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Geochemical studies of hybrid granite from Madugulapalli area, Eastern Dharwar Craton, Southern India: Implications for crustal mixing

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Acta Geochimica 2023年第1期42卷 9-23页

作者： Nagamma j Ratnakar j Ajay kumar A Ashok Ch State Mines and Geology Department 508001 NalgondaIndia Department of Geology Osmania University500007 HyderabadIndia CSIR-National Geophysical Research Institute 500007 UppalHyderabadIndia

Magma produced by melting of continental crust and mantle at the Archean-Proterozoic boundary are compositionally variable and chemical compositions provide evidence for the mixing of two sources. Understanding the composition of hybrid magma is essential for determining the comparative infl uence of crust and mantle sources during orogenesis. The hybrid granites are less documented in Indian cratons, especially less in Dharwar Craton. Here we present petrographic and whole-rock geochemical data of Madgulapalli granitic rocks situated in the NE part of the Eastern Dharwar Craton(EDC), to elucidate their petrogenesis and role in crust formation. The Madugulapalli granites(MPG) are composed chiefl y of plagioclase, quartz, and alkali feldspar with associated biotite showing alteration and inter-granular textures. Geochemically, they are metaluminous to peraluminous in nature with calc-alkaline hybrid granite. The hybrid granites exhibit both negative and positive europium anomalies;the lower Rb/Sr, Rb, Sr, and higher Sr/Y,(Dy/Yb)N ratios suggest that the interaction of older rocks with residual garnet source melted at high pressures. We hypothesize that hybrid granites are formed by interaction(e.g., metasomatism, mingling, or mixing) between parental magmas and pre-existing rocks with the infl uence of sanukitoid melts(heat source) in a subduction environment. The genesis of the hybrid granites demonstrates the mixing coupled with diff erentiation in the petrogeny’s residue system in a syn-collision setting followed by continental crust stability in EDC during the Neoarchean period.

关键词： Madugulapalli granite Hybrid granite Crustal mixing Subduction

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Synthesis and electronic properties of expanded 5-(hetero)arylthien-2-yl substituted 3-ethynyl quinoxalines with AIE characteristics

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Science China Chemistry 2018年第8期61卷 909-924页

作者： Franziska K.Merkt Thomas j.j.Müller Institute of Organic Chemistry and Macromolecular Chemistry Heinrich Heine University Düsseldorf

Expanded 5-(hetero)aryl-thien-2-yl substituted 3-ethynyl quinoxaline dyes with variable substitution pattern on the peripheral thiophene ring were synthesized in moderate to very good yields by Suzuki and Buchwald-Hartwig coupling of the corresponding brominated 3-ethynyl quinoxalines. Dumbbell-shaped bis(thienyl 3-ethynyl quinoxalines) are also accessible by the Suzuki protocol. The photophysical properties were investigated by UV and fluorescence spectroscopy. Most of the obtained compounds display fluorescence in solution and some of them also in the solid state. Additionally, tuning of the emission color of the quinoxaline based chromophores can be conveniently accomplished by the remote substituent group. The determined absorption and emission maximum as well as the Stokes shifts strongly correlate with Hammett σp+parameters. Besides,photophysical properties of selected derivatives in the solid state, biphasic solutions, and PMMA films, along with their relationships, are comparatively investigated. Moreover, two 5-(hetero)aryl-thien-2-yl substituted 3-ethynyl quinoxaline dyes are aggregation induced emission(AIE) chromophores indicated by restriction of molecular motions. A covalently restricted 3-ethynyl quinoxaline supports that the inhibition of molecular rotation is responsible for the significant enhancement of fluorescence in acetonitrile/water mixtures.

关键词： absorption aggregation induced emission cross-coupling fluorescence heterocycles palladium

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Understanding Performance for Two 802.11 Competing Flows

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journal of Computer Science & Technology 2008年第3期23卷 365-376页

作者： Michael j.Feeley Brendan Cully Sharath j.George Department of Computer Science University of British ColumbiaVanconverCanada

It is well known that 802.11 suffers from both inefficiency and unfairness in the face of competition and interference. This paper provides a detailed analysis of the impact of topology and traffic type on network performance when two flows compete with each other for airspace. We consider both TCP and UDP flows and a comprehensive set of node topologies. We vary these topologies to consider all combinations of the following four node-to-node interactions：（1） nodes unable to read or sense each other, （2） nodes able to sense each other but not able to read each other＇s packets and nodes able to communicate with （3） weak and with （4） strong signal. We evaluate all possible cases through simulation and show that the cases can be reduced to 9 UDP and 10 TCP 802.11g models with similar efficiency/fairness characteristics. We also validate our simulation results with extensive experiments conducted in a laboratory testbed. These more detailed models improve on previous work such as hidden-/exposed-terminal categorization and are thus better suited as a basis for adaptive techniques to improve performance in 802.11 multi-hop WLAN or Mesh Networks.

