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Chinese Journal of Chemistry 2020年第8期38卷 830-836页

作者： Reeta T.M.Rangarajan raj pal singh R.P.singh Manjula singh Centre for Fire Explosive and Environment SafetyDRDODelhiIndia Department of Chemistry University of DelhiDelhiIndia Department of Chemistry Sri Venkateswara CollegeUniversity of DelhiNew DelhiIndia Department of Chemistry Shivaji CollegeUniversity of DelhiNew DelhiIndia

An efficient Pd-catalyzed method for C—O cross-coupling of ketoximes and chalcone oximes with activated aryl bromides and bromo-chalcones has been *** oxime ethers were obtained in good to excellent yields by[(π-allyl)PdCl]2/tBuXPhos(L7)catalyst ***(L11)was also found to be effective for the oxime *** method offers an easy and smooth coupling of chalcone oximes with activated aryl bromides and bromo-chalcones,which has not been previously explored.

关键词： coupling coupling bromide

Plant based metabolomics:a future prospective and versatile tool for metabolite databases of Curcuma longa

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未来食品学报(英文) 2024年第1期4卷 37-47页

作者： Shuvendhu Gupta Amrat pal singh Gurpreet singh Xianting Ding Alok Sharma Department of Pharmacognosy ISF College of PharmacyMoga 142001India Department of Pharmaceutical Chemistry ISF College of PharmacyMoga 142001India School of Biomedical Engineering Med-X Research InstituteShanghai Jiao Tong UniversityShanghai 200030China

Sophisticated analytical instruments are used for quality evaluation and scientific validation to compliance the Sophisticated analytical instruments are used for quality evaluation and scientific validation to compliance the market ***,increase in demand of Curcuma longa has led to a high swing in small and medium food *** present review is devoted to an in-depth information on metabolite database of *** from different analytical techniques such as high-performance thin-layer chromatography(HPTLC),liquid chromatography-mass spectrometry,gas chromatography-mass spectrometry and nuclear magnetic *** work highlights different extraction methods,phytochemistry along with structure activity relationship,nutritional profiling,market viability and pharmacology of *** bioactives of *** depends on various factors such as plants growth,temperature,humidity,soil type,collection,drying and extraction *** factors can contribute in quality evaluation of the food supplements if need to be *** introduction of omics approaches can helpful to explore the quality and identification of potential lead of *** results could play an essential role in the area of food-phyto based ***,metabolomics techniques may provide a analytical platfom by combination of different"omics"data souces for future esearch to food sand herbal based products.

关键词： Curcuma longa Omics approaches Multidisciplinary method Quality control Metabolomics

Pipes with Trapezoidal Cut Twisted Tape Inserts in the Laminar Flow Regime:Nusselt Number and Friction Coefficient Analysis

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Fluid Dynamics & Materials Processing 2023年第2期19卷 501-511页

作者： Shrikant Arunrao Thote Netra pal singh Department of Mechanical Engineering Oriental UniversityIndore453555India

The thermal behavior of pipes with a twisted tape inside(used to enhance heat transfer through the tube wall)is studied in the laminar flow *** is used as the work fluid with the corresponding Reynolds Number spanning the interval 200–*** is found that in such conditions the‘Nusselt Number’(Nu)gradually increases with reducing the tape twist ratio,whereas the friction factor is detrimentally affected by the presence of the tape(as witnessed by the comparison with the companion case where a plain tube is considered).In particular,it is shown that the heat transfer efficiency can be improved by nearly 69%if tape inserts with a relatively low twist ratio are *** the basis of these findings,it is concluded that loose fit tape inserts are superior to tight fit tapes in terms of heat transfer and ease of replacement.

