass extinction, mechanism, Tr-J boundary.

Application of backflush and micro-flow techniques to the analysis of C5—C13.hydrocarbons in crude oils and its geochemical significance

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Progress in Natural Science:Materials International 2007年第11期17卷 1382-1387页

作者： Wang Peirong1,2. Zhao Hong2.3. Xu Guanjun1,4, Zhu Cuishan2.3. Xiao Tingrong4, Zhang Min2.3.and Zhang Bin1,4(1. Key Laboratory of petroleum Geochemistry, China national petroleum {3., beijing 100083. China 2. Geochemistry Department of Yangtze University, Jingzhou 43.02.0} China 3. Key Laboratory of {12. Technologies for Oil and Gas Resources, Ministry of Education, Yangtze University, Jingzhou 43.02.0} China 4. petroleum Geology Central Laboratory, research Institute of petroleum {12. and development, PetroChina, beijing 100083. China) Key Laboratory of petroleum Geochemistry China National Petroleum Corporation Beijing 100083 China Geochemistry Department of Yangtze University Jingzhou 434023 China Key Laboratory of exploration Technologies for Oil and Gas Resources Ministry of Education Yangtze University Jingzhou 434023 China petroleum Geology Central Laboratory Research Institute of Petroleum Exploration and Development PetroChina Beijing 100083 China

An Agilent 6890N GC equipped with both FID and Agilent 5975 MSD analyzer has been employed to analyze C5—C13.hydrocarbon fractions of crude oils. A technical combination of program temperature volatilizer injection, backflush and micro-flow controller afforded a fine separation of C5—C13.compounds on a PONA column with the heavy part of crude oils being cut off before entering the analytical column. Both GC-FID chromatogram and GC-MS mass chromatograms (MID and full scan) could be obtained at the same time. The retension time differences of nC6—nC13.alkanes between GC and TIC were in the range of 0.02.0.58 minutes. Totally 2.6 peaks have been assigned group compositions. Results on 8 typical oil samples from CNPC Key Laboratory Crude Oil Library showed that the characteristics of C6—C13.hydrocarbon group composition could be used in oil-oil correlation studies.

关键词： GC analysis GC/MS analysis backflush micro-flow controller light fraction in crude oil

Natural gas geochemistry and its origins in Kuqa depression

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Science China Earth Sciences 2008年第S1期51卷 174-182页

作者： LIU QuanYou 1 ,QIN ShengFei 1 ,LI Jian 2.,LIU WenHui 3.,ZHANG DianWei 3.,ZHOU QingHua 1 &HU AnPing 1 1 {2. Institute of petroleum exploration and {3.,PetroChina,beijing 100083.China 2.Langfang Branch of {2. Institute of petroleum exploration and {3.,PetroChina,Langfang 065007,China 3.exploration and Production {2. Institute,SINOPEC,beijing 100083.China PetroChina Res Inst Petr Explorat & Dev Beijing 100083 Peoples R China PetroChina Langfang Branch Res Inst Petr Explorat & Dev Langfang 065007 Peoples R China SINOPEC Explorat & Prod Res Inst Beijing 100083 Peoples R China

According to gas compositional and carbon isotopic measurement of 114 gas samples from the Kuqa depression,accumulation of the natural gases in the depression is dominated by hydrocarbon gases, with high gas dryness(C1/C1-4)at the middle and northern parts of the depression and low one towards east and west sides and southern *** carbon isotopes of methane and its homologues are relatively enriched in 13.C,and the distributive range ofδ13. 1 ,δ13. 2.andδ13. 3.is-3.‰―-3.‰,-2.‰―-2.‰and-2.‰―-2.‰,*** general,the carbon isotopes of gaseous alkanes become less negative with the increase of carbon ***δ13. CO2.value is less than-10‰in the Kuqa depression,indicating its organogenic *** distributive range of 3.He/ 4 He ratio is within n×10-8 and a decrease in 3.He/ 4 He ratio from north to south in the depression is *** on the geochemical parameters of natural gas above,natural gas in the Kuqa depression is of characteristics of coal-type gas *** possible reasons for the partial reversal of stable carbon isotopes of gaseous alkanes involve the mixing of gases from one common source rock with different thermal maturity or from two separated source rock intervals of similar kerogen type,multistages accumulation of natural gas under high-temperature and over-pressure conditions,and sufficiency and diffusion of natural gas.