关键词： 802.11 wireless unfairness two-flow competition network topology

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Designing architected materials for mechanical compression via simulation, deep learning, and experimentation

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npj Computational Materials 2023年第1期9卷 1534-1542页

作者： Andrew j.Lew Kai jin Markus j.Buehler Laboratory for Atomistic and Molecular Mechanics(LAMM) Massachusetts Institute of Technology77 Massachusetts Ave.CambridgeMA 02139USA Department of Chemistry Massachusetts Institute of Technology77 Massachusetts Ave.CambridgeMA 02139USA Center for Computational Science and Engineering Schwarzman College of ComputingMassachusetts Institute of Technology77 Massachusetts Ave.CambridgeMA 02139USA

Architected materials can achieve enhanced properties compared to their plain *** architecting serves as a powerful design lever to achieve targeted behavior without changing the base ***,the connection between architected structure and resultant properties remains an open field of great interest to many fields,from aerospace to civil to automotive ***,we focus on properties related to mechanical compression,and design hierarchical honeycomb structures to meet specific values of stiffness and compressive *** do so,we employ a combination of techniques in a singular workflow,starting with molecular dynamics simulation of the forward design problem,augmenting with data-driven artificial intelligence models to address the inverse design problem,and verifying the behavior of de novo structures with experimentation of additively manufactured *** thereby demonstrate an approach for architected design that is generalizable to multiple material properties and agnostic to the identity of the base material.

关键词： thereby additive starting

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Microstructure and tensile properties of magnesium nanocomposites fabricated using magnesium chips and carbon black

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journal of Magnesium and Alloys 2020年第3期8卷 860-872页

作者： T.j.Lee W.j.Kim Department of Materials Science and Engineering Hongik UniversityMapo-guSangsu-dong 72-1Seoul 121-791Republic of Korea

In this study,carbon black(0,0.01,0.03 and 0.08 wt%)and AZ31(Mg-3Al-lZn)magnesium chips were used to fabricate carbon black-reinforced magnesium matrix composites with extrusion or a combination of extrusion and high-ratio differential speed *** hot pressing at 693 K and extrusion at 623 K with an extrusion ratio of 22,the magnesium chips coated with carbon black were soundly bonded into a bulk composite *** grain sizes of the extruded materials were similar with a size of 48.2-51.5|im despite the difference in the amount of carbon *** yield strength and ultimate tensile strength increased from 177 to 191 MPa and from 240 to 265 MPa,respectively,as a result of the addition of 0.01%carbon black;however,a further increase in the strength was marginal with additional carbon *** same trend was observed in the strain hardening *** tensile elongation increased by to the addition of 0.01%carbon black(from 15.8%to 17.4%)due to the increased work hardening effect,but decreased with additional carbon black due to its agglomeration and poor dispersion at higher *** high-ratio differential speed rolling(HRDSR)on the extruded materials and subsequent annealing,the AZ31 and AZ31 composites had a similar fine grain size of 16.3-17.9 *** annealed HRDSR composites showed the best mechanical properties at a higher content of carbon black(0.03%)compared to that(0.01%)for the extruded *** resulted from the enhanced dispersion effect of the carbon black due to the high shear flow induced during the HRDSR *** extruded composites exhibited the three distinct hardening stages(stage II,stage III and stage IV),while the annealed HRDSR composites mainly displayed the stage III *** addition of carbon black increased the strain hardening rate at all the strain hardening stages in both of the extruded and annealed HRDSR *** the initial hardening stage,the strain hardening rates of the extruded comp

关键词： Recycling Magnesium alloys chips Carbon black Nanocomposites Extrusion Differential speed rolling

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A structural topological optimization method for multi-displacement constraints and any initial topology configuration

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Acta Mechanica Sinica 2010年第5期26卷 735-744页

作者： j. H. Rong j. H. Yi School of Automotive and Mechanical Engineering Changsha University of Science and TechnologyChangsha 410076 China