关键词： Friction factor laminar flow Nusselt Number trapezoidal-cut twisted tape

Analysis of Friction and Heat Transfer Characteristics of Tubes with Trapezoidal Cut Twisted Tape Inserts

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Fluid Dynamics & Materials Processing 2023年第3期19卷 711-722页

作者： Shrikant Arunrao Thote Netra pal singh Department of Mechanical Engineering Oriental UniversityIndore453555India

The thermo-hydraulic properties of circular tubes with a twisted tape inside(used accordingly to induce turbulence and enhance heat transfer through the tube wall)are described for Reynolds Numbers ranging from 830 to *** twisted with the three distinct twist ratios are considered,namely,6,4.4 and *** is used as the working fluid in several *** the sake of comparison,the standard tube with no insert is also *** is shown that in the presence of the twisted tape,the‘frictional factor’,‘Nusselt Number’and the‘thermal performance factor’are much higher than those obtained for the plain ***,the tapes having the lowest twist ratio,i.e.,3,are more effective than the others in terms of heat transfer ***‘thermal performance factor’is greater than one for all the twisted tapes used in the experiments,which confirms the enhanced performances of the heat exchanger and the related savings in terms of total energy.

关键词： Friction factor nusselt number performance ratio trapezoidal cut twisted tape insert

Is intraspecific trait differentiation in Parthenium hysterophorus a consequence of hereditary factors and/or phenotypic plasticity?

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植物多样性:英文版 2023年第5期45卷 611-620页

作者： Amarpreet Kaur Shalinder Kaur Harminder pal singh Daizy R.Batish Department of Botany Panjab UniversityChandigarh 160014India Department of Environment Studies Panjab UniversityChandigarh 160014India

Of the various strategies adopted by an invasive plant species for expanding its niche breadth,phenotypic differentiation(either due to plasticity and/or adaptive evolution) is proven to be the most ***,we studied the persistence of substantial morpho-functional variations within the individuals of alien invasive plant,Parthenium hysterophorus in Chandigarh,India,through field *** on observed differences,the individuals were categorized into two morphotypes,PAand *** higher leaf area,leaf biomass,and chlorophyll content as compared with ***,PBhad a higher stem circumference,stem specific density,twig dry matter content,profuse branching,bigger canopy,and better reproductive output than *** substantiate the persistence of intraspecific variations in P. hysterophorus and to deduce the possible genesis of these variations,we propagated both the morphotypes under experimental conditions in winter and *** from the key morpho-functional differences observed during the field studies,protein and carbohydrate metabolism were studied in leaves and roots of the propagated *** in plant metabolism were observed only during the early growth period,whereas the morpho-functional traits varied in the mature flowering *** effect of growth season was highly significant on all the studied morpho-functional and biochemical parameters(p ≤0.05).Parent morphotypes(P) and interactions between morphotypes and seasons significantly affected several growth parameters(p ≤0.05).The analyses revealed that the contrasting growth conditions at the time of transplantation and early growth may regulate the phenotype of P. *** pattern of intraspecific variations observed during the study is justified to consider morphotype PAas winter biotype and morphotype PBas summer biotype of P. *** study points towards the role of plasticity or a combination of genetic and environmental(G×E) factors in producing the p

关键词： Biochemical traits Carbohydrate metabolism Morpho-functional traits Phenotypic variations Protein metabolism Ragweed parthenium

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Probiotic fermentation of polyphenols: potential sources of novel functional foods

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Food Production, Processing and Nutrition 2022年第1期4卷 259-274页

作者： Rohit Sharma Bhawna Diwan Brij pal singh Saurabh Kulshrestha Faculty of Applied Sciences&Biotechnology Shoolini University of Biotechnology and Management SciencesSolan173229India Department of Microbiology Central University of HaryanaMahendragarhIndia

Fermented functional food products are among the major segments of food processing *** imparts several characteristic effects on foods including the enhancement of organoleptic characteristics,increased shelf-life,and production of novel health beneficial ***,in addition to macronutrients present in the food,secondary metabolites such as polyphenols are also emerging as suitable fermentable *** the traditional antimicrobial view of polyphenols,accumulating research shows that polyphenols exert differential effects on bacterial communities by suppressing the growth of pathogenic microbes while concomitantly promoting the proliferation and survival of probiotic ***,probiotic bacteria not only survive among polyphenols but also induce their fermentation which often leads to improved bioavailability of polyphenols,production of novel metabolic intermediates,increased polyphenolic content,and thus enhanced functional capacity of the fermented *** addition,selective fermentation of combinations of polyphenol-rich foods or fortification with polyphenols can result in novel functional *** present narrative review specifically explores the potential of polyphenols as fermentable substrates in functional *** discuss the emerging bidirectional relationship between polyphenols and probiotic bacteria with an aim at promoting the development of novel functional foods based on the amalgamation of probiotic bacteria and polyphenols.