关键词： Kuqa depression natural gas stable carbon isotope gas origin

Two conceptual models of displacement transfer and examples

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Science China Earth Sciences 2005年第7期48卷 900-911页

作者： GUAN Shuwei1,2. WANG Xin2. YANG Shufeng2. HE Dengfa1 & ZHAO Weidong3.1. research Institute of {2. exploration and {3., beijing 100083. China 2. Department of Geosciences, Zhejiang University, Hangzhou 3.002., China 3. Tarim Oilfield Company, Korla 841000, China research Institute of petroleum {2. and {3. Beijing 100083 China Department of Geosciences Zhejiang University Hangzhou 310027 China Tarim Oilfield Company Korla 841000 China

This paper presents two conceptual models of displacement transfer, reverse sym- metry model and infinitely equal division model, based on the fault-bend folding theory. If the fault shape is held constant in the trend, then the distribution of slip magnitude, geometry of imbricate structures and its axial surface map all display reverse symmetry on the process of displacement transfer, as called reverse symmetry model in this paper. However, if the ramp height of thrust fault decreases gradually along its strike, the displacement is postulated to be equally and infinitely divided to every thrust that is formed subsequently, this kinematic process is described using infinitely equal division model. In both models, displacement transfer is characterized by the regular changes of imbricate thrusting in the trend. Geometric analysis indicates that the displacement transfer grads can be estimated using the tangent of deflective angle of hinterland structures. Displacement transfer is often responsible for the distortion and branching of the surface anticlines, especially in the region where the multi-level detachment structures is developed. We also present some examples from the frontal structures of the Southern Tianshan fold-and-thrust belt, Xinjiang, China. Displacement transfer between deep imbricate thrusts in the middle segment of Qiulitag anticline zone causes the Kuqatawu and Southern Qiulitag deep an- ticlines left-lateral echelon. The region, where these two deep anticlines overlap, is characterized by duplex structures, and extends about 18 km. The shallow anticline is migrated southward displaying obvious “S” form in this area.

关键词： displacement transfer fault-bend folding reverse symmetry model infinitely equal division model Qiulitag zone.

Wave tectono-sedimentary processes in Tarim basin

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Science China Earth Sciences 2005年第11期48卷 1949-1959页

作者： JIN Zhijun1,2. ZHANG Yiwei1 & CHEN Shuping1 1. Key Laboratory for Hydrocarbon Accumulation, Ministry of Education, China University of petroleum, beijing 102.49, China 2. {2. and Production {3. Institute, China petroleum & Chemical corporation, beijing 100083. China 1. Key Laboratory for Hydrocarbon Accumulation Ministry of Education China University of Petroleum 102249 Beijing China 2. exploration and Production research Institute China Petroleum & Chemical Corporation 100083 Beijing China

Based on the unconformities, the formation times of structures, and geological wave filtering applied to basin fills of typical wells around the Manjiaer area in the Tarim basin, the wave tectono-sedimentary processes in the Tarim Basin are discussed. The results of geological wave filtering of basin fills of typical wells show that, in time domain, the evolution of the Tarim basin was controlled by various wave processes with the periods of 740±Ma, 2.0±Ma, 100±Ma and 3.±Ma. The analyses of basin fills, basin subsidence and unconformities show that the trends of the sedimentary facies belts, depocenters, and centers of subsidence migrated and interchanged periodically with periods of 2.0±Ma. These show the propagation of wave movements in space domain. The wave evolution of the Tarim basin is of significance to understanding the formation of the oil and gas reservoirs in the basin.