In density-based topological design, one expects that the final result consists of elements either black （solid material） or white （void）, without any grey areas. Moreover, one also expects that the optimal topology can be obtained by starting from any initial topology configuration. An improved structural topological optimization method for multidisplacement constraints is proposed in this paper. In the proposed method, the whole optimization process is divided into two optimization adjustment phases and a phase transferring step. Firstly, an optimization model is built to deal with the varied displacement limits, design space adjustments, and reasonable relations between the element stiffness matrix and mass and its element topology variable. Secondly, a procedure is proposed to solve the optimization problem formulated in the first optimization adjustment phase, by starting with a small design space and advancing to a larger deign space. The design space adjustments are automatic when the design domain needs expansions, in which the convergence of the proposed method will not be affected. The final topology obtained by the proposed procedure in the first optimization phase, can approach to the vicinity of the optimum topology. Then, a heuristic algorithm is given to improve the efficiency and make the designed structural topology black/white in both the phase transferring step and the second optimization adjustment phase. And the optimum topology can finally be obtained by the second phase optimization adjustments. Two examples are presented to show that the topologies obtained by the proposed method are of very good 0/1 design distribution property, and the computational efficiency is enhanced by reducing the element number of the design structural finite model during two optimization adjustment phases. And the examples also show that this method is robust and practicable.

关键词： Topological optimization Displacement constraint Continuum structure Design space adjustment Rational approximation material model

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Water transport to the core–mantle boundary

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National Science Review 2021年第4期8卷 13-16页

作者： Michael j.Walter Earth and Planets Laboratory Carnegie Institution for Science

Water can have remarkable effects when exposed to rocks at high pressures and temperatures. It can form new minerals with unique properties and often profoundly affects the physical, transport and rheological properti...

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Gas exchange and water relations of young potted loquat *** under progressive drought conditions

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journal of Integrative Agriculture 2018年第6期17卷 1360-1368页

作者： A.Stellfeldt M.A.Maldonado j.j.Hueso j.Cuevas Department of Agronomy University of AlmeriaceiA3 Almeria 04120Spain Experimental Station of Cajamar Las Palmerillas ceiA3 Almeria 04710Spain

Relationships between plant water status and gas exchange parameters at increasing levels of water stress were determined in Algerie loquats which grown in 50 I pots. Changes in soil water content and stem water potential and their effects on stomatal conductance （Gs ） and net photosynthesis （Pn） rate were followed in control plants and in plants without irrigation until the latter reached near permanent wilting point and some leaf abscission took place. Then, the irrigation was restarted and the comparison repeated. Soil water content and stem water potential gradually diminished in response to drought reaching the minimum values of 0.9 mm and -5.0 MPa, respectively, 9 days after watering suspension. Compromised plant water status had drastic effects on Gs values that dropped by 97％ in the last day of the drought period. Pn was diminished by 80％ at the end of the drought period. The increasing levels of water stress did not cause a steady increase in leaf temperature in non-irrigated plants. Non-irrigated plants wilted and lost some leaves due to the severity of the water stress. However, all non-irrigated plants survived and reached similar Pn than control plants just a week after the irrigation was restarted, confirming drought tolerance of loquat and suggesting that photosynthesis machinery remained intact.

关键词： Eriobotrya japonica deficit irrigation stem water potential net photosynthetic rate stomatal conductance

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Ferrofluid moving thin films for active flow control

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Chinese journal of Aeronautics 2021年第5期34卷 115-119页

作者： Francisco j.ARIAS Department of Fluid Mechanics Polytechnic University of CataloniaESEIAATC/Colom 1108222 BarcelonaSpain

Ferrofluid moving thin films and their possible significance with regard to active flow control for lift and attack angle enhancement are *** this strategy,a very thin film of ferrofluid is strongly attached at the wall of the wing by a normal magnetic field from below and pumped tangentially along the *** a simplified physical model and from the available experimental data on moving walls,the expected lift enhancement and effect on the attack angle were *** research and design is required in order to explore the possibilities in the use of ferrofluid moving thin films.

关键词： Active flow control Boundary layer separation Ferrofluid

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Analysis of ancient mass extinction recoveries in marine environments: generating strategies for managing outcomes of the current mass extinction

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National Science Review 2024年第1期11卷 8-10页

作者： David j.Bottjer Department of Earth Sciences University of Southern California

The defining feature of a mass extinction and its associated recovery is the global amount of extinction that occurred[1]. However, there is finer-scale detail to the story, as seen in the ongoing modern mass extinction(the sixth mass extinction), which exhibits variable effects among marine ecosystems and environments, and hence geographic areas [1].

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