关键词： Probiotics Polyphenols Fermented Foods Lactic acid bacteria Tea

Compatible package-based agriculture systems:an urgent need for agro-ecological balance and climate change adaptation

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Soil Ecology Letters 2022年第3期4卷 187-212页

作者： Rishikesh singh Tanu Kumari Pramit Verma Bhupinder pal singh Akhilesh singh Raghubanshi Integrative Ecology Laboratory(IEL) Institute of Environment&Sustainable Development(IESD)Banaras Hindu UniversityVaranasi 221005India NSW Department of Primary Industries Elizabeth Macarthur Agricultural InstituteMenangleNSW 2568Australia

Besides contributing majorly in the growth of a country,agriculture is one of the severely affected sectors at *** modifications and adaptations are being made in agricultural practices to cope-up with the declining soil fertility and changing climate scenarios across the ***,the development and adoption of a single agricultural practice may not help in the holistic mitigation of the impacts of climate change and may result in economic vulnerability to ***,it is high time to develop and recommend a group of agricultural practices i.e.,package-based agriculture system having some compatibility for one another in the long *** this article,a viewpoint has been given on some emergent agronomic practices adopted in the tropical agroecosystems which have potential to be developed as compatible agricultural package in ***,we also emphasized on exploring some key indicators/environmental factors to assess the compatibility of different agronomic *** identifying the research transition from single to combined agricultural practices,a bibliometric analysis was performed by using conservation agriculture(CA),the system of rice intensification(SRI),organic agriculture and soil(biochar)amendment as the major agronomic practices being used for improving agroecological services such as improving nutrient cycling,soil fertility and crop productivity as well as climate change *** results revealed that scientific communities are now paying attention to exploring the role of combined agricultural practices for agro-ecological balance and climate change ***,the limitations of the adoption of agronomic packages under different agro-climatic zones have also been *** recommendations of the study would further help the environmental decision-makers to develop potential measures for climate change mitigation without compromising the agro-ecological balance.

关键词： Agricultural policies Bibliometric analysis Biochar Conservation agriculture GHG emission Organic farming SRI Sustainable agriculture

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Interactions between lead(Ⅱ) ions and dissolved organic matter derived from organic fertilizers incubated in the field

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Journal of Environmental Sciences 2022年第11期34卷 77-89页

作者： Long Chen Boling Li Zhipeng Wu Qingjie Zhao Qiuyue Wang Hailong Wang Bhupinder pal singh Weidong Wu Chuanliang Fu College of Tropical Crops Hainan UniversityHaikou 570228China School of Environmental and Chemical Engineering Foshan UniversityFoshan 528000China Department of Primary Industries Elizabeth Macarthur Agricultural InstituteMenangleNSW 2568Australia Institute of Agricultural Environment and Soil Hainan Academy of Agricultural SciencesHaikou 571100China Key Laboratory of Arable Land Conservation of Hainan Province Haikou 571100China

This work was to study composition characteristics and the subsequent effect on the lead(Pb) binding properties of dissolved organic matter(DOM) derived from seaweed-based(SWOF) and chicken manure organic fertilizers(CMOF) during a one-year field incubation experiment using the excitation-emission matrix-parallel factor(EEM-PARAFAC) and twodimensional correlation spectroscopy(2DCOS) analysis. Results showed that high aromatic and hydrophobic fluorescent substances were enriched in CMOF-derived DOM and SWOFderived DOM and enhanced over time. And phenolic groups in the fulvic-like substances for SWOF-derived DOM and carboxyl groups in the humic-like substances for CMOF-derived DOM had the fastest responses over time, respectively. Moreover, both non-fluorescent polysaccharides and fluorescent humic-like substances or fulvic-like substances with aromatic(C=C) groups first participated in the binding process of Pb to SWOF-derived DOM on day 0 and 180 during the lead binding process. In contrast, humic-like substances associated with aromatic(C=C) and phenolic groups gave a faster response to Pb binding on day 360. Regarding CMOF-derived DOM, the fulvic-like substances associated with aromatic(C=C) and carboxylic groups displayed a faster response to Pb ions on day 0. Nonetheless,polysaccharides and humic-like associated with phenolic groups had a faster response on days 180 and 360. It is noteworthy that the polysaccharides, which participated in Pb binding to CMOF-derived DOM, posed a higher risk of Pb in the environment after 360 days. Therefore, these findings gave new insights into the long-term applications of commercial organic fertilizers for the amendment of soil.