关键词： Tarim basin, tectonics, sedimentation, crustal undation, wave evolution

Carbon isotope composition and its implications of Lower Cretaceous Aptian-Albian shallow water carbonates in the Cuoqin Basin, North Tibet

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Science China Earth Sciences 2004年第3期47卷 247-254页

作者： ZHU Jingquan1, LI Yongtie2. JIANG Maosheng1 & CHEN Daizhao1 1. Institute of Geology and Geophysics, Chinese Academy of Sciences, beijing 10002., China 2. research Institute of {2. {3. and development, CNPC, beijing 100083. China Chinese Acad Sci Inst Geol & Geophys Beijing 100029 Peoples R China CNPC Res Inst Petr Explorat & Dev Beijing 100083 Peoples R China

The d 13. values of Lower Cretaceous Aptian-Albian platform-type carbonates in the Cuoqin Basin, North Tibet vary between 2.48 and 5.46. The mean value is 3.93. The values are not only provided with positive excursion, but also 1.17 higher than those of con-temporaneous pelagic carbonates which possess pretty high d 13. values. The origin is ap-proached. During the oceanic anoxic events, a great number of organisms were rapidly buried, causing the increase of the d 13. value of oceanic total dissolved carbon (TDC) and generally promoting the values of marine carbonates. After that, owing to the organisms undergoing dif-ferent isotopic fractionation in the paleo-ocean with stratified structure, d 13. values of shallow sea carbonate were obviously higher than those of pelagic carbonates.

关键词： shallow water carbonate, stable carbon isotope, paleooceanography, Aptian-Albian stage, Cuoqin Basin.

Free Radicals in Organic Matter for Thermal History Reconstruction of Carbonate Succession

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Acta Geologica Sinica(English Edition) 2007年第4期81卷 605-613页

作者： QIU Nansheng LI Huili JIN Zhijun and ZHU Yinkang 1 State Key Laboratory of petroleum Resource and Prospecting,China University of petroleum,{2. 102.49 2.Basin and Reservoir {3. Center,China University of petroleum,{2. 102.49 3.Institute of petroleum exploration and development,SINOPEC,{2. 100083 State Key Laboratory of petroleum Resource and Prospecting China Universityof Petroleum Beijing 102249

Geothermometer is one of the most useful methods to reconstruct the thermal history of sedimentary basins. This paper introduces the application of free radicals concentration of organic matter as a thermal indicator in the thermal history reconstruction of carbonate succession, based on anhydrous thermal simulation results of type I and H1 kerogen. A series of free radicals data are obtained under thermal simulation of different heating temperatures and times, and quantitative modds between free radical concentration （Ng） of organic matter and time-temperature index （TTI） for types I and type H1 kerogen are also obtained. This *** relation was used to model the Ordovician thermal gradients of Well TZ12.in the Tarim Basin. The modeling result is corresponding to the results obtained by apatite fission track data and published data. This new method of thermal history reconstruction will be benefit to the hydrocarbon generation and accumulation study and resource assessment of carbonate succession.

关键词： carbonate succession geothermometer free radicals of organic matter apatite fission track thermal history

Formation mechanism of carbonate cemented zones adjacent to the top overpressured surface in the central Junggar Basin,NW China

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Science China Earth Sciences 2010年第4期53卷 529-540页

作者： YANG Zhi1,2.ZOU CaiNeng1,3.HE Sheng2.LI QiYan1,HE ZhiLiang3.WU HengZhi5,CAO Feng1,MENG XianLong4,WANG FuRong2.& XIAO Qilin2. State Key Laboratory of EOR,{2. Institute of petroleum exploration & {3.,PetroChina,beijing 100083.China 2.Key Laboratory of Tectonics and petroleum Resources of Ministry of Education,China University of Geosciences,Wuhan 43.074,China 3.State Key Laboratory of EOR,{2. Institute of petroleum exploration & {3.,Petrochina,beijing 100083.China 4 {2. Institute of petroleum exploration and Production,SINOPEC,beijing 100083.China 5 Southwest Branch Company,SINOPEC,Chengdu 610051,China 1. State Key Laboratory of EOR Research Institute of Petroleum Exploration & Development PetroChina Beijing 100083 China2. Key Laboratory of Tectonics and Petroleum Resources of Ministry of Education China University of Geosciences Wuhan 430074 China3. State Key Laboratory of EOR Research Institute of Petroleum Exploration & Development Petrochina Beijing 100083 China5. Southwest Branch Company SINOPEC Chengdu 610051 China4. Research Institute of Petroleum Exploration and Production SINOPEC Beijing 100083 China