关键词： DOM Commercial organic fertilizer Parallel factor analysis Two-dimensional correlation spectroscopy Lead(Pb)

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Systematic review with expert consensus on use of extracorporeal hemoadsorption in septic shock:An Indian perspective

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World Journal of Critical Care Medicine 2024年第1期13卷 65-75页

作者： Yatin Mehta Abdul Samad Ansari Amit Kumar Mandal Dipanjan Chatterjee Gauri Shankar Sharma Prachee Sathe Purvesh V Umraniya rajib Paul Sachin Gupta Vinod singh Yogendra pal singh Institute of Critical Care and Anesthesiology Medanta The MedicityGurgaon 122001HaryanaIndia Department of Critical Care Nanavati Max Super Specialty HospitalMumbai 400065India Department of Pulmonology Sleep and Critical CareFortis HospitalMohaliPunjabMohali 160062PunjabIndia Department of Cardio-Puimonary Critical Care Medica Superspecialty HospitalKolkata 700099India Department of Critical Care Medicine Fortis HospitalNew Delhi 110070India Department of Critical Care Medicine D.Y.Patil Medical CollegeSant Tukaram NagarPimpri ColonyPimpri-ChinchwadPune 411018India Department of Critical Care Medicine Bhailal Amin General HospitalVadodara 390003GujaratIndia Department of Internal Medicine Apollo HospitalsJubilee HillsHyderabad 500033India Department of Anaesthesiology Narayana Superspeciality HospitalGurugram 122002India Department of Critical Care Medicine Institute of Critical Care MedicineHospital Name-Sir Ganga Ram HospitalNew Delhi 110001India Department of Critical Care Medicine Max Super Speciality HospitalDelhi 110092India

BACKGROUND Septic shock is a severe form of sepsis characterised by deterioration in circulatory and cellular-metabolic *** standard therapy,the outcomes are *** adjuvant therapy,such as CytoSorb®extracorporeal haemoadsorption device,has been investigated and shown promising ***,there is a lack of some guidance to make clinical decisions on the use of CytoSorb®haemoadsorption as an adjuvant therapy in septic shock in Indian ***,this expert consensus was *** To formulate/establish specific consensus statements on the use of CytoSorb®haemoadsorption treatment based on the best available evidence and contextualised to the Indian *** We performed a comprehensive literature on CytoSorb®haemoadsorption in sepsis,septic shock in PubMed selecting papers published between January 2011 and March 20232021 in English *** statements for a consensus document were developed based on the summarised literature analysis and identification of knowledge *** a modified Delphi approach combining evidence appraisal and expert opinion,the following topics related to CytoSorb®in septic shock were addressed:need for adjuvant therapy,initiation timeline,need for Interleukin-6 levels,duration of therapy,change of adsorbers,safety,prerequisite condition,efficacy endpoints and management *** expert members from critical care,emergency medicine,and the intensive care participated and voted on nine statements and one open-ended *** Eleven expert members from critical care,emergency medicine,and the intensive care participated and voted on nine statements and one open-ended *** 11 experts in the consensus group(100%)participated in the first,second and third round of *** three iterative voting rounds and adapting two statements,consensus was achieved on nine statements out of nine *** consensus expert panel also recognised the necessity to form an associatio

关键词： Consensus CytoSorb Cytokine Hemoadsorption Refractory Sepsis Septic shock

Searching systematics for nonfactorizable contributions to B- and■ hadronic decays

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Chinese Physics C 2022年第7期 49-57页

作者： Maninder Kaur Supreet pal singh R.C.Verma Department of Physics Punjabi University

The two-body weak decays ■and■ are examined using isospin analysis to study nonfactorizable contributions. After determining strong interaction phases and obtaining factorizable contributions from spectator-quark diagrams for Nc=3, we determine nonfactorizable isospin amplitudes from the experimental data for these modes. Our results support the universality of the ratio of nonfactorizable isospin reduced amplitudes for these decays within experimental errors. To demonstrate that these systematics are not coincidental, we also plot our results w. r. t. this ratio.

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