Carbonate cemented zones are normally adjacent to the top overpressured surface in the central Junggar Basin,NW *** carbon and oxygen isotopic compositions and petrological investigations of carbonate cements in the carbonate cemented zones indicate that:(1) carbonate cements are composed dominantly of ferrocalcite,ferroan dolomite,and ankerite;(2. carbonate cements are formed under a high temperature circumstance in the subsurface,and organic fluid migration has an important effect on the formation of them;and(3. carbon and oxygen ions in the carbonate cements migrate from the underlying overpressured *** suggests that the occurrence of carbonate cemented zones in this region results from multiple phases of organic fluid expulsion out of the overpressure compartment through geological *** study provides a plausible mechanism of the formation of carbonate cemented zones adjacent to the top overpressured surface in the clastic sedimentary basins,and has an important implication for understanding the internal correlation between the formation of carbonate cemented zones adjacent to top overpressured surface and geofluids expulsion out of overpressured system.

关键词： carbonate cemented zones formation mechanism stable carbon and oxygen isotopic top overpressured surface central Junggar Basin coal-bearing strata

Quantitative studies of hydrocarbon loss of the Silurian bitumen sandstone in the Tarim Basin

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Science China Earth Sciences 2008年第S2期51卷 101-107页

作者： JIANG ZhenXue1,2.PANG XiongQi1,2.LIU LuoFu1,2.WANG XianDong3.ZHANG Jun4 & LI HongYi1,2.1 Basin and Reservoir research Center,China University of {2.,beijing 102.49,China 2.State Key Laboratory of {2. Resource and Prospecting,China University of {2.,beijing 102.49,China 3.research Institute of exploration and development,Daqing Oilfield Company Ltd,Daqing 163.12.China 4 {2. exploration and Production Institute of SINOPEC,beijing 100083.China China Univ Petr Basin & Reservoir Res Ctr Beijing 102249 Peoples R China China Univ Petr State Key Lab Petr Resource & Prospecting Beijing 102249 Peoples R China Daqing Oilfield Co Ltd Res Inst Explorat & Dev Daqing 163712 Peoples R China SINOPEC Petr Explorat & Prod Inst Beijing 100083 Peoples R China

The evolution of Tarim Basin experienced several tectonic movements,of which Caledonian movement caused a serious damage to reservoirs of Silurian. The earlier reservoirs size and the later hydrocarbon loss are two key factors to exploration prospect of Silurian. On the basis of net thickness of bituminous sandstone and recovery coefficient of crude oil converting to bitumen,the scale of the hydrocarbon loss of palaeo-accumulation in bitumen sandstone of Silurian was calculated (86.3.×108t). The deter-mination of net thickness of bitumen sandstone was completed mainly by several methods,such as physical property demarcation,observing lithology,grains with oil inclusion (GOI) technology,and quantitative grains fluorescence (QGF) technology. The samples of black sandstone and white sand-stone were collected and compared by means of the methods mentioned above. The results showed that there was little hydrocarbon,or none,in the white sandstone. The recovery coefficient was ob-tained by the analyses of plentiful physical parameters of crude oil and bitumen sandstone,based on the hypothesis that nonhydrocarbon compounds and bitumen were invariable in the process of bitu-men forming. The calculated result,which is more scientific and actual,indicates the exploration pros-pect is more promising in Silurian of the Tarim Basin.

关键词： Tarim Basin Silurian bitumen sandstone hydrocarbon loss quantitative research recovery coefficient